KR102258489B1 - Tablet-Type Hydrogen Laundry Detergent - Google Patents

Abstract

The present invention relates to a tablet-type hydrogen laundry detergent that has significantly increased antibacterial activity as well as the cleaning power of the detergent, and residues such as fine dust that remain in the laundry with reliable cleaning power for the laundry during laundry treatment, which may cause skin diseases. It is possible to clean and sanitize washing treatment by imparting strong antimicrobial activity against it, while also making it easy to form and process into tablets that are convenient for use and storage. The tablet-type hydrogen laundry detergent of the present invention for realizing this comprises 8-15% by weight of proteolytic enzyme that degrades protein components contained in sweat or oil, 3-5% by weight of lipolytic enzyme that hydrolyzes fat, and starch. 1-2% by weight of starch-degrading enzyme to hydrolyze, 3-5% by weight of fibrinase to hydrolyze fibrin, 5-6% by weight of citric acid, which exhibits fabric softening and sterilization functions, and exhibits bleaching and sterilizing functions 40-45% by weight of sodium percarbonate, 7-10% by weight of sodium hydrogencarbonate, which functions as a dispersant so that the ingredients formulated during washing are quickly decomposed and peeled off, and 7-10% by weight of sodium gluconate that functions as a decomposition and dispersant %, and 1-1.5% by weight of magnesium hydrogen powder that exhibits decomposition power against heavy metals and foreign substances due to its high antioxidant capacity, and zinc oxide as a mineral powder binder that exhibits strong antibacterial activity against (second) fine dust and heavy metals. 3-5% by weight, 7-10% by weight of a fiber lubricant that exhibits a cleaning function, and 8-15% by weight of microcrystalline cellulose that functions as a builder to maintain the tablet formulation of raw materials without the application of hydrogen ionized water. It is formed in the form of tablets including.

Description

Tablet-Type Hydrogen Laundry Detergent}

The present invention relates to a tablet-type hydrogen laundry detergent in which the detergent itself is eco-friendly and has excellent cleaning power and antibacterial activity during washing. In more detail, it is possible to clean and hygienic washing treatment by providing a strong antibacterial effect against residues such as fine dust that may remain in the laundry and cause skin diseases, along with a reliable washing power for the laundry. It relates to a tablet-type hydrogen laundry detergent that facilitates molding and processing operations into tablets that are convenient for storage.

Laundry detergents, which are usually used to wash dirty clothes or cloths, have surfactants added as the main component. Surfactants extracted from petroleum are used a lot because they wash well, have rich foaming power, wash well in cold water, and have inexpensive cleaning power. Has become. In other words, surfactants are substances that have lipophilic and hydrophilic groups such as soaps and detergents, and have adsorption and cleaning power, emulsification, and dispersing power, and are widely used as detergents, fabric softeners, emulsifiers, antistatic agents, and lubricant additives, depending on their characteristics. .

Of course, surfactants include synthetic surfactants extracted from petroleum, as well as lecithin in natural soybeans and egg yolks, and saponin in ginseng and softnuts. Natural surfactants are environmentally friendly and harmless to the human body because they do not irritate the skin, but in reality, they are rarely used as surfactants in laundry detergents due to economical efficiency, and synthetic surfactants are mainly used.

However, in terms of health and the environment, general laundry detergents containing synthetic surfactants as a main component are increasingly looking for eco-friendly laundry detergents that are harmless to the human body and excellent in washing ability due to its toxicity. The development and supply of hydrogen detergents with excellent bleaching power and antibacterial properties are gradually increasing.

As you know, fine dust is a harmful substance containing various heavy metals such as nitric acid and sulfuric acid. Among them, ultrafine dust has very small particles and penetrates directly into the blood vessels, so respiratory diseases such as pneumonia, lung function decline, asthma exacerbation, and skin aging It is the cause of the problem, and interest has been increasing in recent years. However, when washing with a detergent made of chemical ingredients, a detergent must also be carefully selected because residues on the fibers remain and irritate the skin, which may cause skin diseases.

On the other hand, since synthetic surfactants such as sodium lauryl sulfate or sodium laureth sulfate are used as surfactants to increase the cleaning power while increasing foam generation, water pollution is caused, and detergents containing such synthetic surfactants as the main component are used. When the washed fiber is worn, it is in contact with the skin, destroying the sebaceous film and the stratum corneum, promoting skin aging and causing various skin diseases, which are harmful to the human body.

For reference, Patent No. 10-0420466 (manufacture method of highly concentrated photocatalytic powder bleach detergent), Patent Publication No. 10-2011-0053451 (highly concentrated liquid laundry detergent), Patent Publication No. 10-2012-0136853 (Eco Washing Tablet Cleaner And its manufacturing method), etc., are being released in the form of solid (tablet-type) laundry detergents in the form of eggs (tablets) concentrated using active protein-degrading enzymes and components having an oxygen-based bleaching function that is completely harmless to the human body. These have a problem that the cleaning power is slightly inferior despite many advantages such as the effect of being able to wash without generating bubbles.

In addition, in the case of patent No. 10-1753371 (hydrogen washing tablet) as a registered patent to improve all the problems of the disclosed patents, since surfactant is not used, it is harmless to the human body and enhances the surfactant function without causing environmental pollution. It was able to provide strong washing power (cleaning power) by facilitating the separation of foreign matters such as dirt, oil, and dust, but it lacks strong antibacterial power against residues such as fine dust that may remain in the laundry and cause skin diseases. Therefore, it did not solve the limitation of a little lack of antibacterial treatment along with washing treatment of clean laundry.

In addition, even though it is a formulated tablet, that is, it has a weak formulation, so there is a problem that requires care in management due to the inconvenience of blocking moisture during storage before washing, and the decomposition and peeling rate of the tablet raw material is slow when washing is used. That was a factor in reducing the washing effect.

Particularly inconvenient problems, such as sticking to the pressurized molding punch due to moisture in the raw material when tabletting detergent raw materials, and the slow decomposition rate of the tablet raw materials into liquid when using laundry can hinder rapid cleaning power. Could not be resolved.

In the present invention, in the use of a laundry detergent having a strong cleaning power, it is possible to impart a strong antibacterial activity against residues such as fine dust that may remain in the laundry and cause skin diseases as well as a reliable cleaning power for the laundry during laundry treatment. As an alkaline water tank detergent, the detergent itself is eco-friendly and provides clean and hygienic hydrogen laundry detergent without damaging the laundry.Moreover, it is in a tablet form, so it is convenient to store, but the detergent is quickly decomposed when used, and laundry is treated cleanly and hygienically. It is an object of the present invention to provide a tablet-type hydrogen laundry detergent that is capable of not only being able to, but also facilitates molding and processing operations in tablet form.

The present invention is a means for achieving the above object, 8-15% by weight of a protease that degrades protein components contained in sweat or oil, and a lipolytic enzyme (Lipase) 3- 5% by weight, 1-2% by weight of starch-degrading enzyme (Amylase) that hydrolyzes starch, 3-5% by weight of fibrinase (Celluase) that hydrolyzes fibrin, and citric acid that exhibits fiber softening and sterilizing function (Citric Acid) 5-6% by weight, sodium percarbonate 40-45% by weight, which exhibits bleaching and sterilization functions, and sodium hydrogen carbonate, which functions as a dispersant so that formulated ingredients are quickly decomposed and peeled off during washing. (Sodium Bicabonate) 7-10% by weight, Sodium Gluconate 7-10% by weight, which functions as a decomposition and dispersant, and hydrogen magnesium, which exhibits decomposition power for heavy metals and foreign substances due to its high antioxidant capacity. Powder (MgH ₂ ) 1-1.5% by weight, mineral powder that exhibits strong antibacterial activity against (ultra) fine dust and heavy metals, zinc oxide (ZnO) 3-5% by weight of the binder function, and the raw materials without the application of hydrogen ion water A hydrogen laundry detergent is formed in the form of a tablet, including 8-15% by weight of Microcrystalline Cellulose, which functions as a builder for maintaining the tablet formulation.

In particular, the tablet-type hydrogen laundry detergent of the present invention contains 7-10% by weight of a fiber lubricant that exerts a cleaning function as needed, and is mixed with the raw materials to be purified. It has a technical feature even though it is dried at a temperature of 60-70℃ for 24 hours a day so that it does not stick.

According to the tablet-type hydrogen laundry detergent of the present invention, the human body release oil applied to the laundry fiber through an appropriate combination of special enzyme components for decomposition at high concentration, lubricants, and a number of bleaching and sterilizing ingredients, which are characteristic of hydrogen detergents, can be used. It quickly disassembles and removes stains and traces, but eliminates skin irritation, prevents water contamination, and prevents foaming, thereby reducing the use of washing water and preventing discoloration or damage of fibers after washing.

In particular, clean and hygienic washing treatment is possible by providing a strong antibacterial power against residues such as fine dust that may remain in the laundry and cause skin diseases, along with a reliable washing power for the laundry. It is easy to form and process into tablets that are convenient for use and storage by applying hydrogen-rich raw materials without the use of hydrogen ionized water or builders. Different from the hydrogen laundry detergents introduced in the above, it can provide excellent and diverse effects.

Hereinafter, a specific component relationship and an optimum composition range of a preferred composition comprising the tablet-type hydrogen laundry detergent of the present invention will be described in more detail.

First, it has been introduced that the basic washing power and antibacterial function of a tablet-type hydrogen detergent can be provided through registered patent No. 10-1753371 (hydrogen washing tablet) previously developed by the present inventor. In other words, when hydrogen detergent is high concentration, which is a characteristic of the tablet type, it quickly decomposes and removes stains and traces such as oil released from the human body through a special enzyme component for decomposition and a hydrogen binder, which is a characteristic of the tablet type, but eliminates skin irritation and water quality. While preventing contamination and preventing foaming, the composition of the registered patent was difficult to exert enough to satisfy the important antibacterial activity of laundry, as well as the use of hydrogen ionized water and builders that generate a lot of moisture. During pressure molding in tablet form, the molding work itself was difficult because of the moisture adhering to the raw materials.

That is, summarizing the characteristics of the composition of the previously disclosed patent, 25-30% by weight of hydrogen calcium powder having a high ability to decompose heavy metals and foreign substances, and a highly functional active protein-degrading enzyme 15 that decomposes protein components contained in sweat or oil. -20% by weight, 10-15% by weight of an alkaline agent that enhances cleaning power, 7-10% by weight of a lipolytic enzyme that hydrolyzes fat and 7-10% by weight of a functional hydrolase, and sodium percarbonate with bleaching and sterilizing functions 2-4% by weight, with a small amount of builder 0.5-15% by weight to maintain the tablet formulation and a small amount of sodium sulfate 0.5-15% by weight to decompose the builder, the rest of the role of a kind of binder for the preparation of the formulation in the raw material It is composed of hydrogen ion water.

In particular, with only the component level of the above-described composition, reliable cleaning power for laundry during washing treatment is not a big problem, but it remains in the laundry and may cause skin diseases, such as (ultra) fine dust or heavy metals that may be fatal to the human body. It was difficult to exert satisfactory antibacterial activity that could reliably remove and sterilize even the strong antibacterial activity against the residue.

However, through the present invention, as an antibacterial component along with various new decomposing enzymes in laundry, the optimal composition range of ingredients for new raw materials exhibiting bleaching, sterilization and binding and decomposition functions while generating relatively little moisture and drying at the manufacturing stage. Through the new manufacturing conditions of processing, clean and hygienic washing treatment is possible by giving strong antibacterial power to residues such as fine dust that remain in the laundry and can cause skin diseases, along with reliable washing power for the laundry. Molding into tablets that are convenient for use and storage may be possible.

Protease, which primarily decomposes and peels off various foreign substances remaining in the laundry to improve washing power, sterilizes various foreign substances and bacteria, and treats Hwang bacteria, as a raw material for decomposing protein components contained in sweat or oil. -15% by weight, 3-5% by weight of a lipolytic enzyme that hydrolyzes fat, 1-2% by weight of a starch-degrading enzyme (Amylase) that hydrolyzes starch, and a fibrinase that hydrolyzes fibrin (Cellulase) 3-5% by weight and hydrogen magnesium powder (MgH ₂ ) 1-1.5% by weight, which decomposes heavy metals and foreign substances, is basically added due to the high amount of hydrogen generation of antioxidant function.

Also, as raw materials to improve bleaching and sterilization (antibacterial) power for laundry. 5-6% by weight of citric acid, which exhibits fabric softening and sterilization function, 40-45% by weight of sodium percarbonate, which exhibits bleaching and sterilization functions, and (ultra) strong against fine dust and heavy metals. Zinc oxide (ZnO) exhibiting antibacterial activity is added in a mixing ratio of 3-5% by weight.

In addition, 7-10% by weight of sodium hydrogen carbonate (Sodium Bicabonate) functioning as a dispersant, 7-10% by weight of sodium gluconate functioning as a dispersant and dispersant, so that the formulated raw materials are quickly decomposed and peeled off during washing, Along with 7-10% by weight of a fiber lubricant (Polyethylene Glycol) that exhibits a cleaning function, Microcrystalline Cellulose (Microcrystalline Cellulose) that functions as a builder to maintain the tablet formulation of raw materials without the application of additional hydrogen ion water 8- It contains 15% by weight, and if necessary, the fiber lubricant (Polyethylene Glycol), which exhibits a cleaning function, is the remaining% by weight, which is mixed with the above-mentioned composition weight% of all these raw materials, and is seen in the form of a tablet through the molding and drying process. To form the tablet-type hydrogen laundry detergent of the invention.

In addition, when the raw materials of these ingredients are pressed into tablet form, they are granulated with a spray granulator, and then the granulated raw materials are filled in bulk and compressed to form tablets. By drying at a temperature of 60-70℃ for about 24 hours a day to prevent raw materials from sticking to the forming punch, the detergent itself is eco-friendly, and it forms a tablet-type hydrogen laundry detergent that has excellent washing power and antibacterial power during washing. .

Among the raw materials applied to the hydrogen laundry detergent of the present invention, first, a highly functional active protein-degrading enzyme is added to completely decompose protein components contained in sweat or oil from the skin of the human body. Protease is preferably used, and in some cases, papain to increase the protein cleaning effect, bromelain to increase the absorption of nutrients while increasing the protein decomposition effect, and digestive enzymes are used, but the digestive power of protein is low. Pancreatin (Pancreatin), which is excellent in protein decomposition power, is mixed in a weight ratio of 1:1:1:1, and can be added and used as much as the above composition ratio.

Particularly, if the proteolytic enzyme exceeds 15% by weight, erythema may accompany skin contact and may cause disorders in blood coagulation upon absorption in the body. Therefore, it should be added at most 15% by weight or less, and less than 10% by weight. If so, the protein degrading power drops rapidly, so it should be limited to the above range.

In addition, lipolytic enzyme, which is a functional hydrolase, uses Lipase, which hydrolyzes fat by breaking the bond between carboxylic acid and alcohol in lipids (oil), and is preferably used in a small amount of about 3% by weight of the total detergent raw material. , In particular, cellulase used as a starch degrading enzyme is preferably used only in a minimum trace amount of around 1%.

And carboxymethyl cellulose (Carboxymethyl Cellulose), which is an enzyme that decomposes fibrin, is prepared by the reaction between alkaline cellulose and chloroacetate. It is responding sufficiently.

And citric acid (Citric Acid), which is mainly used to exert the flexibility and sterilizing function of fibers, among the raw materials for the hydrogen laundry detergent of the present invention, is 5% by weight because it functions as a softener and disinfectant for the laundry. The role can be sufficiently provided even at a level of around %.

In addition, sodium percarbonate, which is most frequently added among the raw materials constituting the hydrogen laundry detergent of the present invention, is Na ₂ CO ₄ ㆍH ₂ O formed by mixing sodium carbonate and hydrogen peroxide. It functions as a 100% oxygen-based sterilization and bleaching agent that does not contain it. Since sodium percarbonate is in a form in which hydrogen peroxide is attached to sodium carbonate, when it meets with water, it dissolves easily and increases its activity, thereby enhancing sterilization and bleaching functions.

In particular, in the conventional hydrogen detergent, raw materials were reacted by adding hydrogen ionized water together with a builder in forming a tablet form, but in the hydrogen laundry detergent of the present invention, the raw material corresponding to the builder without adding additional hydrogen ionized water. As a binder of the raw materials, it is preferable that the microcrystalline cellulose (Microcrystalline Cellulose) of a builder function for maintaining the tablet formulation of the raw materials is contained in an amount of about 8-15% by weight.

In addition, zinc oxide (ZnO), which has strong antibacterial activity against (ultra) fine dust and heavy metals, is added in a small amount at a level of 3-5% by weight so that the builder function for maintaining the formulation of raw materials can be more effectively supplemented to exert a mineral powder binder function. I can. In addition, of course, microcrystalline cellulose and zinc oxide, which exhibit these builder functions, are added for formulation formulation after granulation, and strengthen immunity as well as strong antioxidant function.

On the other hand, the hydrogen laundry detergent of the present invention is carbonated so that it can be easily dissolved in water when used in laundry washing and released while being decomposed, as opposed to the binding agent function in the formulation of raw materials by the addition of microcrystalline cellulose and zinc oxide above. Sodium Bicabonate is basically added, and it is preferable that sodium gluconate is added at the same level of about 7-10% by weight, respectively, together with the sodium hydrogen carbonate. This makes it possible to dissolve the laundry detergent strongly refined by microcrystalline cellulose and zinc oxide.

In addition, in the hydrogen laundry detergent of the present invention, unlike conventional hydrogen detergents, the amount of hydrogen magnesium powder (MgH ₂ ) exhibiting decomposition power for heavy metals and foreign substances due to the high amount of hydrogen generated without the use of hydrogen ionized water is used in a minimum amount of 1-1.5 weight It is added in% level, which is similar in hydrolysis generation ability compared to hydrogen calcium (CaH2), which was mainly applied in the existing hydrogen laundry detergent, but the hydrogen generation amount of the detergent is almost twice as much at a relatively low cost. Therefore, in the present invention, there is a technical feature even when a small amount is added as a component that exhibits a separate function of decomposition of heavy metals and foreign substances and an antioxidant function.

In addition, in the present invention, a fiber lubricant may be included in an amount of 7-10% by weight so that the cleaning function can be more reliably exhibited with respect to the hydrogen laundry detergent, and the mixture may be reacted.

In particular, in the case of zinc oxide (ZnO), which is added to dramatically increase antibacterial power with excellent cleaning power, the tablet-type hydrogen laundry detergent of the present invention can be used as various ultrafine dusts that may remain in laundry along with important cleaning power of laundry. It is used as a tablet-type binder for hydrogen laundry detergent instead of hydrogen ionized water (hydrogen cation water) while reliably separating and removing heavy metals and bacteria so that antibacterial activity can be improved dramatically. Due to the moisture of the powdered raw materials, it is possible to reliably eliminate the phenomenon of sticking of the raw materials to the molding punch that is pressed up and down in the tablet press.

In other words, since the tablet-type hydrogen laundry detergent of the present invention is prepared into formulation tablets by filling and compressing the granulated raw material into the molding bulk, the raw material filled in the bulk and pressurized does not stick to the molding punch by about 60-70 days. The drying process is performed at a temperature level of ℃. At this time, if the heating temperature is less than 60℃ in the drying process of the raw materials in one day, the moisture evaporation effect of the whole raw material is insufficient, and when it reaches close to 80℃, the raw material itself is heated black and burns. It could be.

In particular, zinc oxide is added in a small amount of 3-5% by weight, such as lipolytic enzymes and functional digestive enzymes, according to various experimental results, which is difficult to achieve satisfactory antibacterial activity when added to 3% by weight or less. If it is added in excess of the weight %, the hydrolysis ability is significantly lowered and the tableting of the raw material may be hindered. Therefore, this composition range was the most desirable experimental result.

For reference, when the raw materials are granulated and tableted in tablet-type hydrogen laundry detergent, the moisture of the powder raw materials sticks to the molding punch that is stamped up and down in the tablet press, so the molding punch cannot be used for a long time. There was a difficulty in wiping. This is because the force exerted on the upper and lower molding punches when tableting raw materials is 3 tons or more, so as the tablets were pressed with heavy force like squeezing oil, there was a phenomenon of sticking to the punch due to moisture in the raw materials. The tablet-type hydrogen laundry detergent according to the invention drastically increases the antibacterial activity while drying these raw materials for a certain period of time with the application of zinc oxide and microcrystalline cellulose to minimize the generation of moisture by the hydrogen ionized water-functional binder. By doing tableting, the phenomenon of sticking to the molding punch is significantly reduced, so that the hydrogen laundry detergent can be accurately and efficiently molded into a tablet form.

Of course, as described above, the tablet-type hydrogen laundry detergent of the present invention, which enables tablet-molding through the application of a binder and an optimal drying process, has a high concentration and decomposition capability, which is basically different from the existing detergent, As it can completely and neatly decompose sexual and fatty grime in a short time, it has a reliable washing power function for laundry, as well as eco-friendly ingredients that do not irritate the skin and do not pollute the water quality, and there is no surfactant itself to suppress foaming. Washing capacity can also be enhanced.

Furthermore, it can also dramatically improve the strong antibacterial function against residues such as fine dust that may remain in the laundry and cause skin diseases, so that a clean and hygienic washing process is possible, but in the form of tablets that are convenient to use and store. Molding and processing are also facilitated. Especially, since it is in the form of tablets, it is convenient to store, and when used, detergents can be disassembled quickly, and laundry can be washed cleanly and hygienically, as well as molding and processing in tablet form. It is expected to exhibit various effects as a tablet-type hydrogen laundry detergent.

Claims (2)

8-15% by weight of proteolytic enzyme that degrades protein components contained in sweat or oil, 3-5% by weight of lipolytic enzyme that hydrolyzes fat, and 1-2% by weight of starch-degrading enzyme that hydrolyzes starch; , 3-5% by weight of fibrinolytic enzyme that hydrolyzes fibrin, 5-6% by weight of citric acid that exhibits fabric softening and sterilization functions, and 40-45% by weight of sodium percarbonate that exhibits bleaching and sterilization functions, and when washing 7-10% by weight of sodium hydrogen carbonate, which acts as a dispersant so that the formulated raw materials are rapidly decomposed and peeled off, 7-10% by weight of sodium gluconate, which acts as a decomposition and dispersant, _{Hydrogen magnesium powder (MgH 2} ) 1-1.5% by weight that exerts decomposition power for foreign substances, and zinc oxide (ZnO) 3-5% by weight as a mineral powder binder that exhibits strong antibacterial activity against (second) fine dust and heavy metals Wow, in the form of tablets, including 8-15% by weight of microcrystalline cellulose that functions as a builder for maintaining the tablet formulation of raw materials without the application of hydrogen ion water, and 7-10% by weight of a fiber lubricant that exhibits a cleaning function. Is formed,
The above raw materials do not stick to the molding punch together with the application of zinc oxide and microcrystalline cellulose so as to dramatically increase the antibacterial power when tableting into tablets by pressure molding, and to minimize the generation of moisture due to the hydrogen ion water-functional binder. Tablet type hydrogen laundry detergent, characterized in that the drying treatment at a temperature level of 60-70 ℃ per day to prevent. delete