CN110129142B - Low-foam bacteriostatic detergent containing soapberry extract - Google Patents
Low-foam bacteriostatic detergent containing soapberry extract Download PDFInfo
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- CN110129142B CN110129142B CN201910424545.8A CN201910424545A CN110129142B CN 110129142 B CN110129142 B CN 110129142B CN 201910424545 A CN201910424545 A CN 201910424545A CN 110129142 B CN110129142 B CN 110129142B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Abstract
The invention discloses a low-foam bacteriostatic detergent containing a soapberry extract, which comprises the following raw materials in percentage by weight: 10wt% of soapberry extract 50-63%, 13wt% of tea saponin aqueous solution 10-23%, natural perfume components 5-17%, APG 3-8%, 2wt% of chitin aqueous solution 2-6%, and the balance of deionized water. The low-foam bacteriostatic detergent provided by the invention can achieve quick cleaning and good bacteriostatic effect, and has wide market prospect.
Description
Technical Field
The invention belongs to the technical field of daily chemical articles, and particularly relates to a low-foam bacteriostatic detergent containing a soapberry extracting solution.
Background
Along with the acceleration of the pace of life of people, the enhancement of consciousness in the aspects of environmental protection and energy conservation, such as the cleaning work of public places such as restaurants, airports, hospitals and the like, the characteristics of quick cleaning, bacteriostasis, automatic degradation, no pollution, water consumption reduction and the like are required. At present, all detergents used in restaurants and other places are detergents with high foam, high water content and poor antibacterial ability, and the invention provides a low-foam antibacterial detergent containing a soapberry extract, which can be used in the current crowded places, has the effects of quick cleaning and bacteriostasis, and conforms to the development trend of food safety, energy conservation and environmental protection.
Disclosure of Invention
The invention aims to provide a low-foam bacteriostatic detergent containing a soapberry extracting solution, which can achieve quick cleaning and good bacteriostatic effects and has wide market prospect.
In order to achieve the purpose, the invention adopts the following technical scheme:
a low-foam bacteriostatic detergent containing soapberry extract comprises the following raw materials in percentage by weight: 10wt% of soapberry extract 50-63%, 13wt% of tea saponin aqueous solution 10-23%, natural perfume components 5-17%, APG (alkyl glycoside) 3-8%, 2wt% of chitin aqueous solution 2-6%, and the balance of deionized water.
Wherein, the components contained in the natural spice components are as follows by weight percent: 2-5% of cassia oil, 2-10% of eugenol, 5-16% of peppermint oil, 40-60% of lavender, 5-20% of wintergreen oil, 5-10% of origanum oil and 5-10% of lemon oil, wherein the sum of the weight percentages is 100%.
Preferably, the low-foam bacteriostatic detergent containing the soapberry extract comprises the following raw materials in percentage by weight: 10wt% of soapberry extract 60%, 13wt% of tea saponin aqueous solution 20%, natural perfume ingredients 10%, APG (alkyl glycoside) 5%, 2wt% of chitin aqueous solution 2.0%, and deionized water 3.0%.
Wherein, the components contained in the natural spice components are as follows by weight percent: 3% of cassia oil, 5% of eugenol, 10% of peppermint oil, 55% of lavender, 12% of wintergreen oil, 8% of origanum oil and 7% of lemon oil.
The invention has the following remarkable advantages:
(1) sapindus saponin and tea saponin are natural nonionic surfactants, are degraded naturally by 100 percent, and have excellent detergency.
(2) The natural perfume ingredients used in the invention have good antibacterial and odor removing effects, and meanwhile, the natural perfume contains a large amount of ester and aromatic compounds, and has small molecular weight, such as limonene in lemon oil, so that stains containing organic ingredients can be well dissolved.
(3) The alkyl glycoside biodegrades quickly and thoroughly, and the synergistic effect is obvious.
(4) Chitin is cationic polysaccharide, has antibacterial and anti-inflammatory effects, contains a large amount of hydroxyl (-OH) in the structure, can generate hydrogen bonds with a large amount of hydrophilic groups in stains, and can enable the stains to be easily separated from the surface to be cleaned under the action of external force.
(5) The low-foam bacteriostatic detergent prepared by the invention can achieve quick cleaning and good bacteriostatic effect, and has wide market prospect.
Detailed Description
In order to make the present invention more comprehensible, the technical solutions of the present invention are further described below with reference to specific embodiments, but the present invention is not limited thereto.
Preparing a soapberry extracting solution: crushing soapberry shells to 0.5-3mm, sieving, adding water according to the mass volume ratio of 1g:6mL for soaking for 12 hours, then adding saccharifying enzyme (20 ten thousand units) according to the mass volume ratio of 3g/kg, carrying out enzymolysis for 2 hours under the conditions of pH value of 3.0-6.5 and temperature of 50 ℃, then carrying out enzyme deactivation treatment for 30 minutes at 95 ℃, placing the mixture into an ultracentrifuge after the mixture is cooled to room temperature, centrifuging at 1.6 ten thousand revolutions per minute, taking supernate and concentrating to 10%.
Preparing a tea saponin aqueous solution: adding water into purchased tea saponin with the purity of 53 percent to prepare a 13 weight percent aqueous solution.
Example 1
A low-foam bacteriostatic detergent containing soapberry extract comprises the following raw materials in percentage by weight: 10wt% of soapberry extract 50%, 13wt% of tea saponin aqueous solution 10%, natural perfume components 10%, APG (alkyl glycoside) 3%, 2wt% of chitin aqueous solution 2.0%, and 25% of deionized water.
Wherein, the components contained in the natural spice components are as follows by weight percent: 2% of cassia oil, 10% of eugenol, 14% of peppermint oil, 40% of lavender, 20% of wintergreen oil, 8% of origanum oil and 6% of lemon oil.
Example 2
A low-foam bacteriostatic detergent containing soapberry extract comprises the following raw materials in percentage by weight: 10wt% of soapberry extract 50%, 13wt% of tea saponin aqueous solution 20%, 10% of natural perfume components, 5% of APG (alkyl glycoside), 2wt% of chitin aqueous solution 2.0%, and 13% of deionized water.
Wherein, the components contained in the natural spice components are as follows by weight percent: 3% of cassia oil, 8% of eugenol, 5% of peppermint oil, 59% of lavender, 5% of wintergreen oil, 10% of origanum oil and 10% of lemon oil.
Example 3
A low-foam bacteriostatic detergent containing soapberry extract comprises the following raw materials in percentage by weight: 10wt% of soapberry extract 60%, 13wt% of tea saponin aqueous solution 10%, natural perfume components 10%, APG (alkyl glycoside) 3%, 2wt% of chitin aqueous solution 2.0%, and deionized water 15%.
Wherein, the components contained in the natural spice components are as follows by weight percent: 5% of cassia oil, 2% of eugenol, 16% of peppermint oil, 57% of lavender, 10% of wintergreen oil, 5% of origanum oil and 5% of lemon oil.
Example 4
A low-foam bacteriostatic detergent containing soapberry extract comprises the following raw materials in percentage by weight: 10wt% of soapberry extract 60%, 13wt% of tea saponin aqueous solution 20%, natural perfume ingredients 10%, APG (alkyl glycoside) 5%, 2wt% of chitin aqueous solution 2.0%, and deionized water 3.0%.
Wherein, the components contained in the natural spice components are as follows by weight percent: 3% of cassia oil, 5% of eugenol, 10% of peppermint oil, 55% of lavender, 12% of wintergreen oil, 8% of origanum oil and 7% of lemon oil.
Bacteriostasis experiment (QB/T2738-
1) Reagent:
A. nutrient agar culture medium
Weighing 10.0g of peptone, 5.0g of beef extract and 5.0g of sodium chloride, adding 1000mL of distilled water for dissolving, adjusting pH to 7.2-7.4, adding 15.0g of agar, heating for dissolving, subpackaging, and sterilizing at 121 ℃ for 20min by steam under pressure for later use.
B. Sabouraud's agar culture medium
Weighing 40.0g of glucose, 10.0g of peptone and 20.0g of agar, adding 1000mL of distilled water, mixing the above components, heating to completely dissolve, adjusting pH to (5.6 +/-0.2), and steam sterilizing at 115 deg.C under pressure for 30 min.
C. Phosphate Buffered Saline (PBS) (0.03 mol/L)
Weighing 2.83g of anhydrous disodium hydrogen phosphate and 1.36g of potassium dihydrogen phosphate, adding 1000mL of distilled water, adjusting the pH value to 7.2-7.4 after complete dissolution, and sterilizing for 20min by using pressure steam at 121 ℃ for later use.
D. Standard hard water (hardness 342m g/L)
Weighing calcium chloride (CaCl)2)0.034g of magnesium chloride (MgCl)2·6H2O)0.139g, adding 1000mL of distilled water, and sterilizing by steam at 121 ℃ for 20min for later use.
E. Preparation of bacterial liquid
a. Preparation of suspension of Escherichia coli and Staphylococcus aureus
Taking a slant fresh culture (18h-24h) of the nutrient agar culture medium of the 3 rd generation to the 14 th generation of the strains, sucking 3.0mL-5.0 mL of PBS diluent by using a 5.0 mL suction pipe, adding into a slant test tube, repeatedly blowing and sucking, and washing off the lawn. The wash solution was then transferred to another sterile tube with a 5.0 mL pipette, mixed (shaken) with an electric mixer for 20s, or shaken 80 times on the palm to suspend the bacteria evenly; the bacteria concentration of the primarily prepared bacterial suspension is roughly measured by a bacteria concentration turbidimetry method, and then the bacterial suspension is diluted to the required concentration by a diluent. The bacterial propagule suspension is stored in a refrigerator at 4 ℃ for later use. Should be used on the day, should not be used overnight.
b. Preparation of Candida albicans suspension
Taking fresh culture (18-24 h) of the strain on the bevel of the Sabouraud's agar culture medium of the 5 th generation or the 6 th generation, sucking PBS diluent by using a 5.0 mL suction pipe, adding 0-5.0 mL of PBS diluent into a bevel test tube, repeatedly blowing and sucking, and washing off lawn. The wash solution was then transferred to another sterile tube with a 5.0 mL pipette, mixed (shaken) with an electric mixer for 20s, or shaken 80 times on the palm to suspend the bacteria evenly; the bacteria concentration of the primarily prepared bacterial suspension is roughly measured by a bacteria concentration turbidimetry method, and then the bacterial suspension is diluted to the required concentration by a diluent.
The bacterial propagule suspension is stored in a refrigerator at 4 ℃ for later use. Should be used on the day, should not be used overnight.
) The operation steps of the bacteriostatic test are as follows:
a) the test bacterial suspension is diluted properly by PBS, and the required concentration is as follows: 0.1mL of control solution (PBS) was added dropwise to 5.0 mL of the sample, and the number of recovered bacteria was 1X 104cfu/mL-9×104cfu/mL；
b) Diluting a test sample to a specified concentration with sterile standard hard water;
c) 5.0 mL of test sample stock solution or diluent thereof is sucked and put into a sterilized test tube, and the temperature is kept constant for 5min at 20 ℃;
d) sucking 0.1mL of test bacterium liquid, adding the test bacterium liquid into a test tube containing 5.0 mL of sample, quickly mixing the test bacterium liquid and the test tube uniformly, and immediately timing;
e) after the test bacteria and the sample are acted for a set time, 0.11mL of mixed solution of the test bacteria and the sample is added into a test tube containing 5.0 mL of sterilized PBS and fully and uniformly mixed;
f) after standing for 10min, 1mL of the sample solution (or diluted appropriately, 2-3 dilutions of the sample solution) was aspirated and placed in sterile plates, and two sterile plates were inoculated for each sample solution or dilution. Pouring 15mL of nutrient agar culture medium (bacteria) or Sabouraud's agar culture medium (yeast) cooled to 40-45 ℃, rotating the plate to fully and uniformly solidify the agar, turning the plate, culturing at 35 +/-2) DEG for 48 h (bacteria) or 72h (yeast), and counting viable bacteria colonies;
g) replacing the test sample with PBS, and performing the steps to obtain a control sample;
h) the experiment was repeated three times and averaged.
Calculation formula
Bacteriostasis rate (%) = (I-II). times.100/I,
in the formula:
i-average colony number of control sample; II-average number of colonies of test sample.
TABLE 1 results of the bacteriostatic test
The result of bacteriostatic experiments shows that when the addition amount of the natural perfume component is 10%, the bacteriostatic effect is good.
Detergency test
a. Preparation of a detergent: mixing 10wt% of soapberry extract and 13wt% of tea saponin aqueous solution according to the proportion, and uniformly stirring; then adding alkyl glycoside, continuously stirring until dissolving, then adding 2wt% chitin aqueous solution, natural perfume component, then adding deionized water (conductivity less than 20), and continuously stirring for 20 minutes to obtain the finished product.
b. Preparing a chemically synthesized detergent: weighing a certain amount of deionized water, sequentially adding AEO-720%, AEO-915%, AEO-56% and AEO-33% under stirring, sequentially adding 2% of monoethanolamine, 1.5% of diethanolamine and 2.5% of triethanolamine after the raw materials are completely dissolved, continuously stirring and uniformly mixing, finally adding 10% of spice, 2% of EDTA and the balance of deionized water, and continuously stirring for 20 minutes to obtain a finished product.
The results of the tests performed according to QB/T1224 are shown in Table 2.
TABLE 2 results of decontamination experiments
According to the detergency experimental result, the composition of the group 4 has the characteristics of optimal experimental effect, strong detergency, low foam and the like, and compared with the formula experimental data of a chemical synthetic detergent, the detergency is equivalent.
The detergent disclosed by the invention has the advantages of strong detergency, good antibacterial effect, rapid biodegradation, water saving, easiness in flushing and the like, has a good application prospect in the aspect of replacing a chemical synthesis surfactant formula, and accords with the development trend of environmental protection.
The above description is only a preferred embodiment of the present invention, and all equivalent changes and modifications made in accordance with the claims of the present invention should be covered by the present invention.
Claims (1)
1. A low-foam bacteriostatic detergent containing soapberry extract is characterized in that: the raw materials are as follows by weight percent: 10wt% of soapberry extract 60%, 13wt% of tea saponin aqueous solution 20%, 10% of natural perfume components, 5% of APG, 2wt% of chitin aqueous solution 2.0%, and 3.0% of deionized water;
the soapberry fruit extracting solution is prepared by crushing soapberry fruit shells to 0.5-3mm, sieving, adding water according to the mass volume ratio of 1g to 6mL for soaking for 12 hours, then adding 20 ten thousand units of saccharifying enzyme according to 3g/kg, carrying out enzymolysis for 2 hours under the conditions of pH value of 3.0-6.5 and temperature of 50 ℃, then carrying out enzyme deactivation treatment for 30 minutes at 95 ℃, cooling to room temperature, then placing into an ultracentrifuge, centrifuging at 1.6 ten thousand revolutions per minute, and taking supernatant and concentrating to 10%;
the natural perfume comprises the following components in percentage by weight: 3% of cassia oil, 5% of eugenol, 10% of peppermint oil, 55% of lavender, 12% of wintergreen oil, 8% of origanum oil and 7% of lemon oil.
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| CN201910424545.8A CN110129142B (en) | 2019-05-21 | 2019-05-21 | Low-foam bacteriostatic detergent containing soapberry extract |
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| CN110129142B true CN110129142B (en) | 2021-09-14 |
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