CN111154553A - Multifunctional composite detergent and preparation method thereof - Google Patents
Multifunctional composite detergent and preparation method thereof Download PDFInfo
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- CN111154553A CN111154553A CN201911352995.7A CN201911352995A CN111154553A CN 111154553 A CN111154553 A CN 111154553A CN 201911352995 A CN201911352995 A CN 201911352995A CN 111154553 A CN111154553 A CN 111154553A
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- sodium
- berberine
- triethylamine
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a multifunctional composite detergent and a preparation method thereof, wherein the multifunctional composite detergent is prepared from the following raw materials in percentage by weight: 20-30% of sodium fatty alcohol-polyoxyethylene ether sulfate, 4-7% of sodium carbonate, 4-7% of sodium silicate, 2-3% of oregano oil, 2-4% of berberine, 0.5-1.0% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and the balance of water, wherein the pH is adjusted to 5-8 by sodium monohydrogen citrate and citric acid. According to the invention, fatty alcohol-polyoxyethylene ether is used as an anionic surfactant, and sodium carbonate and sodium silicate are used as washing aids, so that the compounded combination has good descaling and decontamination effects, and is phosphorus-free and environment-friendly; in addition, the origanum oil and the berberine which are plant sources are adopted, so that the bacteriostatic effect on escherichia coli and staphylococcus aureus is good.
Description
Technical Field
The invention belongs to the technical field of daily chemical articles, and particularly relates to a multifunctional composite detergent and a preparation method thereof.
Background
With the improvement of living standard, the detergent is widely accepted as a necessary product for life. The detergent is a product with detergency and detergency prepared according to a formula, and is prepared by using one or several surfactants as main components and adding various inorganic and organic assistants to improve and improve detergency and detergency. The detergent has irritation effect on human mucosa and skin, and can cause contact dermatitis; after being discharged into the water body, the fish bait consumes dissolved oxygen, has slight toxicity to aquatic organisms and can cause fish deformity. For example, nonionic surfactants have an anesthetic effect on fish, and reduce the ability of taste buds and other sensory organs to lose their ability to avoid avoidance. The detergent sewage has a large amount of foam, which brings difficulty to the operation of a water treatment plant. The content of the detergent reaches a certain concentration, which can have adverse effect on the fermentation process in the biological treatment of the wastewater.
In spite of the development of detergents and the demands of the market, the liquidization of detergents is rapidly developed, products tend to be subdivided and diversified, and the consciousness of people on health and environmental protection is gradually improved. In addition, the domestic detergent has a single effect, and not only a few multifunctional products with washing and sterilizing effects are available, but also the effect is not good.
Disclosure of Invention
In order to solve the problems, the invention provides a multifunctional composite detergent and a preparation method thereof. The product has strong detergency, is mild, does not hurt skin, and is free from phosphorus and chlorine.
The technical scheme adopted by the invention is as follows:
a multifunctional composite detergent is prepared from the following raw materials in percentage by weight:
20-30% of sodium fatty alcohol-polyoxyethylene ether sulfate, 4-7% of sodium carbonate, 4-7% of sodium silicate, 2-3% of oregano oil, 2-4% of berberine, 0.5-1.0% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and the balance of water, wherein the pH is adjusted to 5-8 by sodium monohydrogen citrate and citric acid.
Preferably, the pH value of the product is adjusted to 8 by using sodium alcohol ether sulphate 20%, sodium carbonate 5%, sodium silicate 5%, oregano oil 2%, berberine 3%, stabilizer hydroxyethylidene diphosphonic acid and triethylamine 0.5% in total, and the balance of water, and sodium monohydrogen citrate and citric acid.
Preferably, the pH value of the product is adjusted to 8 by 25 percent of sodium alcohol ether sulfate, 6 percent of sodium carbonate, 6 percent of sodium silicate, 3 percent of origanum oil, 4 percent of berberine, 0.8 percent of stabilizer hydroxyethylidene diphosphonic acid and triethylamine and the balance of water, and sodium monohydrogen citrate and citric acid are additionally used.
Preferably, the pH value of the product is adjusted to 8 by using 30% of sodium alcohol ether sulfate, 7% of sodium carbonate, 7% of sodium silicate, 3% of oregano oil, 4% of berberine, 1.0% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine and the balance of water, and additionally using sodium monohydrogen citrate and citric acid.
The preparation method of any one of the multifunctional composite detergents comprises the following steps:
1) adding fatty alcohol-polyoxyethylene ether sodium sulfate into a clean reaction kettle A, and uniformly stirring;
2) adding sodium carbonate and sodium silicate into a clean reaction kettle B, and uniformly stirring;
3) adding the mixture obtained in the step (1) into a reaction kettle B, and uniformly stirring;
4) keeping the temperature in the reaction kettle at 30 ℃, then adding oregano oil, berberine, stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and continuing stirring for 10 minutes;
5) the temperature in the reaction kettle is kept at 30 ℃, and the pH is adjusted by sodium monohydrogen citrate and citric acid;
6) sampling and detecting, and discharging after the product is qualified.
The fatty alcohol-polyoxyethylene ether is also called polyoxyethylene fatty alcohol ether. The variety which develops the fastest speed and has the largest dosage in the nonionic surfactant. From the aspect of washing efficacy, the detergent has excellent decontamination, emulsification and foaming performances, and more importantly, has hard water resistance. In addition, the detergent can be compounded with other various surfactants for use, so that the detergency is improved. From the aspect of safety and environmental protection, the surfactant is mild in property, does not damage skin, has 99 percent of biodegradation degree, and is an environment-friendly surfactant.
The sodium carbonate in the invention is commonly called soda ash. The anhydrous sodium carbonate is white granular, and is hard after moisture absorption. The sodium carbonate in the formula of the detergent can remove hard ions in water, convert calcium and magnesium ions in the water into calcium carbonate and magnesium carbonate, and precipitate the calcium carbonate and magnesium carbonate out of the solution, so that the water quality is softened; meanwhile, the detergent can make the washing liquid have certain alkalinity, so that the active matters in the detergent have higher detergency and cannot lose efficacy due to acid dirt. In addition, it can be saponified with animal and vegetable oil in oily dirt to increase detergency.
The sodium silicate of the invention can keep the pH value of the solution almost unchanged, thereby having a buffering effect. Most of the dirt is acidic, and the cleaning solution keeps alkaline, which is beneficial to decontamination. Several commonly used alkaline salts maintain a relatively stable pH when titrated with a standard acid, just before the water glass is nearly completely consumed. The sodium silicate produces silicic acid with a micelle structure due to hydrolysis, and the solvated micelle has the suspending and dispersing capacity for dirt particles and has an emulsifying effect on oil stains, so that the redeposition of the dirt is favorably prevented. Sodium silicate also has the effect of enhancing the foamability of the detergent and stabilizing the foam.
The origanum oil is volatile oil obtained by extracting Chinese herbal medicine origanum, and the main antibacterial component is carvacrol. Yellowish oily liquid, aromatic, safe, non-toxic, high-efficiency, sterilizing and no incompatibility.
The berberine in the invention is mainly present in plants such as coptis chinensis, phellodendron and the like. Yellow powdery solid, light Chinese herbal medicine taste, is dissolved in water, and has broad-spectrum antibacterial property.
The invention adopts sodium hydrogen citrate as a metal ion chelating agent and forms a pH buffer pair with citric acid to adjust the pH value of the detergent. The citric acid sodium monohydrogen has super strong dissolubility and excellent chelation performance on calcium and magnesium ions, and has high stability under high light. Citric acids are absolutely safe and non-toxic detergent builders. Sodium monohydrogen citrate is a weak acid strong base salt, which can form a pH buffer pair with citric acid to keep the pH of the detergent system in a relatively stable range.
The key point of the invention is that fatty alcohol-polyoxyethylene ether is used as an anionic surfactant, and sodium carbonate and sodium silicate are used as washing aids, so that the compounded combination has good descaling and decontamination effects, and is phosphorus-free and environment-friendly; in addition, the origanum oil and the berberine which are plant sources are adopted, so that the bacteriostatic effect on escherichia coli and staphylococcus aureus is good.
Detailed Description
The invention is further illustrated by the following examples, without restricting the invention thereto. All changes, modifications and equivalents that do not depart from the spirit of the invention are intended to be included within the scope thereof.
Example 1
The material is prepared from the following raw materials in percentage by weight: 20% of sodium fatty alcohol-polyoxyethylene ether sulfate, 5% of sodium carbonate, 5% of sodium silicate, 2% of origanum oil, 3% of berberine, 0.5% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and the balance of water, and in addition, the pH is adjusted to 8 by sodium monohydrogen citrate and citric acid.
Example 2
The material is prepared from the following raw materials in percentage by weight: 23% of sodium fatty alcohol-polyoxyethylene ether sulfate, 4% of sodium carbonate, 7% of sodium silicate, 3% of origanum oil, 4% of berberine, 1.0% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine and the balance of water, and in addition, the pH is adjusted to 8 by sodium monohydrogen citrate and citric acid.
Example 3
The material is prepared from the following raw materials in percentage by weight: 25% of sodium alcohol ether sulphate, 6% of sodium carbonate, 6% of sodium silicate, 3% of origanum oil, 4% of berberine, 0.8% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and the balance of water, and in addition, the PH is adjusted to 8 by sodium monohydrogen citrate and citric acid.
Example 4
The material is prepared from the following raw materials in percentage by weight: 27% of sodium fatty alcohol-polyoxyethylene ether sulfate, 7% of sodium carbonate, 4% of sodium silicate, 3% of origanum oil, 2% of berberine, 0.8% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and the balance of water, and in addition, the PH is adjusted to 8 by sodium monohydrogen citrate and citric acid.
Example 5
The material is prepared from the following raw materials in percentage by weight: 30% of sodium alcohol ether sulphate, 7% of sodium carbonate, 7% of sodium silicate, 3% of origanum oil, 4% of berberine, 1.0% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and the balance of water, and in addition, the PH is adjusted to 8 by sodium monohydrogen citrate and citric acid.
Example 6
The material is prepared from the following raw materials in percentage by weight: 30% of sodium alcohol ether sulphate, 7% of sodium carbonate, 7% of sodium silicate, 3% of origanum oil, 4% of berberine, 1.0% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and the balance of water, and in addition, the pH is adjusted to 5 by sodium monohydrogen citrate and citric acid.
Example 7
The material is prepared from the following raw materials in percentage by weight: 30% of sodium alcohol ether sulphate, 7% of sodium carbonate, 7% of sodium silicate, 3% of origanum oil, 4% of berberine, 1.0% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and the balance of water, and in addition, the pH is adjusted to 7 by sodium monohydrogen citrate and citric acid.
Comparative example 1
The material is prepared from the following raw materials in percentage by weight: 30% of sodium fatty alcohol-polyoxyethylene ether sulfate, 7% of sodium carbonate, 7% of sodium silicate, 3% of oregano oil, 1.0% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine and the balance of water, and the pH is adjusted to 8 by sodium monohydrogen citrate and citric acid.
Comparative example 2
The material is prepared from the following raw materials in percentage by weight: 30% of sodium alcohol ether sulphate, 7% of sodium carbonate, 7% of sodium silicate, 4% of berberine, 1.0% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and the balance of water, and in addition, the PH value is adjusted to 8 by sodium monohydrogen citrate and citric acid.
Comparative example 3
The material is prepared from the following raw materials in percentage by weight: 30% of sodium fatty alcohol-polyoxyethylene ether sulfate, 7% of sodium carbonate, 7% of sodium silicate, 1.0% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and the balance of water, wherein the pH value is adjusted to 8 by sodium monohydrogen citrate and citric acid.
Example 8 stability assay
According to the technical requirements of national standard DB 9985-; and (3) placing the mixture in a constant temperature oven at 40 ℃ for 24h, taking out the mixture and immediately observing the mixture, wherein no layering and turbidity is generated, the smell is normal, and the stability is judged to be qualified.
Example 9 foam determination
The main factors influencing the amount of the foam are the concentration of the surfactant and the dosage of the washing assistant, the foam is too much and is difficult to rinse clean, and the foam is too little and has insufficient washing effect. 1mL of the samples of examples 1 to 7 and comparative examples 1 to 3 was sampled by a static defoaming method, and 20mL of 5% washing solution prepared by adding water was added to a 100mL measuring cylinder with a plug, and the mixture was uniformly shaken up and down 20 times to measure the foam height of each example, and the test was also performed after 5min and 10 min. The results show that the more the surfactant sodium fatty alcohol polyoxyethylene ether sulfate is, the better the foamability is.
Example 10 detergency determination
The food plate stained with food residue, animal oil and sugar is placed in washing liquid prepared from cold water and hot water, soaked for 5min, and washed with clear water. The results are shown in table 1 below.
TABLE 1 detergency determination
The examples all showed good detergency, and example 6 may show slightly poor cleaning performance in cold water due to weak acidity of PH.
EXAMPLE 11 bacteriostatic assay
The concentrations of example 5, comparative example 1, comparative example 2 and comparative example 3 were dilutedPreparing 20 times of sample to be detected, and taking 1mL colony number as 10 orders of magnitude5cfu/mL of the bacterial suspension was spread on the surface of a plate containing LB medium, and 0.1mL of the sample to be tested was dropped on the middle of the plate, and the plate was covered and inverted over 37 ℃ for overnight culture. The diameter of the antibacterial ring was measured. The larger the diameter, the stronger the bacteriostatic effect.
TABLE 2 comparison of the bacteriostatic effects on E.coli and S.aureus
As can be seen from the table above, the oregano oil and the berberine can play a role in inhibiting escherichia coli and staphylococcus aureus independently, but the oregano oil and the berberine are matched for use, so that the effect is better.
Claims (5)
1. A multifunctional composite detergent is characterized in that: the material is prepared from the following raw materials in percentage by weight:
20-30% of sodium fatty alcohol-polyoxyethylene ether sulfate, 4-7% of sodium carbonate, 4-7% of sodium silicate, 2-3% of oregano oil, 2-4% of berberine, 0.5-1.0% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and the balance of water, wherein the pH is adjusted to 5-8 by sodium monohydrogen citrate and citric acid.
2. The multifunctional composite detergent according to claim 1, characterized in that: the material is prepared from the following raw materials in percentage by weight:
20% of sodium fatty alcohol-polyoxyethylene ether sulfate, 5% of sodium carbonate, 5% of sodium silicate, 2% of origanum oil, 3% of berberine, 0.5% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and the balance of water, and in addition, the pH is adjusted to 8 by sodium monohydrogen citrate and citric acid.
3. The multifunctional composite detergent according to claim 1, characterized in that: the material is prepared from the following raw materials in percentage by weight:
25% of sodium alcohol ether sulphate, 6% of sodium carbonate, 6% of sodium silicate, 3% of origanum oil, 4% of berberine, 0.8% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and the balance of water, and in addition, the PH is adjusted to 8 by sodium monohydrogen citrate and citric acid.
4. The multifunctional composite detergent according to claim 1, characterized in that: the material is prepared from the following raw materials in percentage by weight:
30% of sodium alcohol ether sulphate, 7% of sodium carbonate, 7% of sodium silicate, 3% of origanum oil, 4% of berberine, 1.0% of stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and the balance of water, and in addition, the PH is adjusted to 8 by sodium monohydrogen citrate and citric acid.
5. A method for preparing the multifunctional composite detergent as claimed in any one of claims 1 to 5, which is characterized in that: the method comprises the following steps:
1) adding fatty alcohol-polyoxyethylene ether sodium sulfate into a clean reaction kettle A, and uniformly stirring;
2) adding sodium carbonate and sodium silicate into a clean reaction kettle B, and uniformly stirring;
3) adding the mixture obtained in the step (1) into a reaction kettle B, and uniformly stirring;
4) keeping the temperature in the reaction kettle at 30 ℃, then adding oregano oil, berberine, stabilizer hydroxyethylidene diphosphonic acid and triethylamine, and continuing stirring for 10 minutes;
5) the temperature in the reaction kettle is kept at 30 ℃, and the pH is adjusted by sodium monohydrogen citrate and citric acid;
6) sampling and detecting, and discharging after the product is qualified.
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| CN201911352995.7A CN111154553A (en) | 2019-12-25 | 2019-12-25 | Multifunctional composite detergent and preparation method thereof |
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| CN201911352995.7A CN111154553A (en) | 2019-12-25 | 2019-12-25 | Multifunctional composite detergent and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1222933A (en) * | 1996-05-03 | 1999-07-14 | 普罗格特-甘布尔公司 | Cleaning compositions |
| CN1244891A (en) * | 1996-11-13 | 2000-02-16 | 普罗格特-甘布尔公司 | Aqueous alkaline peroxygen bleach-containing compositions |
| CN105907483A (en) * | 2016-05-08 | 2016-08-31 | 杭州氧泡泡生物科技有限公司 | Oxygen-containing multifunctional detergent composition |
| CN109957467A (en) * | 2017-12-25 | 2019-07-02 | 浙江神英科技有限公司 | A kind of Bactericidal underwear liquid detergent |
-
2019
- 2019-12-25 CN CN201911352995.7A patent/CN111154553A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1222933A (en) * | 1996-05-03 | 1999-07-14 | 普罗格特-甘布尔公司 | Cleaning compositions |
| CN1244891A (en) * | 1996-11-13 | 2000-02-16 | 普罗格特-甘布尔公司 | Aqueous alkaline peroxygen bleach-containing compositions |
| CN105907483A (en) * | 2016-05-08 | 2016-08-31 | 杭州氧泡泡生物科技有限公司 | Oxygen-containing multifunctional detergent composition |
| CN109957467A (en) * | 2017-12-25 | 2019-07-02 | 浙江神英科技有限公司 | A kind of Bactericidal underwear liquid detergent |
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