CN105886147A - Antibacterial acarus killing laundry detergent - Google Patents

Antibacterial acarus killing laundry detergent Download PDF

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Publication number
CN105886147A
CN105886147A CN201610446651.2A CN201610446651A CN105886147A CN 105886147 A CN105886147 A CN 105886147A CN 201610446651 A CN201610446651 A CN 201610446651A CN 105886147 A CN105886147 A CN 105886147A
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parts
sodium
antibacterial
liquid detergent
weight
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CN105886147B (en
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左牧冉
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Guangxi Busheng Biotechnology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/94Mixtures with anionic, cationic or non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/1213Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2065Polyhydric alcohols
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776Heterocyclic compounds, e.g. lactam
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38636Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/30Sulfonation products derived from lignin
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/90Betaines

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Abstract

The invention relates to antibacterial acarus killing laundry detergent. The antibacterial acarus killing laundry detergent is prepared from, by weight, 5-10 parts of dodecyl dimethyl betaine, 5-10 parts of sodium lauroylmethyltaurate, 3-5 parts of sodium lignin sulfonate, 3-5 parts of cleaner LS, 0.5-3 parts of triethanolamine, 0.5-3 parts of sodium borate, 1-5 parts of sodium chloride, 0.5-2 parts of sodium citrate, 0.5-2 parts of complex enzymes, 0.5-2 parts of nano titanium dioxide, 0.5-2 parts of chitosan, 1-5 parts of an emulsifier, 0.5-2 parts of a chelating agent, 5-10 parts of an organic solvent, 0.1-0.5 part of polyvinylpyrrolidone, 0.1-0.5 part of hydroxypropyl methyl cellulose, 0.1-0.5 part of essences, 1-5 parts of a thickening agent, 1-3 parts of sorbitol and 50-100 parts of deionized water. The antibacterial acarus killing laundry detergent is high in detergency power, remarkable in antibacterial and acarus killing effect and free of side effects and avoids clothes fading, skin irritation and pollution.

Description

A kind of antibacterial acaricide liquid detergent
Technical field
The present invention relates to a kind of liquid detergent, in particular to a kind of liquid detergent with antibacterial acaricide effect.
Background technology
Wearing the clothes, be a big fundamental of human lives, from ancient times to the present, it is non-that the cleaning of medicated clothing is always people's daily life A most important part, along with the raising of modern's quality of life, the performance requirement of laundry daily chemicals is also constantly carrying Rising, the most the most commonly used laundry daily chemicals is detergent, and detergent has preferable decontamination cleaning effect, but does washing Powder, as a kind of powder detergent, frequently appears in water insufficient situation of dissolving in use, and one to affect medicated clothing Clean result, in two detergent failing fully to dissolve in local can cause regional area, detergent concentration is excessive so that should The alkalescence in region is very big, medicated clothing can be caused damage, and three carry out detergent due to easily redeposited on medicated clothing containing a lot of solid additives Making fabric harden, meanwhile, detergent is relatively strong to the zest of skin, easily injures the skin of washer's hand, the most nowadays The market share of detergent is more and more lower, and liquid detergent is because of the states of matter character of itself liquid, determines liquid detergent in water Dissolution dispersity be much better than detergent, the dispersibility that liquid detergent is good determines liquid detergent can wash medicated clothing equably, with Time liquid detergent surfactant water-soluble good, easily rinse, deposition less and it can be avoided that because of local concentration cross major injury laundry The hand skin of person, therefore laundry dailyization that the more preferable liquid detergent of performance of people's big more options laundry now is commonly used as family Work product.
Along with improving constantly of health of people consciousness, the requirement of laundry detergent compositions is the most not merely confined to be only capable of by people Clean medicated clothing just, medicated clothing as most frequently contacting the articles for daily use of human body skin, above unavoidable contamination have the antiperspirant on skin The dirts such as body thing are posted on liquid, scurf, skin secretion and skin, simultaneously during clothes contact external environment, the easily extraneous ring of contamination The pollutant such as the antibacterial in border and virus, the two effect medicated clothing is become hotbed that biological pollutant grows and passing to human body The passage broadcast.Acarid is after flea, fly, mankind room insect the most rampant.The skin histology that it sucks exclusively by thorn Cell, the oils and fats etc. of skin gland secretion are made a living.The general long 0.1-0.2 millimeter of acarid, kind is a lot, almost has 500,000 kinds, its Middle human Demodex is a kind of parasite that in crowd, infection rate is higher, and it parasitizes in hair follicle and sebaceous gland, and with Cell sap Deng for nutrient substance;Its strong chelicera also has destruction to the skin histology of host, makes a part of the infected show and faces Bed symptom;There is skin pruritus, little pimple etc. in the lighter, and severe one can cause rosacea, folliculitis, seborrheic dermatitis and acne.And Clothes can only be played the effect of decontamination by the general liquid detergent cleaned, and can not play the effect of sterilization, for health Consider, need a kind of liquid detergent that can effectively play antibacterial acaricide effect.
Summary of the invention
The present invention provides a kind of antibacterial acaricide liquid detergent, this liquid detergent strong detergency, has disinfecting mite-removing effect simultaneously, kills The bacterium time is short, and bactericidal effect is good.
Specifically, the present invention provides antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dimethyl Base glycine betaine 5-10 part, lauroyl N-methyltaurine sodium 5-10 part, sodium lignin sulfonate 3-5 part, to methoxyl group fatty acid amide Base benzene sulfonic acid sodium salt 3-5 part, triethanolamine 0.5-3 part, sodium borate 0.5-3 part, sodium chloride 1-5 part, sodium citrate 0.5-2 part, multiple Synthase 0.5-2 part, nano titanium oxide 0.5-2 part, chitosan 0.5-2 part, emulsifying agent 1-5 part, chelating agen 0.5-2 part is organic Solvent 5-10 part, polyvinylpyrrolidone 0.1-0.5 part, hydroxypropyl methyl cellulose 0.1-0.5 part, essence 0.1-0.5 part, increase Thick dose of 1-5 part, sorbitol 1-3 part, deionized water 50-100 part.
In one specific embodiment of the present invention, described antibacterial acaricide liquid detergent is by the raw material of following parts by weight Making: dodecyldimethylammonium hydroxide inner salt 6 parts, 8 parts of lauroyl N-methyltaurine sodium, sodium lignin sulfonate 4 parts, to methoxy Base fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2 parts, sodium borate 2 parts, 3 parts of sodium chloride, sodium citrate 1 part, compound enzyme 1 Part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying agent 3 parts, chelating agen 1 part, organic solvent 8 parts, polyvinylpyrrolidone 0.3 part, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, sorbitol 2 parts, deionized water 75 parts.
In one specific embodiment of the present invention, described antibacterial acaricide liquid detergent is by the raw material of following parts by weight Making: dodecyldimethylammonium hydroxide inner salt 5 parts, 5 parts of lauroyl N-methyltaurine sodium, sodium lignin sulfonate 3 parts, to methoxy Base fatty acyl amido benzene sulfonic acid sodium salt 3 parts, triethanolamine 0.5 part, sodium borate 0.5 part, 1 part of sodium chloride, sodium citrate 0.5 part, multiple Synthase 0.5 part, nano titanium oxide 0.5 part, chitosan 0.5 part, emulsifying agent 1 part, chelating agen 0.5 part, organic solvent 5 parts, poly- Vinylpyrrolidone 0.1 part, hydroxypropyl methyl cellulose 0.1 part, 0.1 part of essence, thickening agent 1 part, sorbitol 1 part, deionization 50 parts of water.
In one specific embodiment of the present invention, described antibacterial acaricide liquid detergent is by the raw material of following parts by weight Making: dodecyldimethylammonium hydroxide inner salt 10 parts, 10 parts of lauroyl N-methyltaurine sodium, sodium lignin sulfonate 5 parts, to first Epoxide fatty acyl amido benzene sulfonic acid sodium salt 5 parts, triethanolamine 3 parts, sodium borate 3 parts, 5 parts of sodium chloride, sodium citrate 2 parts, compound enzyme 2 Part, nano titanium oxide 2 parts, chitosan 2 parts, emulsifying agent 5 parts, chelating agen 2 parts, organic solvent 10 parts, polyvinylpyrrolidone 0.5 part, hydroxypropyl methyl cellulose 0.5 part, 0.5 part of essence, thickening agent 5 parts, sorbitol 3 parts, deionized water 100 parts.
In one specific embodiment of the present invention, described antibacterial acaricide liquid detergent is by the raw material of following parts by weight Making: dodecyldimethylammonium hydroxide inner salt 5 parts, 10 parts of lauroyl N-methyltaurine sodium, sodium lignin sulfonate 3 parts, to methoxy Base fatty acyl amido benzene sulfonic acid sodium salt 5 parts, triethanolamine 0.5 part, sodium borate 3 parts, 1 part of sodium chloride, sodium citrate 2 parts, compound enzyme 0.5 part, nano titanium oxide 2 parts, chitosan 0.5 part, emulsifying agent 5 parts, chelating agen 0.5 part, organic solvent 10 parts, polyethylene pyrrole Pyrrolidone 0.1 part, hydroxypropyl methyl cellulose 0.5 part, 0.1 part of essence, thickening agent 5 parts, sorbitol 1 part, deionized water 100 Part.
In one specific embodiment of the present invention, described compound enzyme is alkaline protease, α-amylase, circumscribed Portugal Dextranase, the weight ratio of three is 2:1:2.
In one specific embodiment of the present invention, described emulsifying agent is that polyoxyethylene lauryl ether and stearic acid gather Oxygen vinyl acetate, the weight ratio of the two is 1:2.
In one specific embodiment of the present invention, described chelating agen is sodium tartrate and sodium gluconate, the two Weight ratio be 1:1.
In one specific embodiment of the present invention, described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol, The volume ratio of three is 2:1:1.
In one specific embodiment of the present invention, described essence is Oleum menthae, Eucalyptus oil, Fructus Citri Limoniae oil, jasmine essence Oil, Oleum Rosae Rugosae or Oleum Caryophylli.
In one specific embodiment of the present invention, described thickening agent is xanthan gum, carrageenan or carrageenin.
In one specific embodiment of the present invention, the weight average molecular weight of described sodium lignin sulfonate is 2000 dongle Pause to 6000 dalton.
Another aspect of the present invention provides the preparation method of described antibacterial acaricide liquid detergent, comprises the steps:
(1) each raw material for standby is weighed by weight;
(2) in reactor, add deionized water, be warmed up to 50-70 DEG C, then start stirring, and be sequentially added into polyvinyl pyrrole Alkanone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 100~200r/min, stirs Mix time 20min;
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor The pH=7~8 of liquid;Described mixing speed is 100~200r/min;
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min;Described mixing speed is 100~200r/min;
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively 20min, described mixing speed is 100~200r/min, to obtain final product.
In the present invention in the case of without specified otherwise, all percentage ratios are all weight percentage.
Below in conjunction with specific embodiment, the invention will be further described.
Detailed description of the invention
By the following examples can the present invention will be further elaborated, but, the scope of the present invention not office It is limited to following embodiment.Those skilled in the art are it can be appreciated that in the premise without departing substantially from the spirit and scope of the present invention Under, the present invention can be carried out various change and modification.The present invention to test used in material and test method enter The description that row is general and/or concrete.Although being ability by realizing many materials that the object of the invention used and operational approach Known to territory, but the present invention still makees the most detailed description at this.
The present invention to test used in material and test method carry out generality and/or concrete description.Though It is so to it is known in the art that still the present invention is still at this for realizing many materials that the object of the invention used and operational approach Describe in detail as far as possible.It will be apparent to those skilled in the art that hereinafter, if not specified, material therefor of the present invention and Operational approach is well known in the art.
Embodiment 1:
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, Laurel Sulfonylmethyl sodium taurocholate 8 parts, sodium lignin sulfonate 4 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2 Part, sodium borate 2 parts, 3 parts of sodium chloride, sodium citrate 1 part, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying Agent 3 parts, chelating agen 1 part, organic solvent 8 parts, polyvinylpyrrolidone 0.3 part, hydroxypropyl methyl cellulose 0.2 part, essence 0.2 Part, thickening agent 3 parts, sorbitol 2 parts, deionized water 75 parts;
Described compound enzyme is alkaline protease, α-amylase, exoglucanase, and the weight ratio of three is 2:1:2;
Described emulsifying agent is polyoxyethylene lauryl ether and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1:2;
Described chelating agen is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1:1;
Described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol, and the volume ratio of three is 2:1:1;
Preparation method comprises the steps:
(1) each raw material for standby is weighed by weight;
(2) in reactor, add deionized water, be warmed up to 60 DEG C, then start stirring, and be sequentially added into polyvinylpyrrolidine Ketone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 150r/min, mixing time 20min;
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor The pH=7 of liquid;Described mixing speed is 150r/min;
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min;Described mixing speed is 150r/min;
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively 20min, described mixing speed is 150r/min, to obtain final product.
Embodiment 2:
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 5 parts, Laurel Sulfonylmethyl sodium taurocholate 5 parts, sodium lignin sulfonate 3 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 3 parts, triethanolamine 0.5 Part, sodium borate 0.5 part, 1 part of sodium chloride, sodium citrate 0.5 part, compound enzyme 0.5 part, nano titanium oxide 0.5 part, chitosan 0.5 part, emulsifying agent 1 part, chelating agen 0.5 part, organic solvent 5 parts, polyvinylpyrrolidone 0.1 part, hydroxypropyl methyl cellulose 0.1 part, 0.1 part of essence, thickening agent 1 part, sorbitol 1 part, deionized water 50 parts;
Described compound enzyme is alkaline protease, α-amylase, exoglucanase, and the weight ratio of three is 2:1:2;
Described emulsifying agent is polyoxyethylene lauryl ether and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1:2;
Described chelating agen is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1:1;
Described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol, and the volume ratio of three is 2:1:1;
Preparation method comprises the steps:
(1) each raw material for standby is weighed by weight;
(2) in reactor, add deionized water, be warmed up to 50 DEG C, then start stirring, and be sequentially added into polyvinylpyrrolidine Ketone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 100r/min, mixing time 20min;
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor The pH=7 of liquid;Described mixing speed is 100r/min;
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min;Described mixing speed is 100r/min;
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively 20min, described mixing speed is 100r/min, to obtain final product.
Embodiment 3:
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 10 parts, the moon Osmanthus sulfonylmethyl sodium taurocholate 10 parts, sodium lignin sulfonate 5 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 5 parts, triethanolamine 3 parts, sodium borate 3 parts, 5 parts of sodium chloride, sodium citrate 2 parts, compound enzyme 2 parts, nano titanium oxide 2 parts, chitosan 2 parts, emulsifying Agent 5 parts, chelating agen 2 parts, organic solvent 10 parts, polyvinylpyrrolidone 0.5 part, hydroxypropyl methyl cellulose 0.5 part, essence 0.5 part, thickening agent 5 parts, sorbitol 3 parts, deionized water 100 parts;
Described compound enzyme is alkaline protease, α-amylase, exoglucanase, and the weight ratio of three is 2:1:2;
Described emulsifying agent is polyoxyethylene lauryl ether and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1:2;
Described chelating agen is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1:1;
Described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol, and the volume ratio of three is 2:1:1;
Preparation method comprises the steps:
(1) each raw material for standby is weighed by weight;
(2) in reactor, add deionized water, be warmed up to 70 DEG C, then start stirring, and be sequentially added into polyvinylpyrrolidine Ketone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 200r/min, mixing time 20min;
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor The pH=8 of liquid;Described mixing speed is 200r/min;
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min;Described mixing speed is 200r/min;
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively 20min, described mixing speed is 200r/min, to obtain final product.
Embodiment 4:
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 5 parts, Laurel Sulfonylmethyl sodium taurocholate 10 parts, sodium lignin sulfonate 3 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 5 parts, triethanolamine 0.5 part, sodium borate 3 parts, 1 part of sodium chloride, sodium citrate 2 parts, compound enzyme 0.5 part, nano titanium oxide 2 parts, chitosan 0.5 Part, emulsifying agent 5 parts, chelating agen 0.5 part, organic solvent 10 parts, polyvinylpyrrolidone 0.1 part, hydroxypropyl methyl cellulose 0.5 Part, 0.1 part of essence, thickening agent 5 parts, sorbitol 1 part, deionized water 100 parts;
Described compound enzyme is alkaline protease, α-amylase, exoglucanase, and the weight ratio of three is 2:1:2;
Described emulsifying agent is polyoxyethylene lauryl ether and polyoxyethylene stearic acid ester, and the weight ratio of the two is 1:2;
Described chelating agen is sodium tartrate and sodium gluconate, and the weight ratio of the two is 1:1;
Described organic solvent is ethanol, ethylene glycol monobutyl ether and glycerol, and the volume ratio of three is 2:1:1;
Preparation method comprises the steps:
(1) each raw material for standby is weighed by weight;
(2) in reactor, add deionized water, be warmed up to 55 DEG C, then start stirring, and be sequentially added into polyvinylpyrrolidine Ketone, hydroxypropyl methyl cellulose, emulsifying agent and nano titanium oxide, described mixing speed is 120r/min, mixing time 20min;
(3), after step (2) completes, in reactor, dodecyldimethylammonium hydroxide inner salt, lauroyl methyl cattle sulphur it are sequentially added into Acid sodium, sodium lignin sulfonate and to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, after stirring 30min, reaction in regulation reactor The pH=7.5 of liquid;Described mixing speed is 180r/min;
(4), after step (3) completes, reactor is cooled to 35 DEG C, is sequentially added into sodium citrate, compound enzyme and sorbitol, stirs Mix 10min, be subsequently adding triethanolamine, sodium borate, chelating agen and sodium chloride, be stirred for 10min;Described mixing speed is 140r/min;
(5), after step (4) completes, in reactor, chitosan, organic solvent, essence, thickening agent, stirring are added successively 20min, described mixing speed is 150r/min, to obtain final product.
Comparative example 1(omits lauroyl N-methyltaurine sodium)
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, wooden Element sodium sulfonate 4 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2 parts, sodium borate 2 parts, 3 parts of sodium chloride, lemon 1 part of lemon acid sodium, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying agent 3 parts, chelating agen 1 part, organic solvent 8 Part, polyvinylpyrrolidone 0.3 part, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, sorbitol 2 parts, goes Ionized water 75 parts;
Other are with embodiment 1.
Comparative example 2(omits sodium lignin sulfonate)
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, Laurel Sulfonylmethyl sodium taurocholate 8 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2 parts, sodium borate 2 parts, chlorination 3 parts of sodium, sodium citrate 1 part, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying agent 3 parts, chelating agen 1 part, Organic solvent 8 parts, polyvinylpyrrolidone 0.3 part, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, mountain Pears alcohol 2 parts, deionized water 75 parts;
Other are with embodiment 1.
Comparative example 3(is omitted methoxyl group fatty acyl amido benzene sulfonic acid sodium salt)
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, Laurel Sulfonylmethyl sodium taurocholate 8 parts, sodium lignin sulfonate 4 parts, triethanolamine 2 parts, sodium borate 2 parts, 3 parts of sodium chloride, sodium citrate 1 Part, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying agent 3 parts, chelating agen 1 part, organic solvent 8 parts, poly-second Alkene pyrrolidone 0.3 part, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, sorbitol 2 parts, deionized water 75 parts;
Other are with embodiment 1.
Comparative example 4(omits polyvinylpyrrolidone)
A kind of antibacterial acaricide liquid detergent, is made up of the raw material of following parts by weight: dodecyldimethylammonium hydroxide inner salt 6 parts, Laurel Sulfonylmethyl sodium taurocholate 8 parts, sodium lignin sulfonate 4 parts, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 4 parts, triethanolamine 2 Part, sodium borate 2 parts, 3 parts of sodium chloride, sodium citrate 1 part, compound enzyme 1 part, nano titanium oxide 1.5 parts, chitosan 1 part, emulsifying Agent 3 parts, chelating agen 1 part, organic solvent 8 parts, hydroxypropyl methyl cellulose 0.2 part, 0.2 part of essence, thickening agent 3 parts, sorbitol 2 Part, deionized water 75 parts;
Other are with embodiment 1.
Comparative example 5
Described compound enzyme is alkaline protease, exoglucanase, and the weight ratio of three is 2:2;
Other are with embodiment 1.
Comparative example 6
Described emulsifying agent is polyoxyethylene lauryl ether;Other are with embodiment 1.
Comparative example 7
Described chelating agen is sodium tartrate;Other are with embodiment 1.
Comparative example 8
Described organic solvent is ethanol, ethylene glycol monobutyl ether, and the volume ratio of three is 2:1;Other are with embodiment 1.
Test example 1 detergency test
The detergency test of antibacterial acaricide liquid detergent sample is with reference to GB/T13174-2008 " dress material detergent detergency and circulation The mensuration of scourability " carry out, test result indicate that, the antibacterial acaricide liquid detergent pair that embodiment 1-4 and comparative example 1-8 prepare Carbon black oil soiled cotton, albumen soiled cotton, sebum soiled cotton decontamination value are as shown in table 1 with the ratio of standard liquid detergent decontamination value.
Table 1 antibacterial acaricide liquid detergent detergency test result
Group Carbon black oil soiled cotton Albumen soiled cotton Sebum soiled cotton
Embodiment 1 1.38 1.36 1.45
Embodiment 2 1.35 1.38 1.48
Embodiment 3 1.36 1.38 1.46
Embodiment 4 1.37 1.34 1.43
Comparative example 1 1.03 1.05 1.11
Comparative example 2 1.12 1.10 1.16
Comparative example 3 1.08 1.06 1.10
Comparative example 4 1.02 1.05 1.03
Comparative example 5 1.09 1.15 1.18
Comparative example 6 1.13 1.07 1.05
Comparative example 7 1.15 1.19 1.26
Comparative example 8 1.13 1.01 1.08
The data of table 1 show, antibacterial acaricide liquid detergent prepared by embodiment of the present invention 1-4 has stronger detergency, simultaneously table 1 Data also show that each component of the present invention is the most collaborative, omit some component therein and clean effect can be made to decline.
Test example 2: anti-microbial property is tested
With reference to QB/T2738-2012, " daily chemical products is antibacterial and fungistatic effect in the antibacterial ability test of antibacterial acaricide liquid detergent sample Evaluation methodology " carry out, activity 1:100,20 minutes action time, test result indicate that, embodiment 1~4 and comparative example 1-8 all samples is as shown in table 2 to the sterilizing rate of escherichia coli ATCC25922 and staphylococcus glucose bacterium ATCC6538.
The bactericidal effect of table 2 present invention antibacterial acaricide liquid detergent
Group Escherichia coli ATCC25922 Staphylococcus glucose bacterium ATCC6538
Embodiment 1 99.95 99.96
Embodiment 2 99.96 99.92
Embodiment 3 99.93 99.98
Embodiment 4 99.99 99.97
Comparative example 1 99.53 98.59
Comparative example 2 98.72 99.16
Comparative example 3 99.67 99.51
Comparative example 4 98.59 98.24
Comparative example 5 98.35 99.20
Comparative example 6 99.85 99.80
Comparative example 7 99.50 99.42
Comparative example 8 99.37 99.68
The data of table 2 show, antibacterial acaricide liquid detergent prepared by embodiment of the present invention 1-4 has stronger fungistatic effect, simultaneously The data of table 2 also show that each component of the present invention is the most collaborative, omit some component therein and fungistatic effect can be made to decline.

Claims (8)

1. an antibacterial acaricide liquid detergent, it is characterised in that be made up of the raw material of following parts by weight: dodecyl dimethyl is sweet Dish alkali 5-10 part, lauroyl N-methyltaurine sodium 5-10 part, sodium lignin sulfonate 3-5 part, to methoxyl group fatty acyl amido benzene Sodium sulfonate 3-5 part, triethanolamine 0.5-3 part, sodium borate 0.5-3 part, sodium chloride 1-5 part, sodium citrate 0.5-2 part, compound enzyme 0.5-2 part, nano titanium oxide 0.5-2 part, chitosan 0.5-2 part, emulsifying agent 1-5 part, chelating agen 0.5-2 part, organic solvent 5-10 part, polyvinylpyrrolidone 0.1-0.5 part, hydroxypropyl methyl cellulose 0.1-0.5 part, essence 0.1-0.5 part, thickening agent 1-5 part, sorbitol 1-3 part, deionized water 50-100 part.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein compound enzyme is alkaline protease, α-amylase, circumscribed Glucanase, the weight ratio of three is 2:1:2.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein emulsifying agent is polyoxyethylene lauryl ether and stearic acid Polyoxyethylene ester, the weight ratio of the two is 1:2.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein chelating agen is sodium tartrate and sodium gluconate, the two Weight ratio be 1:1.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein organic solvent is ethanol, ethylene glycol monobutyl ether and sweet Oil, the volume ratio of three is 2:1:1.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein essence is Oleum menthae, Eucalyptus oil, Fructus Citri Limoniae oil, jasmine essence Oil, Oleum Rosae Rugosae or Oleum Caryophylli.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein thickening agent is xanthan gum, carrageenan or chondrus ocellatus Holmes Glue.
Antibacterial acaricide liquid detergent the most according to claim 1, wherein the weight average molecular weight of sodium lignin sulfonate is 2000 roads Er Dun to 6000 dalton.
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CN106336963A (en) * 2016-07-29 2017-01-18 林祥岭 Biotin laundry detergent
CN106635458A (en) * 2016-11-14 2017-05-10 陈啟文 Laundry detergent and preparation method thereof
CN106968103A (en) * 2017-04-11 2017-07-21 安徽博硕科技有限公司 A kind of special bleaching agent of clothes and preparation method thereof
CN107345178A (en) * 2017-07-07 2017-11-14 广州克思曼研磨科技有限公司 A kind of nanometer cleaning-nursing liquid and preparation method thereof
CN107524000A (en) * 2017-08-01 2017-12-29 江苏新瑞贝科技股份有限公司 A kind of preparation method of natural antibacterial mite-assistant fabricses coating
CN108102823A (en) * 2016-11-24 2018-06-01 陈君君 A kind of low bubble multifunctional liquid detergent of except mite
CN109055034A (en) * 2018-08-08 2018-12-21 廖家平 Liquid detergent
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CN112210447A (en) * 2020-10-14 2021-01-12 山西洁锐奇化工有限公司 Towel mite-removing cleaning agent and preparation method thereof
CN113528250A (en) * 2021-07-23 2021-10-22 孟庆峰 Antibacterial laundry detergent and preparation method thereof
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CN106336963A (en) * 2016-07-29 2017-01-18 林祥岭 Biotin laundry detergent
CN106635458A (en) * 2016-11-14 2017-05-10 陈啟文 Laundry detergent and preparation method thereof
CN108102823A (en) * 2016-11-24 2018-06-01 陈君君 A kind of low bubble multifunctional liquid detergent of except mite
CN106968103A (en) * 2017-04-11 2017-07-21 安徽博硕科技有限公司 A kind of special bleaching agent of clothes and preparation method thereof
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CN112210447A (en) * 2020-10-14 2021-01-12 山西洁锐奇化工有限公司 Towel mite-removing cleaning agent and preparation method thereof
CN114403159A (en) * 2020-10-28 2022-04-29 广州市华晟健康产业有限公司 Sterilizing spray
CN113528250A (en) * 2021-07-23 2021-10-22 孟庆峰 Antibacterial laundry detergent and preparation method thereof
CN113528250B (en) * 2021-07-23 2022-08-12 孟庆峰 Antibacterial laundry detergent and preparation method thereof

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