WO2013178684A2

WO2013178684A2 - Composition containing amino acid surfactants, betaines and n-methyl-n-acylglucamines and having improved foam quality and higher viscosity

Info

Publication number: WO2013178684A2
Application number: PCT/EP2013/061076
Authority: WO
Inventors: Peter Klug; Carina Mildner
Original assignee: Clariant International Ltd.
Priority date: 2012-05-30
Filing date: 2013-05-29
Publication date: 2013-12-05
Also published as: BR112014029757A2; JP2015523973A; CN104540551A; EP2854951B1; WO2013178684A3; EP2854951A2; US20150141466A1; JP6473414B2; US9452121B2; IN2014DN09931A

Abstract

The invention relates to a composition which contains at least one N-acyl-amino acid surfactant, a betaine surfactant, an N-methyl-N-acylglucamine, said N-methyl-N-acylglucamine having a C₁₆-C₂₀-acyl group, and further contains a solvent and optionally one or more additives. The invention also relates to a method for producing the composition. The invention further relates to the use of the composition for the treatment or care of skin or hair, or for use as a shampoo, face cleaner, liquid cleaner or shower gel.

Description

Composition containing amino acid surfactants, betaines and N-methyl-N-acylglucamine having improved foam quality and higher viscosity

The invention relates to a composition comprising at least one N-acyl amino acid surfactant, a betaine surfactant, an N-methyl-N-acylglucamine, a solvent and optionally one or more additives and a process for the preparation of the composition. Furthermore, the invention relates to the use of the composition for the treatment or care of the skin or hair or as a shampoo, facial cleanser, liquid cleanser or shower bath.

The production of liquid products in the cosmetics and detergents sector is steadily increasing. Especially in the field of body cleansers, it is the liquid hair shampoos, bubble baths and shower baths that have become increasingly important in recent years. Liquid dishwashing detergents and liquid mild detergents have also gained a firm place in the market. It is important for the various applications to adjust a corresponding viscosity, which is achieved by the addition of thickening agents. Ideally, only small amounts of thickening agents or thickeners are necessary.

EP 0 285 786 describes uses of N-polyhydroxyalkyl fatty acid amides as thickeners for liquid aqueous surfactant systems. This problem has been solved by using N-polyhydroxyalkyl fatty acid amides of the general formula I.

in the Ri is an optionally branched alkyl radical having 1 to 17, preferably 7 to 17 carbon atoms,

P _{2 is} hydrogen, an optionally branched, optionally unsaturated, alkyl radical having 1 to 18, preferably 1 to 6 carbon atoms or a radical - ~ CH | - CH - 0) _n H

with n = 0 or 1 to 5 and R ₃ can be hydrogen or -CH ₃ and X is a polyhydroxyalkyl radical having 4 to 7 carbon atoms, which is optionally glycosidically linked to a mono-, di- or oligosaccharide radical, as a thickener for liquid aqueous surfactant systems. However, this patent does not describe the thickening of amino acid surfactants and used as a thickening agent an N-acyl-N- Methylglucamintensid with an alkyl chain distribution of coconut oil and thus with a small proportion of long-chain _C16-C20 glucamides.

WO 98/56496 relates to a surfactant composition having improved foam stability. The surfactant composition comprises: (a) from about 1 to about 40% by weight of a sugar surfactant; (b) from about 1 to about 40% by weight of an anionic surfactant; (c) from about 0.11 to about 10% by weight of an amphoacetate; and (d) balance water, wherein the weights are by weight of the composition.

A prerequisite for a good surfactant formulation is a good storage stability. The composition must not cloud or form deposits in the event of temperature fluctuations and should have a viscosity which can be adapted to the respective application. Thus, the viscosity is a quality criterion. The degree of viscosity depends on the surfactant system and the electrolyte additive. It is known that the thickening agents known from the prior art in the presence of paraffin sulfonates do not show a sufficient increase in viscosity (see Fette - Seifen - Anstrichmittel 78, 200, (1976)). In contrast, amino acid surfactants such as acylglycinates, acylaspartates or acylglutamates are in spite of their good skin compatibility in many cases not sufficiently thickenable and were previously therefore not useful as a primary surfactant because of the high. It has surprisingly been found that longer-chain, but not shorter-chain, N-acyl-N-methylglucamines are suitable as excellent cosurfactants with high thickening power for compositions containing amino acid surfactants.

The object of the present invention is thus to provide improved compositions, in particular with regard to an improved viscosity adjustment.

Accordingly, there is provided a composition comprising: (A) at least one N-acyl-amino acid surfactant as component A,

(B) at least one betaine surfactant as component B,

(C) at least one N-methyl-N-acylglucamine as component C, where the N-methyl-N-acylglucamine has a C 16-C 20 -acyl radical,

(D) at least one solvent as component D, and

(E) optionally one or more additives as component E.

The composition according to the invention advantageously has an increased viscosity.

Further terms for N-methyl-N-acylglucamine are N-methyl-N-1-deoxysorbitol fatty acid amide, N-acyl-N-methyl-glucamine, glucamide or N-methyl-N-alkylglucamide. In this case, N-methyl-N-acylglucamine corresponds to the formula (X), where R is an organic radical:

(X)

By an N-acyl-amino acid surfactant is meant, for example, an acylated amino acid.

In a preferred embodiment, the composition contains:

(A) 5-15% by weight of component A,

(B) 1 - 10 wt .-% of component B,

(C) 1-10% by weight of component C,

(D) 10-93% by weight of a protic solvent as component D, and

(E) 0-10% by weight of component E,

wherein the sum of the components A to E gives 100 wt .-%. The composition preferably consists of (A) 5-15% by weight of component A,

(B) 1 - 10 wt .-% of component B,

(C) 1-10% by weight of component C,

(D) 10-93% by weight of a protic solvent as component D, and

(E) 0-10% by weight of component E,

wherein the sum of the components A to E gives 100 wt .-%.

In a preferred embodiment, the amino acid residue of component A is selected from the group consisting of proteinogenic amino acids, their N-alkylated derivatives or mixtures thereof.

Preferred as component A are acylglycinates, acylalaninates, acylaspartates, acylglutamates and acylsarcosinates, especially sodium cocoyl-glycinate, potassium cocoylglycinate, sodium lauroylglycinate, potassium lauroylglycinate,

Sodium cocoyl glutamate, sodium lauroyl glutamate, sodium cocoyl aspartate,

Sodium lauroyl aspartate and sodium lauroyl sarcosinate.

In a preferred embodiment, component A consists of at least one C8-C22-acylated amino acid, in particular its N-alkylated derivatives. Preference is given to the corresponding lauroyl or cocoyl derivatives of the amino acids.

In a preferred embodiment, component A is selected from the group consisting of acylglycinate, acyl aspartate, acylglutamate, acylsarcosinate or mixtures thereof.

In a preferred embodiment, component B comprises at least one alkyl betaine and / or at least one alkylamidobetaine.

Examples of suitable alkylbetaines are the carboxyalkylation products of secondary and in particular tertiary amines of the formula (III)

R ³

R ⁴ (III) in the R ^{2 are} alkyl and / or alkenyl radicals having 6 to 22 carbon atoms, R ^{3 is} hydrogen or alkyl radicals having 1 to 4 carbon atoms, R ^{4 is} hydrogen or alkyl radicals having 1 to 4 carbon atoms, n is from 1 to 6 and Z is from represents an alkali and / or alkaline earth metal or ammonium. Typical examples are the carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, dodecylmethylamine, dodecyldimethylamine, dodecylethylmethylamine, C 12/14 cocoalkyldimethylamine, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, stearylethylmethylamine, oleyldimethylamine, C 16/18 tallowalkyldimethylamine, and the like technical mixtures.

Examples of suitable alkylaminobetains are carboxyalkylation products of amidoamines. Particularly suitable are amidopropylbetaines of the formula (IV)

wherein R ^{5 is} a linear or branched saturated C7-C21 alkyl group or a linear or branched mono- or polyunsaturated C7-C21 alkenyl group.

Preferred betaine surfactants are amidopropylbetaines such as cocoamidopropylbetaine (R ⁵ CO is the fatty acid residue of coconut oil, chain length Cs-Cis) and alkylbetaines such as coco-betaine (R ² is the alkyl residue of coconut oil, chain length Cs-Cis) or laurylbetaine (R ² is an alkyl radical of Chain length Ci ₂ and C ₁₄ ).

In a preferred embodiment, the component C consists of a mixture of N-methyl-N-acylglucaminen, wherein at least 80 wt .-% of N-methyl-N-acylglucamine have a saturated or unsaturated C ₁₆ - or cis-acyl radical. For example, N-methyl-N-acylglucamine may also be present in the mixture, which have a Ci4-acyl radical, but at least 80 wt .-% of N-methyl-N-acylglucamine have a saturated or unsaturated C ₁₆ - or cis-acyl radical , Preferably, the component C consists of a mixture of N-methyl-N-acylglucaminen, wherein at least 90 wt .-% of N-methyl-N-acylglucamine have a saturated or unsaturated C ₁₆ - or cis-acyl radical. A solvent in the context of the present invention is preferably understood to mean protic solvents such as water, C ₁ -C ₈ -alcohols, in particular C ₁ -C ₆ -alcohols, ethylene glycol, diethylene glycol, triethylene glycol or mixtures thereof, in particular water and / or ethanol or water and / or methanol are preferred. Of the C ₁ -C 6 -alcohols, preference is given to methanol, ethanol, isopropanol, n-butanol or sec-butanol.

In a preferred embodiment, the solvent of component D is water or a mixture of water and propylene glycol.

In a preferred embodiment, the composition is free of alkyl sulfates and / or alkyl ether sulfates. In this case, free means that the composition contains less than 3% by weight, based on the total amount of the composition, preferably less than 0.5% by weight, and in particular no alkyl sulfates and / or alkyl ether sulfates.

Within the scope of a preferred embodiment, the sum of the components A, B, and C is from 7 to 20% by weight, preferably from 8 to 18% by weight, and in particular from 10 to 15% by weight.

In a preferred embodiment, the additives are selected from the group consisting of preservatives, fragrances, dyes, other surfactants, water, oil bodies, cationic polymers, film formers, thickening and gelling agents, superfatting agents, antimicrobial and biogenic agents, moisturizing agents, stabilizers, acids, Alkalis, active enhancers and mixtures thereof, preferably in amounts of 0.1 to 10.0 wt .-%, particularly preferably from 0.5 to 8.0 wt .-% and in particular from 1.0 to 5.0 wt. -%. Suitable preservatives are listed in the relevant annex of European cosmetics legislation preservatives, such as phenoxyethanol, benzyl alcohol, parabens, benzoic acid and sorbic acid, is particularly well suited, for example, 1, 3-bis (hydroxymethyl) -5,5-dimethylimidazolidine-2,4-diones ( Nipaguard DMDMH ^®), piroctone olamine, methylisothiazolinone, or mixtures thereof, preferably piroctone olamine and / or methylisothiazolinone. As perfumes or perfumes or oils individual fragrance compounds, eg. As the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons are used. Fragrance compounds of the ester type are e.g. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate, phenylethylacetate, linalylbenzoate, benzylformate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate and benzylsalicylate. The emers include, for example, benzyl ethyl ether, to the aldehydes z. B. the linear alkanals having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclic aldehyde, Hydroxycitronellal, Lilial and Bourgeonal, to the ketones z. The alcohols include anethole, citronellol, eugenol, geranion, linalol, phenylethyl alcohol and terpineol; the hydrocarbons include, but are not limited to, the terpenes and balsams. Preferably, mixtures of different fragrances are used, which together produce an attractive fragrance.

Perfume oils may also contain natural fragrance mixtures, such as those available from plant or animal sources, e.g. Pine, citrus, jasmine, lily, rose, or ylang-ylang oil. Also essential oils of lower volatility, which are mostly used as aroma components, are suitable as perfume oils, eg. B. sage oil, camomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, oliban oil, galbanum oil and ladanum oil.

The desired viscosity of the compositions can be adjusted (increased or decreased) by adding thickeners and gelling agents. Cellulose ethers and other cellulose derivatives (for example carboxymethylcellulose, hydroxyethylcellulose), gelatin, starch and starch derivatives, sodium alginates, fatty acid polyethylene glycol esters, agar-agar, tragacanth or dextrin derivatives, in particular dextrin esters, are preferably suitable. Also suitable are metal salts of fatty acids, preferably having 12 to 22 carbon atoms, for example sodium stearate, sodium palmitate, sodium laurate, sodium arachidates, sodium behenate, potassium stearate, potassium palmitate, sodium myristate, aluminum monostearate, hydroxyfatty acids, for example 12-hydroxystearic acid, 16-hydroxyhexadecanoic acid; fatty acid amides; fatty acid; Dibenzal sorbitol and alcohol-soluble polyamides and polyacrylamides or mixtures thereof. Furthermore, crosslinked and uncrosslinked polyacrylates such as carbomer, sodium polyacrylate or sulfonic acid-containing polymers such as AmmoniumacryloyldimethyltaurateA ^ P copolymer find use.

Antimicrobial agents include cetyltrimethylammonium chloride, cetylpyridinium chloride, benzethonium chloride, diisobutylethoxyethyldimethylbenzylammonium chloride, sodium N-laurylsarcosinate, sodium N-palmethyl sarcosinate, lauroylsarcosine, N-myristoylglycine, potassium N-laurylsarcosine, trimethylammonium chloride,

Sodium aluminum chlorohydroxylactate, triethyl citrate, tricetylmethylammonium chloride, 2,4,4'-trichloro-2'-hydroxydiphenyl ether (triclosan), phenoxyethanol, 1,5-pentanediol, 1,6-hexanediol, 3,4,4'-trichlorocarbanilide (triclocarban), diaminoalkylamide for example L-lysine hexadecylamide, citrate heavy metal salts, salicylates, piroctose, in particular zinc salts, pyrithiones and their heavy metal salts, in particular zinc pyrithione, zinc phenol sulfate, farnesol, ketoconazole, oxiconazole, bifonazoles, butoconazoles, cloconazoles, clotrimazoles, econazoles, enilconazoles, fenticonazoles, isoconazoles, miconazoles, sulconazoles , Tioconazole, fluconazole, itraconazole, terconazole, naftifine and terbinafme, selenium disulfide and octopirox, iodopropynyl butylcarbamate, methylchloroisothiazolinone, methylisothiazolinone, methyldibromo glutaronitrile, AgCl, chloroxylenol, sodium salt of diethylhexylsulfosuccinate, sodium benzoate, and phenoxyethanol, benzyl alcohol, phenoxyisopropanol, parabens, preferably butyl , Ethyl, methyl u and propylparaben, and their Na salts, pentanediol, 1,2-octanediol, 2-bromo-2-nitropropane-1,3-diol, ethylhexylglycerol, benzyl alcohol, sorbic acid, benzoic acid, lactic acid, imidazolidinyl urea, diazolidinyl urea, dimethyloldimethylhydantoin (DMDMH), Na salt of hydroxymethylglycinate, hydroxyethylglycine of sorbic acid and combinations of these active substances are used.

The compositions of the invention may further contain biogenic agents selected from plant extracts such as aloe vera, as well as local anesthetics, antibiotics, antiphlogistics, antiallergic agents, corticosteroids, sebostatics, Bisabolol®, Allantoin®, Phytantriol®, proteins, vitamins selected from niacin, biotin, vitamin B2 , Vitamin B3, Vitamin B6, Vitamin B3 derivatives (salts, acids, esters, amides, alcohols), Vitamin C and Vitamin C derivatives (salts, acids, esters, amides, alcohols), preferably as the sodium salt of the monophosphoric acid ester of ascorbic acid or as the magnesium salt of the phosphoric acid ester of ascorbic acid, tocopherol and tocopherol acetate, as well as vitamin E and / or its derivatives. As stabilizers metal salts of fatty acids, such as. As magnesium, aluminum and / or zinc stearate.

For example, isopropyl palmitate, glycerol and / or sorbitol are available as a moisturizing substance. Particularly preferred is sorbitol.

Furthermore, the compositions of the invention may contain film formers, which are selected depending on the application of salts of phenylbenzimidazole sulfonic acid, water-soluble polyurethanes, for example Cio Polycarbamylpolyglycerylester, polyvinyl alcohol, Polyvinylpyrrolidoncopolymeren such as PVP / hexanecenes or PVP / eicosene copolymer, for example vinylpyrrolidone / vinyl acetate copolymer, water-soluble acrylic acid polymers Or copolymers or their esters or salts, for example partial ester copolymers of acrylic / methacrylic acid and polyethylene glycols of fatty alcohols, such as acrylate / steareth-20-methacrylate copolymer, water-soluble cellulose, for example hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, water-soluble quaternium, polyquaternium, Carboxyvinyl polymers, such as carbomers and their salts, polysaccharides, for example polydextrose and glucan, vinyl acetate / crotonate, for example under the trade name Aristoflex ^® A 60 (Clariant) available, and polymeric amine oxides, for example, under the trade names Diaformer Z-71 1, 712, 731, 751 available representatives.

Lanolin and lecithin, non-ethoxylated and polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, mono-, di- and triglycerides and / or fatty acid alkanolamides, the latter also serving as foam stabilizers, may preferably be used as superfatting agents.

As acids or alkalis for pH adjustment preferably mineral acids, in particular HCl, inorganic bases, in particular NaOH or KOH, or organic acids, in particular lactic acid, are used.

The active enhancer used may preferably be sorbitan caprylate.

In a preferred embodiment, the composition is a cosmetic, dermatological or pharmaceutical composition. The invention further provides a process for preparing the composition according to the invention, comprising the steps of: a) mixing the component E with D to form a solution,

b) adding component A to the solution from a)

c) mixing component D with, if appropriate, another component E, preferably a humectant, and then adding it to the solution from step b),

d) addition of component B and C, in particular successively, to the solution from c) and

e) adjusting the composition to a pH of 6.8 to 7.5.

In a further variant, the composition according to the invention is prepared by

(A) 5-15% by weight of component A,

(B) 1 - 10 wt .-% of component B,

(C) 1-10% by weight of component C,

(D) 10 to 93% by weight of a protic solvent as component D and

(E) 0-10% by weight of component E,

the sum of components A to E being 100% by weight.

Another object of the invention is the use of the composition of the invention as a shampoo, facial cleanser, liquid cleanser or shower.

Another object of the invention is the use of the composition according to the invention for the treatment or care of the skin.

Another object of the invention is the use of the composition according to the invention for the treatment or care of the hair.

The invention is further illustrated by the following examples. Preparation Example Hl and H2, Example 1 and Comparative Examples 1 and 2

The N-acyl-N-methyl-glucamines described below were prepared according to EP 0 550 637 from the corresponding fatty acid methyl esters and N-methylglucamine in the presence of 1,2-propylene glycol as the solvent and obtained as a solid consisting of active substance and 1,2-propylene glycol.

Table 1

C 12/14 means that the methyl ester consists of a mixture of methyl laurate (C ₂ -acyl radical) and methyl myristate (C ₄ -acyl radical) (ratio 75:25). C16 / 18 means that the methyl ester consists of a mixture of methyl palmitate (C ₆ -acyl radical) and stearic acid methyl ester (cis-acyl radical) (ratio 30:70). C 16/18 'means that the methyl ester consists of a mixture of methyl palmitate, stearic acid methyl ester, oleic acid methyl ester and methyl linoleate (ratio 30: 10: 50: 10).

The viscosities are measured with a Brookfield Viscometer Model DV II, the spindles from the spindle set RV at 20 revolutions / minute and 20 ° C. The spindles 1 to 7 from the spindle set RV are used. Under these measuring conditions, spindle 1 for viscosities of at most 500 mPa · s, spindle 2 for viscosities of at most 1,000 mPa · s, spindle 3 for viscosities of at most 5,000 mPa · s, spindle 4 for viscosities of at most 10,000 mPa · s Spindle 5 for viscosities of not more than 20,000 mPa · s, spindle 6 for viscosities of not more than 50,000 mPa · s and spindle 7 for viscosities of not more than 200,000 mPa · s.

In the following test formulation, the N-acyl-methylglucamine according to preparation example H2 and H3 was tested in comparison with preparation example HI and in comparison with alkylpolyglucosides. Preparation Method

I mixing the components E ^(® Octopirox (Clariant)) and D (water).

II Add component A to I and then stir until the solution is clear.

III Mix the components D (water) and E (sorbitol) and then stir until the solution is clear.

IV addition of III to II and homogenization. V Successive addition of components B (Genagen KB (Clariant)), C (sugar surfactant) and E (Velsan ^® SC (Clariant)) to IV and then stirring until the solution is clear.

VI Adjusting the pH by means of component E (lactic acid) to a value of

7.0 - 7.2.

VII addition of component E (SkyBio ^® M500) to VII, homogenizing. The composition and preparation are summarized in Table 2.

Table 2: Mild hair shampoo

Step Component Name Property

IE Octopirox ^® (Clariant) Konservier0.10%

Piroctone olamine

D water solvent 10.00%

II A SG Hostapon ^® (Clariant) 7.50% Surfactant

(25% solution in water, (surfactant)

calculated on active content)

Sodium cocyl glycinate

III D water solvent ad 100%

E sorbitol moistening1.00% medium

IV B Genagen ^® KB (Clariant) Co -Surfactant 4.50%

(30% solution in water, (surfactant)

calculated on active content)

Coco-Betaine

C sugar surfactant Co-surfactant 4.80%

(Surfactant)

E Velsan ^® SC (Clariant) Enhancer 1.00%

Sorbitan Caprylate

V E lactic acid, 25% neutralizer to pH =

7

VI E SkyBio ^® M500 Conserve0.02%

Methyl isothiazolone lenon Table 3

The use amount of sugar surfactant of 4.8% refers to the active content of the surfactant, d. H. the amount of coco glucoside (Plantacare 818 / BASF SE) corresponds to 9.23% as a commercial product. The N-acyl-N-methylglucamines were used based on the active content of Table 1.

As is apparent from Examples 1 and 2, C16 / 18N-acyl-N-methylglucamine show excellent thickening performance over both short-chain N-acyl-N-methylglucamines (Comparative Example 1) and alkylpolyglucosides (Comparative Example 2).

In addition, the formulations are viscosity-stable even at low temperatures.

Claims

claims

1. Composition comprising:

(A) at least one N-acyl-amino acid surfactant as component A,

(B) at least one betaine surfactant as component B,

(D) at least one solvent as component D and

(E) optionally one or more additives as component E.

2. The composition of claim 1, comprising:

(A) 5-15% by weight of component A,

(B) 1 - 10 wt .-% of component B,

(C) 1-10% by weight of component C,

(D) 10 to 93% by weight of a protic solvent as component D and

(E) 0-10% by weight of component E,

wherein the sum of the components A to E gives 100 wt .-%.

3. The composition according to any one of claims 1 or 2, characterized in that the amino acid residue of the component A is selected from the group consisting of proteinogenic amino acids, their N-alkylated derivatives and mixtures thereof.

4. Composition according to one of claims 1 to 3, characterized in that component A consists of at least one C8-C22-acylated amino acid.

5. The composition according to any one of claims 1 to 4, characterized in that component A is selected from the group consisting of acylglycinate, acyl aspartate, acylglutamate, acylsarcosinate or mixtures thereof.

6. The composition according to any one of claims 1 to 5, characterized in that component B comprises at least one alkyl betaine and / or at least one Alkylamidobetain.

7. The composition according to any one of claims 1 to 6, characterized in that component C consists of a mixture of N-methyl-N-acylglucaminen, wherein at least 80 wt .-% of N-methyl-N-acylglucamine a saturated or unsaturated C ₁₆ - or cis-acyl radical.

8. The composition according to any one of claims 1 or 7, characterized in that the solvent of the component D is water or a mixture of water and propylene glycol.

9. Composition according to one of claims 1 to 8, characterized in that the composition is free of alkyl sulfates and / or alkyl ether sulfates.

10. The composition according to any one of claims 1 to 9, characterized in that the sum of the components A, B, and C of 7 to 20 wt .-% is.

1 1. A composition according to any one of claims 1 to 10, characterized in that the additives from the group consisting of preservatives, fragrances, dyes, other surfactants, water, oil bodies, cationic polymers, film formers, thickening and gelling agents, superfatting agents, antimicrobial and biogenic agents, moisturizing agents, stabilizers, acids, alkalis, potentiators and mixtures thereof.

12. The composition according to any one of claims 1 to 1 1, characterized in that it is the composition of a cosmetic, dermatological or pharmaceutical composition.

13. A process for the preparation of the composition according to any one of claims 1 to 12, comprising the steps:

a) mixing the component E with D to form a solution,

b) adding component A to the solution from a)

c) mixing of component D with optionally a further component E and subsequent addition to the solution from step b),

d) adding component B and C to the solution of c) and

e) adjusting the composition to a pH of 6.8 to 7.5.

14. Use of the composition according to any one of claims 1 to 12 as a shampoo, facial cleanser, liquid cleanser or shower.

15. Use of the composition according to any one of claims 1 to 12 for the treatment or care of the skin.

16. Use of the composition according to any one of claims 1 to 12 for the treatment or care of the hair.