CN114806725A - Efficient household cleaning agent and preparation method thereof - Google Patents
Efficient household cleaning agent and preparation method thereof Download PDFInfo
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- CN114806725A CN114806725A CN202210407441.8A CN202210407441A CN114806725A CN 114806725 A CN114806725 A CN 114806725A CN 202210407441 A CN202210407441 A CN 202210407441A CN 114806725 A CN114806725 A CN 114806725A
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 63
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 102000004190 Enzymes Human genes 0.000 claims abstract description 26
- 108090000790 Enzymes Proteins 0.000 claims abstract description 26
- 239000004094 surface-active agent Substances 0.000 claims abstract description 25
- 239000002738 chelating agent Substances 0.000 claims abstract description 24
- 239000003086 colorant Substances 0.000 claims abstract description 24
- 239000000796 flavoring agent Substances 0.000 claims abstract description 24
- 235000013355 food flavoring agent Nutrition 0.000 claims abstract description 24
- 239000000843 powder Substances 0.000 claims abstract description 24
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 21
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims abstract description 21
- 239000008367 deionised water Substances 0.000 claims abstract description 21
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 21
- 239000001257 hydrogen Substances 0.000 claims abstract description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 21
- 229940119170 jojoba wax Drugs 0.000 claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 14
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011777 magnesium Substances 0.000 claims abstract description 11
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims description 57
- 238000003756 stirring Methods 0.000 claims description 25
- 238000010438 heat treatment Methods 0.000 claims description 22
- 238000009210 therapy by ultrasound Methods 0.000 claims description 12
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 6
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 6
- 239000004382 Amylase Substances 0.000 claims description 3
- 102000013142 Amylases Human genes 0.000 claims description 3
- 108010065511 Amylases Proteins 0.000 claims description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 3
- 108091005804 Peptidases Proteins 0.000 claims description 3
- 239000004365 Protease Substances 0.000 claims description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 3
- 235000019418 amylase Nutrition 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 2
- 235000015165 citric acid Nutrition 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical class C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 2
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 claims description 2
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims description 2
- -1 polyoxyethylene lauryl ether Polymers 0.000 claims description 2
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- CDOUZKKFHVEKRI-UHFFFAOYSA-N 3-bromo-n-[(prop-2-enoylamino)methyl]propanamide Chemical compound BrCCC(=O)NCNC(=O)C=C CDOUZKKFHVEKRI-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 239000003599 detergent Substances 0.000 abstract description 13
- 238000005406 washing Methods 0.000 description 17
- 239000004744 fabric Substances 0.000 description 8
- 239000006260 foam Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 210000002189 macula lutea Anatomy 0.000 description 2
- 229910012375 magnesium hydride Inorganic materials 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 206010025421 Macule Diseases 0.000 description 1
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a high-efficiency household cleaning agent and a preparation method thereof, and relates to the technical field of detergents. The efficient household cleaning agent comprises the following raw materials in parts by weight: 20-35 parts of surfactant, 0.5-3 parts of chelating agent, 2-10 parts of hydrogen peroxide, 0.5-1.5 parts of sodium bicarbonate, 2-7 parts of jojoba oil, 0.05-0.1 part of magnesium hydrogen powder, 1.5-2 parts of biological enzyme, 0-0.05 part of coloring agent, 0-0.01 part of flavoring agent and 70-85 parts of deionized water. The high-efficiency household cleaning agent can effectively remove yellow spots and mildew on clothes.
Description
Technical Field
The invention relates to the technical field of detergents, in particular to a high-efficiency household cleaning agent and a preparation method thereof.
Background
The detergent is one of the necessities of daily life. The liquid laundry detergent as one of the detergents is a liquid laundry detergent, has components similar to those of washing powder, and is suitable for washing heavy-duty fabrics such as underwear, bedding, bed sheets and the like. It has good water solubility, can be quickly dissolved in cold water, and can fully play a role. The detergent has the advantages of convenient use, rapid dissolution, good low-temperature washing effect, mildness to fabrics and skin and the like, so the detergent keeps strong growth in recent years, and the market yield and sales volume rapidly rise, thereby becoming the main direction of detergent development.
If the surface of the clothes has residues such as ink, residual milk, grease and the like, the problems of yellow spots, mildewing and the like can occur if the clothes are not cleaned for a long time. At present, general cleaning agents in the market cannot effectively remove yellow spots and mildew spots remained on clothes for a long time. Therefore, how to obtain a cleaning agent capable of effectively removing the macula lutea and the mildew becomes a research hotspot in the industry.
Disclosure of Invention
In order to solve the problem that common cleaning agents in the market mentioned in the background technology can not effectively remove residual yellow spots and mildew spots on clothes for a long time, the invention provides a high-efficiency household cleaning agent which can effectively remove the yellow spots and the mildew spots on the clothes, and the specific scheme is as follows:
an efficient household cleaning agent comprises the following raw material components in parts by weight: 20-35 parts of surfactant, 0.5-3 parts of chelating agent, 2-10 parts of hydrogen peroxide, 0.5-1.5 parts of sodium bicarbonate, 2-7 parts of jojoba oil, 0.05-0.1 part of magnesium hydrogen powder, 1.5-2 parts of biological enzyme, 0-0.05 part of coloring agent, 0-0.01 part of flavoring agent and 70-85 parts of deionized water.
In the implementation of the above embodiment, preferably, the surfactant is one or more of sodium lauryl sulfate, polyoxyethylene lauryl ether, fatty acid methyl ester ethoxylate sulfonate, and sodium dioctyl sulfosuccinate.
In carrying out the above embodiment, preferably, the chelating agent is one or more of citric acids, organic phosphonates, ethylenediaminetetraacetic acid, glutamic diacetic acid, and glycine diacetic acid.
In the implementation of the above embodiment, preferably, the mass concentration of the hydrogen peroxide is 8% to 35%.
In the above embodiment, preferably, the biological enzyme is one or more of protease, amylase and citrate.
In carrying out the above embodiment, preferably, the colorant is a pigment.
In carrying out the above embodiment, preferably, the flavoring agent is a perfume.
The preparation method of the efficient household cleaning agent comprises the following steps:
step one, mixing sodium bicarbonate, jojoba oil, hydrogen powder and deionized water, and performing microwave treatment to obtain a first mixture;
step two, adding a chelating agent and a surfactant into the first mixture, and heating and stirring to obtain a second mixture;
adding hydrogen peroxide into the second mixture, heating and stirring to obtain a third mixture;
and step four, adding biological enzyme, a coloring agent and a flavoring agent into the third mixing step five, and performing ultrasonic treatment to obtain the high-efficiency household cleaning agent.
When the above embodiment is implemented, preferably, in the step one, the microwave treatment is performed for 15-20min, and the microwave power is 800-; in the fourth step, the ultrasonic treatment is carried out for 1.2-1.4h, and the ultrasonic power is 700- & lt 800 & gt W.
In the implementation of the above embodiment, preferably, in the second step and the third step, the temperature of heating and stirring is 58-60 ℃, the stirring time is 1-2h, and the rotation speed is 150-.
Compared with the prior art, the invention has the advantages that:
1. in the raw material components, sodium lauryl sulfate is used as a surfactant to increase the washing capacity and increase the foam generation, and the amphiphilic compound molecular structure is obtained by compounding the sodium lauryl sulfate and biological enzyme, so that the foam is favorably formed, and the foam can be foamed at a lower dosage. By generating abundant foams, the effective components in the components can quickly contact and react with the stains, so that the stains can be effectively removed.
2. The raw material components of the invention are added with hydrogen peroxide which is used as the source of active oxygen, so as to ensure the oxygen bleaching effect of the laundry detergent, wherein the hydrogen peroxide can remove various stains by oxidation and is converted into harmless water after the action is exerted. In addition, the amphiphilic compound obtained by compounding the sodium lauryl sulfate and the biological enzyme can generate abundant foam, and the abundant foam contains hydrogen peroxide which can contact residues in a large area, so that the macula lutea and mildew stains remained for a long time can be cleaned more easily.
3. The sodium bicarbonate and the magnesium hydride powder are added into the raw material components, the sodium bicarbonate can accelerate the permeation of foam to the fabric, and the magnesium hydride powder in the foam can adsorb clothes residues to further clean residual yellow spots and mildew spots on the clothes.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are some embodiments of the present invention, but not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
It should be noted that the reagents or apparatuses used in the examples are not indicated by the manufacturer, but those not indicated by the specific techniques or conditions described in the literature in the art or by the specifications of the products are all conventional products commercially available.
Some of the reagents used in examples 1-8 are illustrated below:
the surfactant is sodium lauryl sulfate;
the chelating agent is ethylenediamine tetraacetic acid;
the mass concentration of the hydrogen peroxide is 8 percent;
the mass ratio of protease to amylase to citrate enzyme is 6: 4: 5;
colorant: a pigment;
flavoring agent: and (4) essence.
In order that those skilled in the art may readily practice the invention, the following examples are provided for illustration.
Example 1
An efficient household cleaning agent comprises the following raw material components in parts by weight: 20 parts of surfactant, 3 parts of chelating agent, 10 parts of hydrogen peroxide, 1.5 parts of sodium bicarbonate, 7 parts of jojoba oil, 0.1 part of magnesium hydrogen powder, 2 parts of biological enzyme, 0.05 part of colorant, 0.01 part of flavoring agent and 85 parts of deionized water.
According to the proportion, the preparation method comprises the following steps:
mixing sodium bicarbonate, jojoba oil, hydrogen powder and deionized water, and performing microwave treatment for 15min at the microwave power of 1000W to obtain a first mixture;
step two, adding a chelating agent and a surfactant into the first mixture, heating and stirring at 58 ℃ for 2h at a rotation speed of 200r/min to obtain a second mixture;
adding hydrogen peroxide into the second mixture, heating and stirring at 58 ℃ for 2h at the rotating speed of 200r/min to obtain a third mixture;
and step four, adding biological enzyme, a coloring agent and a flavoring agent into the third mixing step five, and carrying out ultrasonic treatment on the mixture for 1.2 at the ultrasonic power of 800W to obtain the high-efficiency household cleaning agent.
Example 2
An efficient household cleaning agent comprises the following raw material components in parts by weight: 35 parts of surfactant, 0.5 part of chelating agent, 10 parts of hydrogen peroxide, 1.5 parts of sodium bicarbonate, 7 parts of jojoba oil, 0.1 part of magnesium hydrogen powder, 2 parts of biological enzyme, 0.05 part of colorant, 0.01 part of flavoring agent and 85 parts of deionized water.
According to the proportion, the preparation method comprises the following steps:
mixing sodium bicarbonate, jojoba oil, hydrogen powder and deionized water, and performing microwave treatment for 20min at the microwave power of 800W to obtain a first mixture;
step two, adding a chelating agent and a surfactant into the first mixture, heating and stirring at the temperature of 60 ℃ for 1h at the rotating speed of 150r/min to obtain a second mixture;
adding hydrogen peroxide into the second mixture, heating and stirring at 60 ℃, stirring for 1h and at the rotating speed of 150r/min to obtain a third mixture;
and step four, adding biological enzyme, a coloring agent and a flavoring agent into the third mixing step five, and carrying out ultrasonic treatment for 1.4h with the ultrasonic power of 700W to obtain the high-efficiency household cleaning agent.
Example 3
An efficient household cleaning agent comprises the following raw material components in parts by weight: 35 parts of surfactant, 3 parts of chelating agent, 2 parts of hydrogen peroxide, 1.5 parts of sodium bicarbonate, 7 parts of jojoba oil, 0.1 part of magnesium hydrogen powder, 2 parts of biological enzyme, 0.05 part of colorant, 0.01 part of flavoring agent and 85 parts of deionized water.
According to the proportion, the preparation method comprises the following steps:
mixing sodium bicarbonate, jojoba oil, hydrogen powder and deionized water, and performing microwave treatment for 15min at the microwave power of 1000W to obtain a first mixture;
step two, adding a chelating agent and a surfactant into the first mixture, heating and stirring at 58 ℃ for 2h at a rotation speed of 200r/min to obtain a second mixture;
adding hydrogen peroxide into the second mixture, heating and stirring at 58 ℃ for 2h at the rotating speed of 200r/min to obtain a third mixture;
and step four, adding biological enzyme, a coloring agent and a flavoring agent into the third mixing step five, and carrying out ultrasonic treatment on the mixture for 1.2 at the ultrasonic power of 800W to obtain the high-efficiency household cleaning agent.
Example 4
An efficient household cleaning agent comprises the following raw material components in parts by weight: 35 parts of surfactant, 3 parts of chelating agent, 10 parts of hydrogen peroxide, 0.5 part of sodium bicarbonate, 7 parts of jojoba oil, 0.1 part of magnesium hydrogen powder, 2 parts of biological enzyme, 0.05 part of colorant, 0.01 part of flavoring agent and 85 parts of deionized water.
According to the proportion, the preparation method comprises the following steps:
mixing sodium bicarbonate, jojoba oil, hydrogen powder and deionized water, and performing microwave treatment for 15min at the microwave power of 1000W to obtain a first mixture;
step two, adding a chelating agent and a surfactant into the first mixture, heating and stirring at 58 ℃ for 2h at a rotation speed of 200r/min to obtain a second mixture;
adding hydrogen peroxide into the second mixture, heating and stirring at 58 ℃ for 2h at the rotating speed of 200r/min to obtain a third mixture;
and step four, adding biological enzyme, a coloring agent and a flavoring agent into the third mixing step five, and carrying out ultrasonic treatment on the mixture for 1.2 at the ultrasonic power of 800W to obtain the high-efficiency household cleaning agent.
Example 5
An efficient household cleaning agent comprises the following raw material components in parts by weight: 35 parts of surfactant, 3 parts of chelating agent, 10 parts of hydrogen peroxide, 1.5 parts of sodium bicarbonate, 2 parts of jojoba oil, 0.1 part of magnesium hydrogen powder, 2 parts of biological enzyme, 0.05 part of colorant, 0.01 part of flavoring agent and 85 parts of deionized water.
According to the proportion, the preparation method comprises the following steps:
mixing sodium bicarbonate, jojoba oil, hydrogen powder and deionized water, and performing microwave treatment for 15min at the microwave power of 1000W to obtain a first mixture;
step two, adding a chelating agent and a surfactant into the first mixture, heating and stirring at 58 ℃ for 2h at a rotation speed of 200r/min to obtain a second mixture;
adding hydrogen peroxide into the second mixture, heating and stirring at 58 ℃ for 2h at the rotating speed of 200r/min to obtain a third mixture;
and step four, adding biological enzyme, a coloring agent and a flavoring agent into the third mixing step five, and carrying out ultrasonic treatment on the mixture for 1.2 at the ultrasonic power of 800W to obtain the high-efficiency household cleaning agent.
Example 6
The efficient household cleaning agent comprises the following raw materials in parts by weight: 35 parts of surfactant, 3 parts of chelating agent, 10 parts of hydrogen peroxide, 1.5 parts of sodium bicarbonate, 7 parts of jojoba oil, 0.05 part of magnesium hydrogen powder, 2 parts of biological enzyme, 0.05 part of colorant, 0.01 part of flavoring agent and 85 parts of deionized water.
According to the proportion, the preparation method comprises the following steps:
mixing sodium bicarbonate, jojoba oil, hydrogen powder and deionized water, and performing microwave treatment for 15min at the microwave power of 1000W to obtain a first mixture;
step two, adding a chelating agent and a surfactant into the first mixture, heating and stirring at 58 ℃ for 2h at a rotation speed of 200r/min to obtain a second mixture;
adding hydrogen peroxide into the second mixture, heating and stirring at 58 ℃ for 2h at the rotating speed of 200r/min to obtain a third mixture;
and step four, adding biological enzyme, a coloring agent and a flavoring agent into the third mixing step five, and carrying out ultrasonic treatment on the mixture for 1.2 at the ultrasonic power of 800W to obtain the high-efficiency household cleaning agent.
Example 7
An efficient household cleaning agent comprises the following raw material components in parts by weight: 35 parts of surfactant, 3 parts of chelating agent, 10 parts of hydrogen peroxide, 1.5 parts of sodium bicarbonate, 7 parts of jojoba oil, 0.1 part of magnesium hydrogen powder, 1.5 parts of biological enzyme, 0.05 part of colorant, 0.01 part of flavoring agent and 85 parts of deionized water.
According to the proportion, the preparation method comprises the following steps:
mixing sodium bicarbonate, jojoba oil, hydrogen powder and deionized water, and performing microwave treatment for 15min at the microwave power of 1000W to obtain a first mixture;
step two, adding a chelating agent and a surfactant into the first mixture, heating and stirring at 58 ℃ for 2h at a rotation speed of 200r/min to obtain a second mixture;
adding hydrogen peroxide into the second mixture, heating and stirring at 58 ℃ for 2h at the rotating speed of 200r/min to obtain a third mixture;
and step four, adding biological enzyme, a coloring agent and a flavoring agent into the third mixing step five, and carrying out ultrasonic treatment on the mixture for 1.2 at the ultrasonic power of 800W to obtain the high-efficiency household cleaning agent.
Example 8
An efficient household cleaning agent comprises the following raw material components in parts by weight: 35 parts of surfactant, 3 parts of chelating agent, 10 parts of hydrogen peroxide, 1.5 parts of sodium bicarbonate, 7 parts of jojoba oil, 0.1 part of magnesium hydrogen powder, 2 parts of biological enzyme, 0.05 part of colorant, 0.01 part of flavoring agent and 70 parts of deionized water.
According to the proportion, the preparation method comprises the following steps:
mixing sodium bicarbonate, jojoba oil, hydrogen powder and deionized water, and performing microwave treatment for 15min at the microwave power of 1000W to obtain a first mixture;
step two, adding a chelating agent and a surfactant into the first mixture, heating and stirring at 58 ℃ for 2h at a rotation speed of 200r/min to obtain a second mixture;
adding hydrogen peroxide into the second mixture, heating and stirring at 58 ℃ for 2h at the rotating speed of 200r/min to obtain a third mixture;
and step four, adding biological enzyme, a coloring agent and a flavoring agent into the third mixing step five, and carrying out ultrasonic treatment on the mixture for 1.2 at the ultrasonic power of 800W to obtain the high-efficiency household cleaning agent.
Comparative example 1
Commercially available normal laundry detergents.
The cleaning agents of examples 1 to 8 and comparative example 1 were subjected to the following tests:
and (3) appearance detection: and pouring the cleaning agent into a transparent beaker, standing, and observing whether the cleaning agent is layered or not and whether precipitates exist or not. If not, the product is qualified; if yes, the product is not qualified.
And (3) odor detection: and (4) detecting whether the cleaning agent accords with the specified odor type or not, and whether the odor exists or not. If the result is in line, the product is qualified; if not, the product is not qualified.
And (3) detecting the stain removing capacity: the washing object is a T-shirt newly stained with ink, milk and grease, and the cleaning agents are respectively tested. Spraying a cleaning agent on the surface of the stain, leaving a spot without treatment and marking, slightly kneading the fabric after 1 minute, washing the place treated by the cleaning agent with water, marking, washing according to a common washing mode, and observing whether the place treated by the cleaning agent and the place not treated have the mark of the stain or not after washing. If the place treated by the cleaning agent is free of stains and the place not treated is stained, the place is qualified; if the place treated by the cleaning agent has dirt, and the place not treated has dirt, the cleaning agent is unqualified.
And (3) detecting the dirt removing capacity of the yellow spot dirt cloth: the subject was a macular T-shirt and each wash was tested separately. Spraying a cleaning agent on the surface of the yellow spots, leaving one yellow spot without treatment and marking, slightly kneading the fabric after 1 minute, washing the place treated by the cleaning agent with water, marking, washing according to a common washing mode, and observing whether the place treated by the cleaning agent and the place not treated have yellow spot marks or not after washing. If the place treated by the cleaning agent is free of stains and the place not treated is stained, the place is qualified; if the place treated by the cleaning agent has dirt, and the place not treated has dirt, the cleaning agent is unqualified.
And (3) detecting the dirt removing capability of mildew stain cloth: the washing object was a moldy T-shirt, and each detergent was tested separately. Spraying a cleaning agent on the surface of the mildew, leaving a mildew without treatment and marking, slightly kneading the fabric after 1 minute, washing the place treated by the cleaning agent with water, marking, washing according to a common washing mode, and observing whether the place treated by the cleaning agent and the place not treated have the mildew mark. If the place treated by the cleaning agent is free of stains and the place not treated is stained, the place is qualified; if the place treated by the cleaning agent has dirt, and the place not treated has dirt, the cleaning agent is unqualified.
The test results are shown in table 1:
TABLE 1
From the test results in Table 1, it can be seen that the cleaning agents of examples 1-8 of the present invention are all effective in removing persistent residual macula and mildew on T-shirts, as compared to the commercial conventional laundry detergent of comparative example 1.
Finally, it should be noted that: the above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and the modifications or the substitutions do not make the essence of the corresponding technical solutions depart from the scope of the technical solutions of the embodiments of the present invention.
Claims (10)
1. The efficient household cleaning agent is characterized by comprising the following raw materials in parts by weight: 20-35 parts of surfactant, 0.5-3 parts of chelating agent, 2-10 parts of hydrogen peroxide, 0.5-1.5 parts of sodium bicarbonate, 2-7 parts of jojoba oil, 0.05-0.1 part of magnesium hydrogen powder, 1.5-2 parts of biological enzyme, 0-0.05 part of coloring agent, 0-0.01 part of flavoring agent and 70-85 parts of deionized water.
2. The high-efficiency household cleaning agent according to claim 1, wherein the surfactant is one or more of sodium lauryl sulfate, polyoxyethylene lauryl ether, fatty acid methyl ester ethoxylate sulfonate and dioctyl sodium sulfosuccinate.
3. A highly effective household cleaning agent as claimed in claim 1, wherein said chelating agent is one or more of citric acids, organic phosphonates, ethylenediaminetetraacetic acids, glutamic diacetic acids and glycine diacetic acids.
4. The efficient household cleaning agent as claimed in claim 1, wherein the mass concentration of hydrogen peroxide is 8% -35%.
5. The high-efficiency household cleaning agent as claimed in claim 1, wherein the biological enzyme is one or more of protease, amylase and citrate.
6. A high efficiency household cleaner as defined in claim 1 wherein said colorant is a pigment.
7. A highly effective household cleaning agent as claimed in claim 1 wherein said flavoring agent is a perfume.
8. A preparation method of a high-efficiency household cleaning agent as claimed in any one of claims 1 to 7, characterized by comprising the following steps:
step one, mixing sodium bicarbonate, jojoba oil, hydrogen powder and deionized water, and performing microwave treatment to obtain a first mixture;
step two, adding a chelating agent and a surfactant into the first mixture, and heating and stirring to obtain a second mixture;
adding hydrogen peroxide into the second mixture, heating and stirring to obtain a third mixture;
and step four, adding biological enzyme, a coloring agent and a flavoring agent into the third mixing step five, and performing ultrasonic treatment to obtain the high-efficiency household cleaning agent.
9. The method for preparing efficient household cleaning agent as claimed in claim 8, wherein in the step one, the microwave treatment is carried out for 15-20min, and the microwave power is 800-; in the fourth step, the ultrasonic treatment is carried out for 1.2-1.4h, and the ultrasonic power is 700- & lt 800 & gt W.
10. The method for preparing efficient household cleaning agent as claimed in claim 8, wherein in the second step and the third step, the temperature of heating and stirring is 58-60 ℃, the stirring time is 1-2h, and the rotation speed is 150-.
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| JP3181927B2 (en) * | 1998-01-22 | 2001-07-03 | ミズ株式会社 | Cleaning method and cleaning device |
| WO2012143041A1 (en) * | 2011-04-18 | 2012-10-26 | Sound Holding Ag | Composition, method for its manufacture and use thereof |
| KR101753371B1 (en) * | 2017-03-06 | 2017-07-04 | (주)지앤테크놀러지 | Washing Tablet |
| WO2018212428A1 (en) * | 2017-05-17 | 2018-11-22 | (주)하이씨엔티 | Hydrogen soap and manufacturing method therefor |
| KR20190070189A (en) * | 2017-12-12 | 2019-06-20 | 박규섭 | Hydrogen Containing Enzyme Tablet Detergent |
| CN110157559A (en) * | 2019-05-10 | 2019-08-23 | 上海和黄白猫有限公司 | A kind of oxygen-containing Liquid laundry composition and its preparation method and application |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3181927B2 (en) * | 1998-01-22 | 2001-07-03 | ミズ株式会社 | Cleaning method and cleaning device |
| WO2012143041A1 (en) * | 2011-04-18 | 2012-10-26 | Sound Holding Ag | Composition, method for its manufacture and use thereof |
| KR101753371B1 (en) * | 2017-03-06 | 2017-07-04 | (주)지앤테크놀러지 | Washing Tablet |
| WO2018212428A1 (en) * | 2017-05-17 | 2018-11-22 | (주)하이씨엔티 | Hydrogen soap and manufacturing method therefor |
| KR20190070189A (en) * | 2017-12-12 | 2019-06-20 | 박규섭 | Hydrogen Containing Enzyme Tablet Detergent |
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