CN105886147A - Antibacterial acarus killing laundry detergent - Google Patents
Antibacterial acarus killing laundry detergent Download PDFInfo
- Publication number
- CN105886147A CN105886147A CN201610446651.2A CN201610446651A CN105886147A CN 105886147 A CN105886147 A CN 105886147A CN 201610446651 A CN201610446651 A CN 201610446651A CN 105886147 A CN105886147 A CN 105886147A
- Authority
- CN
- China
- Prior art keywords
- parts
- sodium
- antibacterial
- liquid detergent
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003599 detergent Substances 0.000 title claims abstract description 58
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 43
- 241000934067 Acarus Species 0.000 title abstract 5
- 230000002147 killing effect Effects 0.000 title abstract 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 38
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 27
- 239000003960 organic solvent Substances 0.000 claims abstract description 27
- 102000004190 Enzymes Human genes 0.000 claims abstract description 25
- 108090000790 Enzymes Proteins 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims abstract description 21
- 239000002562 thickening agent Substances 0.000 claims abstract description 21
- 229920001661 Chitosan Polymers 0.000 claims abstract description 20
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910021538 borax Inorganic materials 0.000 claims abstract description 20
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims abstract description 20
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims abstract description 20
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims abstract description 20
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 20
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims abstract description 20
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims abstract description 19
- 239000011780 sodium chloride Substances 0.000 claims abstract description 19
- 239000001509 sodium citrate Substances 0.000 claims abstract description 19
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 19
- 239000000600 sorbitol Substances 0.000 claims abstract description 19
- 239000008367 deionised water Substances 0.000 claims abstract description 18
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 18
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 13
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 13
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 12
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000007788 liquid Substances 0.000 claims description 50
- 230000000895 acaricidal effect Effects 0.000 claims description 33
- 239000000642 acaricide Substances 0.000 claims description 33
- -1 methoxyl group Chemical group 0.000 claims description 33
- 150000001875 compounds Chemical class 0.000 claims description 24
- 229940088598 enzyme Drugs 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 19
- 239000002994 raw material Substances 0.000 claims description 19
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 19
- 125000003368 amide group Chemical group 0.000 claims description 18
- GFOBSZSXQKGNMN-UHFFFAOYSA-N 2-[dodecanoyl(methyl)amino]ethanesulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)N(C)CCS(O)(=O)=O GFOBSZSXQKGNMN-UHFFFAOYSA-N 0.000 claims description 7
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 7
- 108091005658 Basic proteases Proteins 0.000 claims description 7
- 239000003921 oil Substances 0.000 claims description 7
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 claims description 7
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 claims description 7
- 239000001433 sodium tartrate Substances 0.000 claims description 7
- 229960002167 sodium tartrate Drugs 0.000 claims description 7
- 235000011004 sodium tartrates Nutrition 0.000 claims description 7
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims description 6
- 102000004139 alpha-Amylases Human genes 0.000 claims description 6
- 108090000637 alpha-Amylases Proteins 0.000 claims description 6
- 229940024171 alpha-amylase Drugs 0.000 claims description 6
- 239000000176 sodium gluconate Substances 0.000 claims description 6
- 235000012207 sodium gluconate Nutrition 0.000 claims description 6
- 229940005574 sodium gluconate Drugs 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 5
- 235000010418 carrageenan Nutrition 0.000 claims description 3
- 229920001525 carrageenan Polymers 0.000 claims description 3
- 235000010254 Jasminum officinale Nutrition 0.000 claims description 2
- 240000005385 Jasminum sambac Species 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- 239000000679 carrageenan Substances 0.000 claims description 2
- 229940113118 carrageenan Drugs 0.000 claims description 2
- 229940044949 eucalyptus oil Drugs 0.000 claims description 2
- 239000010642 eucalyptus oil Substances 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 239000000230 xanthan gum Substances 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- 235000010493 xanthan gum Nutrition 0.000 claims description 2
- 229940082509 xanthan gum Drugs 0.000 claims description 2
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 2
- 235000009508 confectionery Nutrition 0.000 claims 2
- 241001147468 Chondrus ocellatus Species 0.000 claims 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- MWOBKFYERIDQSZ-UHFFFAOYSA-N benzene;sodium Chemical compound [Na].C1=CC=CC=C1 MWOBKFYERIDQSZ-UHFFFAOYSA-N 0.000 claims 1
- 125000001924 fatty-acyl group Chemical group 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 239000000686 essence Substances 0.000 abstract description 6
- DABQDIXIAXPQFG-UHFFFAOYSA-N 2-[dodecanoyl(methyl)amino]ethanesulfonic acid Chemical compound CCCCCCCCCCCC(=O)N(C)CCS(O)(=O)=O DABQDIXIAXPQFG-UHFFFAOYSA-N 0.000 abstract 1
- 206010040880 Skin irritation Diseases 0.000 abstract 1
- 239000002738 chelating agent Substances 0.000 abstract 1
- 238000005562 fading Methods 0.000 abstract 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 abstract 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000036556 skin irritation Effects 0.000 abstract 1
- 231100000475 skin irritation Toxicity 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 26
- 238000002156 mixing Methods 0.000 description 24
- 238000003756 stirring Methods 0.000 description 21
- HSHXDCVZWHOWCS-UHFFFAOYSA-N N'-hexadecylthiophene-2-carbohydrazide Chemical compound CCCCCCCCCCCCCCCCNNC(=O)c1cccs1 HSHXDCVZWHOWCS-UHFFFAOYSA-N 0.000 description 18
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 18
- QCCKPZOPTXCJPL-UHFFFAOYSA-N dodecyl(dimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCC[NH+](C)C QCCKPZOPTXCJPL-UHFFFAOYSA-N 0.000 description 17
- 150000002190 fatty acyls Chemical group 0.000 description 17
- 150000003839 salts Chemical class 0.000 description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 16
- 210000003491 skin Anatomy 0.000 description 11
- 238000012360 testing method Methods 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- HYAAPGPZUMZCDM-UHFFFAOYSA-N S(=O)(=O)=C[Na] Chemical compound S(=O)(=O)=C[Na] HYAAPGPZUMZCDM-UHFFFAOYSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 6
- 244000147568 Laurus nobilis Species 0.000 description 6
- 235000017858 Laurus nobilis Nutrition 0.000 description 6
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 241000283690 Bos taurus Species 0.000 description 5
- 101710112457 Exoglucanase Proteins 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000005864 Sulphur Substances 0.000 description 5
- 230000033228 biological regulation Effects 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000012467 final product Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000005202 decontamination Methods 0.000 description 4
- 230000003588 decontaminative effect Effects 0.000 description 4
- 150000002576 ketones Chemical class 0.000 description 4
- 229920006316 polyvinylpyrrolidine Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 230000001408 fungistatic effect Effects 0.000 description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 3
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- 241001360526 Escherichia coli ATCC 25922 Species 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 241000191940 Staphylococcus Species 0.000 description 2
- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 2
- 206010000496 acne Diseases 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 230000028327 secretion Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 208000002874 Acne Vulgaris Diseases 0.000 description 1
- DCRGCLPPXPCTFL-UHFFFAOYSA-N C(C)(=O)OC=C.[O] Chemical compound C(C)(=O)OC=C.[O] DCRGCLPPXPCTFL-UHFFFAOYSA-N 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 241001128004 Demodex Species 0.000 description 1
- 108010001682 Dextranase Proteins 0.000 description 1
- 206010016936 Folliculitis Diseases 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 235000019082 Osmanthus Nutrition 0.000 description 1
- 241000333181 Osmanthus Species 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- 241001303601 Rosacea Species 0.000 description 1
- 206010039793 Seborrhoeic dermatitis Diseases 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 210000003780 hair follicle Anatomy 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 201000004700 rosacea Diseases 0.000 description 1
- 210000001732 sebaceous gland Anatomy 0.000 description 1
- 208000008742 seborrheic dermatitis Diseases 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/30—Sulfonation products derived from lignin
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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Abstract
The invention relates to antibacterial acarus killing laundry detergent. The antibacterial acarus killing laundry detergent is prepared from, by weight, 5-10 parts of dodecyl dimethyl betaine, 5-10 parts of sodium lauroylmethyltaurate, 3-5 parts of sodium lignin sulfonate, 3-5 parts of cleaner LS, 0.5-3 parts of triethanolamine, 0.5-3 parts of sodium borate, 1-5 parts of sodium chloride, 0.5-2 parts of sodium citrate, 0.5-2 parts of complex enzymes, 0.5-2 parts of nano titanium dioxide, 0.5-2 parts of chitosan, 1-5 parts of an emulsifier, 0.5-2 parts of a chelating agent, 5-10 parts of an organic solvent, 0.1-0.5 part of polyvinylpyrrolidone, 0.1-0.5 part of hydroxypropyl methyl cellulose, 0.1-0.5 part of essences, 1-5 parts of a thickening agent, 1-3 parts of sorbitol and 50-100 parts of deionized water. The antibacterial acarus killing laundry detergent is high in detergency power, remarkable in antibacterial and acarus killing effect and free of side effects and avoids clothes fading, skin irritation and pollution.
Description
Technical field
The present invention relates to a kind of liquid detergent, in particular to a kind of liquid detergent with antibacterial acaricide effect.
Background technology
Wearing the clothes, be a big fundamental of human lives, from ancient times to the present, it is non-that the cleaning of medicated clothing is always people's daily life
A most important part, along with the raising of modern's quality of life, the performance requirement of laundry daily chemicals is also constantly carrying
Rising, the most the most commonly used laundry daily chemicals is detergent, and detergent has preferable decontamination cleaning effect, but does washing
Powder, as a kind of powder detergent, frequently appears in water insufficient situation of dissolving in use, and one to affect medicated clothing
Clean result, in two detergent failing fully to dissolve in local can cause regional area, detergent concentration is excessive so that should
The alkalescence in region is very big, medicated clothing can be caused damage, and three carry out detergent due to easily redeposited on medicated clothing containing a lot of solid additives
Making fabric harden, meanwhile, detergent is relatively strong to the zest of skin, easily injures the skin of washer's hand, the most nowadays
The market share of detergent is more and more lower, and liquid detergent is because of the states of matter character of itself liquid, determines liquid detergent in water
Dissolution dispersity be much better than detergent, the dispersibility that liquid detergent is good determines liquid detergent can wash medicated clothing equably, with
Time liquid detergent surfactant water-soluble good, easily rinse, deposition less and it can be avoided that because of local concentration cross major injury laundry
The hand skin of person, therefore laundry dailyization that the more preferable liquid detergent of performance of people's big more options laundry now is commonly used as family
Work product.
Along with improving constantly of health of people consciousness, the requirement of laundry detergent compositions is the most not merely confined to be only capable of by people
Clean medicated clothing just, medicated clothing as most frequently contacting the articles for daily use of human body skin, above unavoidable contamination have the antiperspirant on skin
The dirts such as body thing are posted on liquid, scurf, skin secretion and skin, simultaneously during clothes contact external environment, the easily extraneous ring of contamination
The pollutant such as the antibacterial in border and virus, the two effect medicated clothing is become hotbed that biological pollutant grows and passing to human body
The passage broadcast.Acarid is after flea, fly, mankind room insect the most rampant.The skin histology that it sucks exclusively by thorn
Cell, the oils and fats etc. of skin gland secretion are made a living.The general long 0.1-0.2 millimeter of acarid, kind is a lot, almost has 500,000 kinds, its
Middle human Demodex is a kind of parasite that in crowd, infection rate is higher, and it parasitizes in hair follicle and sebaceous gland, and with Cell sap
Deng for nutrient substance;Its strong chelicera also has destruction to the skin histology of host, makes a part of the infected show and faces
Bed symptom;There is skin pruritus, little pimple etc. in the lighter, and severe one can cause rosacea, folliculitis, seborrheic dermatitis and acne.And
Clothes can only be played the effect of decontamination by the general liquid detergent cleaned, and can not play the effect of sterilization, for health
Consider, need a kind of liquid detergent that can effectively play antibacterial acaricide effect.
Summary of the invention
The present invention provides a kind of antibacterial acaricide liquid detergent, this liquid detergent strong detergency, has disinfecting mite-removing effect simultaneously, kills
The bacterium time is short, and bactericidal effect is good.
Specifically, the present invention provides antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dimethyl
Base glycine betaine 5-10 part, lauroyl N-methyltaurine sodium 5-10 part, sodium lignin sulfonate 3-5 part, to methoxyl group fatty acid amide
Base benzene sulfonic acid sodium salt 3-5 part, triethanolamine 0.5-3 part, sodium borate 0.5-3 part, sodium chloride 1-5 part, sodium citrate 0.5-2 part, multiple
Synthase 0.5-2 part, nano titanium oxide 0.5-2 part, chitosan 0.5-2 part, emulsifying agent 1-5 part, chelating agen 0.5-2 part is organic
Solvent 5-10 part, polyvinylpyrrolidone 0.1-0.5 part, hydroxypropyl methyl cellulose 0.1-0.5 part, essence 0.1-0.5 part, increase
Thick dose of 1-5 part, sorbitol 1-3 part, deionized water 50-100 part.
In one specific embodiment of the present invention, described antibacterial acaricide liquid detergent is by the raw material of following parts by weight
Making: dodecyldimethylammonium hydroxide inner salt 6 parts, 8 parts of lauroyl N-methyltaurine sodium, sodium lignin sulfonate 4 parts, to methoxy
Base fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2 parts, sodium borate 2 parts, 3 parts of sodium chloride, sodium citrate 1 part, compound enzyme 1
Part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying agent 3 parts, chelating agen 1 part, organic solvent 8 parts, polyvinylpyrrolidone
0.3 part, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, sorbitol 2 parts, deionized water 75 parts.
In one specific embodiment of the present invention, described antibacterial acaricide liquid detergent is by the raw material of following parts by weight
Making: dodecyldimethylammonium hydroxide inner salt 5 parts, 5 parts of lauroyl N-methyltaurine sodium, sodium lignin sulfonate 3 parts, to methoxy
Base fatty acyl amido benzene sulfonic acid sodium salt 3 parts, triethanolamine 0.5 part, sodium borate 0.5 part, 1 part of sodium chloride, sodium citrate 0.5 part, multiple
Synthase 0.5 part, nano titanium oxide 0.5 part, chitosan 0.5 part, emulsifying agent 1 part, chelating agen 0.5 part, organic solvent 5 parts, poly-
Vinylpyrrolidone 0.1 part, hydroxypropyl methyl cellulose 0.1 part, 0.1 part of essence, thickening agent 1 part, sorbitol 1 part, deionization
50 parts of water.
In one specific embodiment of the present invention, described antibacterial acaricide liquid detergent is by the raw material of following parts by weight
Making: dodecyldimethylammonium hydroxide inner salt 10 parts, 10 parts of lauroyl N-methyltaurine sodium, sodium lignin sulfonate 5 parts, to first
Epoxide fatty acyl amido benzene sulfonic acid sodium salt 5 parts, triethanolamine 3 parts, sodium borate 3 parts, 5 parts of sodium chloride, sodium citrate 2 parts, compound enzyme 2
Part, nano titanium oxide 2 parts, chitosan 2 parts, emulsifying agent 5 parts, chelating agen 2 parts, organic solvent 10 parts, polyvinylpyrrolidone
0.5 part, hydroxypropyl methyl cellulose 0.5 part, 0.5 part of essence, thickening agent 5 parts, sorbitol 3 parts, deionized water 100 parts.
In one specific embodiment of the present invention, described antibacterial acaricide liquid detergent is by the raw material of following parts by weight
Making: dodecyldimethylammonium hydroxide inner salt 5 parts, 10 parts of lauroyl N-methyltaurine sodium, sodium lignin sulfonate 3 parts, to methoxy
Base fatty acyl amido benzene sulfonic acid sodium salt 5 parts, triethanolamine 0.5 part, sodium borate 3 parts, 1 part of sodium chloride, sodium citrate 2 parts, compound enzyme
0.5 part, nano titanium oxide 2 parts, chitosan 0.5 part, emulsifying agent 5 parts, chelating agen 0.5 part, organic solvent 10 parts, polyethylene pyrrole
Pyrrolidone 0.1 part, hydroxypropyl methyl cellulose 0.5 part, 0.1 part of essence, thickening agent 5 parts, sorbitol 1 part, deionized water 100
Part.
In one specific embodiment of the present invention, described compound enzyme is alkaline protease, α-amylase, circumscribed Portugal
Dextranase, the weight ratio of three is 2:1:2.
In one specific embodiment of the present invention, described emulsifying agent is that polyoxyethylene lauryl ether and stearic acid gather
Oxygen vinyl acetate, the weight ratio of the two is 1:2.
In one specific embodiment of the present invention, described chelating agen is sodium tartrate and sodium gluconate, the two
Weight ratio be 1:1.
In one specific embodiment of the present invention, described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol,
The volume ratio of three is 2:1:1.
In one specific embodiment of the present invention, described essence is Oleum menthae, Eucalyptus oil, Fructus Citri Limoniae oil, jasmine essence
Oil, Oleum Rosae Rugosae or Oleum Caryophylli.
In one specific embodiment of the present invention, described thickening agent is xanthan gum, carrageenan or carrageenin.
In one specific embodiment of the present invention, the weight average molecular weight of described sodium lignin sulfonate is 2000 dongle
Pause to 6000 dalton.
Another aspect of the present invention provides the preparation method of described antibacterial acaricide liquid detergent, comprises the steps:
(1) each raw material for standby is weighed by weight;
(2) in reactor, add deionized water, be warmed up to 50-70 DEG C, then start stirring, and be sequentially added into polyvinyl pyrrole
Alkanone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 100~200r/min, stirs
Mix time 20min;
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into
Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor
The pH=7~8 of liquid;Described mixing speed is 100~200r/min;
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs
Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min;Described mixing speed is
100~200r/min;
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively
20min, described mixing speed is 100~200r/min, to obtain final product.
In the present invention in the case of without specified otherwise, all percentage ratios are all weight percentage.
Below in conjunction with specific embodiment, the invention will be further described.
Detailed description of the invention
By the following examples can the present invention will be further elaborated, but, the scope of the present invention not office
It is limited to following embodiment.Those skilled in the art are it can be appreciated that in the premise without departing substantially from the spirit and scope of the present invention
Under, the present invention can be carried out various change and modification.The present invention to test used in material and test method enter
The description that row is general and/or concrete.Although being ability by realizing many materials that the object of the invention used and operational approach
Known to territory, but the present invention still makees the most detailed description at this.
The present invention to test used in material and test method carry out generality and/or concrete description.Though
It is so to it is known in the art that still the present invention is still at this for realizing many materials that the object of the invention used and operational approach
Describe in detail as far as possible.It will be apparent to those skilled in the art that hereinafter, if not specified, material therefor of the present invention and
Operational approach is well known in the art.
Embodiment 1:
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, Laurel
Sulfonylmethyl sodium taurocholate 8 parts, sodium lignin sulfonate 4 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2
Part, sodium borate 2 parts, 3 parts of sodium chloride, sodium citrate 1 part, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying
Agent 3 parts, chelating agen 1 part, organic solvent 8 parts, polyvinylpyrrolidone 0.3 part, hydroxypropyl methyl cellulose 0.2 part, essence 0.2
Part, thickening agent 3 parts, sorbitol 2 parts, deionized water 75 parts;
Described compound enzyme is alkaline protease, α-amylase, exoglucanase, and the weight ratio of three is 2:1:2;
Described emulsifying agent is polyoxyethylene lauryl ether and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1:2;
Described chelating agen is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1:1;
Described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol, and the volume ratio of three is 2:1:1;
Preparation method comprises the steps:
(1) each raw material for standby is weighed by weight;
(2) in reactor, add deionized water, be warmed up to 60 DEG C, then start stirring, and be sequentially added into polyvinylpyrrolidine
Ketone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 150r/min, mixing time
20min;
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into
Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor
The pH=7 of liquid;Described mixing speed is 150r/min;
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs
Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min;Described mixing speed is
150r/min;
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively
20min, described mixing speed is 150r/min, to obtain final product.
Embodiment 2:
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 5 parts, Laurel
Sulfonylmethyl sodium taurocholate 5 parts, sodium lignin sulfonate 3 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 3 parts, triethanolamine 0.5
Part, sodium borate 0.5 part, 1 part of sodium chloride, sodium citrate 0.5 part, compound enzyme 0.5 part, nano titanium oxide 0.5 part, chitosan
0.5 part, emulsifying agent 1 part, chelating agen 0.5 part, organic solvent 5 parts, polyvinylpyrrolidone 0.1 part, hydroxypropyl methyl cellulose
0.1 part, 0.1 part of essence, thickening agent 1 part, sorbitol 1 part, deionized water 50 parts;
Described compound enzyme is alkaline protease, α-amylase, exoglucanase, and the weight ratio of three is 2:1:2;
Described emulsifying agent is polyoxyethylene lauryl ether and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1:2;
Described chelating agen is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1:1;
Described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol, and the volume ratio of three is 2:1:1;
Preparation method comprises the steps:
(1) each raw material for standby is weighed by weight;
(2) in reactor, add deionized water, be warmed up to 50 DEG C, then start stirring, and be sequentially added into polyvinylpyrrolidine
Ketone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 100r/min, mixing time
20min;
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into
Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor
The pH=7 of liquid;Described mixing speed is 100r/min;
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs
Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min;Described mixing speed is
100r/min;
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively
20min, described mixing speed is 100r/min, to obtain final product.
Embodiment 3:
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 10 parts, the moon
Osmanthus sulfonylmethyl sodium taurocholate 10 parts, sodium lignin sulfonate 5 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 5 parts, triethanolamine
3 parts, sodium borate 3 parts, 5 parts of sodium chloride, sodium citrate 2 parts, compound enzyme 2 parts, nano titanium oxide 2 parts, chitosan 2 parts, emulsifying
Agent 5 parts, chelating agen 2 parts, organic solvent 10 parts, polyvinylpyrrolidone 0.5 part, hydroxypropyl methyl cellulose 0.5 part, essence
0.5 part, thickening agent 5 parts, sorbitol 3 parts, deionized water 100 parts;
Described compound enzyme is alkaline protease, α-amylase, exoglucanase, and the weight ratio of three is 2:1:2;
Described emulsifying agent is polyoxyethylene lauryl ether and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1:2;
Described chelating agen is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1:1;
Described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol, and the volume ratio of three is 2:1:1;
Preparation method comprises the steps:
(1) each raw material for standby is weighed by weight;
(2) in reactor, add deionized water, be warmed up to 70 DEG C, then start stirring, and be sequentially added into polyvinylpyrrolidine
Ketone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 200r/min, mixing time
20min;
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into
Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor
The pH=8 of liquid;Described mixing speed is 200r/min;
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs
Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min;Described mixing speed is
200r/min;
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively
20min, described mixing speed is 200r/min, to obtain final product.
Embodiment 4:
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 5 parts, Laurel
Sulfonylmethyl sodium taurocholate 10 parts, sodium lignin sulfonate 3 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 5 parts, triethanolamine
0.5 part, sodium borate 3 parts, 1 part of sodium chloride, sodium citrate 2 parts, compound enzyme 0.5 part, nano titanium oxide 2 parts, chitosan 0.5
Part, emulsifying agent 5 parts, chelating agen 0.5 part, organic solvent 10 parts, polyvinylpyrrolidone 0.1 part, hydroxypropyl methyl cellulose 0.5
Part, 0.1 part of essence, thickening agent 5 parts, sorbitol 1 part, deionized water 100 parts;
Described compound enzyme is alkaline protease, α-amylase, exoglucanase, and the weight ratio of three is 2:1:2;
Described emulsifying agent is polyoxyethylene lauryl ether and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1:2;
Described chelating agen is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1:1;
Described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol, and the volume ratio of three is 2:1:1;
Preparation method comprises the steps:
(1) each raw material for standby is weighed by weight;
(2) in reactor, add deionized water, be warmed up to 55 DEG C, then start stirring, and be sequentially added into polyvinylpyrrolidine
Ketone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 120r/min, mixing time
20min;
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into
Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor
The pH=7.5 of liquid;Described mixing speed is 180r/min;
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs
Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min;Described mixing speed is
140r/min;
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively
20min, described mixing speed is 150r/min, to obtain final product.
Comparative example 1(omits lauroyl N-methyltaurine sodium)
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, wooden
Element sodium sulfonate 4 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2 parts, sodium borate 2 parts, 3 parts of sodium chloride, lemon
1 part of lemon acid sodium, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying agent 3 parts, chelating agen 1 part, organic solvent 8
Part, polyvinylpyrrolidone 0.3 part, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, sorbitol 2 parts, goes
Ionized water 75 parts;
Other are with embodiment 1.
Comparative example 2(omits sodium lignin sulfonate)
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, Laurel
Sulfonylmethyl sodium taurocholate 8 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2 parts, sodium borate 2 parts, chlorination
3 parts of sodium, sodium citrate 1 part, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying agent 3 parts, chelating agen 1 part,
Organic solvent 8 parts, polyvinylpyrrolidone 0.3 part, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, mountain
Pears alcohol 2 parts, deionized water 75 parts;
Other are with embodiment 1.
Comparative example 3(is omitted methoxyl group fatty acyl amido benzene sulfonic acid sodium salt)
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, Laurel
Sulfonylmethyl sodium taurocholate 8 parts, sodium lignin sulfonate 4 parts, triethanolamine 2 parts, sodium borate 2 parts, 3 parts of sodium chloride, sodium citrate 1
Part, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying agent 3 parts, chelating agen 1 part, organic solvent 8 parts, poly-second
Alkene pyrrolidone 0.3 part, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, sorbitol 2 parts, deionized water
75 parts;
Other are with embodiment 1.
Comparative example 4(omits polyvinylpyrrolidone)
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, Laurel
Sulfonylmethyl sodium taurocholate 8 parts, sodium lignin sulfonate 4 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2
Part, sodium borate 2 parts, 3 parts of sodium chloride, sodium citrate 1 part, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying
Agent 3 parts, chelating agen 1 part, organic solvent 8 parts, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, sorbitol 2
Part, deionized water 75 parts;
Other are with embodiment 1.
Comparative example 5
Described compound enzyme is alkaline protease, exoglucanase, and the weight ratio of three is 2:2;
Other are with embodiment 1.
Comparative example 6
Described emulsifying agent is polyoxyethylene lauryl ether;Other are with embodiment 1.
Comparative example 7
Described chelating agen is sodium tartrate;Other are with embodiment 1.
Comparative example 8
Described organic solvent is ethanol, ethylene glycol monobutyl ether, and the volume ratio of three is 2:1;Other are with embodiment 1.
Test example 1 detergency test
The detergency test of antibacterial acaricide liquid detergent sample is with reference to GB/T13174-2008 " dress material detergent detergency and circulation
The mensuration of scourability " carry out, test result indicate that, the antibacterial acaricide liquid detergent pair that embodiment 1-4 and comparative example 1-8 prepare
Carbon black oil soiled cotton, albumen soiled cotton, sebum soiled cotton decontamination value are as shown in table 1 with the ratio of standard liquid detergent decontamination value.
Table 1 antibacterial acaricide liquid detergent detergency test result
Group | Carbon black oil soiled cotton | Albumen soiled cotton | Sebum soiled cotton |
Embodiment 1 | 1.38 | 1.36 | 1.45 |
Embodiment 2 | 1.35 | 1.38 | 1.48 |
Embodiment 3 | 1.36 | 1.38 | 1.46 |
Embodiment 4 | 1.37 | 1.34 | 1.43 |
Comparative example 1 | 1.03 | 1.05 | 1.11 |
Comparative example 2 | 1.12 | 1.10 | 1.16 |
Comparative example 3 | 1.08 | 1.06 | 1.10 |
Comparative example 4 | 1.02 | 1.05 | 1.03 |
Comparative example 5 | 1.09 | 1.15 | 1.18 |
Comparative example 6 | 1.13 | 1.07 | 1.05 |
Comparative example 7 | 1.15 | 1.19 | 1.26 |
Comparative example 8 | 1.13 | 1.01 | 1.08 |
The data of table 1 show, antibacterial acaricide liquid detergent prepared by embodiment of the present invention 1-4 has stronger detergency, simultaneously table 1
Data also show that each component of the present invention is the most collaborative, omit some component therein and clean effect can be made to decline.
Test example 2: anti-microbial property is tested
With reference to QB/T2738-2012, " daily chemical products is antibacterial and fungistatic effect in the antibacterial ability test of antibacterial acaricide liquid detergent sample
Evaluation methodology " carry out, activity 1:100,20 minutes action time, test result indicate that, embodiment 1~4 and comparative example
1-8 all samples is as shown in table 2 to the sterilizing rate of escherichia coli ATCC25922 and staphylococcus glucose bacterium ATCC6538.
The bactericidal effect of table 2 present invention antibacterial acaricide liquid detergent
Group | Escherichia coli ATCC25922 | Staphylococcus glucose bacterium ATCC6538 |
Embodiment 1 | 99.95 | 99.96 |
Embodiment 2 | 99.96 | 99.92 |
Embodiment 3 | 99.93 | 99.98 |
Embodiment 4 | 99.99 | 99.97 |
Comparative example 1 | 99.53 | 98.59 |
Comparative example 2 | 98.72 | 99.16 |
Comparative example 3 | 99.67 | 99.51 |
Comparative example 4 | 98.59 | 98.24 |
Comparative example 5 | 98.35 | 99.20 |
Comparative example 6 | 99.85 | 99.80 |
Comparative example 7 | 99.50 | 99.42 |
Comparative example 8 | 99.37 | 99.68 |
The data of table 2 show, antibacterial acaricide liquid detergent prepared by embodiment of the present invention 1-4 has stronger fungistatic effect, simultaneously
The data of table 2 also show that each component of the present invention is the most collaborative, omit some component therein and fungistatic effect can be made to decline.
Claims (8)
1. an antibacterial acaricide liquid detergent, it is characterised in that be made up of the raw material of following parts by weight: dodecyl dimethyl is sweet
Dish alkali 5-10 part, lauroyl N-methyltaurine sodium 5-10 part, sodium lignin sulfonate 3-5 part, to methoxyl group fatty acyl amido benzene
Sodium sulfonate 3-5 part, triethanolamine 0.5-3 part, sodium borate 0.5-3 part, sodium chloride 1-5 part, sodium citrate 0.5-2 part, compound enzyme
0.5-2 part, nano titanium oxide 0.5-2 part, chitosan 0.5-2 part, emulsifying agent 1-5 part, chelating agen 0.5-2 part, organic solvent
5-10 part, polyvinylpyrrolidone 0.1-0.5 part, hydroxypropyl methyl cellulose 0.1-0.5 part, essence 0.1-0.5 part, thickening agent
1-5 part, sorbitol 1-3 part, deionized water 50-100 part.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein compound enzyme is alkaline protease, α-amylase, circumscribed
Glucanase, the weight ratio of three is 2:1:2.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein emulsifying agent is polyoxyethylene lauryl ether and stearic acid
Polyoxyethylene ester, the weight ratio of the two is 1:2.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein chelating agen is sodium tartrate and sodium gluconate, the two
Weight ratio be 1:1.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein organic solvent is ethanol, ethylene glycol monobutyl ether and sweet
Oil, the volume ratio of three is 2:1:1.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein essence is Oleum menthae, Eucalyptus oil, Fructus Citri Limoniae oil, jasmine essence
Oil, Oleum Rosae Rugosae or Oleum Caryophylli.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein thickening agent is xanthan gum, carrageenan or chondrus ocellatus Holmes
Glue.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein the weight average molecular weight of sodium lignin sulfonate is 2000 roads
Er Dun to 6000 dalton.
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CN106336963A (en) * | 2016-07-29 | 2017-01-18 | 林祥岭 | Biotin laundry detergent |
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CN112210447A (en) * | 2020-10-14 | 2021-01-12 | 山西洁锐奇化工有限公司 | Towel mite-removing cleaning agent and preparation method thereof |
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