CN105886147A - Antibacterial acarus killing laundry detergent - Google Patents
Antibacterial acarus killing laundry detergent Download PDFInfo
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- CN105886147A CN105886147A CN201610446651.2A CN201610446651A CN105886147A CN 105886147 A CN105886147 A CN 105886147A CN 201610446651 A CN201610446651 A CN 201610446651A CN 105886147 A CN105886147 A CN 105886147A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/30—Sulfonation products derived from lignin
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Abstract
The invention relates to antibacterial acarus killing laundry detergent. The antibacterial acarus killing laundry detergent is prepared from, by weight, 5-10 parts of dodecyl dimethyl betaine, 5-10 parts of sodium lauroylmethyltaurate, 3-5 parts of sodium lignin sulfonate, 3-5 parts of cleaner LS, 0.5-3 parts of triethanolamine, 0.5-3 parts of sodium borate, 1-5 parts of sodium chloride, 0.5-2 parts of sodium citrate, 0.5-2 parts of complex enzymes, 0.5-2 parts of nano titanium dioxide, 0.5-2 parts of chitosan, 1-5 parts of an emulsifier, 0.5-2 parts of a chelating agent, 5-10 parts of an organic solvent, 0.1-0.5 part of polyvinylpyrrolidone, 0.1-0.5 part of hydroxypropyl methyl cellulose, 0.1-0.5 part of essences, 1-5 parts of a thickening agent, 1-3 parts of sorbitol and 50-100 parts of deionized water. The antibacterial acarus killing laundry detergent is high in detergency power, remarkable in antibacterial and acarus killing effect and free of side effects and avoids clothes fading, skin irritation and pollution.
Description
Technical field
The present invention relates to a kind of liquid detergent, in particular to a kind of liquid detergent with antibacterial acaricide effect.
Background technology
Wearing the clothes, be a big fundamental of human lives, from ancient times to the present, it is non-that the cleaning of medicated clothing is always people's daily life
A most important part, along with the raising of modern's quality of life, the performance requirement of laundry daily chemicals is also constantly carrying
Rising, the most the most commonly used laundry daily chemicals is detergent, and detergent has preferable decontamination cleaning effect, but does washing
Powder, as a kind of powder detergent, frequently appears in water insufficient situation of dissolving in use, and one to affect medicated clothing
Clean result, in two detergent failing fully to dissolve in local can cause regional area, detergent concentration is excessive so that should
The alkalescence in region is very big, medicated clothing can be caused damage, and three carry out detergent due to easily redeposited on medicated clothing containing a lot of solid additives
Making fabric harden, meanwhile, detergent is relatively strong to the zest of skin, easily injures the skin of washer's hand, the most nowadays
The market share of detergent is more and more lower, and liquid detergent is because of the states of matter character of itself liquid, determines liquid detergent in water
Dissolution dispersity be much better than detergent, the dispersibility that liquid detergent is good determines liquid detergent can wash medicated clothing equably, with
Time liquid detergent surfactant water-soluble good, easily rinse, deposition less and it can be avoided that because of local concentration cross major injury laundry
The hand skin of person, therefore laundry dailyization that the more preferable liquid detergent of performance of people's big more options laundry now is commonly used as family
Work product.
Along with improving constantly of health of people consciousness, the requirement of laundry detergent compositions is the most not merely confined to be only capable of by people
Clean medicated clothing just, medicated clothing as most frequently contacting the articles for daily use of human body skin, above unavoidable contamination have the antiperspirant on skin
The dirts such as body thing are posted on liquid, scurf, skin secretion and skin, simultaneously during clothes contact external environment, the easily extraneous ring of contamination
The pollutant such as the antibacterial in border and virus, the two effect medicated clothing is become hotbed that biological pollutant grows and passing to human body
The passage broadcast.Acarid is after flea, fly, mankind room insect the most rampant.The skin histology that it sucks exclusively by thorn
Cell, the oils and fats etc. of skin gland secretion are made a living.The general long 0.1-0.2 millimeter of acarid, kind is a lot, almost has 500,000 kinds, its
Middle human Demodex is a kind of parasite that in crowd, infection rate is higher, and it parasitizes in hair follicle and sebaceous gland, and with Cell sap
Deng for nutrient substance；Its strong chelicera also has destruction to the skin histology of host, makes a part of the infected show and faces
Bed symptom；There is skin pruritus, little pimple etc. in the lighter, and severe one can cause rosacea, folliculitis, seborrheic dermatitis and acne.And
Clothes can only be played the effect of decontamination by the general liquid detergent cleaned, and can not play the effect of sterilization, for health
Consider, need a kind of liquid detergent that can effectively play antibacterial acaricide effect.
Summary of the invention
The present invention provides a kind of antibacterial acaricide liquid detergent, this liquid detergent strong detergency, has disinfecting mite-removing effect simultaneously, kills
The bacterium time is short, and bactericidal effect is good.
Specifically, the present invention provides antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dimethyl
Base glycine betaine 5-10 part, lauroyl N-methyltaurine sodium 5-10 part, sodium lignin sulfonate 3-5 part, to methoxyl group fatty acid amide
Base benzene sulfonic acid sodium salt 3-5 part, triethanolamine 0.5-3 part, sodium borate 0.5-3 part, sodium chloride 1-5 part, sodium citrate 0.5-2 part, multiple
Synthase 0.5-2 part, nano titanium oxide 0.5-2 part, chitosan 0.5-2 part, emulsifying agent 1-5 part, chelating agen 0.5-2 part is organic
Solvent 5-10 part, polyvinylpyrrolidone 0.1-0.5 part, hydroxypropyl methyl cellulose 0.1-0.5 part, essence 0.1-0.5 part, increase
Thick dose of 1-5 part, sorbitol 1-3 part, deionized water 50-100 part.
In one specific embodiment of the present invention, described antibacterial acaricide liquid detergent is by the raw material of following parts by weight
Making: dodecyldimethylammonium hydroxide inner salt 6 parts, 8 parts of lauroyl N-methyltaurine sodium, sodium lignin sulfonate 4 parts, to methoxy
Base fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2 parts, sodium borate 2 parts, 3 parts of sodium chloride, sodium citrate 1 part, compound enzyme 1
Part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying agent 3 parts, chelating agen 1 part, organic solvent 8 parts, polyvinylpyrrolidone
0.3 part, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, sorbitol 2 parts, deionized water 75 parts.
In one specific embodiment of the present invention, described antibacterial acaricide liquid detergent is by the raw material of following parts by weight
Making: dodecyldimethylammonium hydroxide inner salt 5 parts, 5 parts of lauroyl N-methyltaurine sodium, sodium lignin sulfonate 3 parts, to methoxy
Base fatty acyl amido benzene sulfonic acid sodium salt 3 parts, triethanolamine 0.5 part, sodium borate 0.5 part, 1 part of sodium chloride, sodium citrate 0.5 part, multiple
Synthase 0.5 part, nano titanium oxide 0.5 part, chitosan 0.5 part, emulsifying agent 1 part, chelating agen 0.5 part, organic solvent 5 parts, poly-
Vinylpyrrolidone 0.1 part, hydroxypropyl methyl cellulose 0.1 part, 0.1 part of essence, thickening agent 1 part, sorbitol 1 part, deionization
50 parts of water.
In one specific embodiment of the present invention, described antibacterial acaricide liquid detergent is by the raw material of following parts by weight
Making: dodecyldimethylammonium hydroxide inner salt 10 parts, 10 parts of lauroyl N-methyltaurine sodium, sodium lignin sulfonate 5 parts, to first
Epoxide fatty acyl amido benzene sulfonic acid sodium salt 5 parts, triethanolamine 3 parts, sodium borate 3 parts, 5 parts of sodium chloride, sodium citrate 2 parts, compound enzyme 2
Part, nano titanium oxide 2 parts, chitosan 2 parts, emulsifying agent 5 parts, chelating agen 2 parts, organic solvent 10 parts, polyvinylpyrrolidone
0.5 part, hydroxypropyl methyl cellulose 0.5 part, 0.5 part of essence, thickening agent 5 parts, sorbitol 3 parts, deionized water 100 parts.
In one specific embodiment of the present invention, described antibacterial acaricide liquid detergent is by the raw material of following parts by weight
Making: dodecyldimethylammonium hydroxide inner salt 5 parts, 10 parts of lauroyl N-methyltaurine sodium, sodium lignin sulfonate 3 parts, to methoxy
Base fatty acyl amido benzene sulfonic acid sodium salt 5 parts, triethanolamine 0.5 part, sodium borate 3 parts, 1 part of sodium chloride, sodium citrate 2 parts, compound enzyme
0.5 part, nano titanium oxide 2 parts, chitosan 0.5 part, emulsifying agent 5 parts, chelating agen 0.5 part, organic solvent 10 parts, polyethylene pyrrole
Pyrrolidone 0.1 part, hydroxypropyl methyl cellulose 0.5 part, 0.1 part of essence, thickening agent 5 parts, sorbitol 1 part, deionized water 100
Part.
In one specific embodiment of the present invention, described compound enzyme is alkaline protease, α-amylase, circumscribed Portugal
Dextranase, the weight ratio of three is 2:1:2.
In one specific embodiment of the present invention, described emulsifying agent is that polyoxyethylene lauryl ether and stearic acid gather
Oxygen vinyl acetate, the weight ratio of the two is 1:2.
In one specific embodiment of the present invention, described chelating agen is sodium tartrate and sodium gluconate, the two
Weight ratio be 1:1.
In one specific embodiment of the present invention, described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol,
The volume ratio of three is 2:1:1.
In one specific embodiment of the present invention, described essence is Oleum menthae, Eucalyptus oil, Fructus Citri Limoniae oil, jasmine essence
Oil, Oleum Rosae Rugosae or Oleum Caryophylli.
In one specific embodiment of the present invention, described thickening agent is xanthan gum, carrageenan or carrageenin.
In one specific embodiment of the present invention, the weight average molecular weight of described sodium lignin sulfonate is 2000 dongle
Pause to 6000 dalton.
Another aspect of the present invention provides the preparation method of described antibacterial acaricide liquid detergent, comprises the steps:
(1) each raw material for standby is weighed by weight；
(2) in reactor, add deionized water, be warmed up to 50-70 DEG C, then start stirring, and be sequentially added into polyvinyl pyrrole
Alkanone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 100～200r/min, stirs
Mix time 20min；
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into
Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor
The pH=7～8 of liquid；Described mixing speed is 100～200r/min；
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs
Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min；Described mixing speed is
100～200r/min；
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively
20min, described mixing speed is 100～200r/min, to obtain final product.
In the present invention in the case of without specified otherwise, all percentage ratios are all weight percentage.
Below in conjunction with specific embodiment, the invention will be further described.
Detailed description of the invention
By the following examples can the present invention will be further elaborated, but, the scope of the present invention not office
It is limited to following embodiment.Those skilled in the art are it can be appreciated that in the premise without departing substantially from the spirit and scope of the present invention
Under, the present invention can be carried out various change and modification.The present invention to test used in material and test method enter
The description that row is general and/or concrete.Although being ability by realizing many materials that the object of the invention used and operational approach
Known to territory, but the present invention still makees the most detailed description at this.
The present invention to test used in material and test method carry out generality and/or concrete description.Though
It is so to it is known in the art that still the present invention is still at this for realizing many materials that the object of the invention used and operational approach
Describe in detail as far as possible.It will be apparent to those skilled in the art that hereinafter, if not specified, material therefor of the present invention and
Operational approach is well known in the art.
Embodiment 1:
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, Laurel
Sulfonylmethyl sodium taurocholate 8 parts, sodium lignin sulfonate 4 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2
Part, sodium borate 2 parts, 3 parts of sodium chloride, sodium citrate 1 part, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying
Agent 3 parts, chelating agen 1 part, organic solvent 8 parts, polyvinylpyrrolidone 0.3 part, hydroxypropyl methyl cellulose 0.2 part, essence 0.2
Part, thickening agent 3 parts, sorbitol 2 parts, deionized water 75 parts；
Described compound enzyme is alkaline protease, α-amylase, exoglucanase, and the weight ratio of three is 2:1:2；
Described emulsifying agent is polyoxyethylene lauryl ether and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1:2；
Described chelating agen is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1:1；
Described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol, and the volume ratio of three is 2:1:1；
Preparation method comprises the steps:
(1) each raw material for standby is weighed by weight；
(2) in reactor, add deionized water, be warmed up to 60 DEG C, then start stirring, and be sequentially added into polyvinylpyrrolidine
Ketone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 150r/min, mixing time
20min；
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into
Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor
The pH=7 of liquid；Described mixing speed is 150r/min；
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs
Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min；Described mixing speed is
150r/min；
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively
20min, described mixing speed is 150r/min, to obtain final product.
Embodiment 2:
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 5 parts, Laurel
Sulfonylmethyl sodium taurocholate 5 parts, sodium lignin sulfonate 3 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 3 parts, triethanolamine 0.5
Part, sodium borate 0.5 part, 1 part of sodium chloride, sodium citrate 0.5 part, compound enzyme 0.5 part, nano titanium oxide 0.5 part, chitosan
0.5 part, emulsifying agent 1 part, chelating agen 0.5 part, organic solvent 5 parts, polyvinylpyrrolidone 0.1 part, hydroxypropyl methyl cellulose
0.1 part, 0.1 part of essence, thickening agent 1 part, sorbitol 1 part, deionized water 50 parts；
Described compound enzyme is alkaline protease, α-amylase, exoglucanase, and the weight ratio of three is 2:1:2；
Described emulsifying agent is polyoxyethylene lauryl ether and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1:2；
Described chelating agen is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1:1；
Described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol, and the volume ratio of three is 2:1:1；
Preparation method comprises the steps:
(1) each raw material for standby is weighed by weight；
(2) in reactor, add deionized water, be warmed up to 50 DEG C, then start stirring, and be sequentially added into polyvinylpyrrolidine
Ketone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 100r/min, mixing time
20min；
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into
Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor
The pH=7 of liquid；Described mixing speed is 100r/min；
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs
Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min；Described mixing speed is
100r/min；
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively
20min, described mixing speed is 100r/min, to obtain final product.
Embodiment 3:
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 10 parts, the moon
Osmanthus sulfonylmethyl sodium taurocholate 10 parts, sodium lignin sulfonate 5 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 5 parts, triethanolamine
3 parts, sodium borate 3 parts, 5 parts of sodium chloride, sodium citrate 2 parts, compound enzyme 2 parts, nano titanium oxide 2 parts, chitosan 2 parts, emulsifying
Agent 5 parts, chelating agen 2 parts, organic solvent 10 parts, polyvinylpyrrolidone 0.5 part, hydroxypropyl methyl cellulose 0.5 part, essence
0.5 part, thickening agent 5 parts, sorbitol 3 parts, deionized water 100 parts；
Described compound enzyme is alkaline protease, α-amylase, exoglucanase, and the weight ratio of three is 2:1:2；
Described emulsifying agent is polyoxyethylene lauryl ether and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1:2；
Described chelating agen is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1:1；
Described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol, and the volume ratio of three is 2:1:1；
Preparation method comprises the steps:
(1) each raw material for standby is weighed by weight；
(2) in reactor, add deionized water, be warmed up to 70 DEG C, then start stirring, and be sequentially added into polyvinylpyrrolidine
Ketone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 200r/min, mixing time
20min；
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into
Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor
The pH=8 of liquid；Described mixing speed is 200r/min；
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs
Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min；Described mixing speed is
200r/min；
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively
20min, described mixing speed is 200r/min, to obtain final product.
Embodiment 4:
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 5 parts, Laurel
Sulfonylmethyl sodium taurocholate 10 parts, sodium lignin sulfonate 3 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 5 parts, triethanolamine
0.5 part, sodium borate 3 parts, 1 part of sodium chloride, sodium citrate 2 parts, compound enzyme 0.5 part, nano titanium oxide 2 parts, chitosan 0.5
Part, emulsifying agent 5 parts, chelating agen 0.5 part, organic solvent 10 parts, polyvinylpyrrolidone 0.1 part, hydroxypropyl methyl cellulose 0.5
Part, 0.1 part of essence, thickening agent 5 parts, sorbitol 1 part, deionized water 100 parts；
Described compound enzyme is alkaline protease, α-amylase, exoglucanase, and the weight ratio of three is 2:1:2；
Described emulsifying agent is polyoxyethylene lauryl ether and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1:2；
Described chelating agen is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1:1；
Described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol, and the volume ratio of three is 2:1:1；
Preparation method comprises the steps:
(1) each raw material for standby is weighed by weight；
(2) in reactor, add deionized water, be warmed up to 55 DEG C, then start stirring, and be sequentially added into polyvinylpyrrolidine
Ketone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 120r/min, mixing time
20min；
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into
Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor
The pH=7.5 of liquid；Described mixing speed is 180r/min；
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs
Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min；Described mixing speed is
140r/min；
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively
20min, described mixing speed is 150r/min, to obtain final product.
Comparative example 1(omits lauroyl N-methyltaurine sodium)
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, wooden
Element sodium sulfonate 4 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2 parts, sodium borate 2 parts, 3 parts of sodium chloride, lemon
1 part of lemon acid sodium, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying agent 3 parts, chelating agen 1 part, organic solvent 8
Part, polyvinylpyrrolidone 0.3 part, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, sorbitol 2 parts, goes
Ionized water 75 parts；
Other are with embodiment 1.
Comparative example 2(omits sodium lignin sulfonate)
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, Laurel
Sulfonylmethyl sodium taurocholate 8 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2 parts, sodium borate 2 parts, chlorination
3 parts of sodium, sodium citrate 1 part, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying agent 3 parts, chelating agen 1 part,
Organic solvent 8 parts, polyvinylpyrrolidone 0.3 part, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, mountain
Pears alcohol 2 parts, deionized water 75 parts；
Other are with embodiment 1.
Comparative example 3(is omitted methoxyl group fatty acyl amido benzene sulfonic acid sodium salt)
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, Laurel
Sulfonylmethyl sodium taurocholate 8 parts, sodium lignin sulfonate 4 parts, triethanolamine 2 parts, sodium borate 2 parts, 3 parts of sodium chloride, sodium citrate 1
Part, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying agent 3 parts, chelating agen 1 part, organic solvent 8 parts, poly-second
Alkene pyrrolidone 0.3 part, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, sorbitol 2 parts, deionized water
75 parts；
Other are with embodiment 1.
Comparative example 4(omits polyvinylpyrrolidone)
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, Laurel
Sulfonylmethyl sodium taurocholate 8 parts, sodium lignin sulfonate 4 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2
Part, sodium borate 2 parts, 3 parts of sodium chloride, sodium citrate 1 part, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying
Agent 3 parts, chelating agen 1 part, organic solvent 8 parts, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, sorbitol 2
Part, deionized water 75 parts；
Other are with embodiment 1.
Comparative example 5
Described compound enzyme is alkaline protease, exoglucanase, and the weight ratio of three is 2:2；
Other are with embodiment 1.
Comparative example 6
Described emulsifying agent is polyoxyethylene lauryl ether；Other are with embodiment 1.
Comparative example 7
Described chelating agen is sodium tartrate；Other are with embodiment 1.
Comparative example 8
Described organic solvent is ethanol, ethylene glycol monobutyl ether, and the volume ratio of three is 2:1；Other are with embodiment 1.
Test example 1 detergency test
The detergency test of antibacterial acaricide liquid detergent sample is with reference to GB/T13174-2008 " dress material detergent detergency and circulation
The mensuration of scourability " carry out, test result indicate that, the antibacterial acaricide liquid detergent pair that embodiment 1-4 and comparative example 1-8 prepare
Carbon black oil soiled cotton, albumen soiled cotton, sebum soiled cotton decontamination value are as shown in table 1 with the ratio of standard liquid detergent decontamination value.
Table 1 antibacterial acaricide liquid detergent detergency test result
| Group | Carbon black oil soiled cotton | Albumen soiled cotton | Sebum soiled cotton |
| Embodiment 1 | 1.38 | 1.36 | 1.45 |
| Embodiment 2 | 1.35 | 1.38 | 1.48 |
| Embodiment 3 | 1.36 | 1.38 | 1.46 |
| Embodiment 4 | 1.37 | 1.34 | 1.43 |
| Comparative example 1 | 1.03 | 1.05 | 1.11 |
| Comparative example 2 | 1.12 | 1.10 | 1.16 |
| Comparative example 3 | 1.08 | 1.06 | 1.10 |
| Comparative example 4 | 1.02 | 1.05 | 1.03 |
| Comparative example 5 | 1.09 | 1.15 | 1.18 |
| Comparative example 6 | 1.13 | 1.07 | 1.05 |
| Comparative example 7 | 1.15 | 1.19 | 1.26 |
| Comparative example 8 | 1.13 | 1.01 | 1.08 |
The data of table 1 show, antibacterial acaricide liquid detergent prepared by embodiment of the present invention 1-4 has stronger detergency, simultaneously table 1
Data also show that each component of the present invention is the most collaborative, omit some component therein and clean effect can be made to decline.
Test example 2: anti-microbial property is tested
With reference to QB/T2738-2012, " daily chemical products is antibacterial and fungistatic effect in the antibacterial ability test of antibacterial acaricide liquid detergent sample
Evaluation methodology " carry out, activity 1:100,20 minutes action time, test result indicate that, embodiment 1～4 and comparative example
1-8 all samples is as shown in table 2 to the sterilizing rate of escherichia coli ATCC25922 and staphylococcus glucose bacterium ATCC6538.
The bactericidal effect of table 2 present invention antibacterial acaricide liquid detergent
| Group | Escherichia coli ATCC25922 | Staphylococcus glucose bacterium ATCC6538 |
| Embodiment 1 | 99.95 | 99.96 |
| Embodiment 2 | 99.96 | 99.92 |
| Embodiment 3 | 99.93 | 99.98 |
| Embodiment 4 | 99.99 | 99.97 |
| Comparative example 1 | 99.53 | 98.59 |
| Comparative example 2 | 98.72 | 99.16 |
| Comparative example 3 | 99.67 | 99.51 |
| Comparative example 4 | 98.59 | 98.24 |
| Comparative example 5 | 98.35 | 99.20 |
| Comparative example 6 | 99.85 | 99.80 |
| Comparative example 7 | 99.50 | 99.42 |
| Comparative example 8 | 99.37 | 99.68 |
The data of table 2 show, antibacterial acaricide liquid detergent prepared by embodiment of the present invention 1-4 has stronger fungistatic effect, simultaneously
The data of table 2 also show that each component of the present invention is the most collaborative, omit some component therein and fungistatic effect can be made to decline.
Claims (8)
1. an antibacterial acaricide liquid detergent, it is characterised in that be made up of the raw material of following parts by weight: dodecyl dimethyl is sweet
Dish alkali 5-10 part, lauroyl N-methyltaurine sodium 5-10 part, sodium lignin sulfonate 3-5 part, to methoxyl group fatty acyl amido benzene
Sodium sulfonate 3-5 part, triethanolamine 0.5-3 part, sodium borate 0.5-3 part, sodium chloride 1-5 part, sodium citrate 0.5-2 part, compound enzyme
0.5-2 part, nano titanium oxide 0.5-2 part, chitosan 0.5-2 part, emulsifying agent 1-5 part, chelating agen 0.5-2 part, organic solvent
5-10 part, polyvinylpyrrolidone 0.1-0.5 part, hydroxypropyl methyl cellulose 0.1-0.5 part, essence 0.1-0.5 part, thickening agent
1-5 part, sorbitol 1-3 part, deionized water 50-100 part.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein compound enzyme is alkaline protease, α-amylase, circumscribed
Glucanase, the weight ratio of three is 2:1:2.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein emulsifying agent is polyoxyethylene lauryl ether and stearic acid
Polyoxyethylene ester, the weight ratio of the two is 1:2.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein chelating agen is sodium tartrate and sodium gluconate, the two
Weight ratio be 1:1.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein organic solvent is ethanol, ethylene glycol monobutyl ether and sweet
Oil, the volume ratio of three is 2:1:1.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein essence is Oleum menthae, Eucalyptus oil, Fructus Citri Limoniae oil, jasmine essence
Oil, Oleum Rosae Rugosae or Oleum Caryophylli.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein thickening agent is xanthan gum, carrageenan or chondrus ocellatus Holmes
Glue.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein the weight average molecular weight of sodium lignin sulfonate is 2000 roads
Er Dun to 6000 dalton.
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| CN106968103A (en) * | 2017-04-11 | 2017-07-21 | 安徽博硕科技有限公司 | A kind of special bleaching agent of clothes and preparation method thereof |
| CN107345178A (en) * | 2017-07-07 | 2017-11-14 | 广州克思曼研磨科技有限公司 | A kind of nanometer cleaning-nursing liquid and preparation method thereof |
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| CN112210447A (en) * | 2020-10-14 | 2021-01-12 | 山西洁锐奇化工有限公司 | Towel mite-removing cleaning agent and preparation method thereof |
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