CN107090366A - A kind of cold water detergent and preparation method thereof - Google Patents

A kind of cold water detergent and preparation method thereof Download PDF

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Publication number
CN107090366A
CN107090366A CN201710338325.4A CN201710338325A CN107090366A CN 107090366 A CN107090366 A CN 107090366A CN 201710338325 A CN201710338325 A CN 201710338325A CN 107090366 A CN107090366 A CN 107090366A
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CN
China
Prior art keywords
cold water
water detergent
detergent
sodium
minutes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710338325.4A
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Chinese (zh)
Inventor
李春如
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Ligao Cleaning Products Co Ltd
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Guangzhou Ligao Cleaning Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN201710338325.4A priority Critical patent/CN107090366A/en
Publication of CN107090366A publication Critical patent/CN107090366A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40Dyes ; Pigments
    • C11D3/42Brightening agents ; Blueing agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D1/721End blocked ethers

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of cold water detergent, include each component of following percentage by weight:0.02% 0.1% distyryl biphenyl sulfonate brightening agent;2% 5% sodium nitrilo triacetate;2% 5% lauryl sodium sulfate;30% 50% α sodium olefin sulfonates;3% 8% AEO;0.005% 0.02% polymerism brightening agent;1% 5% Sodium Polyacrylate;Excess water.A kind of preparation method of cold water detergent, comprises the following steps:The first step, is weighed;Second step, dissolving;3rd step, is stirred mixing, time control was at 80 90 minutes by each component of dissolving;4th step, filtering, obtains filtrate;5th step, it is filling.The cold water detergent of the present invention can quickly dissolve all heavy dirty and oil stains in hard water matter, do not hinder cloth, efficiently brighten, get instant result, make towel, sheet bright and clean snow-white after washing.Also there are good decontamination, whitening effect in normal-temperature water, reduce CO2 emission.The manufacturing technique method of the present invention is simple and easy to apply.

Description

A kind of cold water detergent and preparation method thereof
Technical field
The present invention relates to a kind of cold water detergent and preparation method thereof.
Background technology
Detergent of the prior art can not quickly dissolve all heavy dirty and oil stains in hard water matter, damage cloth, brighten effect It is really poor.Decontamination, whitening effect are poor in normal-temperature water, and heating cost is high, and energy resource consumption is big, not environmentally.
The content of the invention
The present invention proposes a kind of cold water detergent, solves the problem above of prior art presence.
The invention also provides a kind of cold water detergent preparation method, this method is simple and easy to apply.
The technical proposal of the invention is realized in this way:A kind of cold water detergent, includes each group of following percentage by weight Point:0.02%-0.1% distyryl biphenyl sulfonate brightening agent;2%-5% sodium nitrilo triacetate;2%-5% dodecane Base sodium sulphate;30%-50% α-sodium olefin sulfonate;3%-8% AEO;0.005%-0.02% polymerism increases White agent;1%-5% Sodium Polyacrylate;Excess water.
Further, the percentage by weight that the distyryl biphenyl sulfonate brightening agent accounts for the cold water detergent is 0.02%-0.05%。
Further, the percentage by weight that the sodium nitrilo triacetate accounts for the cold water detergent is 3%-4%.
Further, the percentage by weight that the lauryl sodium sulfate accounts for the cold water detergent is 3%-4%.
Further, the percentage by weight that the α-sodium olefin sulfonate accounts for the cold water detergent is 35%-45%.
Further, the percentage by weight that the AEO accounts for the cold water detergent is 4%-6%.
Further, the polymerism brightening agent accounts for the 0.005%-0.01% of the cold water detergent.
Further, the percentage by weight that the Sodium Polyacrylate accounts for the cold water detergent is 2%-4%.
Wherein, distyryl biphenyl sulfonate brightening agent is used as brightening agent, the vividness of increase cloth grass.
Sodium nitrilo triacetate is water softener, calcium, magnesium ion in complexing water, improves the detergency of surfactant;
Lauryl sodium sulfate is surfactant, low temperature strong detergency;
AEO is surfactant;
A- sodium olefin sulfonates(35%)For surfactant, biodegradability is good, low temperature strong detergency;
Polymerism brightening agent is the environmentally friendly whiteness lifting additive of polymerism;
Sodium Polyacrylate is anti-ash, anti redeposition agent.
A kind of preparation method of cold water detergent, comprises the following steps:
The first step, production cylinder is rinsed well, part water is added, is warming up to 45-50 DEG C, heat time 15-25 minute;Start and stir Mix machine, 50-60 revs/min of mixing speed;The distyryl biphenyl sulfonate brightening agent of above-mentioned percentage by weight is added, is stirred Time 2-5 minute;
Second step, adds the sodium nitrilo triacetate of above-mentioned percentage by weight, mixing time 2-5 minutes;
3rd step, adds the lauryl sodium sulfate of above-mentioned percentage by weight, mixing time 4-6 minutes;
4th step, adds the AEO of above-mentioned percentage by weight, mixing time 4-6 minutes;
5th step, adds the a- sodium olefin sulfonates of above-mentioned percentage by weight, mixing time 1-2 minutes;
6th step, adds the polymerism brightening agent in advance with the good above-mentioned percentage by weight of part aqueous solution, 1-2 points of mixing time Clock;
7th step, adds the Sodium Polyacrylate of above-mentioned percentage by weight, mixing time 3-5 minutes;
8th step, polishing excess water, stirring and dissolving stands froth breaking, cold water detergent is obtained with filtered through gauze.
It is preferred that, the mesh number of the gauze is 100 mesh.
Beneficial effects of the present invention are:The cold water detergent of the present invention is blue thick liquid, and alkalescent adds organized enzyme And New-type adjuvant, optimal low temperature, efficient, the concentrated type synthetic detergent of easily biological-degradable surfactant compound are screened, is broken through Traditional milling technology, can quickly dissolve all heavy dirty and oil stains in hard water matter, not hinder cloth, efficiently brighten, get instant result, after washing Make towel, sheet bright and clean snow-white.Adapt to wash temperature 20-70 degree, medium foam.Washing powder is coordinated to use when master washes, 100KG cloth Material plus 100-300 grams of cold water detergent using effect are good.The energy-saving low-temperature detergent made to measure exclusively for washing plant, even if Also there are good decontamination, whitening effect in normal-temperature water, be that user saves a large amount of heating costs, save the energy, reduce titanium dioxide Carbon emission.The manufacturing technique method of the present invention is simple and easy to apply.
Embodiment
To more fully understand the present invention, further specific elaboration, but not is made to the present invention below by following examples Limitation of the invention is can be regarded as, some made for those skilled in the art according to foregoing invention content are nonessential Improve with adjusting, be also considered as being within the scope of the present invention.
Embodiment 1
Cold water detergent one is made in the content provided according to the present invention, inventor, and the weight percent of wherein each component is when prepared Process is as follows:
A kind of cold water detergent one, includes each component of following percentage by weight:0.02% distyryl biphenyl sulfonate increases White agent;2% sodium nitrilo triacetate;2% lauryl sodium sulfate;30% α-sodium olefin sulfonate;3% fatty alcohol polyoxy second Alkene ether;0.005% polymerism brightening agent;1% Sodium Polyacrylate;Excess water.
The preparation method of cold water detergent one, comprises the following steps:
The first step, production cylinder is rinsed well, part water is added, is warming up to 45 DEG C, 15 minutes heat times;Start mixer, 50 revs/min of mixing speed;Add distyryl biphenyl sulfonate brightening agent, mixing time 2 minutes;
Second step, adds sodium nitrilo triacetate, mixing time 2 minutes;
3rd step, adds lauryl sodium sulfate, mixing time 4 minutes;
4th step, adds AEO, mixing time 4 minutes;
5th step, adds a- sodium olefin sulfonates, mixing time 1 minute;
6th step, is added in advance with the good polymerism brightening agent of part aqueous solution, mixing time 1 minute;
7th step, adds Sodium Polyacrylate, mixing time 3 minutes;
8th step, polishing excess water, stirring and dissolving stands froth breaking, cold water detergent is obtained with 200 mesh filtered through gauze.
Embodiment 2
Cold water detergent two is made in the content provided according to the present invention, inventor, and the weight percent of wherein each component is when prepared Process is as follows:
A kind of cold water detergent two, includes each component of following percentage by weight:0.1% distyryl biphenyl sulfonate increases White agent;5% sodium nitrilo triacetate;5% lauryl sodium sulfate;50% α-sodium olefin sulfonate;8% fatty alcohol polyoxy second Alkene ether;0.02% polymerism brightening agent;5% Sodium Polyacrylate;Excess water.
The preparation method of cold water detergent two, comprises the following steps:
The first step, production cylinder is rinsed well, part water is added, is warming up to 50 DEG C, 25 minutes heat times;Start mixer, 60 revs/min of mixing speed;Add distyryl biphenyl sulfonate brightening agent, mixing time 5 minutes;
Second step, adds sodium nitrilo triacetate, mixing time 5 minutes;
3rd step, adds lauryl sodium sulfate, mixing time 6 minutes;
4th step, adds AEO, mixing time 6 minutes;
5th step, adds a- sodium olefin sulfonates, mixing time 2 minutes;
6th step, is added in advance with the good polymerism brightening agent of part aqueous solution, mixing time 2 minutes;
7th step, adds Sodium Polyacrylate, mixing time 5 minutes;
8th step, polishing excess water, stirring and dissolving stands froth breaking, cold water detergent is obtained with filtered through gauze.
Embodiment 3
Cold water detergent is made in the content provided according to the present invention, inventor, and the weight percent of wherein each component was when prepared Journey is as follows:
A kind of cold water detergent three, includes each component of following percentage by weight:0.05% distyryl biphenyl sulfonate increases White agent;3.5% sodium nitrilo triacetate;3.5% lauryl sodium sulfate;40% α-sodium olefin sulfonate;5.5% fatty alcohol APEO;0.01% polymerism brightening agent;3% Sodium Polyacrylate;Excess water.
The preparation method of cold water detergent three, comprises the following steps:
The first step, production cylinder is rinsed well, part water is added, is warming up to 47 DEG C, 20 minutes heat times;Start mixer, 55 revs/min of mixing speed;Add distyryl biphenyl sulfonate brightening agent, mixing time 3 minutes;
Second step, adds sodium nitrilo triacetate, mixing time 3 minutes;
3rd step, adds lauryl sodium sulfate, mixing time 5 minutes;
4th step, adds AEO, mixing time 5 minutes;
5th step, adds a- sodium olefin sulfonates, mixing time 1.5 minutes;
6th step, is added in advance with the good polymerism brightening agent of part aqueous solution, mixing time 1.5 minutes;
7th step, adds Sodium Polyacrylate, mixing time 4 minutes;
8th step, polishing excess water, stirring and dissolving stands froth breaking, cold water detergent is obtained with filtered through gauze.
Cold water detergent one, cold water detergent two, the cold water detergent three being prepared into can quickly dissolve institute in hard water matter There is weight dirty and oil stain, do not hinder cloth, efficiently brighten, get instant result, make towel, sheet bright and clean snow-white after washing.Cold water detergent one, Cold water detergent two, cold water detergent three coordinate washing powder to use, and 100KG clothes add 100-300 grams of cold water detergent to use effect It is really good.The energy-saving low-temperature detergent made to measure exclusively for washing plant, also has good decontamination in normal-temperature water, brightens Effect, is that user saves a large amount of heating costs, saves the energy, reduce CO2 emission.The manufacturing technique method letter of the present invention It is single easy.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.

Claims (10)

1. a kind of cold water detergent, it is characterised in that:Include each component of following percentage by weight:0.02%-0.1% hexichol second Alkenyl diphenylsulfonates brightening agent;2%-5% sodium nitrilo triacetate;2%-5% lauryl sodium sulfate;30%-50% α-alkene Base sodium sulfonate;3%-8% AEO;0.005%-0.02% polymerism brightening agent;1%-5% polyacrylic acid Sodium;Excess water.
2. cold water detergent as claimed in claim 1, it is characterised in that:The distyryl biphenyl sulfonate brightening agent is accounted for The percentage by weight of the cold water detergent is 0.02%-0.05%.
3. cold water detergent as claimed in claim 1, it is characterised in that:The sodium nitrilo triacetate accounts for the cold water detergent Percentage by weight be 3%-4%.
4. cold water detergent as claimed in claim 1, it is characterised in that:The lauryl sodium sulfate accounts for the cold water washing The percentage by weight of agent is 3%-4%.
5. cold water detergent as claimed in claim 1, it is characterised in that:α-the sodium olefin sulfonate accounts for the cold water detergent Percentage by weight be 35%-45%.
6. cold water detergent as claimed in claim 1, it is characterised in that:The AEO accounts for the cold water and washed The percentage by weight for washing agent is 4%-6%.
7. cold water detergent as claimed in claim 1, it is characterised in that:The polymerism brightening agent accounts for the cold water detergent 0.005%-0.01%.
8. cold water detergent as claimed in claim 1, it is characterised in that:The Sodium Polyacrylate accounts for the cold water detergent Percentage by weight is 2%-4%.
9. a kind of preparation method of cold water detergent as described in claim 1-8 is any, it is characterised in that:Including following step Suddenly:
The first step, production cylinder is rinsed well, part water is added, is warming up to 45-50 DEG C, heat time 15-25 minute;Start and stir Mix machine, 50-60 revs/min of mixing speed;Add distyryl biphenyl sulfonate brightening agent, mixing time 2-5 minutes;
Second step, adds sodium nitrilo triacetate, mixing time 2-5 minutes;
3rd step, adds lauryl sodium sulfate, mixing time 4-6 minutes;
4th step, adds AEO, mixing time 4-6 minutes;
5th step, adds a- sodium olefin sulfonates, mixing time 1-2 minutes;
6th step, is added in advance with the good polymerism brightening agent of part aqueous solution, mixing time 1-2 minutes;
7th step, adds Sodium Polyacrylate, mixing time 3-5 minutes;
8th step, polishing excess water, stirring and dissolving stands froth breaking, cold water detergent is obtained with filtered through gauze.
10. the preparation method of cold water detergent as claimed in claim 1, it is characterised in that:The mesh number of the gauze is 100 Mesh.
CN201710338325.4A 2017-05-15 2017-05-15 A kind of cold water detergent and preparation method thereof Pending CN107090366A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113549500A (en) * 2021-07-23 2021-10-26 河南省科学院化学研究所有限公司 Fatty alcohol-polyoxyethylene ether-based detergent and preparation method and application thereof

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1176996A (en) * 1996-09-17 1998-03-25 王连祥 High-efficiency phosphorus-free and aluminum-free super-concentrated soft whitening laundry detergent
CN1210102A (en) * 1997-08-28 1999-03-10 希巴特殊化学控股公司 Fluorescent whitening agent
US6376446B1 (en) * 1999-01-13 2002-04-23 Melaleuca, Inc Liquid detergent composition
JP2009518493A (en) * 2005-12-07 2009-05-07 ザ プロクター アンド ギャンブル カンパニー Liquid laundry detergent with improved brightener stability
CN102051273A (en) * 2011-01-24 2011-05-11 北京洛娃日化有限公司 Carpet cleaner
CN103275829A (en) * 2013-06-17 2013-09-04 纳爱斯集团有限公司 Solvent-free super-concentrated liquid detergent and preparation method thereof
CN103773622A (en) * 2012-10-25 2014-05-07 阳紫威 Liquid detergent
CN103897914A (en) * 2012-12-26 2014-07-02 郭公甫 Laundry detergent
CN105567454A (en) * 2015-12-30 2016-05-11 广州市南大实业有限公司 Antibacterial liquid laundry detergent, preparation method and applications thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1176996A (en) * 1996-09-17 1998-03-25 王连祥 High-efficiency phosphorus-free and aluminum-free super-concentrated soft whitening laundry detergent
CN1210102A (en) * 1997-08-28 1999-03-10 希巴特殊化学控股公司 Fluorescent whitening agent
US6376446B1 (en) * 1999-01-13 2002-04-23 Melaleuca, Inc Liquid detergent composition
JP2009518493A (en) * 2005-12-07 2009-05-07 ザ プロクター アンド ギャンブル カンパニー Liquid laundry detergent with improved brightener stability
CN102051273A (en) * 2011-01-24 2011-05-11 北京洛娃日化有限公司 Carpet cleaner
CN103773622A (en) * 2012-10-25 2014-05-07 阳紫威 Liquid detergent
CN103897914A (en) * 2012-12-26 2014-07-02 郭公甫 Laundry detergent
CN103275829A (en) * 2013-06-17 2013-09-04 纳爱斯集团有限公司 Solvent-free super-concentrated liquid detergent and preparation method thereof
CN105567454A (en) * 2015-12-30 2016-05-11 广州市南大实业有限公司 Antibacterial liquid laundry detergent, preparation method and applications thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113549500A (en) * 2021-07-23 2021-10-26 河南省科学院化学研究所有限公司 Fatty alcohol-polyoxyethylene ether-based detergent and preparation method and application thereof

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Application publication date: 20170825