CN104013542A - Washing product and composition thereof - Google Patents
Washing product and composition thereof Download PDFInfo
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- CN104013542A CN104013542A CN201410004796.8A CN201410004796A CN104013542A CN 104013542 A CN104013542 A CN 104013542A CN 201410004796 A CN201410004796 A CN 201410004796A CN 104013542 A CN104013542 A CN 104013542A
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Abstract
The invention provides a washing product, a production method thereof and a composition for the washing product. The washing product comprises active carbon, perlite, degreased cottonseed meal and/or saw dust and an anionic surfactant and a chelating agent. Perlite and honeycomb-like structure in bamboo coal further facilitate adsorption of oil contamination and pigments, and meanwhile, the frictional force of the washed face is increased to have the kneading effect, so that the surfactant enters into the washed object, namely deep decontamination. No chemical substances are left after washing, and the washing product can be rubbed in a dry manner or dissolved to be washed. The washing product further has a certain purifying effect to water while the object is washed without secondary pollution to the environment.
Description
Technical field
The present invention relates to a kind of articles for washing, relate in particular to the articles for washing of a kind of noresidue,, stable storing little to water quality impact and for the compositions of described articles for washing, the preparation method of described articles for washing.
Background technology
Detergent is the decontamination article for clean medicated clothing, articles for daily use, apparatus, material etc., according to functional classification, comprise laundry detergent compositions, dish washing detergent, metal detergent, optical glass detergent, plastic, rubber detergent, vehicles detergent, food industry detergent, Epoxy resin etc.
As far back as Qin Han period, Pan's juice (washing water of rice), plant ash, roadway gate charcoal/shell-lime, Fructus Gleditsia etc. carry out decontamination, the Thousand Golden Prescriptions Tang Dynasty has also been recorded the method that Pancreas Sus domestica and Semen Glycines powder etc. are made bath bean, people improved on basis again afterwards, substitute Semen Glycines powder with soda (sodium carbonate), make " pancreas ", very approaching with the soap composition of present situation.After World War II, articles for washing explained hereafter has formed complete industrial system, due to the high speed development of the continuous progress of science and technology and oil, chemical industry and people to articles for washing in the urgent need to, whole world articles for washing is produced and is able to fast development.World's articles for washing total amount 1970 is 1637.7 ten thousand tons, and nineteen ninety-five is 4300 tons (wherein approximately 9,000,000 tons, soap), by 5,800,000,000 people, and approximately 7.9 kilograms of world's year consumption per heads.Estimate, to mid-21st Century, whole world articles for washing requirement will rise to 100,000,000-1.2 hundred million tons.
In detergent, surfactant is main decontamination active component, skin and mucosa are had to zest, and in surfactant, contain a large amount of compounds such as phosphorus, nitrogen, in addition, in detergent, also contain organized enzyme, this all can cause the eutrophication of water, cause red tide and algaeization phenomenon, not only heavy damage river, lake and marine environment, also causes multiplying of various antibacterials, virus simultaneously.
CN101550379A discloses a kind of Oleum Cocois and fatty alcohol-polyoxyethylene ether is main abluent, to skin nonirritant, and also little to environmental hazard, but this abluent is difficult for rinsing.
CN1063306A, CN102296007A, CN103194323A all disclose one and have utilized the tea dregs of rice (tea seed cake) to make the method for detergent, in the tea dregs of rice, contain tea saponin, there is good de-sludging, fungistatic effect, just be widely used as far back as the period of Ming and Qing, but because tea dregs of rice output is few, cannot large-scale application, cost of material is higher.In addition, tea dregs of rice frictional force is limited, causes the dirt-removing power in water to be restricted.
Patent CN101020870A also discloses the abstergent that a kind of wood flour, spaonin powder, oil tea saponin are made, but too high wood flour content makes this abstergent in water, use inconvenience, and while oil tea saponin is to extract from the tea dregs of rice, and its cost is higher.
Summary of the invention
For the existing above-mentioned defect of current articles for washing, the articles for washing of the invention provides that a kind of dirt-removing power is strong, easily rinsing, cost are low, free from environmental pollution and compositions and preparation method for described articles for washing.
First aspect of the present invention is to provide a kind of articles for washing compositions, according to part by weight, comprising:
Perlite 20-45 weight portions;
Active carbon 10-28 weight portions;
Degreased cottonseed meal 6-15 weight portions and/or wood flour 0-24 weight portions;
Bamboo fibre 0-12 weight portions;
Alkylsulfonate and/or alkyl sulfate anion surfactant 8-14 weight portion;
Soap anion surfactant 2-5 weight portion;
Chelating agen 1-3 weight portion.
Wherein, in foregoing of the present invention, described soap anion surfactant is preferably one or more in C8-C25 carboxylate, more preferably one or more in C10-C20 carboxylate, more preferably one or more in C12-C20, as any one or a few in stearate, palmitate, oleate, more preferably stearate.
Wherein, in foregoing of the present invention, described alkylsulfonate and/or alkyl sulfate anion surfactant are preferably C8-C25 alkylsulfonate, any one or a few in C8-C25 alkyl sulfate salt, more preferably C10-C20 alkylsulfonate, any one or a few in C10-C20 alkyl sulfate salt, more preferably C12-C20 alkylsulfonate, any one or a few in C12-C20 alkyl sulfate salt, more preferably C14-C18 alkylsulfonate, any one or a few in C14-C18 alkyl sulfate salt, more preferably C15-C16 alkylsulfonate, any one or a few in C15-C16 alkyl sulfate salt, as dodecane sulfonate, cetyl sulfonate, lauryl sulfate, polyoxyethylene alkyl ether sulfate salt, any one or a few in oleyl alcohol sulfuric acid, more preferably laurilsulfate salt, any one in dodecane sulfonate or two kinds.
Wherein, described chelating agen is preferably chelating agen or its salt with following structure:
Wherein, R is the alkyl that contains the C1-C15 of the substituent group replacement of the group that is selected from carboxyl, hydroxyl, ester group, acyl group, or H, or C1-C15 alkyl, or C1-C15 alkanoyl, as carboxyethyl, ethoxy, carboxymethyl, lauroyl etc.
Wherein, described chelating agen can be to be selected from ethylenediaminetetraacetic acid, N-hydroxyethyl-ethylenediamine-N, N '; N '-triacetic acid, N-lauroyl ethylenediamine-N, N ', N '-triacetic acid, N-alkyl ethylenediamine-N; N ', any one or a few in the salt of N '-triacetic acid, above-mentioned acid.
Wherein, in foregoing of the present invention, described salt is preferably any one or a few in alkali metal salt, as sodium salt and/or potassium salt, more preferably sodium salt.
During one in the present invention aspect first is preferably implemented, according to part by weight, described compositions can also comprise following any one or a few component:
Thickening agent 0-5 weight portion;
C8-C20 fatty acid 0-2 weight portion;
Wetting agent 1-4 weight portions;
Water soluble carbonate hydrogen salt 0-0.5 weight portion;
Sulfur 1-10 weight portions.
Wherein, described C8-C20 fatty acid is preferably any one or a few in C10-C18 fatty acid, more preferably any one or a few in C12-C18 fatty acid, more preferably any one or a few in C14-C18 fatty acid, as stearic acid, palmitic acid, oleic acid, more preferably stearic acid.
Wherein, described thickening agent can be to be selected from any one or a few in pre-gelatinized starch, hydroxyethyl-cellulose, hydroxypropyl cellulose, hydroxy methocel, ethyl cellulose, methylcellulose, more preferably hydroxyethyl-cellulose, pre-gelatinized starch.
Wherein, described wetting agent can be to be selected from any one or a few in sorbitol, Polyethylene Glycol, more preferably Polyethylene Glycol.
Wherein, described Polyethylene Glycol number-average molecular weight is preferably 2000-10000, more preferably 3000-8000, more preferably 4000-6000.
Wherein, described water soluble carbonate hydrogen salt is preferably alkali metal hydrogencarbonate, as sodium bicarbonate, potassium bicarbonate, more preferably potassium bicarbonate.
In a kind of preferred embodiment of above-mentioned composition of the present invention, according to part by weight, described compositions comprises following any one or a few component:
Perlite 20-45 weight portions;
Active carbon 10-28 weight portions;
Degreased cottonseed meal 6-15 weight portions and/or wood flour 0-24 weight portions;
Bamboo fibre 0-12 weight portions;
Alkylsulfonate and/or alkyl sulfate anion surfactant 8-14 weight portion;
Soap anion surfactant 2-5 weight portion;
Chelating agen 1-3 weight portion.
Pre-gelatinized starch 0-4 weight portion;
C8-C20 fatty acid 0-2 weight portion;
Hydroxyethyl-cellulose 0-1 weight portion;
Wetting agent 1-4 weight portions;
Water soluble carbonate hydrogen salt 0-0.5 weight portion;
Sulfur 1-10 weight portions.
Second aspect of the present invention is to provide a kind of articles for washing, and described articles for washing comprises any one compositions described in first aspect of the present invention.
Articles for washing described in second aspect of the present invention can be bulk, powder, granule, lamellar or liquid form.
Third aspect of the present invention is to provide a kind of method of producing described articles for washing, comprising:
(a) described perlite, described active carbon, described degreased cottonseed meal and/or wood are cut and mixed, then worn into 80-120 object fine graineds with grinder;
(b) described alkylsulfonate and/or alkyl sulfate anion surfactant, soap anion surfactant, chelating agen are joined in described fine grained;
(c) be mixed to get product.
In a kind of preferred embodiment of third aspect of the present invention, in step a and/or b, also comprise the step that bamboo fibre is mixed with described fine grained.
In a kind of preferred embodiment of third aspect of the present invention, described method also comprises: (b1) any one or a few in described pre-gelatinized starch, described C8-C20 fatty acid, described lubricant, described wetting agent, described water soluble carbonate hydrogen salt, described sulfur joined to the step in described fine grained.
Wherein, (b1) can carry out with (b) simultaneously, or carry out before or after (b).
In a kind of preferred embodiment of third aspect of the present invention, described method also comprises: (e1) products obtained therefrom is carried out to briquetting.
In a kind of preferred embodiment of third aspect of the present invention, described method also comprises: (e2) by products obtained therefrom in (c) and/or (e1) gained briquetting product pack.
Articles for washing tool provided by the present invention has the following advantages:
1, transportation and packing: save transport and packing cost.
2, cheap: to save use cost 30% than commercially available fluid product.
3, easy to use: can dry powder package, convenient storage; Can do and rub with the hands or dissolve after washing, chemical composition is not easy to be attached to washings surface.
4, of many uses: to can be used for employee's greasy dirt hand-washing powder, family's hand-washing powder, the beautifying whitening powder that washes one's face.
5, superpower degreasing: be rich in perlite, active carbon, degreased cottonseed meal or wood and cut or bamboo fibre, increase the frictional force of the face that is cleaned, can play the effect of rubbing, make surfactant enter cleaned material inside from microcosmic, namely deep layer degreasing, increase clean surface contact area, residual chemicals not after washing, chemical surfactant is lower than market 20%-40%, degreasing is active to improve more than 20%, greatly improve surfactant utilization ratio, reduce the pollution of chemical detergent to environment, and the cost of this cleaning dry powder is far below general detergent.
6, health environment-friendly, natural material compositing formula, pH value is neutral, hands is not hindered in without phosphorus, nontoxic, skin protection, environment friendly and pollution-free.Also there is antibacterial and adsorpting pigment effect simultaneously,
7, be convenient to storage, product quality is not affected by temperature and time, not perishable, long shelf-life.
Detailed description of the invention
embodiment 1(E1)
First perlite 35g, active carbon 17g, degreased cottonseed meal 8g, wood flour 14g are mixed in blender, then this mixture is worn in grinder to 80-120 order powder.
Then add successively sodium lauryl sulphate 14g, sodium stearate 3g, hydroxyethylethylene diamine tri-acetic acid 1g, pre-gelatinized starch 2g, Polyethylene Glycol 1g, sulfur 5g, after mix homogeneously, pack.
The cleanser that the present embodiment prepares, can be used for general industry and cleans, and has degreasing performance effect strong, easy to use.
embodiment 2(E2)
First perlite 27g, active carbon 24g, degreased cottonseed meal 7g, bamboo fibre 10g are mixed in blender, then this mixture is worn in grinder to 80-120 order powder.
Then add successively sodium lauryl sulphate 13g, sodium stearate 4g, hydroxyethylethylene diamine tri-acetic acid 2g, lauric acid 1g, pre-gelatinized starch 1g, hydroxyethyl-cellulose 0.6g, potassium bicarbonate 0.4g, Polyethylene Glycol 3g, sulfur 7g, after mix homogeneously, pack.
The cleanser that the present embodiment prepares, washes one's hands for family life, and the purposes such as wash one's face, can effectively dispel greasy dirt, has that sterilization is antibacterial, health care Bearberry Extract.
The alveolate texture of bamboo carbon inside is conducive to adsorb greasy dirt, pigment etc. more, and easier rinse chemical substance, also can be used as factory's hand-washing powder.
embodiment 3(E3)
First perlite 25g, active carbon 27g, degreased cottonseed meal 8g, bamboo fibre 12g are mixed in blender, then this mixture is worn in grinder to 80-120 order powder.
Then add successively sodium lauryl sulphate 11g, sodium stearate 2g, hydroxyethylethylene diamine tri-acetic acid 3g, lauric acid 2g, hydroxyethyl-cellulose 1g, potassium bicarbonate 0.2g, Polyethylene Glycol 3g, sulfur 6g, after mix homogeneously, after briquetting, pack.
The cleanser that the present embodiment prepares, for purposes such as family life wash one's face, has a bath, can effectively dispel greasy dirt, has antibacterial, the health care Bearberry Extract that sterilizes, easy to use.
embodiment 4(E4)
First perlite 35g, active carbon 15g, degreased cottonseed meal 10g, bamboo fibre 8g are mixed in blender, then this mixture is worn in grinder to 80-120 order powder.
Then add successively sodium lauryl sulphate 10g, sodium stearate 5g, hydroxyethylethylene diamine tri-acetic acid 1g, lauric acid 1g, hydroxyethyl-cellulose 0.4g, potassium bicarbonate 0.3g, Polyethylene Glycol 1g, sulfur 2g, after mix homogeneously, packaging.
embodiment 5(E5)
First perlite 33g, active carbon 17g, wood flour 20g, bamboo fibre 6g are mixed in blender, then this mixture is worn in grinder to 80-120 order powder.
Then add successively sodium lauryl sulphate 13g, sodium stearate 3g, hydroxyethylethylene diamine tri-acetic acid 1.5g, pre-gelatinized starch 1g, lauric acid 0.5g, ethyl cellulose 0.8g, Polyethylene Glycol 3g, sulfur 4g, after mix homogeneously, packaging.
Table 1, embodiment of the present invention 1-5 articles for washing performance test results
| Project | Standard-required | E1 | E2 | E3 | E4 | E5 |
| PH value | 6-10.5 | 7.2 | 7.0 | 7.2 | 7.1 | 7.2 |
| Total plate count (cfu/g) | ≤1000 | ＜10 | ＜10 | ＜10 | ＜10 | ＜10 |
| Heavy metal (wg) | ≤1000 | ＜100 | ＜100 | ＜100 | ＜100 | ＜100 |
| Surfactant is residual | ? | Do not measure | Do not measure | Do not measure | Do not measure | Do not measure |
| Dirt-removing power (Pi) | ≥1.0 | 1.6 | 1.5 | 1.7 | 1.5 | 1.6 |
As can be seen from Table 1, articles for washing of the present invention is neutral substantially, and skin is not produced to zest, meets GB/T13173-2008 standard.
Total plate count is obviously better than the sanitary index that GB4789.2-2010 specifies, is also obviously better than the bacteria resistance detergent sanitary index that GB/T2850-2007 specifies simultaneously.
Adopt GB/T13174-2008 standard to test dirt-removing power, articles for washing dirt-removing power of the present invention is significantly better than standard wash agent.
Active carbon and perlite that the present invention adopts have good adsorption effect, and surfactant can not be adsorbed onto washings surface, thereby can not produce residually, and simultaneously active carbon and perlite, by after SURFACTANT ADSORPTION, can not cause obvious impact to water quality; And after common detergent use, conventionally have a large amount of surfactants to remain in water, after discharge, water quality is polluted.
Above specific embodiments of the invention be have been described in detail, but it is just as example, the present invention is not restricted to specific embodiment described above.To those skilled in the art, any equivalent modifications that the present invention is carried out and alternative also all among category of the present invention.Therefore, equalization conversion and the amendment done without departing from the spirit and scope of the invention, all should contain within the scope of the invention.
Claims (10)
1. an articles for washing compositions, is characterized in that, according to part by weight, comprising:
Perlite 20-45 weight portions;
Active carbon 10-28 weight portions;
Degreased cottonseed meal 6-15 weight portions and/or wood flour 0-24 weight portions;
Bamboo fibre 0-12 weight portions;
Alkylsulfonate and/or alkyl sulfate anion surfactant 8-14 weight portion;
Soap anion surfactant 2-5 weight portion;
Chelating agen 1-3 weight portion.
2. compositions according to claim 1, is characterized in that, described soap anion surfactant is one or more in C8-C25 carboxylate; Described alkylsulfonate and/or alkyl sulfate anion surfactant are any one or a few in C8-C25 alkylsulfonate, C8-C25 alkyl sulfate salt.
3. compositions according to claim 1, is characterized in that, described chelating agen is preferably chelating agen or its salt with following structure:
Wherein, R is the alkyl that contains the C1-C15 of the substituent group replacement of the group that is selected from carboxyl, hydroxyl, ester group, or H, or C1-C15 alkyl, or C1-C15 alkanoyl.
4. compositions according to claim 1, is characterized in that, according to part by weight, described compositions also comprises following any one or a few component:
Thickening agent 0-5 weight portion;
C8-C20 fatty acid 0-2 weight portion;
Wetting agent 1-4 weight portions;
Water soluble carbonate hydrogen salt 0-0.5 weight portion;
Sulfur 1-10 weight portions.
5. compositions according to claim 4, is characterized in that, described thickening agent can be to be selected from any one or a few in pre-gelatinized starch, hydroxyethyl-cellulose, hydroxypropyl cellulose, hydroxy methocel, ethyl cellulose, methylcellulose.
6. compositions according to claim 4, is characterized in that, described wetting agent is selected from any one or a few in sorbitol, Polyethylene Glycol.
7. an articles for washing, is characterized in that, described articles for washing comprises compositions claimed in claim 1.
8. a method of producing described articles for washing, is characterized in that, comprising:
(a) described perlite, described active carbon, described degreased cottonseed meal and/or wood are cut and mixed, then worn into 80-120 object fine graineds with grinder;
(b) described alkylsulfonate and/or alkyl sulfate anion surfactant, soap anion surfactant, chelating agen are joined in described fine grained;
(c) be mixed to get product.
9. method according to claim 8, it is characterized in that, also comprise: any one or a few in pre-gelatinized starch described in claim 4, described C8-C20 fatty acid, described lubricant, described wetting agent, described water soluble carbonate hydrogen salt, described sulfur joined to the step in described fine grained.
10. method according to claim 8, is characterized in that, in step a and/or b, also comprises the step that bamboo fibre is mixed with described fine grained.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410004796.8A CN104013542A (en) | 2014-01-02 | 2014-01-02 | Washing product and composition thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410004796.8A CN104013542A (en) | 2014-01-02 | 2014-01-02 | Washing product and composition thereof |
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| CN201410004796.8A Pending CN104013542A (en) | 2014-01-02 | 2014-01-02 | Washing product and composition thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105296200A (en) * | 2015-10-21 | 2016-02-03 | 和县科嘉阀门铸造有限公司 | Ultrasonic cleaning agent for oil product conveying valve |
| CN105463489A (en) * | 2015-12-29 | 2016-04-06 | 滁州和富精密机械有限公司 | Degreasing composition for household appliance metal sheet degreasing |
| CN105754763A (en) * | 2016-02-01 | 2016-07-13 | 安徽埃斯克制泵有限公司 | Centrifugal pump motor surface cleaning agent |
| CN105802773A (en) * | 2016-04-14 | 2016-07-27 | 巢湖市荷花渔网有限公司 | Fishing net sterilization stain remover |
| CN105838521A (en) * | 2016-04-14 | 2016-08-10 | 巢湖市荷花渔网有限公司 | Detergent for fishing net |
| CN106265154A (en) * | 2016-08-31 | 2017-01-04 | 施秀丽 | Shaving cream |
| CN107502453A (en) * | 2017-07-25 | 2017-12-22 | 安徽胜利精密制造科技有限公司 | A kind of notebook computer shell degreasing agent and application this degreasing agent progress ungrease treatment technique |
| CN107955760A (en) * | 2017-11-25 | 2018-04-24 | 蚌埠市福沃特车轮制造科技有限公司 | A kind of pre- degreasing cleaning fluid of wheel hub |
| CN108018562A (en) * | 2017-11-25 | 2018-05-11 | 蚌埠市福沃特车轮制造科技有限公司 | A kind of pre- degreasing method of wheel hub |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105296200A (en) * | 2015-10-21 | 2016-02-03 | 和县科嘉阀门铸造有限公司 | Ultrasonic cleaning agent for oil product conveying valve |
| CN105463489A (en) * | 2015-12-29 | 2016-04-06 | 滁州和富精密机械有限公司 | Degreasing composition for household appliance metal sheet degreasing |
| CN105754763A (en) * | 2016-02-01 | 2016-07-13 | 安徽埃斯克制泵有限公司 | Centrifugal pump motor surface cleaning agent |
| CN105802773A (en) * | 2016-04-14 | 2016-07-27 | 巢湖市荷花渔网有限公司 | Fishing net sterilization stain remover |
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| CN106265154A (en) * | 2016-08-31 | 2017-01-04 | 施秀丽 | Shaving cream |
| CN107502453A (en) * | 2017-07-25 | 2017-12-22 | 安徽胜利精密制造科技有限公司 | A kind of notebook computer shell degreasing agent and application this degreasing agent progress ungrease treatment technique |
| CN107955760A (en) * | 2017-11-25 | 2018-04-24 | 蚌埠市福沃特车轮制造科技有限公司 | A kind of pre- degreasing cleaning fluid of wheel hub |
| CN108018562A (en) * | 2017-11-25 | 2018-05-11 | 蚌埠市福沃特车轮制造科技有限公司 | A kind of pre- degreasing method of wheel hub |
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