CN110157553A - A kind of high-strength hard water adaptive type washes the dishes salt and preparation method thereof - Google Patents
A kind of high-strength hard water adaptive type washes the dishes salt and preparation method thereof Download PDFInfo
- Publication number
- CN110157553A CN110157553A CN201910497247.1A CN201910497247A CN110157553A CN 110157553 A CN110157553 A CN 110157553A CN 201910497247 A CN201910497247 A CN 201910497247A CN 110157553 A CN110157553 A CN 110157553A
- Authority
- CN
- China
- Prior art keywords
- parts
- salt
- hard water
- dishes
- washes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000008233 hard water Substances 0.000 title claims abstract description 120
- 150000003839 salts Chemical class 0.000 title claims abstract description 115
- 230000003044 adaptive effect Effects 0.000 title claims abstract description 85
- 238000002360 preparation method Methods 0.000 title claims abstract description 67
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 171
- 239000000284 extract Substances 0.000 claims abstract description 115
- 235000009024 Ceanothus sanguineus Nutrition 0.000 claims abstract description 108
- 240000003553 Leptospermum scoparium Species 0.000 claims abstract description 108
- 235000015459 Lycium barbarum Nutrition 0.000 claims abstract description 108
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 85
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 85
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 81
- 239000011780 sodium chloride Substances 0.000 claims abstract description 54
- 239000000203 mixture Substances 0.000 claims abstract description 27
- 239000002270 dispersing agent Substances 0.000 claims abstract description 15
- 239000003381 stabilizer Substances 0.000 claims abstract description 9
- 235000002639 sodium chloride Nutrition 0.000 claims description 164
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 43
- 239000000047 product Substances 0.000 claims description 37
- 238000001035 drying Methods 0.000 claims description 31
- 239000007788 liquid Substances 0.000 claims description 21
- -1 K-IAO Chemical compound 0.000 claims description 18
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 15
- 239000011734 sodium Substances 0.000 claims description 15
- 229910052708 sodium Inorganic materials 0.000 claims description 15
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 14
- 235000015424 sodium Nutrition 0.000 claims description 14
- 241001122767 Theaceae Species 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 13
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 claims description 12
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 claims description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 11
- 150000002148 esters Chemical class 0.000 claims description 11
- 239000003513 alkali Substances 0.000 claims description 10
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 6
- 235000015165 citric acid Nutrition 0.000 claims description 6
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 5
- 239000002585 base Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 239000005457 ice water Substances 0.000 claims description 5
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 4
- 229920001817 Agar Polymers 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 4
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 239000005864 Sulphur Substances 0.000 claims description 4
- 239000008272 agar Substances 0.000 claims description 4
- 235000010419 agar Nutrition 0.000 claims description 4
- 229920000615 alginic acid Polymers 0.000 claims description 4
- 235000010443 alginic acid Nutrition 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- 239000000706 filtrate Substances 0.000 claims description 4
- QEWYKACRFQMRMB-UHFFFAOYSA-N fluoroacetic acid Chemical compound OC(=O)CF QEWYKACRFQMRMB-UHFFFAOYSA-N 0.000 claims description 4
- 239000008141 laxative Substances 0.000 claims description 4
- 230000002475 laxative effect Effects 0.000 claims description 4
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 4
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical group OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 235000012207 sodium gluconate Nutrition 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 150000004676 glycans Chemical class 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 229920001282 polysaccharide Polymers 0.000 claims description 3
- 239000005017 polysaccharide Substances 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 239000000176 sodium gluconate Substances 0.000 claims description 3
- 229940005574 sodium gluconate Drugs 0.000 claims description 3
- 241000894007 species Species 0.000 claims description 3
- GYBINGQBXROMRS-UHFFFAOYSA-J tetrasodium;2-(1,2-dicarboxylatoethylamino)butanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC(C([O-])=O)NC(C([O-])=O)CC([O-])=O GYBINGQBXROMRS-UHFFFAOYSA-J 0.000 claims description 3
- UOFGSWVZMUXXIY-UHFFFAOYSA-N 1,5-Diphenyl-3-thiocarbazone Chemical compound C=1C=CC=CC=1N=NC(=S)NNC1=CC=CC=C1 UOFGSWVZMUXXIY-UHFFFAOYSA-N 0.000 claims description 2
- 244000215068 Acacia senegal Species 0.000 claims description 2
- VVGNRIZWGFQMQW-UHFFFAOYSA-N C(CC)C(C(=O)O)C(=O)O.FCC(=O)O Chemical compound C(CC)C(C(=O)O)C(=O)O.FCC(=O)O VVGNRIZWGFQMQW-UHFFFAOYSA-N 0.000 claims description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 2
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 229920000084 Gum arabic Polymers 0.000 claims description 2
- FSVCELGFZIQNCK-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)glycine Chemical compound OCCN(CCO)CC(O)=O FSVCELGFZIQNCK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 239000000205 acacia gum Substances 0.000 claims description 2
- 235000010489 acacia gum Nutrition 0.000 claims description 2
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 239000007998 bicine buffer Substances 0.000 claims description 2
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 claims description 2
- 239000001639 calcium acetate Substances 0.000 claims description 2
- 235000011092 calcium acetate Nutrition 0.000 claims description 2
- 229960005147 calcium acetate Drugs 0.000 claims description 2
- 239000004227 calcium gluconate Substances 0.000 claims description 2
- 235000013927 calcium gluconate Nutrition 0.000 claims description 2
- 229960004494 calcium gluconate Drugs 0.000 claims description 2
- NEEHYRZPVYRGPP-UHFFFAOYSA-L calcium;2,3,4,5,6-pentahydroxyhexanoate Chemical compound [Ca+2].OCC(O)C(O)C(O)C(O)C([O-])=O.OCC(O)C(O)C(O)C(O)C([O-])=O NEEHYRZPVYRGPP-UHFFFAOYSA-L 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 150000003983 crown ethers Chemical class 0.000 claims description 2
- SZDRZMKKMAXBHS-UHFFFAOYSA-L disodium 2-(1,2-dicarboxyethylamino)butanedioate Chemical compound N(C(C(=O)O)CC(=O)O)C(C(=O)[O-])CC(=O)[O-].[Na+].[Na+] SZDRZMKKMAXBHS-UHFFFAOYSA-L 0.000 claims description 2
- 229940124274 edetate disodium Drugs 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 239000000174 gluconic acid Substances 0.000 claims description 2
- 235000012208 gluconic acid Nutrition 0.000 claims description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 claims description 2
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 238000006386 neutralization reaction Methods 0.000 claims description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 2
- 229960003424 phenylacetic acid Drugs 0.000 claims description 2
- 239000003279 phenylacetic acid Substances 0.000 claims description 2
- YRWWOAFMPXPHEJ-OFBPEYICSA-K sodium L-ascorbic acid 2-phosphate Chemical compound [Na+].[Na+].[Na+].OC[C@H](O)[C@H]1OC(=O)C(OP([O-])([O-])=O)=C1[O-] YRWWOAFMPXPHEJ-OFBPEYICSA-K 0.000 claims description 2
- 229940048058 sodium ascorbyl phosphate Drugs 0.000 claims description 2
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 150000000000 tetracarboxylic acids Chemical class 0.000 claims description 2
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 claims 1
- 241000195493 Cryptophyta Species 0.000 claims 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims 1
- 102000002322 Egg Proteins Human genes 0.000 claims 1
- 108010000912 Egg Proteins Proteins 0.000 claims 1
- 239000004348 Glyceryl diacetate Substances 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 claims 1
- 229920001429 chelating resin Polymers 0.000 claims 1
- 235000014103 egg white Nutrition 0.000 claims 1
- 210000000969 egg white Anatomy 0.000 claims 1
- 235000019443 glyceryl diacetate Nutrition 0.000 claims 1
- 239000001814 pectin Substances 0.000 claims 1
- 235000010987 pectin Nutrition 0.000 claims 1
- 229920001277 pectin Polymers 0.000 claims 1
- 229920000768 polyamine Chemical class 0.000 claims 1
- 150000004033 porphyrin derivatives Chemical class 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 239000000344 soap Substances 0.000 claims 1
- 239000001488 sodium phosphate Substances 0.000 claims 1
- 229910000162 sodium phosphate Inorganic materials 0.000 claims 1
- 229940095064 tartrate Drugs 0.000 claims 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims 1
- 239000000230 xanthan gum Substances 0.000 claims 1
- 235000010493 xanthan gum Nutrition 0.000 claims 1
- 229940082509 xanthan gum Drugs 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 20
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 8
- 238000004140 cleaning Methods 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 5
- 230000003389 potentiating effect Effects 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 230000009471 action Effects 0.000 description 24
- 238000004851 dishwashing Methods 0.000 description 22
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical class [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 20
- 238000010907 mechanical stirring Methods 0.000 description 20
- 235000017557 sodium bicarbonate Nutrition 0.000 description 20
- 239000003599 detergent Substances 0.000 description 18
- 230000000694 effects Effects 0.000 description 18
- 239000001509 sodium citrate Substances 0.000 description 17
- 235000011083 sodium citrates Nutrition 0.000 description 17
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 16
- 229930182490 saponin Natural products 0.000 description 16
- 150000007949 saponins Chemical class 0.000 description 16
- 238000012360 testing method Methods 0.000 description 16
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical class [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 15
- 230000001954 sterilising effect Effects 0.000 description 15
- 238000000034 method Methods 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 235000019441 ethanol Nutrition 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 235000018102 proteins Nutrition 0.000 description 7
- 108090000623 proteins and genes Proteins 0.000 description 7
- 102000004169 proteins and genes Human genes 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229960005069 calcium Drugs 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- RRKTZKIUPZVBMF-IBTVXLQLSA-N brucine Chemical compound O([C@@H]1[C@H]([C@H]2C3)[C@@H]4N(C(C1)=O)C=1C=C(C(=CC=11)OC)OC)CC=C2CN2[C@@H]3[C@]41CC2 RRKTZKIUPZVBMF-IBTVXLQLSA-N 0.000 description 4
- RRKTZKIUPZVBMF-UHFFFAOYSA-N brucine Natural products C1=2C=C(OC)C(OC)=CC=2N(C(C2)=O)C3C(C4C5)C2OCC=C4CN2C5C31CC2 RRKTZKIUPZVBMF-UHFFFAOYSA-N 0.000 description 4
- 238000005202 decontamination Methods 0.000 description 4
- 230000003588 decontaminative effect Effects 0.000 description 4
- 238000002386 leaching Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 230000001376 precipitating effect Effects 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 4
- 244000182633 Cinchona succirubra Species 0.000 description 3
- 235000006768 Cinchona succirubra Nutrition 0.000 description 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229940009662 edetate Drugs 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 229910001425 magnesium ion Inorganic materials 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KWGRBVOPPLSCSI-WPRPVWTQSA-N (-)-ephedrine Chemical compound CN[C@@H](C)[C@H](O)C1=CC=CC=C1 KWGRBVOPPLSCSI-WPRPVWTQSA-N 0.000 description 2
- WITLAWYGGVAFLU-UHFFFAOYSA-N 3-(6-methoxy-1,3-benzodioxol-5-yl)-8,8-dimethylpyrano[2,3-f]chromen-4-one Chemical compound C1=CC(C)(C)OC2=CC=C(C(C(C3=CC=4OCOC=4C=C3OC)=CO3)=O)C3=C21 WITLAWYGGVAFLU-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- WNGSUWLDMZFYNZ-UHFFFAOYSA-N Leonurine Chemical compound COC1=CC(C(=O)OCCCCN=C(N)N)=CC(OC)=C1O WNGSUWLDMZFYNZ-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 description 2
- 240000006365 Vitis vinifera Species 0.000 description 2
- 235000014787 Vitis vinifera Nutrition 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 230000000840 anti-viral effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- IDAGXRIGDWCIET-SDFKWCIISA-L disodium;(2s,3s,4s,5r)-2,3,4,5-tetrahydroxyhexanedioate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O IDAGXRIGDWCIET-SDFKWCIISA-L 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- VZOPRCCTKLAGPN-UHFFFAOYSA-L potassium;sodium;2,3-dihydroxybutanedioate;tetrahydrate Chemical class O.O.O.O.[Na+].[K+].[O-]C(=O)C(O)C(O)C([O-])=O VZOPRCCTKLAGPN-UHFFFAOYSA-L 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 2
- 239000001433 sodium tartrate Substances 0.000 description 2
- 229960002167 sodium tartrate Drugs 0.000 description 2
- 235000011004 sodium tartrates Nutrition 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 235000008939 whole milk Nutrition 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- WZRCQWQRFZITDX-UHFFFAOYSA-N (RS)-norcoclaurine Chemical compound C1=CC(O)=CC=C1CC1C2=CC(O)=C(O)C=C2CCN1 WZRCQWQRFZITDX-UHFFFAOYSA-N 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical class CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- XVPBINOPNYFXID-JARXUMMXSA-N 85u4c366qs Chemical compound C([C@@H]1CCC[N@+]2(CCC[C@H]3[C@@H]21)[O-])N1[C@@H]3CCCC1=O XVPBINOPNYFXID-JARXUMMXSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- CMVHOLZLFLESKY-UHFFFAOYSA-N Anisodine Natural products CN1C2CC(CC1C3OC23)C(=O)OC(O)(CO)c4ccccc4 CMVHOLZLFLESKY-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 240000001548 Camellia japonica Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 241000165940 Houjia Species 0.000 description 1
- 241000372132 Hydrometridae Species 0.000 description 1
- ZSBXGIUJOOQZMP-UHFFFAOYSA-N Isomatrine Natural products C1CCC2CN3C(=O)CCCC3C3C2N1CCC3 ZSBXGIUJOOQZMP-UHFFFAOYSA-N 0.000 description 1
- YXVXMURDCBMPRH-UHFFFAOYSA-N Lirinidine Natural products C1C2=CC=CC=C2C2=C(O)C(OC)=CC3=C2C1N(C)CC3 YXVXMURDCBMPRH-UHFFFAOYSA-N 0.000 description 1
- ZSBXGIUJOOQZMP-JLNYLFASSA-N Matrine Chemical compound C1CC[C@H]2CN3C(=O)CCC[C@@H]3[C@@H]3[C@H]2N1CCC3 ZSBXGIUJOOQZMP-JLNYLFASSA-N 0.000 description 1
- WZRCQWQRFZITDX-AWEZNQCLSA-N Norcoclaurine Natural products C1=CC(O)=CC=C1C[C@H]1C2=CC(O)=C(O)C=C2CCN1 WZRCQWQRFZITDX-AWEZNQCLSA-N 0.000 description 1
- ORJVQPIHKOARKV-UHFFFAOYSA-N Nuciferine Natural products C1C2=CC=CC=C2C2=C(OC)C(OC)=CC3=C2C1N(C)CC3 ORJVQPIHKOARKV-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000008431 aliphatic amides Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- JEJREKXHLFEVHN-QDXGGTILSA-N anisodine Chemical compound C1([C@](O)(CO)C(=O)OC2C[C@@H]3N([C@H](C2)[C@@H]2[C@H]3O2)C)=CC=CC=C1 JEJREKXHLFEVHN-QDXGGTILSA-N 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- VSJKWCGYPAHWDS-FQEVSTJZSA-N camptothecin Chemical compound C1=CC=C2C=C(CN3C4=CC5=C(C3=O)COC(=O)[C@]5(O)CC)C4=NC2=C1 VSJKWCGYPAHWDS-FQEVSTJZSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 235000018597 common camellia Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- KWGRBVOPPLSCSI-UHFFFAOYSA-N d-ephedrine Natural products CNC(C)C(O)C1=CC=CC=C1 KWGRBVOPPLSCSI-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 229960002179 ephedrine Drugs 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- OUDSFQBUEBFSPS-UHFFFAOYSA-N ethylenediaminetriacetic acid Chemical compound OC(=O)CNCCN(CC(O)=O)CC(O)=O OUDSFQBUEBFSPS-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229930014456 matrine Natural products 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 238000000874 microwave-assisted extraction Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- ORJVQPIHKOARKV-OAHLLOKOSA-N nuciferine Chemical compound C1C2=CC=CC=C2C2=C(OC)C(OC)=CC3=C2[C@@H]1N(C)CC3 ORJVQPIHKOARKV-OAHLLOKOSA-N 0.000 description 1
- 239000006916 nutrient agar Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229930015582 oxymatrine Natural products 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000007785 strong electrolyte Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 238000000194 supercritical-fluid extraction Methods 0.000 description 1
- 150000003892 tartrate salts Chemical class 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- AEQDJSLRWYMAQI-KRWDZBQOSA-N tetrahydropalmatine Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3C[C@H]2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-KRWDZBQOSA-N 0.000 description 1
- 238000002137 ultrasound extraction Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention belongs to daily cleaning product technical field, in particular to a kind of high-strength hard water adaptive type washes the dishes salt and preparation method thereof.The parts by weight composition of the salt that washes the dishes is as follows: 1-20 parts of tea tree extract sodium sulphate, 10-90 parts of sodium chloride, 5-90 parts of builder, hard water resistance dose 1-90 parts, 0-5 parts of stabilizer, 0-40 parts of dispersing agent.High-strength hard water adaptive type of the present invention wash the dishes salt with strong detergency, after washing tableware residual is low；The advantages that potent antibacterial, stability are good, the fast defoaming of blistering is rapid, easily biological-degradable, environmental protection and public nuisance free, is easy to be acceptable to the market and promote.
Description
Technical field
The invention belongs to daily cleaning product technical field, in particular to a kind of high-strength hard water adaptive type washes the dishes salt and its preparation
Method.
Background technique
With the rapid development of society, scientific and technical with rapid changepl. never-ending changes and improvements, the continuous improvement of living standard, fast pace life are urgent
Make the raising of working efficiency.Dish-washing machine gradually comes into thousand ten thousand as product of the time, the public places such as the hotel Yi Cong, dining room
Family.However, often eat in public places it is found that can also remain oil stain on tableware, therefore, the washing of dish-washing machine
Effect becomes the important barrier that dish-washing machine moves towards daily life.Furthermore dish-washing machine is often in wet environment, it is easy to nourish thin
How bacterium realizes the problem of comparing concern to dish-washing machine progress sterilization processing and consumer while washing the dishes.
Surfactant is the important component in cleaning product, has fixed hydrophilic lipophilic group, hydrophobic group
Dirt " is caught " in cleaning solution；Hydrophilic radical is separated dirt by emulsification and wetting action with water flow from cleaning materials
Out, to achieve the effect that washing is clean.But general surfactant is more sensitive to hard water at present, calcium in hard water,
Magnesium ion produces metal salt in conjunction with the surfactant in cleaning product, and being deposited on the wall of washing implement influences clearly
Effect is washed, and surfactant is made to lose vigor, reduces the major function of detergent.In addition, the calcium and magnesium ion in hard water is held
The fouling in the inside of dish-washing machine and pipeline easily in washing process, reduces the service life of dish-washing machine, while increasing dish-washing machine
Maintenance cost.Therefore, it develops a kind of high-strength hard water adaptive type with stain removal bactericidal ability and washes the dishes salt with realistic meaning, it will
The market of dish-washing machine can greatly be expanded.
Summary of the invention
Present invention aim to address current dish-washing machine, existing washing decontamination is not thorough, in dish-washing machine in use
The problems such as portion easily breeds bacterium, resistance to hard water is poor and a kind of high-strength hard water adaptive type suitable for various dish-washing machines is provided and is washed the dishes
Salt and preparation method thereof.
In order to solve the above technical problems, The technical solution adopted by the invention is as follows:
A kind of high-strength hard water adaptive type washes the dishes salt, and the parts by weight composition of the salt that washes the dishes is as follows:
1-20 parts of tea tree extract sodium sulphate, 10-90 parts of sodium chloride, 5-90 parts of builder, hard water resistance dose 1-90 parts, stablize
0-5 parts of agent, 0-40 parts of dispersing agent.
The high-strength hard water adaptive type salt that washes the dishes can be powder, bulk or liquid.
The high-strength hard water adaptive type wash the dishes salt be it is powdered when, the salt that washes the dishes parts by weight composition it is as follows:
2-20 parts of tea tree extract sodium sulphate, 20-70 parts of sodium chloride, 10-40 parts of builder, hard water resistance dose 20-50 parts.
The high-strength hard water adaptive type washes the dishes salt when being blocky, and the parts by weight composition of the salt that washes the dishes is as follows:
2-20 parts of tea tree extract sodium sulphate, 30-60 parts of sodium chloride, 10-30 parts of builder, hard water resistance dose 20-30 parts, point
1-5 parts of powder.
The high-strength hard water adaptive type wash the dishes salt be it is liquid when, the salt that washes the dishes parts by weight composition it is as follows:
2-20 parts of tea tree extract sodium sulphate, 30-40 parts of sodium chloride, 8-30 parts of builder, hard water resistance dose 10-30 parts, point
25-40 parts of powder, 0.1-0.5 parts of stabilizer.
Preferably, the tea tree extract sodium sulphate is obtained by laxative remedy:, will under conditions of control temperature is not higher than 40 DEG C
Chlorosulfonic acid is mixed with tea tree extract, later in 0-40 DEG C of reaction 1-6h, is later isolated and purified reaction product described in obtaining
Tea tree extract sodium sulphate.
Further, the mass ratio of the tea tree extract and chlorosulfonic acid is 1-5:1.
Described isolates and purifies to pour into reaction product in mixture of ice and water, is sufficiently stirred in the case where ice-water bath is cooling
It mixes, is later 7-9 with alkali neutralization to pH, later filtering, filtrate condensing crystallizing, tea tree extract sulphur is obtained after filtering and dry again
Sour sodium.
The mass ratio of ice and water is 1-5:1 in the mixture of ice and water.According to the amount of the chlorosulfonic acid of addition, adjustment is corresponding
Mixture of ice and water in ice, water mass ratio, to avoid react it is too violent.
Specifically, the tea tree extract sodium sulphate is obtained by laxative remedy:
It is added tea tree extract in a kettle, 0-30 DEG C of temperature control, in the case where being sufficiently stirred in being slowly added dropwise in 10-120min
Suitable chlorosulfonic acid (mass ratio of tea tree extract and chlorosulfonic acid is 1-5:1), temperature does not exceed 0-40 DEG C when dropwise addition, pays attention to
It spumes, does not overflow material.After adding chlorosulfonic acid, the hydrogen chloride gas matter that is generated in 0-40 DEG C of reaction 1-6h, reaction
Score 5-50% sodium hydroxide solution is measured to absorb.After reaction, reaction mixture is slowly poured into and fills appropriate ice water and mixes
It closes in the processing unit of object (ice: water=1-5:1), is sufficiently stirred simultaneously, it is cooling with ice-water bath outside device.After mixing evenly,
Mass fraction 5-50% sodium hydroxide solution is added dropwise under stiring to carry out being neutralized to pH being 7-9.Mixed liquor is filtered, then by filtrate
Condensing crystallizing, filtering are dry to get tea tree extract sodium sulphate.
Wherein, the tea tree extract is one of kinds such as camellia, oil tea, thick short stamen tea, short stamen tea or a kind of
Above extract.Preferably Tea Saponin content is not less than 50% tea tree extract.
The acquisition form of specific extract, and have no special requirements.The root of such as tea tree, stem, leaf, seed it is a kind of or it is a kind of with
Upper tissue drying crushes, juicing extraction method, crystallisation, microwave extraction method, ultrasonic extraction, solution extraction, leaching from
The tea tree that one of heart method, enzymatic treatment method, super critical extraction, fermentation method, freeze-drying or a variety of extracting methods obtain
Extract is all possible.
The builder is bases；One of following or more than one mixture: sodium hydroxide, hydrogen-oxygen specifically may be selected
Change potassium, the carbonate of alkali metal, bicarbonate, silicate, meta-aluminate, sulphite, borate, phosphate, set alkali, grass greatly
The wooden alkali, Peruvian bark tree bark extract, Nuciferine, nicotine, ephedrine, jamaicin, brucine, new brucine, Oxymatrine
Alkali, anisodine, leonurine, tetrahydropalmatine, demethyl coclaurine, matrine, camptothecine, basic amino acid etc..
Described hard water resistance dose is selected from one of following or more than one mixture: EDETATE DISODIUM, EDTA tetrasodium salt, Portugal
It is grape sodium saccharate, K-IAO, calcium gluconate, potassium pyrophosphate, phosphate, amino carboxylic acid, 1,3- diketone, hydroxycarboxylic acid, more
Amine, porphyrin analog derivative, crown ether analog derivative, iminodisuccinic acid disodium salt, iminodisuccinic acid tetrasodium salt, tartaric acid
Salt, citrate, calcium acetate, citric acid, tartaric acid, aminotriacetic acid, 1-hydroxy ethylidene-1,1-diphosphonic acid, ethylenediamine tetraacetic methyl pitch phosphoric acid
The adjacent phenylacetic acid of sodium, five methene phosphoric acid of diethylenetriamine, ethylenediamine two, ethylenediamine two adjacent sodium, sodium tripolyphosphate, ammonia
Base trimethyl pitch phosphoric acid, 1-hydroxy ethylidene-1,1-diphosphonic acid, diethylenetriamine pentamethylene phosphoric acid, 2- phosphoric acid butane -1,2,4- tricarboxylic acids,
Di acyl acetic acid, diethylenetriamine pentamethylene sodium ascorbyl phosphate, dithizone, gluconic acid, sodium metasilicate, ethoxy second
Ethylenediamine triacetic acid, bicine N-, tetracarboxylic acid cyclopentane, 2- fluoroacetic acid propylmalonic acid, 2- fluoroacetic acid base fourth are led, chelate tree
Rouge, glutamic acid diacetic acid salt, humate, fatty alcohol polyoxyethylene ether sulfate, fatty alcohol polyoxyethylene ether and its esters, alcohol
Ether carboxylic acids, alpha-alkene sulfonate etc..
The stabilizer is selected from one of following or more than one mixture: starch, agar, gelatin, algin sodium, fruit
Glue, algin propylene diester, carboxymethyl cellulose and its esters, various converted starches, gum arabic, guar gum, xanthan
Glue.
The dispersing agent is selected from one of following or more than one mixture: water, alcohols, fatty acid, aliphatic acyl
Amine, esters, high molecular polymerization species, cellulose derivative class, polysaccharide.As ethyl alcohol, isopropanol, ethylene glycol may be selected in alcohols
Deng optional stearic acid of fatty acid etc., the optional vinyl bis-stearamides of aliphatic amide type etc., the optional tristearin of esters
Polyethylene glycol, fatty acid polyethylene glycol ester etc. may be selected in sour monoglyceride, glyceryl tristearate etc., high molecular polymerization species,
Hydroxymethyl cellulose etc. may be selected in cellulose derivative class, and guar gum etc. may be selected in polysaccharide, other can be used as dispersing agent certainly
Material it is also possible.
In the present invention, the application of tea tree extract sodium sulphate is a very big bright spot.
Tea Saponin is rich in tea tree, Tea Saponin is by different aglycons, sugared body and organic acid, with different connection type groups
At, it is a kind of natural nonionic surfactant, there are the function such as good foaming, foam stabilizing, dispersion, decontamination, emulsification, wetting
Can, while Tea Saponin also has outstanding antimicrobial antiviral activity.In addition to this, Tea Saponin derives from the extraction of natural plants,
Can be degradable by microorganism, and it is non-toxic to humans.Therefore, Tea Saponin is the ideal material for making antimicrobial form cleaning chemical products
Material.But Tea Saponin is soluble in hot water, is slightly soluble in warm water, so that the use condition of Tea Saponin cleaning chemical products is restricted.And tea
Contain a large amount of modifiable hydroxyl in saponin, the present invention is modified it using chlorosulfonic acid, and tea tree extract sodium sulphate is made
Novel surfactant, the surfactant have the advantages that anion and nonionic surface active agent simultaneously, can not only increase
Add its solubility, its dirt-removing power also can be enhanced.In addition, Tea Saponin molecule is only that a small amount of hydroxyl is modified, subject characteristic
It will not change, still there is antibacterial, antiviral ability.Meanwhile the sodium sulphate group newly introduced is non-toxic to humans, it is also easily logical
It is Tea Saponin and sulfate that hydrolysis, which is crossed, by the microorganism conversion of nature, does not influence the degradation of microorganism.Therefore, it was modified
Tea tree extract sodium sulphate not only there is outstanding antibacterial dirt-removing power, also have the characteristics that environmentally protective, harmless.
This patent uses the tea tree extract rich in Tea Saponin as raw material, with chlorosulfonic acid through single step reaction, then passes through subsequent simple place
Reason, is made tea tree extract sodium sulphate, raw material sources are extensive, and at low cost, method of modifying is simple to operation.Still further aspect, tea
It sets in extract also containing substances such as tea polyphenols, tea tree ethereal oils, all has good sterilizing ability, further promote tea tree and extract
The bactericidal effect of object sodium sulphate.
Sodium chloride is mostly used to make flavoring agent in daily life.But in fact, bacterium can be dehydrated death in salt water, therefore
Sodium chloride has good bactericidal effect.In protein aqueous solution, sodium chloride can increase the charge on protein molecule surface,
Enhance the effect of protein and hydrone, so that the solubility of protein in aqueous solution be made to increase, therefore, sodium chloride can have
Effect removes isolating protein.And sodium chloride strong electrolyte person's character, grease can be accelerated and paste the disengaging of block, therefore, sodium chloride can also be with
Effectively remove intractable grease and paste block.
In the present invention, while using the effect of the advantage of tea tree extract sodium sulphate and sodium chloride, the effect of the two is had
Machine combines and realizes cooperative compensating, and the salt that washes the dishes developed to tableware and is washed with high-effective cleansing ability, and while washing the dishes
Bowl machine carries out depth sterilization processing, and without in addition addition fungicide.
Hard water resistance dose can form complex compound, the hardness of water is effectively reduced with the calcium in hard water, the coordination of magnesium plasma, from
And detergent caused by hard water is avoided to inactivate and influence washing effect, while from preventing calcium and magnesium ion in hard water from tying in dish-washing machine
Dirt.
To sum up, the present invention by simple method by tea tree extract sodium sulphate, sodium chloride, builder, hard water resistance dose, it is steady
Determine agent and dispersing agent is homogenously mixed together, and the amount by changing dispersing agent, realizes the preparation of solid and liquid dishwasher salt；Its
Middle detergent bar salt can realize the regulation of its exterior appearance, match the washing of all dish-washing machines by the difference of molding die
Slot.
From the composition for washing the dishes salt, the present invention cleverly utilizes effective decontamination and the sterilizing ability of tea tree extract sodium sulphate
And sodium chloride good dissolubility and sterilizing ability, the washing effect of salt so that enhancing is washed the dishes, and pass through tea tree extract sulphur
The double sterilization function of sour sodium and sodium chloride promotes the sterilizing ability for the salt that washes the dishes.And by tea tree extract sodium sulphate, sodium chloride
Characteristic and builder, hard water resistance dose, after the effect of stabilizer, dispersing agent cooperates with together, the salt that washes the dishes of acquisition is just provided with fastly
Instant solution, it is potent go isolating protein, potent degreasing and the abilities such as sterilize, while the shadow of calcium in hard water, magnesium plasma can be eliminated
It rings, dishes is made to be easier to clean up, play the effect of protection dishwasher components.
The present invention wash the dishes salt raw material sources it is extensive, it is at low cost, be easily biodegradable, be harmless, highlight economical environment-protective
Harmless quality；Salt decontamination of washing the dishes is thorough, has superpower removal energy in particular for protein, intractable grease and paste block etc.
Power；Sterilizing ability is strong, softened water, raw material easily biological-degradable.The present invention salt that washes the dishes is applicable not only to family, while being also applied for wine
The places dish-washing machine such as shop, restaurant, dining room uses.
It washes the dishes the preparation method of salt invention further provides the high-strength hard water adaptive type, takes tea according to the weight ratio
Tree extract sodium sulphate, sodium chloride, builder and hard water resistance dose are sufficiently mixed, and drying and crushing obtains powdered form and washes the dishes later
Salt.
Or tea tree extract sodium sulphate, sodium chloride, builder, hard water resistance dose of mixing, Zhi Houjia are taken according to the weight ratio
Enter dispersing agent to be sufficiently mixed, drying and crushing and form later, obtains bulk and wash the dishes salt.
Or take tea tree extract sodium sulphate, sodium chloride, builder, hard water resistance dose and stabilizer mixed according to the weight ratio
It closes, dispersing agent is added later and is sufficiently mixed uniformly, obtains liquid dishwasher salt.
In the above method, it can use the methods of ball milling or stirring and promote being sufficiently mixed for each component.
Compared with the prior art, the invention has the following advantages:
High-strength hard water adaptive type of the present invention wash the dishes salt with strong detergency, after washing tableware residual is low；Potent antibacterial,
The advantages that stability is good, strong water adaptability, easily biological-degradable, environmental protection and public nuisance free, is easy to be acceptable to the market and promote.
Specific embodiment
Below the technical scheme of the invention is illustrated by a specific example, but the scope of the present invention is not limited thereto:
Embodiment 1
A kind of powdered salt that washes the dishes of high-strength hard water adaptive type, preparation process in turn include the following steps:
Weigh 20 parts of tea tree extract sodium sulphate, 50 parts of sea salt, 10 parts of sodium bicarbonates, 20 parts of sodium citrates.It is stirred in machinery
Under the action of mixing, each component is uniformly mixed, through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.
Wherein tea tree extract sodium sulphate is made by laxative remedy:
(1) choosing Wuyi Mountain, fujian tea free is raw material, through artificial drying, is crushed, and then extracts precipitating legal system by water
At tea tree extract:
The tea free of acquisition is dried, is crushed, by tea free crushed material water (crushed material is 1:5 with water quality ratio) in 50
~60 DEG C are soaked for a period of time and are stirred continuously, and filter to obtain leaching liquor.Isolated crushed material is used flooding 3 times again, is closed
And all leaching liquors.A certain amount of precipitating reagent CaO is added into leaching liquor, filters to obtain precipitating, then converts precipitating with ion
Agent turns molten, and tea tree extract product is obtained after concentrated, filtering, drying (Tea Saponin content is greater than 90%).
(2) it is added tea tree extract in a kettle, 10 DEG C of temperature control, in the case where being sufficiently stirred in chlorine is slowly added dropwise in 20min
Sulfonic acid (mass ratio of tea tree extract and chlorosulfonic acid be 4:1), temperature does not exceed 15 DEG C when dropwise addition, pays attention to spuming, not make
Material overflows.Add hydrogen chloride gas 5% sodium hydroxide of mass fraction generated in 25 DEG C of reaction 2h, reaction after chlorosulfonic acid
Solution absorbs.After reaction, reaction mixture is slowly poured into the processing unit for filling appropriate mixture of ice and water (ice:
Water=3:1), it is sufficiently stirred simultaneously, it is cooling with ice-water bath outside device.After mixing evenly, mass fraction is added dropwise under stiring
30% sodium hydroxide solution carries out being neutralized to pH being 7.5.Mixed liquor is filtered, then by filtrate condensing crystallizing, is filtered, dry, system
Obtain tea tree extract sodium sulphate.
Embodiment 2
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type includes the following steps:
Weigh 18 parts of tea tree extract sodium sulphate, 52 parts of sea salt, 10 parts of sodium bicarbonates, 20 parts of sodium citrates.It is stirred in machinery
Under the action of mixing, each component is uniformly mixed, through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.Its
The preparation method is the same as that of Example 1 for middle tea tree extract sodium sulphate.
Embodiment 3
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type includes the following steps:
Weigh 16 parts of tea tree extract sodium sulphate, 54 parts of sea salt, 10 parts of sodium bicarbonates, 20 parts of sodium citrates.It is stirred in machinery
Under the action of mixing, each component is uniformly mixed, through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.Its
The preparation method is the same as that of Example 1 for middle tea tree extract sodium sulphate.
Embodiment 4
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type includes the following steps:
Weigh 14 parts of tea tree extract sodium sulphate, 56 parts of sea salt, 10 parts of sodium bicarbonates, 20 parts of sodium citrates.It is stirred in machinery
Under the action of mixing, each component is uniformly mixed, through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.Its
The preparation method is the same as that of Example 1 for middle tea tree extract sodium sulphate.
Embodiment 5
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type includes the following steps:
Weigh 12 parts of tea tree extract sodium sulphate, 58 parts of sea salt, 10 parts of sodium bicarbonates, 20 parts of sodium citrates.It is stirred in machinery
Under the action of mixing, each component is uniformly mixed, through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.Its
The preparation method is the same as that of Example 1 for middle tea tree extract sodium sulphate.
Embodiment 6
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type includes the following steps:
Weigh 10 parts of tea tree extract sodium sulphate, 60 parts of sea salt, 10 parts of sodium bicarbonates, 20 parts of sodium citrates.It is stirred in machinery
Under the action of mixing, each component is uniformly mixed, through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.Its
The preparation method is the same as that of Example 1 for middle tea tree extract sodium sulphate.
Embodiment 7
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type is as follows:
Weigh 8 parts of tea tree extract sodium sulphate, 62 parts of sea salt, 10 parts of sodium bicarbonates, 20 parts of sodium citrates.In mechanical stirring
Under the action of, each component is uniformly mixed, through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.Wherein
The preparation method is the same as that of Example 1 for tea tree extract sodium sulphate.
Embodiment 8
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type is as follows:
Weigh 6 parts of tea tree extract sodium sulphate, 64 parts of sea salt, 10 parts of sodium bicarbonates, 20 parts of sodium citrates.In mechanical stirring
Under the action of, each component is uniformly mixed, through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.Wherein
The preparation method is the same as that of Example 1 for tea tree extract sodium sulphate.
Embodiment 9
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type is as follows:
Weigh 4 parts of tea tree extract sodium sulphate, 66 parts of sea salt, 10 parts of sodium bicarbonates, 20 parts of sodium citrates.In mechanical stirring
Under the action of, each component is uniformly mixed, through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.Wherein
The preparation method is the same as that of Example 1 for tea tree extract sodium sulphate.
Embodiment 10
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type is as follows:
Weigh 2 parts of tea tree extract sodium sulphate, 68 parts of sea salt, 10 parts of sodium bicarbonates, 20 parts of sodium citrates.In mechanical stirring
Under the action of, each component is uniformly mixed, through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.Wherein
The preparation method is the same as that of Example 1 for tea tree extract sodium sulphate.
Embodiment 11
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type in turn includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 62 parts of lake salt, 10 parts of sodium bicarbonates, 20 parts of sodium citrates.In mechanical stirring
Under the action of, each component is uniformly mixed, through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.Wherein
The preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 12
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type in turn includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 50 parts of sea salt, 12 parts of camptothecines, 10 parts of sodium bicarbonates, 20 parts of citric acids
Sodium.Under the action of mechanical stirring, each component is uniformly mixed, through drying, crushes, is made that high-strength hard water adaptive type is powdered to be washed
Bowl product salt.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 13
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type in turn includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 40 parts of sea salt, 22 parts of sodium carbonate, 10 parts of sodium bicarbonates, 20 parts of citric acids
Sodium.Under the action of mechanical stirring, each component is uniformly mixed, through drying, crushes, is made that high-strength hard water adaptive type is powdered to be washed
Bowl product salt.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 14
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type in turn includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 30 parts of sea salt, 10 parts of sodium bicarbonates, 12 parts of vegetation alkali, 20 parts of citric acids
Sodium, 20 parts of sodium gluconates.Under the action of mechanical stirring, each component is uniformly mixed, through drying, is crushed, is made high strong
The powdered product salt that washes the dishes of water adaptive type.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 15
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type in turn includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 20 parts of sea salt, 14 parts of Peruvian bark tree bark extracts, 14 parts of sodium bicarbonates, 24
Part sodium tartrate, 20 parts of EDETATE DISODIUMs.Under the action of mechanical stirring, each component is uniformly mixed, through drying, is crushed, system
Obtain the high-strength powdered product salt that washes the dishes of hard water adaptive type.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 16
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type in turn includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 62 parts of sea salt, 10 parts of Nuciferines, 20 parts of sodium citrates.Churned mechanically
Under effect, each component is uniformly mixed, through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.Wherein tea
Set the preparation method such as embodiment 1 of extract sodium sulphate.
Embodiment 17
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type in turn includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 62 parts of sea salt, 5 parts of sodium carbonate, 5 parts of basic amino acids, 20 parts of citric acids
Sodium.Under the action of mechanical stirring, each component is uniformly mixed, through drying, crushes, is made that high-strength hard water adaptive type is powdered to be washed
Bowl product salt.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 18
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type in turn includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 62 parts of sea salt, 10 parts of sodium bicarbonates, 20 parts of EDETATE DISODIUMs.It is stirred in machinery
Under the action of mixing, each component is uniformly mixed, through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.Its
The preparation method of middle tea tree extract sodium sulphate such as embodiment 1.
Embodiment 19
The wash the dishes preparation process of salt of high-strength hard water adaptive type bulk in turn includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 54 parts of sea salt, 13 parts of sodium carbonate, 10 parts of sodium citrates, 10 parts of EDETATE SODIUMs
Salt, 5 parts of polyethylene glycol.Under the action of mechanical stirring, each component is uniformly mixed, through drying, crushes, then passes through punching press
Machine forms said mixture in suitable mold, and high-strength hard water adaptive type bulk is made and washes the dishes product salt.Wherein tea tree
The preparation method of extract sodium sulphate such as embodiment 1.
Embodiment 20
The wash the dishes preparation process of salt of high-strength hard water adaptive type bulk in turn includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 32 parts of sea salt, 10 parts of Peruvian bark tree bark extracts, 15 parts of sodium carbonate, 10 parts
Sodium tartrate, 20 parts of iminodisuccinic acid tetrasodium salts, 5 parts of glyceryl monostearates.Under the action of mechanical stirring, by each group
Divide and be uniformly mixed, through drying, crush, then formed said mixture in suitable mold by press machine, is made high
Strong water adaptive type bulk washes the dishes product salt.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 21
The wash the dishes preparation process of salt of high-strength hard water adaptive type bulk in turn includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 42 parts of sea salt, 10 parts of vegetation alkali, 15 parts of matrines, 20 parts of aminotriacetic acids
Sodium, 1 part of ethylene glycol, 4 parts of ethyl alcohol.Under the action of mechanical stirring, each component is uniformly mixed, through drying, crushes, then passes through
Press machine forms said mixture in suitable mold, and high-strength hard water adaptive type bulk is made and washes the dishes product salt.Wherein
The preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 22
The preparation process of high-strength hard water adaptive type liquid dishwasher salt in turn includes the following steps:
It is 100 parts according to weight summation, weighs 8 parts of tea tree extract sodium sulphate, 30 parts of sea salt, 10 parts of sodium bicarbonates, 20
Part sodium citrate, 0.5 part of agar, 1 part of polyethylene glycol, 5 parts of ethyl alcohol, surplus water.Mechanical stirring is carried out, until be uniformly mixed,
High-strength hard water adaptive type liquid dishwasher product salt is made.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 23
The preparation process of high-strength hard water adaptive type liquid dishwasher salt in turn includes the following steps:
According to weight summation be 100 parts, weigh 8 parts of tea tree extract sodium sulphate, 30 parts of sea salt, 10 parts of new brucine,
20 parts of sodium potassium tartrate tetrahydrates, 0.1 part of sodium carboxymethylcellulose, 1 part of glycerine, 10 parts of ethyl alcohol, surplus water.Mechanical stirring is carried out,
Until being uniformly mixed, high-strength hard water adaptive type liquid dishwasher product salt is made.The wherein preparation method of tea tree extract sodium sulphate
Such as embodiment 1.
Embodiment 24
The preparation process of high-strength hard water adaptive type liquid dishwasher salt in turn includes the following steps:
It is 100 parts according to weight summation, weighs 8 parts of tea tree extract sodium sulphate, 35 parts of sea salt, 8 parts of sodium carbonate, 20 parts of Portugals
Grape sodium saccharate, 0.5 part of algin propylene diester, 1 part of ethylene glycol, 8 parts of ethyl alcohol, surplus water.Mechanical stirring is carried out, until mixing
Uniformly, high-strength hard water adaptive type liquid dishwasher product salt is made.The wherein preparation method of tea tree extract sodium sulphate such as embodiment
1。
Comparative example
Comparative example 1 (uses not modified tea tree extract)
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type in turn includes the following steps in this comparative example:
Weigh 8 parts of tea tree extracts, 30 parts of sea salt, 10 parts of sodium bicarbonates, 12 parts of vegetation alkali, 20 parts of sodium citrates, 20 parts
Sodium gluconate.Under the action of mechanical stirring, each component is uniformly mixed, through drying, crushes, high-strength hard water adaptive type is made
The powdered product salt that washes the dishes.
The wherein preparation method of tea tree extract such as embodiment 1.
(sodium chloride is not added) in comparative example 2
The preparation process of high-strength hard water adaptive type liquid dishwasher salt in turn includes the following steps in this comparative example.
Weigh 8 parts of tea tree extract sodium sulphate, 10 parts of new brucine, 20 parts of sodium potassium tartrate tetrahydrates, 0.1 part of carboxymethyl cellulose
Plain sodium, 1 part of glycerine, 10 parts of ethyl alcohol, surplus water.Mechanical stirring is carried out, until being uniformly mixed, high-strength hard water adaptive type is made
Liquid dishwasher product salt.
The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
(builder is not added) in comparative example 3
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type in turn includes the following steps in this comparative example.
Weigh 8 parts of tea tree extract sodium sulphate, 72 parts of sea salt, 20 parts of sodium citrates.It, will be each under the action of mechanical stirring
Component is uniformly mixed, and through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.Wherein tea tree extract sulphur
The preparation method of sour sodium such as embodiment 1.
Comparative example 4 (is not added hard water resistance dose)
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type in turn includes the following steps in this comparative example.
Weigh 8 parts of tea tree extract sodium sulphate, 30 parts of sea salt, 30 parts of sodium bicarbonates, 32 parts of vegetation alkali.Churned mechanically
Under effect, each component is uniformly mixed, through drying, crushes, the powdered product salt that washes the dishes of high-strength hard water adaptive type is made.Wherein tea
Set the preparation method such as embodiment 1 of extract sodium sulphate.
Comparative example 5 (replaces tea tree extract sodium sulphate using Tea Saponin sulfuric ester)
The preparation process of the high-strength powdered salt that washes the dishes of hard water adaptive type is as follows in this comparative example:
Weigh 8 parts of Tea Saponin sulfuric esters, 30 parts of sea salt, 10 parts of sodium bicarbonates, 12 parts of vegetation alkali, 20 parts of sodium citrates, 20
Part sodium gluconate.Under the action of mechanical stirring, each component is uniformly mixed, through drying, is crushed, high-strength hard water is made and is applicable in
The powdered product salt that washes the dishes of type.Wherein the preparation method of Tea Saponin sulfuric ester uses that application No. is implement in 201410053599.5
The method of example 1.
Effect experiment:
1, it is tested using the true washing effect of dish-washing machine:
Copy manual dishwashing with gone in detergent standard GB/T 9985-2000 oil cut rate method to above embodiments and right
Ratio detergent carries out true detergency test in dishwasher into operation condition: by clean plate with electronic scale be precisely weighed for
m0, then by a certain amount of artificial dirt (miscella 15%, wheat flour 15%, whole milk powder 7.5%, fresh whole egg liquid
30%, distilled water 32.5%, mass ratio) it is coated on plate, 4h is hung at room temperature, to imitate stain.Then electricity consumption
Plate after defiling is precisely weighed as m by sub- scale1.Plate after defiling is placed on the wash stand in certain brand dish-washing machine,
The corresponding detergent of 15g is added in detergent tank, setting wash temperature is 30 DEG C, and setting wash time is 10min, is then started
Power supply starts to wash.After washing, plate is taken out, after being rinsed 2 times with clear water, places hang on the top of the shelf at room temperature
The correct amount after 3h that dries in the air is m2。
Test result is as follows:
The test result really washed using dish-washing machine
2, antibiotic property is tested:
According to antibacterial bacteriostatic detergent industry standard QB/T 2738-2005 to above embodiments and comparative example detergent
It carries out antibiotic property test: the above detergent use Sterile standard hard water being dissolved to defined concentration, cleaning solution 5.0mL is drawn and puts
Enter in sterilizing test tubes, 20 DEG C of constant temperature 5min, then draws test bacteria liquid 0.1mL and be added in the test tube of the sample containing 5.0mL, rapidly
It mixes, and timing immediately.After effect to setting time, the mixed liquor 0.1mL of test organisms and sample is taken, is added to and is passed through containing 5.0mL
In the test tube of the neutralizer of sterilizing, mix.After neutralizing 10min, sample liquid 1mL is drawn, is placed in sterilizing plates, each sample liquid or dilute
It releases liquid and is inoculated with two sterilizing plates.It is poured into cool to 40-45 DEG C of nutrient agar 15mL, rotates plate, fill it
Divide uniformly, plate is overturn after agar solidification, (35 ± 2) DEG C culture 48h does the counting of viable bacteria bacterium colony, and compares with control sample, counts
Calculate sterilizing rate.
Test result is as follows:
Antibiotic rate test result
Note: sterilizing rate 1- is directed to staphylococcus aureus；Sterilizing rate 2- is directed to escherichia coli.
3, detergent measures examination:
Using the residual quantity of anionic surfactant in methylene blue laws measurement washing effect, the specific method is as follows:
Plate is washed using above embodiments and comparative example detergent in dish-washing machine, appropriate deionization is used after washing
Water rinses plate, pipettes appropriate rinsing test solution in 250mL separatory funnel, adds water to 100mL, chloroform is added
For 5mL in separatory funnel, repetition is extracted to that chloroform layer is colourless, all chloroform layers through absorbent cotton filter to
In 100mL volumetric flask, then with a little chloroform elution absorbent cotton, constant volume is mixed.With spectrophotometer under wavelength 650nm
Measure absorbance, reference standards curve determination content.
Test result is as follows:
Detergent measures test result
4, resistance to hard water measures
Copy manual dishwashing with gone in detergent standard GB/T 9985-2000 oil cut rate method to embodiment 14,20,23 with
And 4 detergent of comparative example carries out true detergency test in dishwasher into operation condition: clean plate electronic scale is accurately claimed
Weight is m0, then by a certain amount of artificial dirt (miscella 15%, wheat flour 15%, whole milk powder 7.5%, fresh full egg
Liquid 30%, distilled water 32.5%) it is coated on plate, 4h is hung at room temperature, to imitate stain.Then electronic scale will
Plate after defiling is precisely weighed as m1.Plate after defiling is placed on the wash stand in certain brand dish-washing machine, in detergent
The corresponding detergent of 15g is added in slot, setting wash temperature is 30 DEG C, and setting wash time is 10min, then startup power supply,
Start to wash.After washing, plate is taken out, after being rinsed 2 times with clear water, is placed after hanging the 3h that dries in the air on the top of the shelf at room temperature
Correct amount is m2。
Test result is as follows:
The true washing effect test result under different hard water conditions
| Detergent | Embodiment 14 | Embodiment 20 | Embodiment 23 | Comparative example 4 |
| Under 250mg/L hard water | > 99 | > 99 | > 99 | > 99 |
| Under 300mg/L hard water | > 99 | > 99 | > 99 | 97.6 |
| Under 350mg/L hard water | > 99 | > 99 | > 99 | 90.4 |
| Under 450mg/L hard water | > 99 | > 99 | 95.2 | 75.7 |
It is any ripe although the present invention is disclosed as above with embodiment, its protection scope being not intended to limit the invention
The technical staff for knowing this technology changes and retouches made without departing from the spirit and scope of the invention, should belong to this
The protection scope of invention.
Claims (10)
- The salt 1. a kind of high-strength hard water adaptive type washes the dishes, which is characterized in that the parts by weight composition of the salt that washes the dishes is as follows:1-20 parts of tea tree extract sodium sulphate, 10-90 parts of sodium chloride, 5-90 parts of builder, hard water resistance dose 1-90 parts, stabilizer 0- 5 parts, 0-40 parts of dispersing agent.
- The salt 2. high-strength hard water adaptive type as described in claim 1 washes the dishes, which is characterized in that the tea tree extract sodium sulphate is logical It crosses laxative remedy acquisition: under conditions of control temperature is not higher than 40 DEG C, chlorosulfonic acid being mixed with tea tree extract, later in 0-40 DEG C 1-6 h is reacted, reaction product is isolated and purified obtain the tea tree extract sodium sulphate later.
- The salt 3. high-strength hard water adaptive type as claimed in claim 2 washes the dishes, which is characterized in that the tea tree extract is tea soap The mass ratio of tea tree extract of the cellulose content not less than 50%, tea tree extract and chlorosulfonic acid is 1-5:1.
- The salt 4. high-strength hard water adaptive type as claimed in claim 2 washes the dishes, which is characterized in that described isolates and purifies as that will react Product pours into mixture of ice and water, is sufficiently stirred in the case where ice-water bath is cooling, is later 7-9 with alkali neutralization to pH, later mistake Filter, filtrate condensing crystallizing obtain tea tree extract sodium sulphate after filtering and dry again.
- The salt 5. high-strength hard water adaptive type as claimed in claim 4 washes the dishes, which is characterized in that in the mixture of ice and water ice with The mass ratio of water is 1-5:1.
- The salt 6. high-strength hard water adaptive type as described in claim 1 washes the dishes, which is characterized in that the builder is bases；Institute Hard water resistance dose stated is selected from one of following or more than one mixture: EDETATE DISODIUM, EDTA tetrasodium salt, sodium gluconate, K-IAO, calcium gluconate, potassium pyrophosphate, phosphate, amino carboxylic acid, 1,3- diketone, hydroxycarboxylic acid, polyamines, porphyrin Derivative, crown ether analog derivative, iminodisuccinic acid disodium salt, iminodisuccinic acid tetrasodium salt, tartrate, citric acid Salt, calcium acetate, citric acid, tartaric acid, aminotriacetic acid, 1-hydroxy ethylidene-1,1-diphosphonic acid, ethylenediamine tetraacetic methyl pitch sodium phosphate, divinyl The adjacent phenylacetic acid of five methene phosphoric acid of triamine, ethylenediamine two, ethylenediamine two adjacent sodium, sodium tripolyphosphate, amino trimethyl Pitch phosphoric acid, 1-hydroxy ethylidene-1,1-diphosphonic acid, diethylenetriamine pentamethylene phosphoric acid, 2- phosphoric acid butane -1,2,4- tricarboxylic acids, di Acyl acetic acid, diethylenetriamine pentamethylene sodium ascorbyl phosphate, dithizone, gluconic acid, sodium metasilicate, three second of hydroxyethyl ethylenediamine Acid, bicine N-, tetracarboxylic acid cyclopentane, 2- fluoroacetic acid propylmalonic acid, 2- fluoroacetic acid base fourth lead, chelating resin, paddy ammonia Sour diacetin, humate, fatty alcohol polyoxyethylene ether sulfate, fatty alcohol polyoxyethylene ether and its esters, alcohol ether carboxylate Class, alpha-alkene sulfonate；The stabilizer is selected from one of following or more than one mixture: starch, agar, gelatin, algae egg White acid sodium, pectin, algin propylene diester, carboxymethyl cellulose and its esters, various converted starches, gum arabic, Guar Bean gum, xanthan gum；The dispersing agent is selected from one of following or more than one mixture: water, alcohols, fatty acid, fat Race's amides, esters, high molecular polymerization species, cellulose derivative class, polysaccharide.
- The salt 7. high-strength hard water adaptive type as described in claim 1 washes the dishes, which is characterized in that the high-strength hard water adaptive type is washed Bowl salt is powder, bulk or liquid；The high-strength hard water adaptive type washes the dishes salt as powder, and the parts by weight composition for the salt that washes the dishes is as follows: tea tree extract sodium sulphate 2-20 parts, 20-70 parts of sodium chloride, 10-40 parts of builder, hard water resistance dose 20-50 parts；The high-strength hard water adaptive type washes the dishes salt as bulk, and the parts by weight composition of the salt that washes the dishes is as follows: tea tree extract sulphur Sour sodium 2-20 parts, 30-60 parts of sodium chloride, 10-30 parts of builder, hard water resistance dose 20-30 parts, 1-5 parts of dispersing agent；The high-strength hard water adaptive type wash the dishes salt be it is liquid, the parts by weight of the salt that washes the dishes composition is as follows: tea tree extract 2-20 parts of sodium sulphate, 30-40 parts of sodium chloride, 8-30 parts of builder, hard water resistance dose 10-30 parts, 25-40 parts of dispersing agent, stabilizer 0.1-0.5 parts.
- The preparation method of salt 8. any high-strength hard water adaptive type of claim 1-7 washes the dishes, which is characterized in that match according to weight Than taking tea tree extract sodium sulphate, sodium chloride, builder and hard water resistance dose to be sufficiently mixed, drying and crushing obtains powdered form later Wash the dishes salt.
- The preparation method of salt 9. any high-strength hard water adaptive type of claim 1-7 washes the dishes, which is characterized in that match according to weight Than taking tea tree extract sodium sulphate, sodium chloride, builder, hard water resistance dose of mixing, addition dispersing agent is sufficiently mixed later, Zhi Hougan It is dry to crush simultaneously through press machine punch forming, it obtains bulk and washes the dishes salt.
- The preparation method of salt 10. any high-strength hard water adaptive type of claim 1-7 washes the dishes, which is characterized in that according to weight Proportion takes tea tree extract sodium sulphate, sodium chloride, builder, hard water resistance dose and stabilizer mixing, and dispersing agent is added later and fills Divide and be uniformly mixed, obtains liquid dishwasher salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910497247.1A CN110157553A (en) | 2019-06-10 | 2019-06-10 | A kind of high-strength hard water adaptive type washes the dishes salt and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910497247.1A CN110157553A (en) | 2019-06-10 | 2019-06-10 | A kind of high-strength hard water adaptive type washes the dishes salt and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110157553A true CN110157553A (en) | 2019-08-23 |
Family
ID=67628199
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910497247.1A Pending CN110157553A (en) | 2019-06-10 | 2019-06-10 | A kind of high-strength hard water adaptive type washes the dishes salt and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110157553A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111394206A (en) * | 2020-04-02 | 2020-07-10 | 周栋 | Bowl washing tablet with slow release function and preparation method thereof |
| CN111484903A (en) * | 2020-05-21 | 2020-08-04 | 上海毅诺生物科技有限公司 | Multipurpose cleaning agent containing tea saponin polyoxyethylene laurate and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991015190A1 (en) * | 1988-03-04 | 1991-10-17 | Robell Research | A powder composition for forming a mouthwash |
| JP2001278718A (en) * | 2000-03-28 | 2001-10-10 | Nissan Chem Ind Ltd | Seaweed-proofing agent |
| CN103804461A (en) * | 2014-02-17 | 2014-05-21 | 浙江大学 | Preparation method of tea saponin sulfate surfactant and product thereof |
| CN105969557A (en) * | 2016-05-28 | 2016-09-28 | 重庆合川盐化工业有限公司 | Salt composite and method for tableware cleaning |
| EP3219743A1 (en) * | 2016-03-14 | 2017-09-20 | Procter & Gamble International Operations SA | Hydrophobically modified urea ethers as structurants for hydrophobic systems |
| CN107828563A (en) * | 2017-11-07 | 2018-03-23 | 重庆市盐业（集团）有限公司 | One kind cleaning salt and its preparation and application |
| CN109370793A (en) * | 2018-10-30 | 2019-02-22 | 四川夏商生物科技有限公司 | One kind removing pesticide residue washing salt and preparation method thereof |
-
2019
- 2019-06-10 CN CN201910497247.1A patent/CN110157553A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991015190A1 (en) * | 1988-03-04 | 1991-10-17 | Robell Research | A powder composition for forming a mouthwash |
| JP2001278718A (en) * | 2000-03-28 | 2001-10-10 | Nissan Chem Ind Ltd | Seaweed-proofing agent |
| CN103804461A (en) * | 2014-02-17 | 2014-05-21 | 浙江大学 | Preparation method of tea saponin sulfate surfactant and product thereof |
| EP3219743A1 (en) * | 2016-03-14 | 2017-09-20 | Procter & Gamble International Operations SA | Hydrophobically modified urea ethers as structurants for hydrophobic systems |
| CN105969557A (en) * | 2016-05-28 | 2016-09-28 | 重庆合川盐化工业有限公司 | Salt composite and method for tableware cleaning |
| CN107828563A (en) * | 2017-11-07 | 2018-03-23 | 重庆市盐业（集团）有限公司 | One kind cleaning salt and its preparation and application |
| CN109370793A (en) * | 2018-10-30 | 2019-02-22 | 四川夏商生物科技有限公司 | One kind removing pesticide residue washing salt and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 刘昕: "基于茶皂素分子改性的表面活性剂的研究", <<中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑>> * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111394206A (en) * | 2020-04-02 | 2020-07-10 | 周栋 | Bowl washing tablet with slow release function and preparation method thereof |
| CN111394206B (en) * | 2020-04-02 | 2022-09-13 | 芊碟净智能家居科技(广东)有限公司 | Bowl washing tablet with slow release function and preparation method thereof |
| CN111484903A (en) * | 2020-05-21 | 2020-08-04 | 上海毅诺生物科技有限公司 | Multipurpose cleaning agent containing tea saponin polyoxyethylene laurate and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103194321B (en) | antibacterial detergent for tableware and preparation method thereof | |
| CN106083765B (en) | A kind of Environmental Safety cleaning agent with antibacterial functions | |
| CN106753937A (en) | Antibacterial laundry soap and its production method | |
| CN108359543A (en) | The aerobic foam washing compound powder of environment-friendly highly efficient decontamination that safe pro-skin, profession are sterilized | |
| CN110157553A (en) | A kind of high-strength hard water adaptive type washes the dishes salt and preparation method thereof | |
| CN106434019A (en) | Laundry sheet applicable to underwear sterilization | |
| CN107828564A (en) | A kind of soap for being capable of mosquito-expelling bactericidal and preparation method thereof | |
| CN106566691A (en) | A Daye tea extract product liquid detergent and a preparing method thereof | |
| CN106701350B (en) | A kind of multi-functional blueberry ferment laundry dew | |
| CN109602667B (en) | Antibacterial hand sanitizer and preparation method thereof | |
| CN102703229B (en) | Tea stain and besmirch cleaning agent and moist towelette, and preparation methods thereof | |
| KR102488475B1 (en) | Multipurpose Water-Based Cleaner Composition | |
| CN104962408A (en) | Marine fish oil washing product and preparation method thereof | |
| CN110093216A (en) | Low bubble environment friendly dishwashing salt of one kind and preparation method thereof | |
| CN110157552A (en) | A kind of high-effective cleansing of natural green washes the dishes salt and preparation method thereof | |
| JP2006282896A (en) | Detergent and method for producing the same | |
| CN102634421A (en) | Clothes washing agent and preparation method thereof | |
| CN110093217A (en) | A kind of high-activity bio-enzyme washes the dishes salt and preparation method thereof | |
| CN108865503A (en) | A kind of Tea Saponin washing powder and preparation method thereof | |
| CN108531320A (en) | A kind of function perfumed soap and preparation method thereof | |
| CN106590951A (en) | Big-leaf tea extract detergent and preparation method thereof | |
| CN113736578A (en) | Plant antibacterial laundry detergent and preparation method thereof | |
| CN107557195A (en) | A kind of gleditsia sinensis ganoderma lucidum laundry soap and preparation method thereof | |
| CN110129142B (en) | Low-foam bacteriostatic detergent containing soapberry extract | |
| CN107338129A (en) | A kind of preparation method of the Traditional Chinese medicine laundry detergent containing Honegsukle flower P.E |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190823 |
|
| RJ01 | Rejection of invention patent application after publication |