CN111440676A - Foam cleaning agent with disinfection and cleaning functions and preparation method thereof - Google Patents
Foam cleaning agent with disinfection and cleaning functions and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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Abstract
The invention relates to the technical field of cleaning agents, and particularly relates to a foam cleaning agent with disinfection and cleaning functions and a preparation method thereof. The preparation raw materials at least comprise the following components in parts by weight: 10-25 parts of cationic surfactant, 20-45 parts of anionic surfactant, 1-8 parts of nonionic surfactant, 8-19 parts of solubilizer, 1-8 parts of chelating agent, 1-8 parts of antirust agent, 0.5-1.5 parts of pH regulator, 1-8 parts of micromolecular alcohol and 60-90 parts of water. The preparation method is simple, safe, convenient to operate, wide in preparation raw material source, low in cost, remarkable in cleaning and sterilizing effects and wide in development prospect.
Description
Technical Field
The invention relates to the technical field of cleaning agents, and particularly relates to a foam cleaning agent with disinfection and cleaning functions and a preparation method thereof.
Background
The disinfection is taken as the most important measure for biological safety prevention and control in the livestock and poultry breeding production process, and is also the most important measure for preventing and controlling various animal epidemic diseases, a large amount of excrement, residual bait and other substances exist in the environment of the livestock and poultry farm, various accumulated filths with grease and biomembranes are easily formed in the livestock and poultry farm, the disinfection effect is seriously influenced, and the disinfection measure cannot effectively prevent and stop the propagation of various animal epidemic diseases. All rely on using the caustic soda of a large amount of high concentration to wash beasts and birds plant among traditional beasts and birds breeding process, use high concentration caustic soda to wash and cause the washing liquid to flow into the big environment easily and cause the pollution to the environment, caustic soda has very strong corrosivity to equipment etc. simultaneously. Therefore, the whole livestock and poultry farm is lack of a safe, environment-friendly and efficient cleaning agent with double effects of cleaning and disinfection at present.
Disclosure of Invention
In order to solve the technical problems, the invention provides a foam cleaning agent with disinfection and cleaning functions, which is prepared from the following raw materials in parts by weight: 10-25 parts of cationic surfactant, 20-45 parts of anionic surfactant, 1-8 parts of nonionic surfactant, 8-19 parts of solubilizer, 1-8 parts of chelating agent, 1-8 parts of antirust agent, 0.5-1.5 parts of pH regulator, 1-8 parts of micromolecular alcohol and 60-90 parts of water.
In a preferred embodiment of the present invention, the cationic surfactant is one or more selected from the group consisting of an amine salt type cationic surfactant, a quaternary ammonium salt type cationic surfactant, and a heterocyclic type cationic surfactant.
In a preferred embodiment of the present invention, the anionic surfactant is selected from one or more of ethoxylated alkyl sodium sulfate, sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, sodium diisooctyl succinate sulfonate, sodium lauroyl glutamate, potassium lauroyl glutamate, sodium cocoyl glutamate, potassium cocoyl glutamate, sodium cocoyl sarcosinate, and potassium cocoyl sarcosinate.
In a preferred embodiment of the present invention, the nonionic surfactant is one or more selected from octyl alcohol triethoxy ether, decyl alcohol octa-ethoxy ether, dodecyl alcohol hexa-polyoxyethylene ether, tridecyl alcohol deca-polyoxyethylene ether, condensation product of fatty alcohol and ethylene oxide, and ethylene glycol diester.
In a preferred embodiment of the present invention, the solubilizer is selected from one or more of sodium xylene sulfonate, ethylene glycol monobutyl ether, and polyoxyethylene laurate.
As a preferable technical scheme of the invention, the chelating agent is selected from one or more of sodium metasilicate, ethylene diamine tetraacetic acid, sodium gluconate, sodium citrate, tetrasodium ethylene diamine tetraacetic acid and disodium ethylene diamine tetraacetic acid.
As a preferable technical solution of the present invention, the rust inhibitor is one or more selected from hydroxyethylidene diphosphonic acid, triethanolamine, sodium tetraborate, cyclohexylamine, monoethanolamine, diethanolamine, monoethanolamine benzoate, and diethanolamine benzoate.
In a preferred embodiment of the present invention, the pH adjuster is one or more selected from sodium hydroxide, potassium hydroxide, sodium bicarbonate, potassium bicarbonate, sodium carbonate, and potassium carbonate.
As a preferable technical scheme of the invention, the small molecule alcohol is selected from one or more of methanol, ethanol, n-propanol, isopropanol, n-butanol and isobutanol.
The second aspect of the invention provides a preparation method of a foam cleaning agent with disinfection and cleaning functions, which comprises the following steps: mixing cationic surfactant, anionic surfactant, nonionic surfactant, solubilizer, chelating agent, antirust agent, pH regulator, small molecular alcohol and water, and stirring.
Has the advantages that: the invention provides a foam cleaning agent with disinfection and cleaning functions and a preparation method thereof. Secondly, the preparation method is simple, safe, convenient to operate, wide in source of preparation raw materials, low in cost, remarkable in cleaning and sterilizing effects and wide in development prospect.
Detailed Description
The disclosure may be understood more readily by reference to the following detailed description of preferred embodiments of the invention and the examples included therein. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, the present specification, including definitions, will control.
The term "prepared from …" as used herein is synonymous with "comprising". The terms "comprises," "comprising," "includes," "including," "has," "having," "contains," "containing," or any other variation thereof, as used herein, are intended to cover a non-exclusive inclusion. For example, a composition, process, method, article, or apparatus that comprises a list of elements is not necessarily limited to only those elements but may include other elements not expressly listed or inherent to such composition, process, method, article, or apparatus.
The conjunction "consisting of …" excludes any unspecified elements, steps or components. If used in a claim, the phrase is intended to claim as closed, meaning that it does not contain materials other than those described, except for the conventional impurities associated therewith. When the phrase "consisting of …" appears in a clause of the subject matter of the claims rather than immediately after the subject matter, it defines only the elements described in the clause; other elements are not excluded from the claims as a whole.
When an amount, concentration, or other value or parameter is expressed as a range, preferred range, or as a range of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether ranges are separately disclosed. For example, when a range of "1 to 5" is disclosed, the described range should be interpreted to include the ranges "1 to 4", "1 to 3", "1 to 2 and 4 to 5", "1 to 3 and 5", and the like. When a range of values is described herein, unless otherwise stated, the range is intended to include the endpoints thereof and all integers and fractions within the range.
The singular forms "a", "an" and "the" include plural referents unless the context clearly dictates otherwise. "optional" or "any" means that the subsequently described event or events may or may not occur, and that the description includes instances where the event occurs and instances where it does not.
Approximating language, as used herein throughout the specification and claims, is intended to modify a quantity, such that the invention is not limited to the specific quantity, but includes portions that are literally received for modification without substantial change in the basic function to which the invention is related. Accordingly, the use of "about" to modify a numerical value means that the invention is not limited to the precise value. In some instances, the approximating language may correspond to the precision of an instrument for measuring the value. In the present description and claims, range limitations may be combined and/or interchanged, including all sub-ranges contained therein if not otherwise stated.
In addition, the indefinite articles "a" and "an" preceding an element or component of the invention are not intended to limit the number requirement (i.e., the number of occurrences) of the element or component. Thus, "a" or "an" should be read to include one or at least one, and the singular form of an element or component also includes the plural unless the stated number clearly indicates that the singular form is intended.
In order to solve the technical problems, the invention provides a foam cleaning agent with disinfection and cleaning functions, which is prepared from the following raw materials in parts by weight: 10-25 parts of cationic surfactant, 20-45 parts of anionic surfactant, 1-8 parts of nonionic surfactant, 8-19 parts of solubilizer, 1-8 parts of chelating agent, 1-8 parts of antirust agent, 0.5-1.5 parts of pH regulator, 1-8 parts of micromolecular alcohol and 60-90 parts of water.
In a preferred embodiment, the foam cleaning agent with the functions of disinfection and cleaning is prepared from at least the following raw materials in parts by weight: 12-20 parts of cationic surfactant, 25-40 parts of anionic surfactant, 2-5 parts of nonionic surfactant, 10-14 parts of solubilizer, 3-6 parts of chelating agent, 3-6 parts of antirust agent, 0.8-1.3 parts of pH regulator, 2-7 parts of micromolecular alcohol and 70-85 parts of water.
In a most preferred embodiment, the foam cleaning agent with the functions of disinfection and cleaning is prepared from at least the following raw materials in parts by weight: 15 parts of cationic surfactant, 30 parts of anionic surfactant, 3 parts of nonionic surfactant, 12 parts of solubilizer, 5 parts of chelating agent, 5 parts of antirust agent, 1 part of pH regulator, 5 parts of micromolecular alcohol and 80 parts of water.
Cationic surfactant
The cationic surfactant is mainly a nitrogenous organic amine derivative, and the nitrogen atom in the molecule of the cationic surfactant contains lone pair electrons, so that the nitrogen atom can be combined with hydrogen in acid molecules through hydrogen bonds to enable amino groups to carry positive charges. Therefore, they have good surface activity in acidic media; and easily precipitate in an alkaline medium to lose surface activity.
Cationic surfactants generally have good emulsifying, wetting, washing, sterilizing, softening, antistatic and corrosion-resistant properties, have good development potential due to special properties and application thereof, and will continue to increase in variety and demand as the application range of industrial and civil use is continuously expanded.
In a preferred embodiment, the cationic surfactant is selected from one or more of an amine salt type cationic surfactant, a quaternary ammonium salt type cationic surfactant, and a heterocyclic type cationic surfactant.
In a more preferred embodiment, the cationic surfactant is a combination of decamethyl ammonium bromide and dodecyltrimethyl ammonium chloride, wherein the mass ratio of decamethyl ammonium bromide to dodecyltrimethyl ammonium chloride is (1-4): 1.
in a more preferred embodiment, the cationic surfactant is a combination of decamethyl ammonium bromide and dodecyltrimethyl ammonium chloride, wherein the mass ratio of decamethyl ammonium bromide to dodecyltrimethyl ammonium chloride is (1.5-2.5): 1.
in a most preferred embodiment, the cationic surfactant is a combination of decamethyl ammonium bromide and dodecyl trimethyl ammonium chloride, wherein the mass ratio of decamethyl ammonium bromide to dodecyl trimethyl ammonium chloride is 2: 1.
anionic surfactants
The anionic surfactant refers to a partially negatively charged surfactant which plays a role in surface activity after being ionized in water.
In a preferred embodiment, the anionic surfactant is selected from one or more of ethoxylated alkyl sodium sulfate, sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, sodium diisooctyl succinate sulfonate, sodium lauroyl glutamate, potassium lauroyl glutamate, sodium cocoyl glutamate, potassium cocoyl glutamate, sodium cocoyl sarcosinate, and potassium cocoyl sarcosinate.
In a most preferred embodiment, the anionic surfactant is ethoxylated sodium alkyl sulfate.
The sodium ethoxylated alkyl sulfate of the present invention is commercially available from a manufacturer including, but not limited to, Guangzhou intelligent chemical Co., Ltd, type AES-70.
Nonionic surfactant
The nonionic surfactant is a surfactant which contains an ether group which is not dissociated in an aqueous solution as a main hydrophilic group in a molecule, and the surface activity of the surfactant is represented by a neutral molecule. The nonionic surfactant has high surface activity, good solubilization, washing, antistatic, calcium soap dispersion and other performances, small irritation, and excellent wetting and washing functions. The pH value range of the surfactant can be wider than that of the common ionic surfactant, and the surfactant can also be used together with other ionic surfactants, and the surfactant of the system can be improved by adding a small amount of nonionic surfactant into the ionic surfactant.
In a preferred embodiment, the nonionic surfactant is selected from one or more of octyl alcohol triethoxy ether, decyl alcohol octa-ethoxy ether, dodecyl alcohol hexa-polyoxyethylene ether, tridecyl alcohol deca-polyoxyethylene ether, condensation product of fatty alcohol and ethylene oxide, and ethylene glycol diester.
In a most preferred embodiment, the nonionic surfactant is a condensate of an aliphatic alcohol and ethylene oxide.
The fatty alcohol-ethylene oxide condensate of the present invention is commercially available from a manufacturer including, but not limited to, Hainan county, Wassi surfactant Co., Ltd., model number JFC-2.
Solubilizer
The solubilizer is a substance with solubilizing capability, and a process of increasing the solubility of an insoluble substance in a solvent and forming a solution is carried out under the action of the solubilizer.
In a preferred embodiment, the solubilizer is selected from one or more of sodium xylene sulfonate, ethylene glycol monobutyl ether, polyoxyethylene laurate.
In a most preferred embodiment, the solubilizer is sodium xylene sulfonate.
Chelating agents
The metal atom or ion reacts with a ligand containing two or more coordinating atoms to form a complex having a cyclic structure, which is called a chelate. Such ligand substances capable of forming chelates are called chelating agents, also known as complexing agents.
In a preferred embodiment, the chelating agent is selected from one or more of sodium metasilicate, ethylenediaminetetraacetic acid, sodium gluconate, sodium citrate, tetrasodium ethylenediaminetetraacetate, disodium ethylenediaminetetraacetate.
In a most preferred embodiment, the chelating agent is disodium edetate.
Rust inhibitor
In a preferred embodiment, the rust inhibitor is selected from one or more of hydroxyethylidene diphosphonic acid, triethanolamine, sodium tetraborate, cyclohexylamine, monoethanolamine, diethanolamine, monoethanolamine benzoate, and diethanolamine benzoate.
In a most preferred embodiment, the rust inhibitor is triethanolamine.
pH regulator
The pH regulator is also called acidity regulator and is used for regulating the pH value of solution and products.
In a preferred embodiment, the pH adjusting agent is selected from one or more of sodium hydroxide, potassium hydroxide, sodium bicarbonate, potassium bicarbonate, sodium carbonate, potassium carbonate.
In a most preferred embodiment, the pH adjusting agent is sodium hydroxide.
Small molecule alcohol
In a preferred embodiment, the small molecule alcohol is selected from one or more of methanol, ethanol, n-propanol, isopropanol, n-butanol and isobutanol.
In a most preferred embodiment, the small molecule alcohol is isopropanol.
The second aspect of the invention provides a preparation method of a foam cleaning agent with disinfection and cleaning functions, which comprises the following steps: mixing cationic surfactant, anionic surfactant, nonionic surfactant, solubilizer, chelating agent, antirust agent, pH regulator, small molecular alcohol and water, and stirring.
The inventor finds in experiments that the surface cleaning capability of the cleaning agent can be improved by adopting the decamethylammonium bromide and the dodecyltrimethylammonium chloride as the cationic surfactants and compounding with the JFC-2, and the possible reason is that the cationic surfactants and the anionic surfactants have a synergistic effect, so that the dissolution degree of pollutants in a water body can be effectively increased, and the decontamination and emulsification capabilities of the cleaning agent can be improved, but the decamethylammonium bromide has low activity when the nonionic surfactants JFC-2 coexist, so that through experimental researches, when the anionic surfactant ethoxylated sodium alkyl sulfate is added into the system, the phenomenon can be effectively relieved, and the sterilization capability of the cleaning agent can be effectively improved. In addition, the chelating agent EDTA-4Na is added to effectively remove calcium and magnesium ions in water, and the sodium hydroxide is added to further improve the detergency of the cleaning agent, so that the cleaning agent has strong capacity of removing oil stains on hard surfaces.
It should be noted that the following examples are only for illustrating the present invention and should not be construed as limiting the scope of the present invention, and that the insubstantial modifications and adaptations of the present invention by those skilled in the art based on the above disclosure are still within the scope of the present invention.
In addition, the raw materials used are commercially available from national chemical reagents, unless otherwise specified.
Examples
In order to better understand the above technical solutions, the following detailed descriptions will be provided with reference to specific embodiments. It should be noted that the following examples are only for illustrating the present invention and should not be construed as limiting the scope of the present invention, and that the insubstantial modifications and adaptations of the present invention by those skilled in the art based on the above disclosure are still within the scope of the present invention. In addition, the raw materials are commercially available and the extraction methods of the extract are all conventional extraction methods, if not otherwise specified.
Example 1
The foam cleaning agent with the functions of disinfection and cleaning is provided, and the preparation raw materials comprise the following components in parts by weight: 15 parts of cationic surfactant, 30 parts of anionic surfactant, 3 parts of nonionic surfactant, 12 parts of solubilizer, 5 parts of chelating agent, 5 parts of antirust agent, 1 part of pH regulator, 5 parts of micromolecular alcohol and 80 parts of water.
The cationic surfactant is a combination of decamethyl ammonium bromide and dodecyl trimethyl ammonium chloride, wherein the mass ratio of the decamethyl ammonium bromide to the dodecyl trimethyl ammonium chloride is 2: 1.
the anionic surfactant is ethoxylated sodium alkyl sulfate which is commercially available and is manufactured by Guangzhou intelligent chemical industry Co., Ltd, and the model is AES-70.
The nonionic surfactant is a condensate of fatty alcohol and ethylene oxide, and is commercially available, and the manufacturer is Haian county Huasi surfactant Co., Ltd, and the model is JFC-2.
The solubilizer is sodium xylene sulfonate.
The chelating agent is disodium ethylene diamine tetraacetate.
The antirust agent is triethanolamine.
The pH regulator is sodium hydroxide.
The small molecular alcohol is isopropanol.
The preparation method of the foam cleaning agent with the functions of disinfection and cleaning comprises the following steps: mixing cationic surfactant, anionic surfactant, nonionic surfactant, solubilizer, chelating agent, antirust agent, pH regulator, small molecular alcohol and water, and stirring.
Example 2
The foam cleaning agent with the functions of disinfection and cleaning is provided, and the preparation raw materials comprise the following components in parts by weight: 10 parts of cationic surfactant, 20 parts of anionic surfactant, 1 part of nonionic surfactant, 8 parts of solubilizer, 1 part of chelating agent, 1 part of antirust agent, 0.5 part of pH regulator, 1 part of micromolecular alcohol and 60 parts of water.
The cationic surfactant is a combination of decamethyl ammonium bromide and dodecyl trimethyl ammonium chloride, wherein the mass ratio of the decamethyl ammonium bromide to the dodecyl trimethyl ammonium chloride is 2: 1.
the anionic surfactant is ethoxylated sodium alkyl sulfate which is commercially available and is manufactured by Guangzhou intelligent chemical industry Co., Ltd, and the model is AES-70.
The nonionic surfactant is a condensate of fatty alcohol and ethylene oxide, and is commercially available, and the manufacturer is Haian county Huasi surfactant Co., Ltd, and the model is JFC-2.
The solubilizer is sodium xylene sulfonate.
The chelating agent is disodium ethylene diamine tetraacetate.
The antirust agent is triethanolamine.
The pH regulator is sodium hydroxide.
The small molecular alcohol is isopropanol.
The preparation method of the foam cleaning agent with the functions of disinfection and cleaning comprises the following steps: mixing cationic surfactant, anionic surfactant, nonionic surfactant, solubilizer, chelating agent, antirust agent, pH regulator, small molecular alcohol and water, and stirring.
Example 3
The foam cleaning agent with the functions of disinfection and cleaning is provided, and the preparation raw materials comprise the following components in parts by weight: 25 parts of cationic surfactant, 45 parts of anionic surfactant, 8 parts of nonionic surfactant, 19 parts of solubilizer, 8 parts of chelating agent, 8 parts of antirust agent, 1.5 parts of pH regulator, 8 parts of micromolecular alcohol and 90 parts of water.
The cationic surfactant is a combination of decamethyl ammonium bromide and dodecyl trimethyl ammonium chloride, wherein the mass ratio of the decamethyl ammonium bromide to the dodecyl trimethyl ammonium chloride is 2: 1.
the anionic surfactant is ethoxylated sodium alkyl sulfate which is commercially available and is manufactured by Guangzhou intelligent chemical industry Co., Ltd, and the model is AES-70.
The nonionic surfactant is a condensate of fatty alcohol and ethylene oxide, and is commercially available, and the manufacturer is Haian county Huasi surfactant Co., Ltd, and the model is JFC-2.
The solubilizer is sodium xylene sulfonate.
The chelating agent is disodium ethylene diamine tetraacetate.
The antirust agent is triethanolamine.
The pH regulator is sodium hydroxide.
The small molecular alcohol is isopropanol.
The preparation method of the foam cleaning agent with the functions of disinfection and cleaning comprises the following steps: mixing cationic surfactant, anionic surfactant, nonionic surfactant, solubilizer, chelating agent, antirust agent, pH regulator, small molecular alcohol and water, and stirring.
Example 4
Similar to example 1, except that the cationic surfactant was devoid of dodecyltrimethylammonium chloride.
Example 5
Similar to example 1, except that the cationic surfactant was free of decamethylammonium bromide.
Example 6
Similar to example 1, except that the starting materials were made without anionic surfactant.
Example 7
Similar to example 1, except that the starting materials were made without nonionic surfactant.
Evaluation of Performance
1. And (3) testing the cleaning capability: the foam cleaning agents with the disinfection and cleaning functions provided in examples 1-7 were tested according to the JB/T4323.2-1999 cleaning agent test method, and the results are shown in Table 1;
table 1 cleaning agent performance test results
2. Sterilization and disinfection Capacity test
The disinfectant provided by the embodiment 1-7 is subjected to a carrier soaking quantitative sterilization test, wherein experimental bacteria are respectively staphylococcus aureus (ATCC6538), escherichia coli (8099) and candida albicans (ATCC 10231), the formula solutions obtained in the embodiment 1-7 are respectively added into a sterile flat dish according to the dosage of 5.0m L of a bacterial sheet, the sterile flat dish is placed on a water bath at the temperature of 19-21 ℃ for preheating for 5min, the bacterial sheet is added, the bacterial sheet is acted for a certain time, the bacterial sheet is moved into a test tube filled with 5.0m L of neutralizing agent, the test tube is beaten for 80 times for neutralization, bacteria on the bacterial sheet are eluted and uniformly mixed, the eluent 5.0m L is taken for viable bacteria counting, and the killing rate is calculated, and the obtained results are shown in Table 2.
TABLE 2 results of bactericidal power test
The foregoing examples are merely illustrative and serve to explain some of the features of the method of the present invention. The appended claims are intended to claim as broad a scope as is contemplated, and the examples presented herein are merely illustrative of selected implementations in accordance with all possible combinations of examples. Accordingly, it is applicants' intention that the appended claims are not to be limited by the choice of examples illustrating features of the invention. Also, where numerical ranges are used in the claims, subranges therein are included, and variations in these ranges are also to be construed as possible being covered by the appended claims.
Claims (10)
1. The foam cleaning agent with the functions of disinfection and cleaning is characterized by at least comprising the following preparation raw materials in parts by weight: 10-25 parts of cationic surfactant, 20-45 parts of anionic surfactant, 1-8 parts of nonionic surfactant, 8-19 parts of solubilizer, 1-8 parts of chelating agent, 1-8 parts of antirust agent, 0.5-1.5 parts of pH regulator, 1-8 parts of micromolecular alcohol and 60-90 parts of water.
2. The foam cleaning agent with disinfecting and cleaning functions as claimed in claim 1, wherein the cationic surfactant is selected from one or more of amine salt type cationic surfactant, quaternary ammonium salt type cationic surfactant and heterocyclic type cationic surfactant.
3. The foam cleaning agent with disinfecting and cleaning functions as claimed in claim 1, wherein the anionic surfactant is selected from one or more of ethoxylated alkyl sodium sulfate, sodium dodecylbenzene sulfonate, sodium dodecyl sulfate, sodium diisooctyl succinate sulfonate, sodium lauroyl glutamate, potassium lauroyl glutamate, sodium cocoyl glutamate, potassium cocoyl glutamate, sodium cocoyl sarcosinate and potassium cocoyl sarcosinate.
4. The foam cleaning agent with disinfection and cleaning functions as claimed in claim 1, wherein said nonionic surfactant is selected from one or more of octyl alcohol tri-polyoxyethylene ether, decyl alcohol octa-polyoxyethylene ether, dodecyl alcohol hexa-polyoxyethylene ether, tridecyl alcohol deca-polyoxyethylene ether, condensation product of fatty alcohol and ethylene oxide, and ethylene glycol diester.
5. The foam cleaning agent with disinfection and cleaning functions as claimed in claim 1, wherein the solubilizer is selected from one or more of sodium xylene sulfonate, ethylene glycol monobutyl ether and polyoxyethylene laurate.
6. The foam cleaning agent with disinfection and cleaning functions as claimed in claim 1, wherein the chelating agent is selected from one or more of sodium metasilicate, ethylenediamine tetraacetic acid, sodium gluconate, sodium citrate, tetrasodium ethylenediamine tetraacetic acid and disodium ethylenediamine tetraacetic acid.
7. The foam cleaning agent with disinfection and cleaning functions as claimed in claim 1, wherein said rust inhibitor is selected from one or more of hydroxyethylidene diphosphonic acid, triethanolamine, sodium tetraborate, cyclohexylamine, monoethanolamine, diethanolamine, monoethanolamine benzoate, and diethanolamine benzoate.
8. The foam cleaning agent with disinfection and cleaning functions as claimed in claim 1, wherein said pH regulator is selected from one or more of sodium hydroxide, potassium hydroxide, sodium bicarbonate, potassium bicarbonate, sodium carbonate and potassium carbonate.
9. The foam cleaning agent with disinfection and cleaning functions as claimed in claim 1, wherein the small molecule alcohol is selected from one or more of methanol, ethanol, n-propanol, isopropanol, n-butanol and isobutanol.
10. The preparation method of the foam cleaning agent with disinfection and cleaning functions as claimed in any one of claims 1-9, characterized in that the preparation method comprises the following steps: mixing cationic surfactant, anionic surfactant, nonionic surfactant, solubilizer, chelating agent, antirust agent, pH regulator, small molecular alcohol and water, and stirring.
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| CN114107998A (en) * | 2021-12-06 | 2022-03-01 | 佛山市顺德区正泽精细化工有限公司 | Environment-friendly cleaning degreaser |
| CN115161131A (en) * | 2022-07-19 | 2022-10-11 | 橙的(福建)卫生用品有限责任公司 | Cleaning composition and small white shoe wiping wet tissue applying same |
| CN115806863A (en) * | 2022-11-30 | 2023-03-17 | 四川科宏达集团有限责任公司 | Alkaline foam cleaning agent and preparation method thereof |
| CN115806862A (en) * | 2022-11-30 | 2023-03-17 | 成都科宏达科技有限公司 | Acidic foam cleaning agent applied to water curtain of pig farm |
| CN115820350A (en) * | 2022-11-30 | 2023-03-21 | 四川科宏达集团有限责任公司 | Surfactant synergistic foam cleaning agent and preparation method thereof |
| CN115895790A (en) * | 2022-11-30 | 2023-04-04 | 四川科宏达集团有限责任公司 | Anion-cation surfactant compound cleaning agent and preparation method thereof |
| CN116004330A (en) * | 2022-11-30 | 2023-04-25 | 四川科宏达集团有限责任公司 | Foam cleaning agent with sterilization performance and preparation method thereof |
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| CN116004330A (en) * | 2022-11-30 | 2023-04-25 | 四川科宏达集团有限责任公司 | Foam cleaning agent with sterilization performance and preparation method thereof |
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