CN1176996A - High-efficiency phosphorus-free and aluminum-free super-concentrated soft whitening laundry detergent - Google Patents
High-efficiency phosphorus-free and aluminum-free super-concentrated soft whitening laundry detergent Download PDFInfo
- Publication number
- CN1176996A CN1176996A CN 96111868 CN96111868A CN1176996A CN 1176996 A CN1176996 A CN 1176996A CN 96111868 CN96111868 CN 96111868 CN 96111868 A CN96111868 A CN 96111868A CN 1176996 A CN1176996 A CN 1176996A
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- CN
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- Prior art keywords
- prescription
- agent
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- free
- aeo
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 230000002087 whitening effect Effects 0.000 title claims abstract 4
- 239000003599 detergent Substances 0.000 title abstract 6
- 238000005406 washing Methods 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- 239000008233 hard water Substances 0.000 claims abstract description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 3
- 230000000694 effects Effects 0.000 claims abstract description 3
- 239000011574 phosphorus Substances 0.000 claims abstract description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 3
- 239000004902 Softening Agent Substances 0.000 claims abstract 2
- 239000002904 solvent Substances 0.000 claims abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000004411 aluminium Substances 0.000 claims description 5
- LXAHHHIGZXPRKQ-UHFFFAOYSA-N 5-fluoro-2-methylpyridine Chemical compound CC1=CC=C(F)C=N1 LXAHHHIGZXPRKQ-UHFFFAOYSA-N 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 4
- 235000010234 sodium benzoate Nutrition 0.000 claims description 4
- 239000004299 sodium benzoate Substances 0.000 claims description 4
- 229960004418 trolamine Drugs 0.000 claims description 4
- 235000010254 Jasminum officinale Nutrition 0.000 claims description 3
- 240000005385 Jasminum sambac Species 0.000 claims description 3
- 239000003205 fragrance Substances 0.000 claims description 3
- 230000008676 import Effects 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 238000011109 contamination Methods 0.000 claims description 2
- 230000001737 promoting effect Effects 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims 2
- 230000000996 additive effect Effects 0.000 claims 2
- 238000005260 corrosion Methods 0.000 claims 2
- 239000000975 dye Substances 0.000 claims 2
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 239000000039 congener Substances 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 238000005201 scrubbing Methods 0.000 claims 1
- 238000010025 steaming Methods 0.000 claims 1
- 238000005202 decontamination Methods 0.000 abstract description 4
- 230000003588 decontaminative effect Effects 0.000 abstract description 4
- 239000002736 nonionic surfactant Substances 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 239000004480 active ingredient Substances 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 239000006172 buffering agent Substances 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 240000000774 Cunila origanoides Species 0.000 description 1
- 235000018274 Cunila origanoides Nutrition 0.000 description 1
- 235000014866 Dictamnus albus Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a high-efficiency super-concentrated soft whitening detergent, which has the active ingredient content of more than 40 percent, contains no phosphorus, no aluminum, has weak alkalinity, does not pollute the environment and does not irritate the skin, adopts water as a solvent, is suitable for mechanized washing, and has good effect in chilled water quality. The detergent contains anion, nonionic surfactant, softening agent, anti-hard water agent, stabilizer, preservative, whitening agent and pH value buffering agent, and is a novel mixed liquid detergent representing the development direction of the current detergent, and the decontamination index of the detergent reaches 2.1 (1.0 for standard washing powder).
Description
The invention belongs to a kind of free of contamination soapless soap.
Current, for solving Cleaning preparations series of new techniques has been used in the pollution problem of environment, in the hope of the harm that can reach without phosphorus, aluminium and purpose that can rapid degraded in soil.Guaranteed again when the invention enables above-mentioned target to reach product efficient, soft, brighten and use, accumulating advantage easily, be a kind of product innovation of the current international and domestic washing composition developing trend of representative.
Existing Cleaning preparations comprises the liquid-type of powder type, wherein have phosphorous, contain aluminium, but decontamination index is not high; Though not phosphorous, the aluminium that have, prescription is simple, and only about 18%-30%, decontamination index also is confined to about 1.5-1.7 non-ionic surfactant concentration.
The invention belongs to a kind of mixed type liquid washing agent, not only contain anion surfactant but also contain nonionogenic tenside, surfactant content is up to more than the 4O%, and pH value is low; Constant product quality, in-5 ℃ of-40 ℃ of temperature ranges not thick knot, do not solidify, haze-free, not stratified, in hard water, cold water, as usual use, the clothing quality softness that washes out, great shaggy-fruited dittany are gorgeous, not skin irritation, do not hinder fabric fibre, thereby effect is fine.
Other outstanding feature of this washing composition is:
One, optimum mechanize washing: counterweight greasy dirt place needn't hand-launder in advance, need only with this product a little or spread or smear the dirty places of heavy oil such as neckline, cuff and can drop into washing machine and normally wash;
Two, energy-conservation: this product production process is simple, does not need valuable filler and joins slurry, drying process, in the easy molten ortho-water;
Three, save packing: hyperconcentration makes same pail pack portability more surfactant, has avoided the packing plastics bag to the pollution of environment, the waste of having saved wrapping material comparatively speaking;
Four, moderate foam is easy to rinsing.
The present invention solves homogeneously in kinds of surface promoting agent, auxiliary agent to steam to stay in the water, is aided with specific odor type and color and is made into.Prescription and content range are as follows: (weight percent)
(1)、AEO_9???：????8％-16％
(2)、AES?????：????2％-7％
(3)、ABS?????????：????5％-15％
(4)、6501????????：????4％-10％
(5), EDTA disodium: 1%-3%
(6), trolamine: 1%-3%
(7), Sodium Benzoate: 1%-5%
(8), ethanol: 3%-10%
(9), fluorescent bleaches: 0.1%-0.35%
(10), pigment: 0.01%-0.02% (green)
(11), essence: 0.01%-0.02%
(import jasmine fragrance)
(12), aquae destillata: surplus (being supplemented to 100%)
Embodiment 1:
Following each component is dropped in the agitator by weight percentage, get final product after stirring through 0.5-2 hour.
Proportioning raw materials:
(1)、AEO_9???????：????15％
(2)、AES?????????：????5％
(3)、ABS?????????：????15％
(4)、6501????????：????8％
(5), EDTA disodium: 2%
(6), trolamine: 3%
(7), Sodium Benzoate: 3%
(8), ethanol: 6%
(9), fluorescent bleaches: 0.3%
(10), pigment: 0.01% (green)
(11), essence: 0.01% (import jasmine fragrance)
(12), aquae destillata: surplus
Through the check of national functional body, the every index of this product all reaches or is better than standard value.Every leading indicator is as follows:
| Check top order | Standard code | The water product |
| Outward appearance | Evenly, nothing, mechanical acrobatics | Qualified |
| Cold-resistant heat-resisting | -5 ℃ ± 2 ℃/24h return to 15 ℃～5 ℃-40 ℃ ± 2 ℃/24h is not stratified not to be precipitated | Qualified |
| Tensio-active agent (%) | ????≥10 | 43 |
| Relative decontamination ratio | ????≥1.0 | 2.1 |
| The PH value | ????≤1.0 | 8.5 |
| Foam | ????≤300 | 300 |
Claims (11)
1, the free of contamination mixed type liquid washing agent of a kind of new and effective hyperconcentration is characterized in that without phosphorus, aluminium public hazards, pollution-free, efficient, hyperconcentration and is the liquid washing agent of mixed type;
2, according to the said liquid scrubbing of claim 1 be a kind of be the washing composition of solvent with water;
3, be prescription and the each component content range that specification sheets provides according to claim 1 pointed its prescription of washing composition and each component content range;
4, be AEO_9 and AEO series product according to listed nonionogenic tenside in the said prescription of claim 3, include interior up to AEO_12 from AEO_3; Another kind of nonionogenic tenside is 6501, and its congener comprises all alkylolamides; These two kinds of promoting agents provide soft, scourability efficiently just;
5, be auxiliary agent according to EDTA disodium and the ethanol listed in the pointed prescription of claim 3, they give steady quality, appearance stablity character and the anti-hard water of product fine just;
6, be a kind of anti-corrosion additive according to the Sodium Benzoate of listing in the said prescription of claim 3, it can also reduce product viscosity simultaneously, increases product appearance and inner quality stability;
7, give the washing effect that brightens of product fine according to the white dyes of listing in the said prescription of claim 3;
8, be to make product have the washing assistant of stable pH value according to the trolamine of listing in the said prescription of claim 3;
9, be one group of characteristic formula that comprises the hyperconcentration mixed type liquid washing agent of negatively charged ion and nonionogenic tenside, softening agent, anti-hard water agent, stablizer, anti-corrosion additive, whitening agent, pH value buffer reagent according to the listed prescription of claim 3;
10, be that feature as product of the present invention is odor type and characteristic color according to odor type that adopts in the pointed prescription of claim 3 and pigment;
11, the optimum content scope by the listed prescription of claim 3 is:
One, AEO_9: 9%-15%
Two, AES: 3%-5%
Three, ABS: 10%-15%
Four, 6501: 6%-8%
Five, EDTA disodium: 1.5%-2% six, trolamine: 1.5%-3% seven, Sodium Benzoate: 2%-5% eight, ethanol: 4%-6% nine, white dyes: 0.2%-0.35% ten, pigment: 0.05%-0.01% (green) 11, essence: 0.05%-0.01%
Water is stayed in (import jasmine fragrance) 12, steaming: surplus (being supplemented to 100%) (above each component all is weight percents)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96111868 CN1176996A (en) | 1996-09-17 | 1996-09-17 | High-efficiency phosphorus-free and aluminum-free super-concentrated soft whitening laundry detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96111868 CN1176996A (en) | 1996-09-17 | 1996-09-17 | High-efficiency phosphorus-free and aluminum-free super-concentrated soft whitening laundry detergent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1176996A true CN1176996A (en) | 1998-03-25 |
Family
ID=5121277
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 96111868 Pending CN1176996A (en) | 1996-09-17 | 1996-09-17 | High-efficiency phosphorus-free and aluminum-free super-concentrated soft whitening laundry detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1176996A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1086198C (en) * | 1999-02-05 | 2002-06-12 | 安徽芳草日化股份有限公司 | Multifunctional concentrated phosphorus-free liquid detergent |
| CN101979488A (en) * | 2010-09-29 | 2011-02-23 | 东南大学 | Multifunctional cleaning solution for pore pressure filter rings for pore pressure static cone penetration test |
| CN103361197A (en) * | 2013-07-23 | 2013-10-23 | 百氏得森(上海)精细化工有限公司 | Laundry liquid using gel to stably disperse microcapsule essence and preparation technology thereof |
| CN103409245A (en) * | 2010-06-30 | 2013-11-27 | 杨红宇 | Concentrated laundry detergent |
| CN104694293A (en) * | 2013-12-07 | 2015-06-10 | 招远鲁娃婴幼儿用品有限公司 | Children clothes cleaning fluid |
| CN107090366A (en) * | 2017-05-15 | 2017-08-25 | 广州市丽高洗涤用品有限公司 | A kind of cold water detergent and preparation method thereof |
| CN111304015A (en) * | 2020-03-04 | 2020-06-19 | 广州衣鸣日化科技有限公司 | Antibacterial high-concentration laundry detergent and preparation method thereof |
| CN111778114A (en) * | 2020-07-24 | 2020-10-16 | 江南大学 | Ultra-concentrated liquid detergent and preparation method thereof |
-
1996
- 1996-09-17 CN CN 96111868 patent/CN1176996A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1086198C (en) * | 1999-02-05 | 2002-06-12 | 安徽芳草日化股份有限公司 | Multifunctional concentrated phosphorus-free liquid detergent |
| CN103409245A (en) * | 2010-06-30 | 2013-11-27 | 杨红宇 | Concentrated laundry detergent |
| CN101979488A (en) * | 2010-09-29 | 2011-02-23 | 东南大学 | Multifunctional cleaning solution for pore pressure filter rings for pore pressure static cone penetration test |
| CN103361197A (en) * | 2013-07-23 | 2013-10-23 | 百氏得森(上海)精细化工有限公司 | Laundry liquid using gel to stably disperse microcapsule essence and preparation technology thereof |
| CN104694293A (en) * | 2013-12-07 | 2015-06-10 | 招远鲁娃婴幼儿用品有限公司 | Children clothes cleaning fluid |
| CN107090366A (en) * | 2017-05-15 | 2017-08-25 | 广州市丽高洗涤用品有限公司 | A kind of cold water detergent and preparation method thereof |
| CN111304015A (en) * | 2020-03-04 | 2020-06-19 | 广州衣鸣日化科技有限公司 | Antibacterial high-concentration laundry detergent and preparation method thereof |
| CN111778114A (en) * | 2020-07-24 | 2020-10-16 | 江南大学 | Ultra-concentrated liquid detergent and preparation method thereof |
| CN111778114B (en) * | 2020-07-24 | 2021-10-01 | 江南大学 | Ultra-concentrated liquid detergent and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |