CN103126939B - A kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant - Google Patents

A kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant Download PDF

Info

Publication number
CN103126939B
CN103126939B CN201110375200.1A CN201110375200A CN103126939B CN 103126939 B CN103126939 B CN 103126939B CN 201110375200 A CN201110375200 A CN 201110375200A CN 103126939 B CN103126939 B CN 103126939B
Authority
CN
China
Prior art keywords
lauroyl
surfactant
acid
sodium salt
potassium salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201110375200.1A
Other languages
Chinese (zh)
Other versions
CN103126939A (en
Inventor
张健
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU WEIMEI BIOLOGICAL TECHNOLOGY Co Ltd
Original Assignee
SUZHOU WEIMEI BIOLOGICAL TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUZHOU WEIMEI BIOLOGICAL TECHNOLOGY Co Ltd filed Critical SUZHOU WEIMEI BIOLOGICAL TECHNOLOGY Co Ltd
Priority to CN201110375200.1A priority Critical patent/CN103126939B/en
Publication of CN103126939A publication Critical patent/CN103126939A/en
Application granted granted Critical
Publication of CN103126939B publication Critical patent/CN103126939B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Cosmetics (AREA)

Abstract

The invention discloses a kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant, it, relative to the percentage ratio of its quality, comprises: N-lauroyl-ALANINE sodium salt or potassium salt, 10%-20%; Cocos nucifera oil acyl Kaglutam, 1.0%-5.0%; LAA, 1.0%-3.0%; Cocoalkyl-betanin, 1.0%-5.0%; The solution of 50% pyridine alkane keto carboxylic acid sodium, 1.0%-3.0%; Glycerol monolaurate, 1.0%-2.0%; Water, 70-80%; Hydrolysis hyaluronic acid, 0.1%-0.5%; Phenoxyethanol, benzoic acid, dehydroactic acid (and) Sensiva SC50,1.0%-3.0%; Propylene glycol, water (and) nettle extract, 1.0%-3.0%; Spice, 1.0%-2.0%; Citric acid is appropriate, makes product keep DI-I value 5.5-6.5; The present invention has the following advantages: dirt-removing power is strong, have the good compatibility, environmental protection, little to the zest of skin, cost is low.

Description

A kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant
Technical field
The present invention relates to a kind of bath gel, especially a kind of containing N-lauroyl-ALANINE sodium salt or potassium salt as the bath gel of surfactant, belong to hair shampoo article technical field.
Background technology
In bath gel, need to use surfactant, common surfactant, although because of have good characteristic be widely used in produce, life in, its biological degradability and eco-compatibility poor, can work the mischief to ecological environment.Along with people more and more pay close attention to the safety of various product, mildness and the raising to environmental protection requirement, study and develop multi-functional high-quality environmental friendliness surfactant oneself becomes the Main way of Surfactant Industry.
Amino acid type surfactant is the surfactant based on biological substance, owing to having amino acid backbone in molecule, except having other series of surfactants performances concurrently, also there are some functions of other uniqueness, if any fungistatic effect, good biocompatibility, degrades safety quick.
Amino acid classes has kind more than 200, can be used for synthesizing just tens kinds of primary amino acids wherein of N-acyl amino acid surfactant at present, as long as there is sarcosine in existing market for the conventional aminoacid of cosmetics synthesis N-lauroyl amino acid surfactant and salt thereof, glutamic acid, serine, lysine, leucine etc., reach a climax from 20th century its application and research of century 70, oneself obtains extensive use to current the type product abroad, the more influential Hamposyl having the U.S., the Medialan of Germany, the products such as the Amisoft of Japan, produce also immature in China, main dependence on import in demand, expensive, constrain the development of domestic bath gel etc.
Summary of the invention
The present invention seeks to propose a kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant to overcome the deficiencies in the prior art.
For achieving the above object, the technical solution used in the present invention is: a kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant, it, relative to the percentage ratio of its quality, comprises:
N-lauroyl-ALANINE sodium salt or potassium salt, 10%-20%;
Cocos nucifera oil acyl Kaglutam, 1.0%-5.0%;
LAA, 1.0%-3.0%;
Cocoalkyl-betanin, 1.0%-5.0%;
The solution of 50% pyridine alkane keto carboxylic acid sodium, 1.0%-3.0%;
Glycerol monolaurate, 1.0%-2.0%;
Water, 70%-80%;
Hydrolysis hyaluronic acid, 0.1%-0.5%;
Phenoxyethanol, benzoic acid, dehydroactic acid (and) Sensiva SC50,1.0%-3.0%;
Propylene glycol, water (and) nettle extract, 1.0%-3.0%;
Spice, 1.0%-2.0%;
Citric acid is appropriate, makes product keep DI-I value 5.5-6.5.
Due to the utilization of technique scheme, the present invention compared with prior art has following advantages:
Of the present invention containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant; Have the following advantages:
1, dirt-removing power is strong
Long-chain fatty acid and natural amino acid form amido link to be had novel molecule and independently fills performance, about chelating being formed with a lot of molecule, strange selection chelating oil molecule is selected in oil water mixture, there is very strong dirt-removing power, and the dirt-removing power of N-lauroyl-ALANINE sodium salt is more better than N-lauroyl-Pidolidone disodium and N-lauroyl-L-sodium sarcosinate, can separately as cleansing.
2, there is the good compatibility
Articles for washing containing N-lauroyl-ALANINE natrium surfactant, the sense of touch when washing and after washing is all good, and skin can not be too dry and astringent and have tender sense of touch.
3, environmental protection
Its biological degradability of common surfactant and eco-compatibility poor, can work the mischief to ecological environment, its catabolite of N-lauroyl-ALANINE is that aminoacid and fatty acid almost do not affect environment.
4, little to the zest of skin
Emphasize oiliness skin or the special Cleansing Foam of male at present, the most frequently used cleansing is sodium lauryl sulphate, because being the extremely strong surfactant of degrease power for this reason, but it has potential zest to skin and descends rice to reduce making the defence capability of skin self for a long time, causes the phenomenon such as dermatitis, skin aging.Long-chain fatty acid before N-lauroyl-Pidolidone natrium surfactant is similar to dodecyl, there is same dirt-removing power, but because it is adopt natural component be raw material manufacture and obtain, composition itself can be adjusted to about faintly acid PH6.5-7, so very little to skin irritation, life-time service, misgivings can not be needed to have injury to skin, and anemia of pregnant woman and infant product are suitable for too.
5, cost is low
N-lauroyl-ALANINE belongs to ammonia propylhomoserin type surfactant, and on existing market, such surfactant is used for superior cosmetics, this is on the one hand because the pH value of this kind of surfactant and skin is close, nontoxic non-stimulated to skin, also because production cost is high, purity is low.And the production technology of N-lauroyl-ALANINE is simple and easy to get, the high purity product being greater than 98% can be prepared, the domestic vast demand to the type surfactant can be met.
Detailed description of the invention
Embodiment 1
Of the present invention a kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant, it, relative to the percentage ratio of its quality, comprises:
N-lauroyl-ALANINE sodium salt or potassium salt, 12%;
Cocos nucifera oil acyl Kaglutam, 2.5%;
LAA, 3.0%;
Cocoalkyl-betanin, 1.0%;
The solution of 50% pyridine alkane keto carboxylic acid sodium, 2.0%;
Glycerol monolaurate, 1.0%;
Water, 75%;
Hydrolysis hyaluronic acid, 0.5%;
Phenoxyethanol, 1.0%;
Propylene glycol, water (and) nettle extract, 1.0%;
Spice, 1.0%;
Citric acid is appropriate, makes product keep DI-I value 5.5-6.5.
Embodiment 2
Of the present invention a kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant, it, relative to the percentage ratio of its quality, comprises:
N-lauroyl-ALANINE sodium salt or potassium salt, 10%;
Cocos nucifera oil acyl Kaglutam, 5.0%;
LAA, 2.0%;
Cocoalkyl-betanin, 1.0%;
The solution of 50% pyridine alkane keto carboxylic acid sodium, 1.0%;
Glycerol monolaurate, 1.0%;
Water, 73%;
Hydrolysis hyaluronic acid, 0.5%;
Benzoic acid, 2.0%;
Propylene glycol, water (and) nettle extract, 2.5%;
Spice, 2.0%;
Citric acid is appropriate, makes product keep DI-I value 5.5-6.5.
Embodiment 3
Of the present invention a kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant, it, relative to the percentage ratio of its quality, comprises:
N-lauroyl-ALANINE sodium salt or potassium salt, 11%;
Cocos nucifera oil acyl Kaglutam, 5.0%;
LAA, 2.0%;
Cocoalkyl-betanin, 1.0%;
The solution of 50% pyridine alkane keto carboxylic acid sodium, 2.0%;
Glycerol monolaurate, 2.0%;
Water, 70%;
Hydrolysis hyaluronic acid, 0.1%;
Dehydroactic acid (and) Sensiva SC50,1.9%;
Propylene glycol, water (and) nettle extract, 3.0%;
Spice, 2.0%;
Citric acid is appropriate, makes product keep DI-I value 5.5-6.5.
Due to the utilization of technique scheme, the present invention compared with prior art has following advantages:
Of the present invention containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant; Have the following advantages:
1, dirt-removing power is strong
Long-chain fatty acid and natural amino acid form amido link to be had novel molecule and independently fills performance, about chelating being formed with a lot of molecule, strange selection chelating oil molecule is selected in oil water mixture, there is very strong dirt-removing power, and the dirt-removing power of N-lauroyl-ALANINE sodium salt is more better than N-lauroyl-Pidolidone disodium and N-lauroyl-L-sodium sarcosinate, can separately as cleansing.
2, there is the good compatibility
Articles for washing containing N-lauroyl-ALANINE natrium surfactant, the sense of touch when washing and after washing is all good, and skin can not be too dry and astringent and have tender sense of touch.
3, environmental protection
Its biological degradability of common surfactant and eco-compatibility poor, can work the mischief to ecological environment, its catabolite of N-lauroyl-ALANINE is that aminoacid and fatty acid almost do not affect environment.
4, little to the zest of skin
Emphasize oiliness skin or the special Cleansing Foam of male at present, the most frequently used cleansing is sodium lauryl sulphate, because being the extremely strong surfactant of degrease power for this reason, but it has potential zest to skin and descends rice to reduce making the defence capability of skin self for a long time, causes the phenomenon such as dermatitis, skin aging.Long-chain fatty acid before N-lauroyl-Pidolidone natrium surfactant is similar to dodecyl, there is same dirt-removing power, but because it is adopt natural component be raw material manufacture and obtain, composition itself can be adjusted to about faintly acid PH6.5-7, so very little to skin irritation, life-time service, misgivings can not be needed to have injury to skin, and anemia of pregnant woman and infant product are suitable for too.
5, cost is low
N-lauroyl-ALANINE belongs to ammonia propylhomoserin type surfactant, and on existing market, such surfactant is used for superior cosmetics, this is on the one hand because the pH value of this kind of surfactant and skin is close, nontoxic non-stimulated to skin, also because production cost is high, purity is low.And the production technology of N-lauroyl-ALANINE is simple and easy to get, the high purity product being greater than 98% can be prepared, the domestic vast demand to the type surfactant can be met.
Above-described embodiment is only for illustrating technical conceive of the present invention and feature; its object is to person skilled in the art can be understood content of the present invention and be implemented; can not limit the scope of the invention with this; all equivalences done according to spirit of the present invention change or modify, and all should be encompassed in protection scope of the present invention.

Claims (1)

1., containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant, it, relative to the percentage ratio of its quality, comprises:
N-lauroyl-ALANINE sodium salt or potassium salt, 10%-20%;
Cocos nucifera oil acyl Kaglutam, 1.0%-5.0%;
LAA, 1.0%-3.0%;
Cocoalkyl-betanin, 1.0%-5.0%;
The solution of 50% pyridine alkane keto carboxylic acid sodium, 1.0%-3.0%;
Glycerol monolaurate, 1.0%-2.0%;
Water, 70%-80%;
Hydrolysis hyaluronic acid, 0.1%-0.5%;
Phenoxyethanol, benzoic acid, dehydroactic acid and Sensiva SC50,1.0%-3.0%;
Propylene glycol and water and nettle extract, 1.0%-3.0%;
Spice, 1.0%-2.0%;
Citric acid is appropriate, makes product keep DI-I value 5.5-6.5.
CN201110375200.1A 2011-11-23 2011-11-23 A kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant Active CN103126939B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201110375200.1A CN103126939B (en) 2011-11-23 2011-11-23 A kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201110375200.1A CN103126939B (en) 2011-11-23 2011-11-23 A kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant

Publications (2)

Publication Number Publication Date
CN103126939A CN103126939A (en) 2013-06-05
CN103126939B true CN103126939B (en) 2016-02-17

Family

ID=48487822

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201110375200.1A Active CN103126939B (en) 2011-11-23 2011-11-23 A kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant

Country Status (1)

Country Link
CN (1) CN103126939B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106118914A (en) * 2016-07-08 2016-11-16 张健 A kind of aminoacid adult's liquid detergent
CN106109376A (en) * 2016-07-08 2016-11-16 张健 A kind of aminoacid baby has one's hair wash shower bubble
CN105997734A (en) * 2016-07-11 2016-10-12 广州丹奇日用化工厂有限公司 Shower gel containing artemisia seleirgensis extract
CN109350553B (en) * 2018-12-04 2021-10-22 浙江大学自贡创新中心 Mineral salt amino acid shower gel

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1059933A (en) * 1990-09-14 1992-04-01 大制药株式会社 Detergent composition

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5121187B2 (en) * 2006-08-28 2013-01-16 旭化成ケミカルズ株式会社 Skin flora improving agent

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1059933A (en) * 1990-09-14 1992-04-01 大制药株式会社 Detergent composition

Also Published As

Publication number Publication date
CN103126939A (en) 2013-06-05

Similar Documents

Publication Publication Date Title
JP7496099B2 (en) Thickened cleansing composition and its application and method of preparation
JP5548464B2 (en) Washing soap
CN103126925A (en) Hair shampoo with N-lauroyl-L-alanine sodium salt or potassium salt as surfactant
CN103126939B (en) A kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant
WO2013098066A3 (en) Aqueous hair and skin cleaning compositions comprising biotensides
JP6183849B2 (en) Skin cleanser composition
CN103126921B (en) A kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt handwashing liquid as surfactant
WO2013131307A1 (en) Transparent beauty soap composition
CN103720595A (en) Amino acid type pearly facial cleansing foam composition and preparation method thereof
CN106176438A (en) A kind of U.S. flesh skin care bath gel
CN103690394A (en) Anionic surfactant-free bubble bath agent
JPWO2016067853A1 (en) Shampoo composition
CN105616250A (en) Bath lotion
CN105828792A (en) Cosmetic composition
JP6103210B2 (en) Skin cleanser composition
CN103126926B (en) A kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt cleansing milk as surfactant
CN109806203A (en) A kind of shampoo of the extract of floral leaf containing industrial hemp
CN103637931B (en) A kind of clean mousse and preparation method thereof
CN103767885B (en) A kind of shampoo
CN108785175A (en) A kind of Chinese herbal medicine bath lotion and preparation method thereof
CN106265110B (en) Surfactant composition
CN103948519A (en) Multifunctional shampoo
CN108324593A (en) A kind of high stability amino acid surfactant composition, Pearly-lustre type paste Sodium Glycinate facial cleanser
CN108056984A (en) A kind of shower cream
JP2014108987A (en) Thickner for surfactants, detergent composition and hair washing agent composition

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
PP01 Preservation of patent right
PP01 Preservation of patent right

Effective date of registration: 20180925

Granted publication date: 20160217

PD01 Discharge of preservation of patent
PD01 Discharge of preservation of patent

Date of cancellation: 20181123

Granted publication date: 20160217