CN110129142A - A kind of antibacterial detergent of low bubble containing soapberry extract - Google Patents

A kind of antibacterial detergent of low bubble containing soapberry extract Download PDF

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Publication number
CN110129142A
CN110129142A CN201910424545.8A CN201910424545A CN110129142A CN 110129142 A CN110129142 A CN 110129142A CN 201910424545 A CN201910424545 A CN 201910424545A CN 110129142 A CN110129142 A CN 110129142A
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China
Prior art keywords
soapberry extract
oil
low bubble
antibacterial detergent
follows
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CN201910424545.8A
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Chinese (zh)
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CN110129142B (en
Inventor
余水洪
于�玲
游丽丽
欧霖拱
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FUJIAN PROV LIGHT INDUSTRY INST
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FUJIAN PROV LIGHT INDUSTRY INST
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes

Abstract

The invention discloses a kind of low bubble, antibacterial detergent containing soapberry extract, it uses raw material percentage are as follows: 10wt% soapberry extract 50-63%, 13wt% Tea Saponin aqueous solution 10-23%, natural flavoring ingredients 5-17%, APG 3-8%, 2wt% chitin water soluble liquid 2-6%, surplus is deionized water.It is provided by the invention it is low bubble, antibacterial detergent can play rapid cleaning and good fungistatic effect, have broad mass market prospect.

Description

A kind of antibacterial detergent of low bubble containing soapberry extract
Technical field
The invention belongs to daily chemical product technical fields, and in particular to a kind of low bubble containing soapberry extract, antibacterial decontamination Agent.
Background technique
With the acceleration of people's life rhythm, the enhancing that environmental protection, energy conservation aspect are realized, such as dining room, airport, hospital are public The cleaning in place needs rapid cleaning, antibacterial, can degrade automatically, pollution-free, reduce the features such as water consumption.Currently, dining room The detergent in equal places is all high bubble, water amount mostly and the detergent of bacteriostasis difference, the present invention propose that " one kind contains soapberry Low bubble, the antibacterial detergent of extracting solution " can meet the intensive place of current persons and use, play rapid cleaning and antibacterial effect Fruit meets food safety, energy-saving and environment-friendly development trend.
Summary of the invention
The purpose of the present invention is to provide a kind of low bubble, antibacterial detergent containing soapberry extract can play quickly Cleaning and good fungistatic effect have broad mass market prospect.
To achieve the above object, the present invention adopts the following technical scheme:
A kind of low bubble containing soapberry extract, antibacterial detergent, raw materials used percentage are as follows: 10wt% is without trouble Sub- extracting solution 50-63%, 13wt% Tea Saponin aqueous solution 10-23%, natural flavoring ingredients 5-17%, APG(alkyl glycosides) 3-8%, 2wt% chitin water soluble liquid 2-6%, surplus is deionized water.
Wherein, contained component percentage in natural flavoring ingredients are as follows: cassia oil 2-5%, eugenol 2-10%, thin Lotus oil 5-16%, lavender 40-60%, wintergreen 5-20%, origanum oil 5-10%, lemon oil 5-10%, the sum of weight percent are 100%。
Preferably, the low bubble containing soapberry extract, the raw materials used percentage of antibacterial detergent are as follows: 10wt% soapberry extract 60%, 13wt% Tea Saponin aqueous solution 20%, natural flavoring ingredients 10%, APG(alkyl glycosides) 5%, 2wt% chitin water soluble liquid 2.0%, deionized water 3.0%.
Wherein, contained component percentage in natural flavoring ingredients are as follows: cassia oil 3%, eugenol 5%, peppermint oil 10%, lavender 55%, wintergreen 12%, origanum oil 8%, lemon oil 7%.
Remarkable advantage of the invention is:
(1) sapindoside, Tea Saponin are natural nonionic surfactant, and 100% natural degradation has excellent detergency.
(2) natural flavoring ingredients used in the present invention have good antibacterial, peculiar smell effect of dispelling, meanwhile, contain in natural perfume material There are a large amount of esters and arene compounds, and molecular weight is smaller, such as the limonene in lemon oil, therefore can be with excellent dissolution containing organic The spot of ingredient.
(3) alkyl glycosides biodegrade is thorough rapidly, and it is obvious to join in a common effort effect.
(4) chitin is cationic polysaccharide, has antibacterial and anti-inflammation functions, and contains a large amount of hydroxyl (- OH) in its structure, Hydrogen bond can be generated with many hydrophilic radicals in spot can make spot be easier to from the surface to be cleaned by external force It is detached from.
(5) low bubble prepared by the present invention, antibacterial detergent can play rapid cleaning and good fungistatic effect, have wide city Field prospect.
Specific embodiment
In order to make content of the present invention easily facilitate understanding, With reference to embodiment to of the present invention Technical solution is described further, but the present invention is not limited only to this.
The preparation of soapberry extract: being crushed to 0.5-3mm for soapberry shell, sieving, by mass volume ratio 1g:6mL It soaks in water 12 hours, carbohydrase (200,000 unit) then is added by 3g/kg, under conditions of pH value 3.0-6.5, temperature 50 C Enzymatic hydrolysis 2 hours, later in 95 DEG C destroy the enzyme treatment 30 minutes, be cooled to room temperature and be put into ultracentrifuge to it, with 1.6 ten thousand turns/ Minute centrifugation, takes supernatant to be concentrated into 10%.
The preparation of Tea Saponin aqueous solution: water is added to be configured to the aqueous solution of 13wt% the Tea Saponin that the purity of outsourcing is 53%.
Embodiment 1
A kind of low bubble containing soapberry extract, antibacterial detergent, raw materials used percentage are as follows: 10wt% is without trouble Sub- extracting solution 50%, 13wt% Tea Saponin aqueous solution 10%, natural flavoring ingredients 10%, APG(alkyl glycosides) 3%, 2wt% chitin Aqueous solution 2.0%, deionized water 25%.
Wherein, contained component percentage in natural flavoring ingredients are as follows: cassia oil 2%, eugenol 10%, peppermint oil 14%, lavender 40%, wintergreen 20%, origanum oil 8%, lemon oil 6%.
Embodiment 2
A kind of low bubble containing soapberry extract, antibacterial detergent, raw materials used percentage are as follows: 10wt% is without trouble Sub- extracting solution 50%, 13wt% Tea Saponin aqueous solution 20%, natural flavoring ingredients 10%, APG(alkyl glycosides) 5%, 2wt% chitin Aqueous solution 2.0%, deionized water 13%.
Wherein, contained component percentage in natural flavoring ingredients are as follows: cassia oil 3%, eugenol 8%, peppermint oil 5%, lavender 59%, wintergreen 5%, origanum oil 10%, lemon oil 10%.
Embodiment 3
A kind of low bubble containing soapberry extract, antibacterial detergent, raw materials used percentage are as follows: 10wt% is without trouble Sub- extracting solution 60%, 13wt% Tea Saponin aqueous solution 10%, natural flavoring ingredients 10%, APG(alkyl glycosides) 3%, 2wt% chitin Aqueous solution 2.0%, deionized water 15%.
Wherein, contained component percentage in natural flavoring ingredients are as follows: cassia oil 5%, eugenol 2%, peppermint oil 16%, lavender 57%, wintergreen 10%, origanum oil 5%, lemon oil 5%.
Embodiment 4
A kind of low bubble containing soapberry extract, antibacterial detergent, raw materials used percentage are as follows: 10wt% is without trouble Sub- extracting solution 60%, 13wt% Tea Saponin aqueous solution 20%, natural flavoring ingredients 10%, APG(alkyl glycosides) 5%, 2wt% chitin Aqueous solution 2.0%, deionized water 3.0%.
Wherein, contained component percentage in natural flavoring ingredients are as follows: cassia oil 3%, eugenol 5%, peppermint oil 10%, lavender 55%, wintergreen 12%, origanum oil 8%, lemon oil 7%.
, bacteriostatic experiment (QB/T 2738-2012)
1) reagent:
A. nutrient agar
Peptone 10.0g, beef extract 5.0g, sodium chloride 5.0g are weighed, distilled water 1000mL is added to dissolve, adjusts pH to 7.2-7.4, so Agar 15.0g is added afterwards to dissolve by heating, packing is spare after 121 DEG C of pressuresteam sterilization 20min.
B. sabouraud's agar
Glucose 40.0g, peptone 10.0g, agar 20.0g are weighed, adds distilled water 1000mL, after mentioned component is mixed, add Heat adjusts pH to (5.6 ± 0.2) to being completely dissolved, spare after 115 DEG C of pressuresteam sterilization 30min.
C. phosphate buffer (PBS) (0.03 mol/L)
Anhydrous Disodium Phosphate 2.83g, potassium dihydrogen phosphate 1.36g are weighed, distilled water 1000mL is added, until completely dissolved, adjusts pH Value is spare after 121 DEG C of pressuresteam sterilization 20min to 7.2-7.4.
D. standard hard water (hardness 342m g/L)
Weigh calcium chloride (CaCl2) 0.034g, magnesium chloride (MgCl2·6H2O) 0.139g adds distilled water 1000mL, presses through 121 DEG C It is spare after power steam sterilizing 20min.
E. prepared by bacterium solution
A. the preparation of escherichia coli and staphylococcus aureus suspension
The nutrient agar inclined-plane fresh cultured object (18h-24h) for taking 14 generation of the 3rd Dai-the of strain is inhaled with 5.0 mL suction pipes PBS dilution 3.0mL-5.0 mL is taken to be added in slant tube, pressure-vaccum, washes lower lawn repeatedly.It will then be washed with 5.0 mL suction pipes Liquid moves in another sterile test tube, mixes (oscillation) 20s with motorized agitator, or shake and strike 80 times on palm, so that bacterium is outstanding It is floating uniform；Bacteria suspension made of preliminary first uses the bigness scale of bacterial concentration nephelometry, and it contains bacteria concentration, then with diluted To the required concentration used.Bacterial propagule suspension is stored in spare in 4 DEG C of refrigerators.Should day use, should not stay overnight.
B. the preparation of Candida albicans bacteria suspension
The sabouraud's agar inclined-plane fresh cultured object (18h-24h) for taking the 5th generation of strain or the 6th generation is inhaled with 5.0 mL suction pipes PBS dilution .0mL-5.0 mL is taken to be added in slant tube, pressure-vaccum, washes lower lawn repeatedly.Then with 5.0 mL suction pipes by washing lotion It moves in another sterile test tube, (oscillation) 20s is mixed with motorized agitator, or shake and strike 80 times on palm, so that bacterial suspension Uniformly；Bacteria suspension made of preliminary first uses the bigness scale of bacterial concentration nephelometry, and it contains bacteria concentration, then extremely with diluted The required concentration used.
Bacterial propagule suspension is stored in spare in 4 DEG C of refrigerators.Should day use, should not stay overnight.
) bacteriostatic test operating procedure:
A) appropriate dilution is done by bacteria suspension is tested with PBS liquid, it is desirable that concentration are as follows: take 0.1mL that control sample liquid (PBS) 5.0 is added dropwise ML, bacterial count recovered are 1 × 104cfu/mL-9×104cfu/mL；
B) test specimen is diluted to defined concentration with Sterile standard hard water；
C) it draws test specimen stoste or 5.0 mL of its dilution is put into sterilizing test tubes, 20 DEG C of constant temperature 5min；
D) it draws 0.1 ml of test bacteria liquid to be added in the test tube of 5.0 mL containing sample, mix rapidly, and timing immediately；
E) after effect to setting time, test organisms and sample mixed liquor 0.11mL is taken, the PBS sterilized containing 5.0 mL is added to Test tube in, mix well；
F) after placing 10min, sample liquid (or after making appropriate dilution, taking the dilution of wherein 2-3 dilution) 1mL is drawn, is placed in In sterilizing plates, each sample liquid or dilution are inoculated with two sterilizing plates.With cool to 40 DEG C -45 DEG C of nutrient agar (bacterium) or sabouraud's agar (saccharomycete) 15mL is poured into, and is rotated plate, is kept its full and uniform, turn over after agar solidification Turn plate, after (35 ± 2) DEG C cultivate 48 h (bacterium) or 72h (saccharomycete), does the counting of viable bacteria bacterium colony；
G) test specimen is replaced with PBS, is operated by above-mentioned steps, as control sample；
H) experiment in triplicate, is averaged.
, calculation formula
Bacteriostasis rate (%)=(I-II) × 100/I,
In formula:
I-control sample average colony number；II-test specimen average colony number.
1 bacteriostatic test result of table
The result shows that, when natural flavoring ingredients additive amount is 10%, there is good fungistatic effect through bacteriostatic experiment.
, detergency experiment
A. the preparation of detergent: 10wt% soapberry extract, 13wt% Tea Saponin aqueous solution are mixed by component proportion, stirring is equal It is even；Then alkyl glycosides is added, continues stirring to dissolving, adds 2wt% chitin water soluble liquid, natural flavoring ingredients, add Deionized water (conductivity is less than 20) continues stirring 20 minutes, finished product.
B. the preparation of chemical synthesis detergent: weighing a certain amount of deionized water, sequentially adds AEO-7 under stirring 20%, AEO-9 15%, AEO-5 6%, AEO-3 3%, are completely dissolved to above-mentioned raw materials, sequentially add monoethanolamine 2%, diethyl Hydramine 1.5%, triethanolamine 2.5%, continue to be uniformly mixed, and are eventually adding fragrance 10%, EDTA 2% and balance deionized water, Continue stirring 20 minutes, finished product.
It is detected according to QB/T 1224, the results are shown in Table 2.
2 washing tests result of table
It according to detergency experimental result, show that the 4th group of composite formula experiment effect is best, there are the spies such as strong detergency, low bubble Point, compared with chemical synthesis detergent compositions experimental data, detergency ability is suitable.
By above content as it can be seen that detergent of the present invention has strong detergency, good antimicrobial effect, biodegrade is rapid, water-saving The advantages that easily rinsing, and had a good application prospect in terms of substituting synthetic surfactant formula, meet environmentally protective Development trend.
The foregoing is merely presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with Modification, is all covered by the present invention.

Claims (4)

1. a kind of low bubble containing soapberry extract, antibacterial detergent, it is characterised in that: its raw materials used weight percent It is calculated as: 10wt% soapberry extract 50-63%, 13wt% Tea Saponin aqueous solution 10-23%, natural flavoring ingredients 5-17%, APG 3- 8%, 2wt% chitin water soluble liquid 2-6%, surplus is deionized water.
2. the low bubble according to claim 1 containing soapberry extract, antibacterial detergent, it is characterised in that: it is used former Expect percentage are as follows: 10wt% soapberry extract 60%, 13wt% Tea Saponin aqueous solution 20%, natural flavoring ingredients 10%, APG 5%, 2wt% chitin water soluble liquid 2.0%, deionized water 3.0%.
3. the low bubble according to claim 1 or 2 containing soapberry extract, antibacterial detergent, it is characterised in that: natural perfume Expect contained component percentage in ingredient are as follows: cassia oil 2-5%, eugenol 2-10%, peppermint oil 5-16%, lavender 40- 60%, wintergreen 5-20%, origanum oil 5-10%, lemon oil 5-10%, the sum of weight percent are 100%.
4. the low bubble according to claim 1 or 2 containing soapberry extract, antibacterial detergent, it is characterised in that: natural perfume Expect contained component percentage in ingredient are as follows: cassia oil 3%, eugenol 5%, peppermint oil 10%, lavender 55%, wintergreen 12%, origanum oil 8%, lemon oil 7%.
CN201910424545.8A 2019-05-21 2019-05-21 Low-foam bacteriostatic detergent containing soapberry extract Active CN110129142B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114854099A (en) * 2022-05-25 2022-08-05 何大伟 Preparation method of composite starch base

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106635459A (en) * 2016-11-24 2017-05-10 池州市建东生物科技有限公司 Plant washing liquid with disinsectization, bacteria inhibition and decontamination effects and preparation method thereof
CN107893002A (en) * 2017-11-29 2018-04-10 山东卓健医疗科技有限公司 A kind of natural antibacterial skin care soap lye and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106635459A (en) * 2016-11-24 2017-05-10 池州市建东生物科技有限公司 Plant washing liquid with disinsectization, bacteria inhibition and decontamination effects and preparation method thereof
CN107893002A (en) * 2017-11-29 2018-04-10 山东卓健医疗科技有限公司 A kind of natural antibacterial skin care soap lye and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114854099A (en) * 2022-05-25 2022-08-05 何大伟 Preparation method of composite starch base

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