JPH08510002A - Mixing sequence for preparing an aqueous detergent composition - Google Patents

Mixing sequence for preparing an aqueous detergent composition

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Publication number
JPH08510002A
JPH08510002A JP6525444A JP52544494A JPH08510002A JP H08510002 A JPH08510002 A JP H08510002A JP 6525444 A JP6525444 A JP 6525444A JP 52544494 A JP52544494 A JP 52544494A JP H08510002 A JPH08510002 A JP H08510002A
Authority
JP
Japan
Prior art keywords
composition
aqueous detergent
producing
weight
detergent composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6525444A
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Japanese (ja)
Inventor
バツォーリ，ジャンニ
リッチ．カルロ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
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Procter and Gamble Co
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Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of JPH08510002A publication Critical patent/JPH08510002A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
    • C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Abstract

(57)【要約】 実質量の有機成分を含む、水性洗剤組成物の製造方法を開示する。前記有機成分を特定順序で加えることによって、澄んで透明な最終生成物が得られる。   (57) [Summary] Disclosed is a method of making an aqueous detergent composition that includes true amounts of organic components. A clear and transparent final product is obtained by adding the organic components in a specific order.

Description

【発明の詳細な説明】 水性洗剤組成物を調製するための混合順序 技術分野 本発明は、水性洗剤組成物の製造方法に関する。本発明は特に、実質量の有機 成分を含むそのような組成物を調製するための混合順序に関する。 背景技術 水性洗剤組成物は、従来技術において広範に記載されている。特に、そのよう な組成物が、水、および界面活性剤、香料、安定剤などのような有機成分を含む 溶液として調製されてもよいことはよく知られている。このような有機成分は、 主として水に難溶であるかあるいは不溶である。したがって、前記有機成分はそ の水性マトリックス中に完全には溶解するものではないので、前記組成物は不透 明、つまり濁ってしまうという自然の傾向がある。これは、有機成分の全比率が 増加するにつれてさらに問題となる。この現象は、消費者の受け入れを低減させ る結果となる。したがって、本発明が解決しようとする課題は、最終的に得られ る組成物における濁りを回避することである。 この技術課題に対し、出願人らは、このような水性洗剤組成物の製造に際して 、異なる有機成分を特定の順序で混合することによって、澄みかつ透明な最終組 成物を得ることができることを見出した。 したがって、本発明の目的は、澄みかつ透明な水性洗剤組成物を得ることであ る。 出願人による、欧州特許出願ＥＰ−Ａ−５１７９９６は、その方法の最終工程 として加えられる過酸化水素を除いて、すべての成分を一緒に混合することによ り製造される、安定な過酸化水素含有漂白組成物を開示している。前記出願は、 前出の不透明性の問題に関しては、開示するものはない。 発明の概要 本発明は、非イオン界面活性剤、陰イオン界面活性剤および香料を含んでなる 水性洗剤組成物の製造方法であって、以下の工程を含む。 非イオン界面活性剤を水に混合し（組成物Ａ）、 香料を前記陰イオン界面活性剤に溶解させ（組成物Ｂ）、 その後、前記組成物Ｂを前記組成物Ａに混合する（組成物Ｃ）。 詳細な説明 本発明は、水性洗剤組成物の製造に関する。前記水性洗剤組成物は、水、非イ オン界面活性剤、陰イオン界面活性剤および香料を含む。本発明の組成物は、様 々の異なった態様、特に家内クリーナとして調製することもできる。 本発明によって製造される組成物は、第１必須成分として、以下の一般式の非 イオン界面活性剤を含んでなる。 Ｒ1−Ｏ−［（Ｒ2Ｏ）n（Ｒ3Ｏ）m］−Ｒ4 （ここで、式中、 Ｒ1はＣ1-25のアルキルまたはアルケニル鎖、好ましくはＣI0-15、好ましくは アルキル、 Ｒ2はＣ2-4の脂肪族炭化水素鎖、好ましくはＣ2、 Ｒ3はメチルまたはエチルモノ置換Ｃ2-4脂肪族炭化水素鎖、好ましくは、メチ ル置換エチレン、 Ｒ4は、Ｃ1-25アルキルまたはアルケニルカルボキシル鎖、またはＨ、好まし くはＨ、 ｎは、１〜１０の整数、好ましくは１〜５、 ｍは、０〜２０の整数、好ましくは０〜１０、最も好ましくは０〜３、 またはそれらの混合物） 上記化学式においては、Ｒ2ＯおよびＲ3Ｏ基は、この分子内でどのような順序 で出現してもよく、さらに、ｎおよびｍが１を超える場合、異なったＲ2Ｏおよ びＲ3Ｏ基が同じ分子中に存在してもよいことが理解されるべきである。市販さ れている非イオン界面活性剤は、例えば欧州特許出願ＥＰ−Ａ−０５１８４０１ またはＥＰ−Ａ−０５１７９９６の中に記載されている。本発明によって製造さ れる組成物は、全組成物の０．１〜３０重量％、好ましくは０．５〜１０重量％ の前記非イオン界面活性剤またはそれらの混合物を含む。 本発明によって製造される組成物は、第２の必須成分として、さらに陰イオン 界面活性剤または、それらの混合物を含んでなる。本発明において好適に用いら れる陰イオン界面活性剤は、従来技術に広範に記載されているものであり、アル キルベンゼンスルホネートおよびアルキルサルフェートを含む。本発明で用いる アルキルサルフェート界面活性剤は、例えばココナツなどの天然原料から得るこ とができる。したがって、本発明により製造される組成物は、好ましくは、全組 成物の０．５〜４０重量％、好ましくは０．５〜１０重量％の前記陰イオン界面 活性剤またはその混合物を含む。本発明において特に好ましいものは、ココナツ アルキル硫酸ナトリウムである。 本発明によって製造される組成物は、陽イオン、および双性イオン界面活性剤 を含む従来技術に記載されたものなどの追加的な界面活性剤をさらに含んでいて もよい。 本発明によって製造される組成物は、第３の必須成分として、さらに全組成物 の０．０３〜５重量％、好ましくは０．０３〜３重量％の香料を含んでなる。 本発明によって製造される組成物は、全組成物の６０〜９９重量％、好ましく は８０〜９５重量％の水を含んでなる。 本発明によって製造される組成物は、溶媒、好水性物質、キレート剤、増粘剤 、芳香剤、および白色化剤のような追加的な慣用成分をさらに含んでいてもよく 、提供されるこれらのすべての成分は、この組成物に併存可能である。前記成分 は、本発明の組成物の透明性に関して重要ではない。 本発明によって製造される組成物の好ましい具体例は、さらに全組成物の１〜 １５重量％、好ましくは２〜１０重量％の漂白剤を含んでなる。本発明において 好ましい漂白剤は過酸化水素である。 本発明によって製造される組成物は、好ましくは酸性であり、ｐＨは２〜６、 好ましくは３〜５、最も好ましくは４である。このようなｐＨ範囲は、有機また は無機酸、ｐＨを酸性値に緩衝する酸性塩のような適当な酸性化剤を添加するこ とによって達成され得る。 酸性化剤の好適例は、硫酸、リン酸（しかしながらこれは環境保護の観点から は好ましくない）、塩酸、ホスホン酸、クエン酸、酢酸、酒石酸、マレイン酸な どである。 本発明によって製造される組成物のさらに好ましい具体例は、さらにブチルヒ ドロキシトルエンを、酸化防止剤およびＨ2Ｏ2安定剤として加えてなる。前記組 成物は、全組成物の０．０１〜１重量％、好ましくは０．０１〜０．８重量％の ブチルヒドロキシトルエンを含む。 本発明による方法は、以下の工程を含む。 １工程において、上記非イオン界面活性剤を水に混合し、組成物を得る（以後 、組成物Ａという）。 別の工程では、上記香料を上記陰イオン界面活性剤に溶解させて、組成物を得 る（以後、組成物Ｂという）。 組成物ＡおよびＢを製造する順序は、本発明においては重要ではない。 本発明による方法のさらなる工程は、前記組成物Ｂを前記組成物Ａ中に混合し て、組成物Ｃを得る。当該工程においては、前記組成物ＡとＢとが共に混合され たときに、本発明の組成物は澄んで透明になる。 本発明により製造される組成物の好ましい具体例は、さらに漂白剤を含み、こ の漂白剤は、その方法の最終工程としてこの組成物Ｃの上に加えられる。 本発明により製造される組成物のさらに好ましい具体例は、さらにブチルヒド ロキシトルエンを含み、このブチルヒドロキシトルエンは、前記香料が前記陰イ オン界面活性剤に溶解され組成物Ｂが得られる工程の前に、その香料に溶解する 。 さらに好ましい具体例にあっては、前記水性漂白剤組成物はさらに酸性化剤を 含み、好ましくは、本発明の方法に、その漂白剤組成物の最終添加の前に、前記 酸性化剤を組成物Ｃに加える追加の工程を含む。この酸性化剤は純粋のまままた は予め希釈して加えることができる。 実施例 以下の組成物を以下に記載された本発明の方法により、表中の成分、表中の比 率によって製造した。 本発明による方法の１工程では、そのポリエトキシプロポキシアルコールを水 に混合する。得られた組成物をＡとする。 別の工程では、そのブチルヒドロキシトルエンをその香料の中に溶解させる。 その後、その香料をその陰イオン界面活性剤に溶解させる。その結果の組成物を Ｂとする。 その後、本発明による方法のさらなる工程として、組成物Ｂを組成物Ａに混合 する。 そのｐＨを調節する。 そして最終的に、その組成物の残部の上にその方法の最終工程として過酸化水 素を添加する。 本発明の特定の混合順序によって調製される本発明の組成物は、澄みかつ透明 である。Detailed Description of the Invention                  Mixing sequence for preparing an aqueous detergent composition                                 Technical field   The present invention relates to a method for producing an aqueous detergent composition. The present invention is particularly applicable to substantial amounts of organic It relates to a mixing sequence for preparing such a composition comprising the components.                                 Background technology   Aqueous detergent compositions have been extensively described in the prior art. Especially as such Compositions include water and organic components such as surfactants, fragrances, stabilizers, etc. It is well known that it may be prepared as a solution. Such organic components are Mainly sparingly soluble or insoluble in water. Therefore, the organic component is The composition is impermeable because it is not completely soluble in the aqueous matrix of There is a natural tendency to become muddy, that is, cloudy. This is because the total proportion of organic components is As the number increases, it becomes more problematic. This phenomenon reduces consumer acceptance Result. Therefore, the problem to be solved by the present invention is finally obtained. To avoid turbidity in the composition.   In response to this technical problem, the Applicants have been involved in the production of such an aqueous detergent composition. , A clear and transparent final set by mixing different organic components in a specific order It was found that the product can be obtained.   Therefore, it is an object of the present invention to obtain a clear and transparent aqueous detergent composition. It   Applicant's European patent application EP-A-517996 is the final step of the process. By mixing all the ingredients together, with the exception of hydrogen peroxide, which is added as Disclosed is a stable bleaching composition containing hydrogen peroxide produced by the method. The application is There is nothing to disclose regarding the issue of opacity described above.                                Summary of the invention   The present invention comprises a nonionic surfactant, an anionic surfactant and a perfume. A method for producing an aqueous detergent composition, comprising the following steps.   Mixing a nonionic surfactant with water (composition A),   A fragrance is dissolved in the anionic surfactant (composition B),   Then, the composition B is mixed with the composition A (composition C).                                Detailed description   The present invention relates to the production of aqueous detergent compositions. The aqueous detergent composition is Includes on-surfactants, anionic surfactants and fragrances. The composition of the present invention is It can also be prepared in different ways, especially as a home cleaner.   The composition produced according to the present invention has, as a first essential component, a non-compound of the following general formula: It comprises an ionic surfactant.   R1-O-[(R2O)n(R3O)m] -RFour (Where   R1Is C1-25An alkyl or alkenyl chain of, preferably CI0-15,Preferably Alkyl,   R2Is C2-4An aliphatic hydrocarbon chain, preferably C2,   R3Is methyl or ethyl mono-substituted C2-4Aliphatic hydrocarbon chains, preferably methyl -Substituted ethylene,   RFourIs C1-25Alkyl or alkenyl carboxyl chain, or H, preferred Ku H,   n is an integer of 1 to 10, preferably 1 to 5,   m is an integer of 0-20, preferably 0-10, most preferably 0-3, Or a mixture of them)   In the above chemical formula, R2O and R3What is the order of the O groups in this molecule? May occur at the same time, and when n and m are greater than 1, different R2O and And R3It should be understood that the O groups may be present in the same molecule. Commercially available The nonionic surfactants mentioned are, for example, European patent application EP-A-0518401. Or it is described in EP-A-0517996. Manufactured by the present invention The composition is 0.1 to 30% by weight of the total composition, preferably 0.5 to 10% by weight. Of said nonionic surfactants or mixtures thereof.   The composition produced according to the present invention further comprises, as a second essential component, an anion. It comprises a surfactant or a mixture thereof. Preferably used in the present invention The anionic surfactants mentioned are those widely described in the prior art, Includes killbenzene sulfonate and alkyl sulphate. Used in the present invention Alkyl sulfate surfactants can be obtained from natural sources such as coconut. You can Therefore, the composition produced according to the present invention preferably comprises the whole set. 0.5-40% by weight of the product, preferably 0.5-10% by weight of said anionic interface It contains an active agent or a mixture thereof. Especially preferred in the present invention is coconut It is sodium alkylsulfate.   The composition produced according to the present invention comprises a cation and a zwitterionic surfactant. Further comprising additional surfactants such as those described in the prior art including Good.   The composition produced by the present invention further comprises, as a third essential ingredient, the total composition 0.03-5% by weight, preferably 0.03-3% by weight of fragrance.   The composition produced according to the invention comprises 60 to 99% by weight of the total composition, preferably Comprises 80-95% by weight of water.   The composition produced by the present invention comprises a solvent, a hydrophile, a chelating agent, and a thickener. May further include additional conventional ingredients such as, fragrances, and whitening agents. All these ingredients provided are co-existent in this composition. Ingredient Are not important with respect to the transparency of the composition of the invention.   Preferred embodiments of the composition produced according to the present invention further include It comprises 15% by weight, preferably 2-10% by weight of bleach. In the present invention The preferred bleaching agent is hydrogen peroxide.   The composition produced according to the present invention is preferably acidic and has a pH of 2-6, It is preferably 3 to 5, and most preferably 4. Such a pH range is Is a suitable acidifying agent such as an inorganic acid or an acid salt that buffers the pH to an acidic value. Can be achieved by.   Suitable examples of acidifying agents include sulfuric acid and phosphoric acid (however, this is from the viewpoint of environmental protection. Is not preferred), hydrochloric acid, phosphonic acid, citric acid, acetic acid, tartaric acid, maleic acid, etc. How is it?   More preferred embodiments of the composition produced by the present invention further include butyl ester. Droxytoluene, antioxidant and H2O2It is added as a stabilizer. The group The product comprises 0.01 to 1% by weight of the total composition, preferably 0.01 to 0.8% by weight. Contains butylhydroxytoluene.   The method according to the invention comprises the following steps.   In one step, the nonionic surfactant is mixed with water to obtain a composition (hereinafter referred to as “composition”). , Composition A).   In another step, the fragrance is dissolved in the anionic surfactant to give a composition. (Hereinafter referred to as composition B).   The order of making compositions A and B is not critical to the invention.   The further step of the method according to the invention is to mix said composition B into said composition A. To obtain a composition C. In this step, the compositions A and B are mixed together When exposed, the composition of the present invention becomes clear and transparent.   A preferred embodiment of the composition produced according to the invention further comprises a bleaching agent, Bleach is added on top of this composition C as the final step of the process.   Further preferred embodiments of the composition produced according to the present invention are further butylhydroxide Roxytoluene is contained in the butylhydroxytoluene, and Dissolve in the perfume before the step of dissolving in on-surfactant to obtain composition B .   In a more preferred embodiment, the aqueous bleach composition further comprises an acidifying agent. And preferably before the final addition of the bleaching composition to the process of the invention It includes the additional step of adding an acidifying agent to composition C. This acidifier remains pure Can be diluted in advance and added.                                  Example   The following compositions were prepared according to the method of the present invention described below by the components in the tables and the ratios in the tables. Manufactured by rate.   In one step of the process according to the invention, the polyethoxypropoxy alcohol is treated with water. To mix. The composition obtained is designated as A.   In another step, the butyl hydroxytoluene is dissolved in the perfume. Then, the perfume is dissolved in the anionic surfactant. The resulting composition Let B.   Then, as a further step of the method according to the invention, composition B is mixed with composition A. To do.   Adjust its pH.   And finally, on top of the rest of the composition water peroxide as the final step of the process. Add element.   The compositions of the present invention prepared by the particular mixing sequence of the present invention are clear and transparent. Is.

Claims (1)

【特許請求の範囲】 １． 非イオン界面活性剤、陰イオン界面活性剤および香料を含んでなる水性 洗剤組成物の製造方法であって、下記の工程、 前記非イオン界面活性剤を水に混合し（組成物Ａ）、 前記香料を前記陰イオン界面活性剤に溶解させ（組成物Ｂ）、 次いで、前記組成物Ｂを前記組成物Ａに混合する（組成物Ｃ） 工程を含むことを特徴とする方法。 ２． 下記一般式によって示される前記非イオン界面活性剤を含む、請求項１ に記載の水性洗剤組成物の製造方法。 Ｒ1−Ｏ−［（Ｒ2Ｏ）n（Ｒ3Ｏ）m］−Ｒ4 （ここで、式中、 Ｒ1はＣ1-25のアルキルまたはアルケニル鎖、 Ｒ2はＣ2-4の脂肪族炭化水素鎖、 Ｒ3はメチルまたはエチルモノ置換Ｃ2−Ｃ4脂肪族炭化水素鎖、 Ｒ4はＣ1-25アルキルまたはアルケニルまたはカルボキシル鎖、またはＨ、 ｎは、１〜１０の整数、 ｍは、０〜２０の整数、 またはそれらの混合物） ３． 前記組成物が、全組成物の０．１〜３０重量％の前記非イオン界面活性 剤を含む、前記いずれかの請求項に記載の水性洗剤組成物の製造方法。 ４． 前記組成物が、全組成物の０．５〜４０重量％の前記陰イオン界面活性 剤を含む、前記いずれかの請求項に記載の水性洗剤組成物の製造方法。 ５． 前記組成物が、全組成物の０．０３〜５重量％の前記香料を含む、前記 いずれかの請求項に記載の水性洗剤組成物の製造方法。 ６． 前記組成物が、さらに漂白剤組成物を含み、前記漂白剤組成物が最終工 程として前記組成物Ｃに添加される、前記いずれかの請求項に記載の水性洗剤組 成物の製造方法。 ７． 前記組成物が、前記漂白剤組成物として、全組成物の１〜１５重量％の 過酸化水素を含む、請求項６に記載の水性洗剤組成物の製造方法。 ８． 前記組成物が、ブチルヒドロキシトルエンをさらに含み、前記ブチルヒ ドロキシトルエンが、前記香料が前記陰イオン界面活性剤に溶解される工程の前 にその香料に溶解される、前記いずれかの請求項に記載の水性洗剤組成物の製造 方法。 ９． 前記組成物が、全組成物の０．０１〜１重量％の前記ブチルヒドロキシ トルエンを含む、請求項８に記載の水性洗剤組成物の製造方法。 １０． 前記組成物が、全組成物の６０〜９９重量％、好ましくは８０〜９５ 重量％の水を含む、前記いずれかの請求項に記載の水性洗剤組成物の製造方法。[Claims]   1. Aqueous comprising nonionic surfactant, anionic surfactant and perfume A method for producing a detergent composition, comprising the following steps,   Mixing the nonionic surfactant in water (composition A),   Dissolving the fragrance in the anionic surfactant (composition B),   Next, the composition B is mixed with the composition A (composition C).   A method comprising the steps of:   2. The nonionic surfactant represented by the following general formula is included: A method for producing the aqueous detergent composition according to the item 1.   R1-O-[(R2O)n(R3O)m] -RFour (Where   R1Is C1-25An alkyl or alkenyl chain of   R2Is C2-4An aliphatic hydrocarbon chain of   R3Is methyl or ethyl mono-substituted C2-CFourAliphatic hydrocarbon chain,   RFourIs C1-25Alkyl or alkenyl or carboxyl chain, or H,   n is an integer of 1 to 10,   m is an integer from 0 to 20,   Or a mixture of them)   3. The composition comprises 0.1 to 30% by weight of the total composition of the nonionic surfactant. The method for producing the aqueous detergent composition according to any one of the preceding claims, which comprises an agent.   4. The composition comprises 0.5-40% by weight of the total composition of the anionic surfactant. The method for producing the aqueous detergent composition according to any one of the preceding claims, which comprises an agent.   5. Said composition comprising 0.03 to 5% by weight of the total composition of said perfume. A method for producing the aqueous detergent composition according to any one of claims.   6. The composition further comprises a bleaching agent composition, and the bleaching agent composition is Aqueous detergent set according to any of the preceding claims, which is added to the composition C as a matter of course. Method for producing a product.   7. The composition is used as the bleach composition in an amount of 1 to 15% by weight of the total composition. The method for producing an aqueous detergent composition according to claim 6, which comprises hydrogen peroxide.   8. Wherein the composition further comprises butyl hydroxytoluene, Droxytoluene before the step in which the perfume is dissolved in the anionic surfactant The production of the aqueous detergent composition according to any one of the preceding claims, wherein the aqueous detergent composition is dissolved in the perfume. Method.   9. The composition comprises 0.01 to 1% by weight of the total composition of the butyl hydroxy. The method for producing the aqueous detergent composition according to claim 8, comprising toluene.   10. 60-99% by weight of the total composition, preferably 80-95 The method for producing an aqueous detergent composition according to any one of the preceding claims, which comprises wt% water.
JP6525444A 1993-05-06 1994-04-20 Mixing sequence for preparing an aqueous detergent composition Pending JPH08510002A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP93201287.5 1993-05-06
EP93201287A EP0623671A1 (en) 1993-05-06 1993-05-06 Mixing order to prepare aqueous clear detergent compositions
PCT/US1994/004329 WO1994026856A1 (en) 1993-05-06 1994-04-20 Mixing order to prepare aqueous detergent compositions

Publications (1)

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JPH08510002A true JPH08510002A (en) 1996-10-22

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JP (1) JPH08510002A (en)
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WO (1) WO1994026856A1 (en)

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Publication number Priority date Publication date Assignee Title
NL1000065C2 (en) * 1995-04-05 1996-10-08 Dija Zeist B V Method and means for cleaning surfaces.
ES2224117T3 (en) * 1995-07-05 2005-03-01 THE PROCTER & GAMBLE COMPANY PRE-TREATMENT FOR CLOTHING WASHING WITH IMPROVED SECURITY FOR FABRICS AND COLORS.
IT1293587B1 (en) * 1997-07-08 1999-03-08 Manitoba Italia Spa COMPOSITIONS BASED ON PERCARBOXYLIC ACIDS AS STAIN REMOVER AND SANITIZERS
DE19750455C1 (en) * 1997-11-14 1999-04-29 Henkel Kgaa Aqueous hydrogen peroxide formulation used as bleach for pretreating soiled textile, especially laundry
KR100347665B1 (en) * 2000-07-11 2002-08-07 주식회사 동산씨앤지 Clear shampoo composition containing capsules and method of making the same
DE102008012061A1 (en) * 2008-02-29 2009-09-03 Henkel Ag & Co. Kgaa Low Concentrated Liquid Detergent or Detergent with Perfume
EP2746379B1 (en) 2012-12-20 2017-03-29 The Procter & Gamble Company Process for the production of a liquid composition

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CA1072852A (en) * 1975-09-22 1980-03-04 Gregory S. Foster Heavy-duty liquid detergent and process
DE3232616A1 (en) * 1982-09-02 1984-03-08 Henkel KGaA, 4000 Düsseldorf LIQUID, INORGANIC FRUIT SALT, IN ESSENTIAL FREE DETERGENT AND CLEANING AGENT
GB8422372D0 (en) * 1984-09-05 1984-10-10 Unilever Plc Fragrant liquid cleaning compositions
JPS63277300A (en) * 1987-05-08 1988-11-15 Kao Corp Liquid detergent composition
AU627734B2 (en) * 1988-06-13 1992-09-03 Colgate-Palmolive Company, The Stable and homogeneous concentrated all purpose cleaner
DE69100809T2 (en) * 1991-06-14 1994-05-19 Procter & Gamble Stable bleaching compositions containing hydrogen peroxide.
DK0518401T3 (en) * 1991-06-14 1996-03-04 Procter & Gamble Self-thickened cleaning compositions

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AU6771194A (en) 1994-12-12
WO1994026856A1 (en) 1994-11-24
CA2162112A1 (en) 1994-11-24

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