CN105886147B - A kind of antibacterial except mite liquid detergent - Google Patents
A kind of antibacterial except mite liquid detergent Download PDFInfo
- Publication number
- CN105886147B CN105886147B CN201610446651.2A CN201610446651A CN105886147B CN 105886147 B CN105886147 B CN 105886147B CN 201610446651 A CN201610446651 A CN 201610446651A CN 105886147 B CN105886147 B CN 105886147B
- Authority
- CN
- China
- Prior art keywords
- parts
- sodium
- liquid detergent
- except mite
- reaction kettle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 48
- 239000003599 detergent Substances 0.000 title claims abstract description 46
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 39
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 40
- -1 methoxyl group Chemical group 0.000 claims abstract description 38
- 239000002738 chelating agent Substances 0.000 claims abstract description 28
- 102000004190 Enzymes Human genes 0.000 claims abstract description 26
- 108090000790 Enzymes Proteins 0.000 claims abstract description 26
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 26
- 239000003960 organic solvent Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims abstract description 22
- 239000002562 thickening agent Substances 0.000 claims abstract description 22
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 21
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 claims abstract description 21
- 229920001661 Chitosan Polymers 0.000 claims abstract description 20
- 125000003368 amide group Chemical group 0.000 claims abstract description 20
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims abstract description 20
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims abstract description 20
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims abstract description 20
- 150000003839 salts Chemical class 0.000 claims abstract description 20
- 239000011780 sodium chloride Substances 0.000 claims abstract description 20
- 239000001509 sodium citrate Substances 0.000 claims abstract description 20
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 20
- 239000008367 deionised water Substances 0.000 claims abstract description 19
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 19
- QCCKPZOPTXCJPL-UHFFFAOYSA-N dodecyl(dimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCC[NH+](C)C QCCKPZOPTXCJPL-UHFFFAOYSA-N 0.000 claims abstract description 19
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 16
- GFOBSZSXQKGNMN-UHFFFAOYSA-N 2-[dodecanoyl(methyl)amino]ethanesulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)N(C)CCS(O)(=O)=O GFOBSZSXQKGNMN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 13
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 13
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 13
- 125000001924 fatty-acyl group Chemical group 0.000 claims abstract 3
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims abstract 3
- 238000006243 chemical reaction Methods 0.000 claims description 36
- 238000003756 stirring Methods 0.000 claims description 29
- 229940088598 enzyme Drugs 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- 238000002156 mixing Methods 0.000 claims description 20
- 235000019441 ethanol Nutrition 0.000 claims description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 10
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 7
- 108091005804 Peptidases Proteins 0.000 claims description 7
- 239000004365 Protease Substances 0.000 claims description 7
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 7
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical group CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 7
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical group [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 claims description 7
- 239000001433 sodium tartrate Substances 0.000 claims description 7
- 229960002167 sodium tartrate Drugs 0.000 claims description 7
- 235000011004 sodium tartrates Nutrition 0.000 claims description 7
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims description 6
- 101710112457 Exoglucanase Proteins 0.000 claims description 6
- 102000004139 alpha-Amylases Human genes 0.000 claims description 6
- 108090000637 alpha-Amylases Proteins 0.000 claims description 6
- 229940024171 alpha-amylase Drugs 0.000 claims description 6
- 239000000686 essence Substances 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 239000000176 sodium gluconate Substances 0.000 claims description 6
- 235000012207 sodium gluconate Nutrition 0.000 claims description 6
- 229940005574 sodium gluconate Drugs 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- 235000019198 oils Nutrition 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 241000206575 Chondrus crispus Species 0.000 claims description 2
- 235000005979 Citrus limon Nutrition 0.000 claims description 2
- 244000131522 Citrus pyriformis Species 0.000 claims description 2
- 235000019501 Lemon oil Nutrition 0.000 claims description 2
- 241000220317 Rosa Species 0.000 claims description 2
- 239000000679 carrageenan Substances 0.000 claims description 2
- 235000010418 carrageenan Nutrition 0.000 claims description 2
- 229920001525 carrageenan Polymers 0.000 claims description 2
- 229940113118 carrageenan Drugs 0.000 claims description 2
- 239000010642 eucalyptus oil Substances 0.000 claims description 2
- 229940044949 eucalyptus oil Drugs 0.000 claims description 2
- 239000010501 lemon oil Substances 0.000 claims description 2
- 239000001525 mentha piperita l. herb oil Substances 0.000 claims description 2
- 235000019477 peppermint oil Nutrition 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 238000004945 emulsification Methods 0.000 claims 1
- 239000010656 jasmine oil Substances 0.000 claims 1
- 229920005610 lignin Polymers 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 7
- 230000001954 sterilising effect Effects 0.000 abstract description 3
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 25
- HSHXDCVZWHOWCS-UHFFFAOYSA-N N'-hexadecylthiophene-2-carbohydrazide Chemical compound CCCCCCCCCCCCCCCCNNC(=O)c1cccs1 HSHXDCVZWHOWCS-UHFFFAOYSA-N 0.000 description 17
- 150000002190 fatty acyls Chemical group 0.000 description 17
- 239000000843 powder Substances 0.000 description 10
- 210000003491 skin Anatomy 0.000 description 10
- 238000005406 washing Methods 0.000 description 10
- 238000012360 testing method Methods 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 6
- 125000005909 ethyl alcohol group Chemical group 0.000 description 6
- 239000002585 base Substances 0.000 description 5
- JAJWGJBVLPIOOH-IZYKLYLVSA-M sodium taurocholate Chemical compound [Na+].C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(=O)NCCS([O-])(=O)=O)C)[C@@]2(C)[C@@H](O)C1 JAJWGJBVLPIOOH-IZYKLYLVSA-M 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 238000005202 decontamination Methods 0.000 description 4
- 230000003588 decontaminative effect Effects 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 3
- 238000011017 operating method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- 241001360526 Escherichia coli ATCC 25922 Species 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 241000191940 Staphylococcus Species 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000001408 fungistatic effect Effects 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 230000028327 secretion Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 208000002874 Acne Vulgaris Diseases 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 241001128004 Demodex Species 0.000 description 1
- 108010001682 Dextranase Proteins 0.000 description 1
- 235000010254 Jasminum officinale Nutrition 0.000 description 1
- 240000005385 Jasminum sambac Species 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 206010033733 Papule Diseases 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- 206010039792 Seborrhoea Diseases 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 1
- 206010000496 acne Diseases 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 235000013532 brandy Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 210000003780 hair follicle Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 210000001732 sebaceous gland Anatomy 0.000 description 1
- 208000008742 seborrheic dermatitis Diseases 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/30—Sulfonation products derived from lignin
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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Abstract
The present invention relates to a kind of antibacterial except mite liquid detergents, are made of the raw material of following parts by weight：5 10 parts of dodecyldimethylammonium hydroxide inner salt, 5 10 parts of lauroyl N-methyltaurine sodium, 35 parts of sodium lignin sulfonate, to 35 parts of methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, 0.5 3 parts of triethanolamine, 0.5 3 parts of Boratex, 15 parts of sodium chloride, 0.5 2 parts of sodium citrate, 0.5 2 parts of complex enzyme, 0.5 2 parts of nano-titanium dioxide, 0.5 2 parts of chitosan, 15 parts of emulsifier, 0.5 2 parts of chelating agent, 5 10 parts of organic solvent, 0.1 0.5 parts of polyvinylpyrrolidone, 0.1 0.5 parts of hydroxypropyl methyl cellulose, 0.1 0.5 parts of essence, 15 parts of thickener, 13 parts of sorbierite, 50 100 parts of deionized water.The antibacterial except mite liquid detergent strong detergency, while there is significant sterilization and except mite effect, without side-effects, dress material is colour-fast, does not stimulate skin, pollution-free.
Description
Technical field
The present invention relates to a kind of liquid detergent, in particular to a kind of liquid detergent with antibacterial except mite effect.
Background technology
It wears the clothes, is the big fundamental of human lives, from ancient times to the present, the cleaning of clothing is always that people's daily life is non-
An often important part, with the raising of modern life quality, laundry is also constantly being carried with the performance requirement of daily chemicals
It rises, the most commonly used laundry in the past is washing powder with daily chemicals, and washing powder has preferable decontamination cleaning effect, but does washing
Powder frequently appears in insufficient situation is dissolved in water when in use, one that clothing can be influenced as a kind of powder detergent
Washing effect, two can cause washing powder concentration in regional area excessive to fail the washing powder fully dissolved in part so that should
The alkalescence in region is very big, and clothing can be caused to damage, and three carry out washing powder due to containing the easily redeposition of many solid additives on clothing
Fabric is made to harden, meanwhile, washing powder is stronger to the irritation of skin, easily injures the skin of washer's hand, therefore nowadays
The occupation rate of market of washing powder is more and more lower, and liquid detergent determines liquid detergent in water because of the states of matter property of itself liquid
Dissolution dispersity be much better than washing powder, the good dispersiveness of liquid detergent determines that liquid detergent can equably wash clothing, together
When liquid detergent surfactant water-soluble it is good, easily rinse, deposition less and can avoid because local concentration cross major injury laundry
The hand skin of person, therefore the big more options laundry better liquid detergent of performance of people is as common laundry dailyization of family now
Work product.
With the continuous improvement of people's health consciousness, requirement of the people to laundry detergent compositions is not merely confined to be only capable of
Just, clothing is inevitably infected with the sweat having on skin to clean clothing above as the articles for daily use for most frequently contacting human skin
The dirts such as body object are posted on liquid, scurf, skin secretion and skin, while during clothes contact external environment, are easily infected with extraneous ring
The pollutants such as bacterium and virus in border, the two acts on so that clothing becomes the hotbed of biological pollutant growth and passed to human body
The passage broadcast.Acarid is the mankind room pest the most rampant after flea, fly.It is exclusively by the skin histology of thorn sucking
Cell, the grease etc. of skin gland secretion are made a living.Acarid is generally 0.1-0.2 millimeters long, and there are many species, almost there is 500,000 kinds,
Middle human Demodex is a kind of parasite that infection rate is higher in crowd, it is parasitized in hair follicle and sebaceous glands, and with cell liquid
Deng for nutriment；Its strong chelicera also has destruction to the skin histology of host, and a part of the infected is made to show to face
Bed symptom；There is pruitus, small papule etc. in the lighter, and severe one can cause brandy nose, epifolliculitis, seborrhea and acne.And
The liquid detergent of general cleaning can only play the role of clothes decontamination, and cannot play sterilization, for health
Consider, it is necessary to a kind of liquid detergent that can effectively play antibacterial except mite effect.
The content of the invention
The present invention provides a kind of antibacterial except mite liquid detergent, the liquid detergent strong detergency, while has disinfecting mite-removing effect, kills
The bacterium time is short, and bactericidal effect is good.
Specifically, the present invention provides antibacterial except mite liquid detergent, is made of the raw material of following parts by weight：Dimethyl
5-10 parts of base glycine betaine, 5-10 parts of lauroyl N-methyltaurine sodium, 3-5 parts of sodium lignin sulfonate, to methoxyl group fatty acid amide
3-5 parts of base benzene sulfonic acid sodium salt, 0.5-3 parts of triethanolamine, 0.5-3 parts of Boratex, 1-5 parts of sodium chloride, 0.5-2 parts of sodium citrate are multiple
0.5-2 parts of synthase, 0.5-2 parts of nano-titanium dioxide, 0.5-2 parts of chitosan, 1-5 parts of emulsifier, 0.5-2 parts of chelating agent are organic
5-10 parts of solvent, 0.1-0.5 parts of polyvinylpyrrolidone, 0.1-0.5 parts of hydroxypropyl methyl cellulose, 0.1-0.5 parts of essence increase
Thick dose 1-5 parts, 1-3 parts of sorbierite, 50-100 parts of deionized water.
In a specific embodiment of the invention, the antibacterial except mite liquid detergent by following parts by weight raw material
It is made：6 parts of dodecyldimethylammonium hydroxide inner salt, 8 parts of lauroyl N-methyltaurine sodium, 4 parts of sodium lignin sulfonate, to methoxy
4 parts of base fatty acyl amido benzene sulfonic acid sodium salt, 2 parts of triethanolamine, 2 parts of Boratex, 3 parts of sodium chloride, 1 part of sodium citrate, complex enzyme 1
Part, 1.5 parts of nano-titanium dioxide, 1 part of chitosan, 3 parts of emulsifier, 1 part of chelating agent, 8 parts of organic solvent, polyvinylpyrrolidone
0.3 part, 0.2 part of hydroxypropyl methyl cellulose, 0.2 part of essence, 3 parts of thickener, 2 parts of sorbierite, 75 parts of deionized water.
In a specific embodiment of the invention, the antibacterial except mite liquid detergent by following parts by weight raw material
It is made：5 parts of dodecyldimethylammonium hydroxide inner salt, 5 parts of lauroyl N-methyltaurine sodium, 3 parts of sodium lignin sulfonate, to methoxy
3 parts of base fatty acyl amido benzene sulfonic acid sodium salt, 0.5 part of triethanolamine, 0.5 part of Boratex, 1 part of sodium chloride, 0.5 part of sodium citrate are multiple
0.5 part of synthase, 0.5 part of nano-titanium dioxide, 0.5 part of chitosan, 1 part of emulsifier, 0.5 part of chelating agent, 5 parts of organic solvent gather
0.1 part of vinylpyrrolidone, 0.1 part of hydroxypropyl methyl cellulose, 0.1 part of essence, 1 part of thickener, 1 part of sorbierite, deionization
50 parts of water.
In a specific embodiment of the invention, the antibacterial except mite liquid detergent by following parts by weight raw material
It is made：10 parts of dodecyldimethylammonium hydroxide inner salt, 10 parts of lauroyl N-methyltaurine sodium, 5 parts of sodium lignin sulfonate, to first
5 parts of oxygroup fatty acyl amido benzene sulfonic acid sodium salt, 3 parts of triethanolamine, 3 parts of Boratex, 5 parts of sodium chloride, 2 parts of sodium citrate, complex enzyme 2
Part, 2 parts of nano-titanium dioxide, 2 parts of chitosan, 5 parts of emulsifier, 2 parts of chelating agent, 10 parts of organic solvent, polyvinylpyrrolidone
0.5 part, 0.5 part of hydroxypropyl methyl cellulose, 0.5 part of essence, 5 parts of thickener, 3 parts of sorbierite, 100 parts of deionized water.
In a specific embodiment of the invention, the antibacterial except mite liquid detergent by following parts by weight raw material
It is made：5 parts of dodecyldimethylammonium hydroxide inner salt, 10 parts of lauroyl N-methyltaurine sodium, 3 parts of sodium lignin sulfonate, to methoxy
5 parts of base fatty acyl amido benzene sulfonic acid sodium salt, 0.5 part of triethanolamine, 3 parts of Boratex, 1 part of sodium chloride, 2 parts of sodium citrate, complex enzyme
0.5 part, 2 parts of nano-titanium dioxide, 0.5 part of chitosan, 5 parts of emulsifier, 0.5 part of chelating agent, 10 parts of organic solvent, polyethylene pyrrole
0.1 part of pyrrolidone, 0.5 part of hydroxypropyl methyl cellulose, 0.1 part of essence, 5 parts of thickener, 1 part of sorbierite, deionized water 100
Part.
In a specific embodiment of the invention, the complex enzyme is alkali protease, alpha-amylase, circumscribed Portugal
Dextranase, the weight ratio of three is 2：1：2.
In a specific embodiment of the invention, the emulsifier gathers for ethoxylated dodecyl alcohol and stearic acid
Ethylene oxide ester, the weight ratio of the two is 1：2.
In a specific embodiment of the invention, the chelating agent is sodium tartrate and sodium gluconate, the two
Weight ratio be 1：1.
In a specific embodiment of the invention, the organic solvent is ethyl alcohol, ethylene glycol monobutyl ether and glycerine,
The volume ratio of three is 2:1:1.
In a specific embodiment of the invention, the essence is peppermint oil, eucalyptus oil, lemon oil, jasmine essence
Oil, attar of rose or caryophyllus oil.
In a specific embodiment of the invention, the thickener is xanthans, carragheen or carrageenan.
In a specific embodiment of the invention, the weight average molecular weight of the sodium lignin sulfonate is 2000 dongles
Pause to 6000 dalton.
Another aspect of the present invention provides the preparation method of the antibacterial except mite liquid detergent, includes the following steps：
（1）Each raw material for standby is weighed in parts by weight；
（2）Deionized water is added in into reaction kettle, is warming up to 50-70 DEG C, then starts to stir, and sequentially adds polyethylene
Pyrrolidones, hydroxypropyl methyl cellulose, emulsifier and nano-titanium dioxide, the mixing speed are 100~200r/
Min, mixing time 20min；
（3）, step（2）After finishing, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl are sequentially added into reaction kettle
Sodium taurocholate, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, are adjusted in reaction kettle
PH=7~8 of reaction solution；The mixing speed is 100~200r/min；
（4）, step（3）After finishing, reaction kettle is cooled to 35 DEG C, sequentially adds sodium citrate, complex enzyme and sorb
Alcohol stirs 10min, then adds in triethanolamine, Boratex, chelating agent and sodium chloride, is stirred for 10min；The stirring speed
It spends for 100~200r/min；
（5）, step（4）After finishing, chitosan, organic solvent, essence, thickener, stirring are added in into reaction kettle successively
20min, the mixing speed for 100~200r/min to get.
In the present invention in the case of no specified otherwise, all percentages are weight percentage.
With reference to specific embodiment, the invention will be further described.
Specific embodiment
It can be with the present invention will be further elaborated, however, the scope of the present invention not office by the following examples
It is limited to following embodiments.Those skilled in the art are it can be appreciated that in the premise without departing substantially from the spirit and scope of the present invention
Under, various change and modification can be carried out to the present invention.The present invention to the material that is arrived used in experiment and test method into
Row is general and/or specifically describes.Although many materials used in purpose and operating method are abilities to realize the present invention
Well known to domain, but the present invention still makees description as detailed as possible herein.
The present invention carries out the material and test method that are arrived used in experiment general and/or specific description.Though
So to realize the present invention many materials and operating method used in purpose be it is known in the art that still the present invention still herein
It is described in detail as far as possible.It will be apparent to those skilled in the art that hereinafter, if not specified, material therefor of the present invention and
Operating method is well known in the art.
Embodiment 1：
A kind of antibacterial except mite liquid detergent, is made of the raw material of following parts by weight：6 parts of dodecyldimethylammonium hydroxide inner salt,
8 parts of lauroyl N-methyltaurine sodium, 4 parts of sodium lignin sulfonate, to 4 parts of methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, three ethyl alcohol
2 parts of amine, 2 parts of Boratex, 3 parts of sodium chloride, 1 part of sodium citrate, 1 part of complex enzyme, 1.5 parts of nano-titanium dioxide, 1 part of chitosan,
3 parts of emulsifier, 1 part of chelating agent, 8 parts of organic solvent, 0.3 part of polyvinylpyrrolidone, 0.2 part of hydroxypropyl methyl cellulose are fragrant
0.2 part of essence, 3 parts of thickener, 2 parts of sorbierite, 75 parts of deionized water；
The complex enzyme is alkali protease, alpha-amylase, exoglucanase, and the weight ratio of three is 2：1：2；
The emulsifier is ethoxylated dodecyl alcohol and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1：2；
The chelating agent is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1：1；
The organic solvent is ethyl alcohol, ethylene glycol monobutyl ether and glycerine, and the volume ratio of three is 2:1:1；
Preparation method includes the following steps：
（1）Each raw material for standby is weighed in parts by weight；
（2）Deionized water is added in into reaction kettle, is warming up to 60 DEG C, then starts to stir, and sequentially adds polyethylene pyrrole
Pyrrolidone, hydroxypropyl methyl cellulose, emulsifier and nano-titanium dioxide, the mixing speed are 150r/min, are stirred
Time 20min；
（3）, step（2）After finishing, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl are sequentially added into reaction kettle
Sodium taurocholate, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, are adjusted in reaction kettle
The pH=7 of reaction solution；The mixing speed is 150r/min；
（4）, step（3）After finishing, reaction kettle is cooled to 35 DEG C, sequentially adds sodium citrate, complex enzyme and sorb
Alcohol stirs 10min, then adds in triethanolamine, Boratex, chelating agent and sodium chloride, is stirred for 10min；The stirring speed
It spends for 150r/min；
（5）, step（4）After finishing, chitosan, organic solvent, essence, thickener, stirring are added in into reaction kettle successively
20min, the mixing speed for 150r/min to get.
Embodiment 2:
A kind of antibacterial except mite liquid detergent, is made of the raw material of following parts by weight：5 parts of dodecyldimethylammonium hydroxide inner salt,
5 parts of lauroyl N-methyltaurine sodium, 3 parts of sodium lignin sulfonate, to 3 parts of methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, three ethyl alcohol
0.5 part of amine, 0.5 part of Boratex, 1 part of sodium chloride, 0.5 part of sodium citrate, 0.5 part of complex enzyme, 0.5 part of nano-titanium dioxide, shell
0.5 part of glycan, 1 part of emulsifier, 0.5 part of chelating agent, 5 parts of organic solvent, 0.1 part of polyvinylpyrrolidone, hydroxypropyl methyl are fine
0.1 part of dimension element, 0.1 part of essence, 1 part of thickener, 1 part of sorbierite, 50 parts of deionized water；
The complex enzyme is alkali protease, alpha-amylase, exoglucanase, and the weight ratio of three is 2：1：2；
The emulsifier is ethoxylated dodecyl alcohol and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1：2；
The chelating agent is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1：1；
The organic solvent is ethyl alcohol, ethylene glycol monobutyl ether and glycerine, and the volume ratio of three is 2:1:1；
Preparation method includes the following steps：
（1）Each raw material for standby is weighed in parts by weight；
（2）Deionized water is added in into reaction kettle, is warming up to 50 DEG C, then starts to stir, and sequentially adds polyethylene pyrrole
Pyrrolidone, hydroxypropyl methyl cellulose, emulsifier and nano-titanium dioxide, the mixing speed are 100r/min, are stirred
Time 20min；
（3）, step（2）After finishing, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl are sequentially added into reaction kettle
Sodium taurocholate, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, are adjusted in reaction kettle
The pH=7 of reaction solution；The mixing speed is 100r/min；
（4）, step（3）After finishing, reaction kettle is cooled to 35 DEG C, sequentially adds sodium citrate, complex enzyme and sorb
Alcohol stirs 10min, then adds in triethanolamine, Boratex, chelating agent and sodium chloride, is stirred for 10min；The stirring speed
It spends for 100r/min；
（5）, step（4）After finishing, chitosan, organic solvent, essence, thickener, stirring are added in into reaction kettle successively
20min, the mixing speed for 100r/min to get.
Embodiment 3：
A kind of antibacterial except mite liquid detergent, is made of the raw material of following parts by weight：Dodecyldimethylammonium hydroxide inner salt 10
Part, 10 parts of lauroyl N-methyltaurine sodium, 5 parts of sodium lignin sulfonate, to 5 parts of methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, three
3 parts of ethanolamine, 3 parts of Boratex, 5 parts of sodium chloride, 2 parts of sodium citrate, 2 parts of complex enzyme, 2 parts of nano-titanium dioxide, chitosan 2
Part, 5 parts of emulsifier, 2 parts of chelating agent, 10 parts of organic solvent, 0.5 part of polyvinylpyrrolidone, hydroxypropyl methyl cellulose 0.5
Part, 0.5 part of essence, 5 parts of thickener, 3 parts of sorbierite, 100 parts of deionized water；
The complex enzyme is alkali protease, alpha-amylase, exoglucanase, and the weight ratio of three is 2：1：2；
The emulsifier is ethoxylated dodecyl alcohol and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1：2；
The chelating agent is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1：1；
The organic solvent is ethyl alcohol, ethylene glycol monobutyl ether and glycerine, and the volume ratio of three is 2:1:1；
Preparation method includes the following steps：
（1）Each raw material for standby is weighed in parts by weight；
（2）Deionized water is added in into reaction kettle, is warming up to 70 DEG C, then starts to stir, and sequentially adds polyethylene pyrrole
Pyrrolidone, hydroxypropyl methyl cellulose, emulsifier and nano-titanium dioxide, the mixing speed are 200r/min, are stirred
Time 20min；
（3）, step（2）After finishing, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl are sequentially added into reaction kettle
Sodium taurocholate, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, are adjusted in reaction kettle
The pH=8 of reaction solution；The mixing speed is 200r/min；
（4）, step（3）After finishing, reaction kettle is cooled to 35 DEG C, sequentially adds sodium citrate, complex enzyme and sorb
Alcohol stirs 10min, then adds in triethanolamine, Boratex, chelating agent and sodium chloride, is stirred for 10min；The stirring speed
It spends for 200r/min；
（5）, step（4）After finishing, chitosan, organic solvent, essence, thickener, stirring are added in into reaction kettle successively
20min, the mixing speed for 200r/min to get.
Embodiment 4：
A kind of antibacterial except mite liquid detergent, is made of the raw material of following parts by weight：5 parts of dodecyldimethylammonium hydroxide inner salt,
10 parts of lauroyl N-methyltaurine sodium, 3 parts of sodium lignin sulfonate, to 5 parts of methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, three ethyl alcohol
0.5 part of amine, 3 parts of Boratex, 1 part of sodium chloride, 2 parts of sodium citrate, 0.5 part of complex enzyme, 2 parts of nano-titanium dioxide, chitosan 0.5
Part, 5 parts of emulsifier, 0.5 part of chelating agent, 10 parts of organic solvent, 0.1 part of polyvinylpyrrolidone, hydroxypropyl methyl cellulose 0.5
Part, 0.1 part of essence, 5 parts of thickener, 1 part of sorbierite, 100 parts of deionized water；
The complex enzyme is alkali protease, alpha-amylase, exoglucanase, and the weight ratio of three is 2：1：2；
The emulsifier is ethoxylated dodecyl alcohol and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1：2；
The chelating agent is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1：1；
The organic solvent is ethyl alcohol, ethylene glycol monobutyl ether and glycerine, and the volume ratio of three is 2:1:1；
Preparation method includes the following steps：
（1）Each raw material for standby is weighed in parts by weight；
（2）Deionized water is added in into reaction kettle, is warming up to 55 DEG C, then starts to stir, and sequentially adds polyethylene pyrrole
Pyrrolidone, hydroxypropyl methyl cellulose, emulsifier and nano-titanium dioxide, the mixing speed are 120r/min, are stirred
Time 20min；
（3）, step（2）After finishing, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl are sequentially added into reaction kettle
Sodium taurocholate, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, are adjusted in reaction kettle
The pH=7.5 of reaction solution；The mixing speed is 180r/min；
（4）, step（3）After finishing, reaction kettle is cooled to 35 DEG C, sequentially adds sodium citrate, complex enzyme and sorb
Alcohol stirs 10min, then adds in triethanolamine, Boratex, chelating agent and sodium chloride, is stirred for 10min；The stirring speed
It spends for 140r/min；
（5）, step（4）After finishing, chitosan, organic solvent, essence, thickener, stirring are added in into reaction kettle successively
20min, the mixing speed for 150r/min to get.
Comparative example 1（Omit lauroyl N-methyltaurine sodium）
A kind of antibacterial except mite liquid detergent, is made of the raw material of following parts by weight：6 parts of dodecyldimethylammonium hydroxide inner salt,
4 parts of sodium lignin sulfonate, to 4 parts of methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, 2 parts of triethanolamine, 2 parts of Boratex, sodium chloride 3
Part, 1 part of sodium citrate, 1 part of complex enzyme, 1.5 parts of nano-titanium dioxide, 1 part of chitosan, 3 parts of emulsifier, 1 part of chelating agent are organic
8 parts of solvent, 0.3 part of polyvinylpyrrolidone, 0.2 part of hydroxypropyl methyl cellulose, 0.2 part of essence, 3 parts of thickener, sorbierite 2
Part, 75 parts of deionized water；
Other are the same as embodiment 1.
Comparative example 2（Omit sodium lignin sulfonate）
A kind of antibacterial except mite liquid detergent, is made of the raw material of following parts by weight：6 parts of dodecyldimethylammonium hydroxide inner salt,
8 parts of lauroyl N-methyltaurine sodium, to 4 parts of methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, 2 parts of triethanolamine, 2 parts of Boratex,
3 parts of sodium chloride, 1 part of sodium citrate, 1 part of complex enzyme, 1.5 parts of nano-titanium dioxide, 1 part of chitosan, 3 parts of emulsifier, chelating agent 1
Part, 8 parts of organic solvent, 0.3 part of polyvinylpyrrolidone, 0.2 part of hydroxypropyl methyl cellulose, 0.2 part of essence, 3 parts of thickener,
2 parts of sorbierite, 75 parts of deionized water；
Other are the same as embodiment 1.
Comparative example 3（It omits to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt）
A kind of antibacterial except mite liquid detergent, is made of the raw material of following parts by weight：6 parts of dodecyldimethylammonium hydroxide inner salt,
8 parts of lauroyl N-methyltaurine sodium, 4 parts of sodium lignin sulfonate, 2 parts of triethanolamine, 2 parts of Boratex, 3 parts of sodium chloride, lemon
Sour 1 part of sodium, 1 part of complex enzyme, 1.5 parts of nano-titanium dioxide, 1 part of chitosan, 3 parts of emulsifier, 1 part of chelating agent, organic solvent 8
Part, 0.3 part of polyvinylpyrrolidone, 0.2 part of hydroxypropyl methyl cellulose, 0.2 part of essence, 3 parts of thickener, 2 parts of sorbierite are gone
75 parts of ionized water；
Other are the same as embodiment 1.
Comparative example 4（Omit polyvinylpyrrolidone）
A kind of antibacterial except mite liquid detergent, is made of the raw material of following parts by weight：6 parts of dodecyldimethylammonium hydroxide inner salt,
8 parts of lauroyl N-methyltaurine sodium, 4 parts of sodium lignin sulfonate, to 4 parts of methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, three ethyl alcohol
2 parts of amine, 2 parts of Boratex, 3 parts of sodium chloride, 1 part of sodium citrate, 1 part of complex enzyme, 1.5 parts of nano-titanium dioxide, 1 part of chitosan,
3 parts of emulsifier, 1 part of chelating agent, 8 parts of organic solvent, 0.2 part of hydroxypropyl methyl cellulose, 0.2 part of essence, 3 parts of thickener, mountain
2 parts of pears alcohol, 75 parts of deionized water；
Other are the same as embodiment 1.
Comparative example 5
The complex enzyme is alkali protease, exoglucanase, and the weight ratio of three is 2：2；
Other are the same as embodiment 1.
Comparative example 6
The emulsifier is ethoxylated dodecyl alcohol；Other are the same as embodiment 1.
Comparative example 7
The chelating agent is sodium tartrate；Other are the same as embodiment 1.
Comparative example 8
The organic solvent is ethyl alcohol, ethylene glycol monobutyl ether, and the volume ratio of three is 2:1；Other are the same as embodiment 1.
1 detergency test of test example
The detergency test of antibacterial except mite liquid detergent sample is with reference to GB/T13174-2008《Dress material with detergent detergency and
Cycle the measure of scourability》It carries out, the experimental results showed that, antibacterial except mite laundry made from embodiment 1-4 and comparative example 1-8
Liquid is as shown in table 1 to carbon black oil soiled cotton, albumen soiled cotton, sebum soiled cotton decontamination value and the ratio of standard liquid detergent decontamination value.
1 antibacterial except mite liquid detergent detergency test result of table
| Group | Carbon black oil soiled cotton | Albumen soiled cotton | Sebum soiled cotton |
| Embodiment 1 | 1.38 | 1.36 | 1.45 |
| Embodiment 2 | 1.35 | 1.38 | 1.48 |
| Embodiment 3 | 1.36 | 1.38 | 1.46 |
| Embodiment 4 | 1.37 | 1.34 | 1.43 |
| Comparative example 1 | 1.03 | 1.05 | 1.11 |
| Comparative example 2 | 1.12 | 1.10 | 1.16 |
| Comparative example 3 | 1.08 | 1.06 | 1.10 |
| Comparative example 4 | 1.02 | 1.05 | 1.03 |
| Comparative example 5 | 1.09 | 1.15 | 1.18 |
| Comparative example 6 | 1.13 | 1.07 | 1.05 |
| Comparative example 7 | 1.15 | 1.19 | 1.26 |
| Comparative example 8 | 1.13 | 1.01 | 1.08 |
Table 1 statistics indicate that, 1-4 of the embodiment of the present invention prepare antibacterial except mite liquid detergent have stronger detergency, together
When table 1 data also show that each component of the present invention mutually cooperates with, clean effect can be declined by omitting some components therein.
Test example 2：Anti-microbial property test
The antibacterial ability test of antibacterial except mite liquid detergent sample is with reference to QB/T2738-2012《Daily chemical products antibacterial and antibacterial
The evaluation method of effect》It carries out, activity 1:100,20 minutes action time, the experimental results showed that, Examples 1 to 4 and right
Ratio 1-8 all samples are as shown in table 2 to the sterilizing rate of Escherichia coli ATCC25922 and staphylococcus glucose bacterium ATCC6538.
The bactericidal effect of the 2 antibacterial except mite liquid detergent of the present invention of table
| Group | Escherichia coli ATCC25922 | Staphylococcus glucose bacterium ATCC6538 |
| Embodiment 1 | 99.95 | 99.96 |
| Embodiment 2 | 99.96 | 99.92 |
| Embodiment 3 | 99.93 | 99.98 |
| Embodiment 4 | 99.99 | 99.97 |
| Comparative example 1 | 99.53 | 98.59 |
| Comparative example 2 | 98.72 | 99.16 |
| Comparative example 3 | 99.67 | 99.51 |
| Comparative example 4 | 98.59 | 98.24 |
| Comparative example 5 | 98.35 | 99.20 |
| Comparative example 6 | 99.85 | 99.80 |
| Comparative example 7 | 99.50 | 99.42 |
| Comparative example 8 | 99.37 | 99.68 |
Table 2 statistics indicate that, 1-4 of the embodiment of the present invention prepare antibacterial except mite liquid detergent have stronger fungistatic effect,
The data of table 2 also show that each component of the present invention mutually cooperates with simultaneously, and fungistatic effect can be declined by omitting some components therein.
Claims (4)
1. a kind of preparation method of antibacterial except mite liquid detergent, which is characterized in that the antibacterial except mite liquid detergent is by following parts by weight
Several raw materials are made：5-10 parts of dodecyldimethylammonium hydroxide inner salt, 5-10 parts of lauroyl N-methyltaurine sodium, sulfomethylated lignin
Sour sodium 3-5 parts, to 3-5 parts of methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, 0.5-3 parts of triethanolamine, 0.5-3 parts of Boratex, chlorination
1-5 parts of sodium, 0.5-2 parts of sodium citrate, 0.5-2 parts of complex enzyme, 0.5-2 parts of nano-titanium dioxide, 0.5-2 parts of chitosan, emulsification
1-5 parts of agent, 0.5-2 parts of chelating agent, 5-10 parts of organic solvent, 0.1-0.5 parts of polyvinylpyrrolidone, hydroxypropyl methyl cellulose
0.1-0.5 parts, 0.1-0.5 parts of essence, 1-5 parts of thickener, 1-3 parts of sorbierite, 50-100 parts of deionized water；
Wherein complex enzyme is alkali protease, alpha-amylase, exoglucanase, and the weight ratio of three is 2：1：2；Wherein emulsify
Agent is ethoxylated dodecyl alcohol and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1：2；Wherein chelating agent is sodium tartrate
And sodium gluconate, the weight ratio of the two is 1：1；Wherein organic solvent be ethyl alcohol, ethylene glycol monobutyl ether and glycerine, the body of three
Product is than being 2:1:1；
The preparation method of the antibacterial except mite liquid detergent includes the following steps：
（1）Each raw material for standby is weighed in parts by weight；
（2）Deionized water is added in into reaction kettle, is warming up to 50-70 DEG C, then starts to stir, and sequentially adds polyvinyl pyrrole
Alkanone, hydroxypropyl methyl cellulose, emulsifier and nano-titanium dioxide, the mixing speed are 100~200r/min, are stirred
Mix time 20min；
（3）Step（2）After finishing, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl ox sulphur are sequentially added into reaction kettle
Sour sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, adjust reaction in reaction kettle
PH=7~8 of liquid；The mixing speed is 100~200r/min；
（4）, step（3）After finishing, reaction kettle is cooled to 35 DEG C, sequentially adds sodium citrate, complex enzyme and sorbierite, stir
10min is mixed, triethanolamine, Boratex, chelating agent and sodium chloride is then added in, is stirred for 10min；The mixing speed is
100~200r/min；
（5）, step（4）After finishing, chitosan, organic solvent, essence, thickener, stirring are added in into reaction kettle successively
20min, the mixing speed for 100~200r/min to get.
2. the preparation method of antibacterial except mite liquid detergent according to claim 1, wherein essence are peppermint oil, eucalyptus oil, lemon
Lemon oil, refined jasmine oil, attar of rose or caryophyllus oil.
3. the preparation method of antibacterial except mite liquid detergent according to claim 1, wherein thickener for xanthans, carragheen or
Person's carrageenan.
4. the Weight-average molecular of the preparation method, wherein sodium lignin sulfonate of antibacterial except mite liquid detergent according to claim 1
It measures as 2000 dalton to 6000 dalton.
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| CN106336963A (en) * | 2016-07-29 | 2017-01-18 | 林祥岭 | Biotin laundry detergent |
| CN106635458A (en) * | 2016-11-14 | 2017-05-10 | 陈啟文 | Laundry detergent and preparation method thereof |
| CN108102823A (en) * | 2016-11-24 | 2018-06-01 | 陈君君 | A kind of low bubble multifunctional liquid detergent of except mite |
| CN106968103A (en) * | 2017-04-11 | 2017-07-21 | 安徽博硕科技有限公司 | A kind of special bleaching agent of clothes and preparation method thereof |
| CN107345178A (en) * | 2017-07-07 | 2017-11-14 | 广州克思曼研磨科技有限公司 | A kind of nanometer cleaning-nursing liquid and preparation method thereof |
| CN107524000A (en) * | 2017-08-01 | 2017-12-29 | 江苏新瑞贝科技股份有限公司 | A kind of preparation method of natural antibacterial mite-assistant fabricses coating |
| CN109055034A (en) * | 2018-08-08 | 2018-12-21 | 廖家平 | Liquid detergent |
| DE102019102452A1 (en) * | 2019-01-31 | 2020-08-06 | Henkel Ag & Co. Kgaa | Improving washing performance with Taurat surfactants |
| CN112210447A (en) * | 2020-10-14 | 2021-01-12 | 山西洁锐奇化工有限公司 | Towel mite-removing cleaning agent and preparation method thereof |
| CN114403159A (en) * | 2020-10-28 | 2022-04-29 | 广州市华晟健康产业有限公司 | Sterilizing spray |
| CN113528250B (en) * | 2021-07-23 | 2022-08-12 | 孟庆峰 | Antibacterial laundry detergent and preparation method thereof |
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| CN105400611A (en) * | 2014-09-06 | 2016-03-16 | 天津市天亨洗涤剂有限公司 | Multifunctional laundry detergent |
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