CN104987960A - Fabric fiber care type bio-enzyme laundry detergent and preparation method thereof - Google Patents

Fabric fiber care type bio-enzyme laundry detergent and preparation method thereof Download PDF

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Publication number
CN104987960A
CN104987960A CN201510407687.5A CN201510407687A CN104987960A CN 104987960 A CN104987960 A CN 104987960A CN 201510407687 A CN201510407687 A CN 201510407687A CN 104987960 A CN104987960 A CN 104987960A
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chemical structure
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sodium
alkyl
parts
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Chinese (zh)
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于文
贺春良
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XI'AN KAIMI CO Ltd
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XI'AN KAIMI CO Ltd
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Abstract

The invention relates to fabric fiber care type bio-enzyme laundry detergent and a preparation method thereof. After fabric is washed repeatedly by common laundry detergent on the current market, the appearances and the colors of fabric fibers go bad gradually, and the fabric is grayed and darkened. The fabric fiber care type bio-enzyme laundry detergent is prepared by compounding a nonionic surfactant, an anionic surfactant, cellulase, a high polymer care agent, a pH value modifier, water, a zwitterionic surfactant, a water-soluble solvent, a preservative and an essence. The cellulase and the high polymer care agent are added into the laundry detergent according to a specific proportion and cooperate with each other, so that the cleaning effect of the laundry detergent is improved, the fabric fiber care effect is improved, the cleaning care effect on whiteness maintenance, ash resistance, fading resistance and pilling resistance of the fabric fibers is obviously improved, and the bright colors of the fabric fibers are kept.

Description

Fabric fibre nursing type biological enzyme washing liquid and preparation method thereof
Technical field
the present invention relates to a kind of washing liquid and preparation method thereof, be specifically related to a kind of fabric fibre nursing type biological enzyme washing liquid and preparation method thereof.
Background technology
Washing liquid is a kind of easy to use, Yi Rong, sweet-scented fabric washing articles for use, is subject to liking of human consumer.
By the restriction of raw material and technology, there is certain functional defect in ordinary liquid laundry detergent in the market.Although can remove the common dirt on fabric, reach the effect of clean textile, ordinary liquid laundry detergent does not have fabric care effect: namely ordinary liquid laundry detergent laundering of textile fabrics repeatedly after, textile fiber appearance, color and luster are deteriorated gradually, and fabric becomes burnt hair and dimmed.
Although adopt the method for adding white dyes in washing liquid, can improve the whiteness of fabric fibre, make clothing seem whiter, its essence just a kind of optical effect, there is no nursing efficacy effectively to fabric, the dirt in fabric fibre can not be removed.
With ordinary liquid laundry detergent laundering of textile fabrics burnt hair and color and luster dimmed, its reason is: fabric fibre is cotton fibre mainly, through permanent dress with repeatedly after washing, can produce many primitive fibers (outstanding fiber, broken fiber).These primitive fibers increase, and can make light scatter, thus weaken the original color and luster of fiber; These primitive fibers have the trend of attract dirt particulate simultaneously, as carbon particulate, dirt particles etc.Dirt small-particle on fabric catch by the cotton primitive fiber on fabric, and there is certain package action.The dirt mixture formed, is difficult to remove with the washing of common washing liquid.The vivid degree of fabric color can be made after the long period to be deteriorated, reduce fabric whiteness, the outward appearance of clothing just seems burnt hair and dimmed.
Adopt the method for adding cellulase in washing liquid, when fabric washing, the primitive fiber removed in fabric cotton fibre can be decomposed.By micro-fiber structure depolymerization or be cracked into less, solubilized or dispersible composition, the dirt particles wherein wrapped up is discharged; Adopt simultaneously and add superpolymer nursing agent, the dirt particles that cellulase can be decomposed, small molecules thing, suspend, adsorb or wrap up, and is dispersed in washing water, makes it no longer adhere on fabric fibre.But be used alone cellulase in washing liquid, do not reach good nursing efficacy.
Summary of the invention
The object of this invention is to provide a kind of fabric fibre nursing type biological enzyme washing liquid and preparation method thereof, improve the whiteness maintenance to fabric fibre, and reach nursing efficacy.
The technical solution adopted in the present invention is:
Fabric fibre nursing type biological enzyme washing liquid, is characterized in that:
Prepared by the component of following mass parts:
Nonionogenic tenside 1.0 ~ 40.0 parts;
Anion surfactant 1.0 ~ 40.0 parts;
Cellulase 0.001 ~ 2.0 part;
Superpolymer nursing agent 0.001 ~ 5.0 part;
PH value regulator 0.01 ~ 5.0 part; ;
Water surplus;
Add up to 100 parts.
Also comprise the component of following mass parts:
Zwitterionics is not more than 40.0 parts;
Water-soluble solvent is not more than 20.0 parts;
Sanitas is not more than 1.0 parts;
Essence is not more than 0.5 part.
Described nonionogenic tenside is fatty alcohol-polyoxyethylene ether, alkyl-glucoside, lauric acid amide of ethanol, alkyl dimethyl amine oxide, dodecanamide propyl amine oxide or sorbitan mono-laurate Soxylat A 25-7 20;
Wherein, fatty alcohol-polyoxyethylene ether has following chemical structure:
C nh 2n+1o (CH 2cH 2o) 7-10h, wherein n=8-16;
Wherein, alkyl-glucoside has following chemical structure:
, wherein R=C 8-18alkyl, n=1-3;
Wherein, fatty diglycollic amide has following chemical structure:
RCON(CH 2CH 2OH) 2；
Wherein, alkyl dimethyl amine oxide has following chemical structure:
R-N (CH 3) 2o, R=C 12-18straight chained alkyl;
Wherein, dodecanamide propyl amine oxide has following chemical structure:
C 11H 23CO-NH(CH 2) 3-N(CH 3) 2O；
Wherein, sorbitan mono-laurate Soxylat A 25-7 20 has following chemical structure:
C 11H 25COOC 6H 11O 4(CH 2CH 2O) 20H。
Described anion surfactant is polyoxyethylenated alcohol sodium sulfate, Seconary Alkane Sulphonate Sodium, alkyl sulfuric ester sodium, α-sodium olefin sulfonate, methyl sodiosul foaliphatate, soap or Sodium dodecylbenzene sulfonate;
Wherein, polyoxyethylene alkyl ether sulfate sodium has following chemical structure:
C nh 2n+1-(CH 2cH 2o) 2-3sO 4na, wherein n=8-16;
Wherein, Seconary Alkane Sulphonate Sodium has following chemical structure:
R 1-CH (R 2) SO 3na, wherein R 1+ R 2=C 11-17alkyl;
Wherein, alkyl sulfuric ester sodium has following chemical structure:
C nh 2n+1oSO 3na, wherein n=8-16;
Wherein, α-sodium olefin sulfonate has following chemical structure:
RCH=CH (CH 2) SO 3na and RCHOH (CH 2) nsO 3na, wherein R=C 10-16straight chained alkyl;
Wherein, methyl sodiosul foaliphatate has following chemical structure:
RCH (SO 3na) COOCH 3, wherein R=C12-18 alkyl;
Wherein, soap has following chemical structure:
C nh 2n+1-COONa, wherein n=11-17;
Wherein, Sodium dodecylbenzene sulfonate has following chemical structure:
C 12h 25-C 6h 5-SO 3na, wherein R=C 12-18straight chained alkyl.
Described zwitterionics is empgen BB or AMONYL 380LC;
Wherein, empgen BB has following chemical structure:
C 12H 25-N +(CH 3) 2CH 2COO -；
Wherein, AMONYL 380LC has following chemical structure:
C 11H 23CO-NH(CH 2) 3-N +(CH 3) 2CH 2CH 2COO -。
Described cellulase is endo-glucanase cellulase or cellobiohydrolase.
Described superpolymer nursing agent is acrylate copolymer sodium salt, vinylformic acid/maleic acid sodium salt, maleic acid sodium salt or polyvinylpyrrolidone.
Described water-soluble solvent is ethanol, Virahol, 1,2-PD, butyl glycol ether, glycol propyl ether, propandiol butyl ether, diethylene glycol ether, butyl, dipropylene glycol propyl ether or dipropylene;
Described pH value regulator is sodium hydroxide, potassium hydroxide, trolamine, diethanolamine, monoethanolamine, sodium carbonate, sodium bicarbonate, citric acid or its soluble salt, regulates washing liquid pH value to be 7.0 ~ 10.0;
Described sanitas is isothiazolinone derivatives, BIT, phenylformic acid/sodium, Sorbic Acid/potassium sorbate, Triclosan or parachlormetaxylenol;
Wherein, isothiazolinone derivatives is the mixture of CMIT and MIT.
The preparation method of fabric fibre nursing type biological enzyme washing liquid, is characterized in that:
Comprise the following steps:
Step one: prepare raw material by following mass parts formula:
Nonionogenic tenside 1.0 ~ 40.0 parts;
Anion surfactant 1.0 ~ 40.0 parts;
Zwitterionics 0 ~ 40.0 part;
Cellulase 0.001 ~ 2.0 part;
Superpolymer nursing agent 0.001 ~ 5.0 part;
Water-soluble solvent 0 ~ 20.0 part;
PH value regulator 0.01 ~ 5.0 part;
Sanitas 0 ~ 1.0 part;
0 ~ 0.5 part, essence;
Water surplus;
Add up to 100 parts;
Step 2: nonionogenic tenside, anion surfactant are placed in mixing tank, selectivity adds zwitterionics and water-soluble solvent, is heated to 55 DEG C ~ 60 DEG C, is stirred to dissolving, is uniformly dispersed, and stops heating;
Step 3: add under agitation 55 DEG C ~ 60 DEG C water to dissolving completely, evenly;
Step 4: add cellulase under agitation, adds superpolymer nursing agent;
Step 5: add pH value regulator under agitation, controls and adjust ph is 7.0 ~ 10.0;
Step 6: under agitation, treat that liquid material temperature is down to less than 35 DEG C, selectivity adds sanitas and essence, is stirred to evenly;
Step 7: sampling Detection, finished product packing.
Described nonionogenic tenside is fatty alcohol-polyoxyethylene ether, alkyl-glucoside, lauric acid amide of ethanol, alkyl dimethyl amine oxide, dodecanamide propyl amine oxide or sorbitan mono-laurate Soxylat A 25-7 20;
Wherein, fatty alcohol-polyoxyethylene ether has following chemical structure:
C nh 2n+1o (CH 2cH 2o) 7-10h, wherein n=8-16;
Wherein, alkyl-glucoside has following chemical structure:
, wherein R=C 8-18alkyl, n=1-3;
Wherein, fatty diglycollic amide has following chemical structure:
RCON(CH 2CH 2OH) 2；
Wherein, alkyl dimethyl amine oxide has following chemical structure:
R-N (CH 3) 2o, R=C 12-18straight chained alkyl;
Wherein, dodecanamide propyl amine oxide has following chemical structure:
C 11H 23CO-NH(CH 2) 3-N(CH 3) 2O；
Wherein, sorbitan mono-laurate Soxylat A 25-7 20 has following chemical structure:
C 11H 25COOC 6H 11O 4(CH 2CH 2O) 20H；
Described anion surfactant is polyoxyethylenated alcohol sodium sulfate, Seconary Alkane Sulphonate Sodium, alkyl sulfuric ester sodium, α-sodium olefin sulfonate, methyl sodiosul foaliphatate, soap or Sodium dodecylbenzene sulfonate;
Wherein, polyoxyethylene alkyl ether sulfate sodium has following chemical structure:
C nh 2n+1-(CH 2cH 2o) 2-3sO 4na, wherein n=8-16;
Wherein, Seconary Alkane Sulphonate Sodium has following chemical structure:
R 1-CH (R 2) SO 3na, wherein R 1+ R 2=C 11-17alkyl;
Wherein, alkyl sulfuric ester sodium has following chemical structure:
C nh 2n+1oSO 3na, wherein n=8-16;
Wherein, α-sodium olefin sulfonate has following chemical structure:
RCH=CH (CH 2) SO 3na and RCHOH (CH 2) nsO 3na, wherein R=C 10-16straight chained alkyl;
Wherein, methyl sodiosul foaliphatate has following chemical structure:
RCH (SO 3na) COOCH 3, wherein R=C12-18 alkyl;
Wherein, soap has following chemical structure:
C nh 2n+1-COONa, wherein n=11-17;
Wherein, Sodium dodecylbenzene sulfonate has following chemical structure:
C 12h 25-C 6h 5-SO 3na, wherein R=C 12-18straight chained alkyl;
Zwitterionics is empgen BB or AMONYL 380LC;
Wherein, empgen BB has following chemical structure:
C 12H 25-N +(CH 3) 2CH 2COO -；
Wherein, AMONYL 380LC has following chemical structure:
C 11H 23CO-NH(CH 2) 3-N +(CH 3) 2CH 2CH 2COO -；
Described cellulase is endo-glucanase cellulase or cellobiohydrolase;
Described superpolymer nursing agent is acrylate copolymer sodium salt, vinylformic acid/maleic acid sodium salt, maleic acid sodium salt or polyvinylpyrrolidone;
Described water-soluble solvent is ethanol, Virahol, 1,2-PD, butyl glycol ether, glycol propyl ether, propandiol butyl ether, diethylene glycol ether, butyl, dipropylene glycol propyl ether or dipropylene;
Described pH value regulator is sodium hydroxide, potassium hydroxide, trolamine, diethanolamine, monoethanolamine, sodium carbonate, sodium bicarbonate, citric acid or its soluble salt, regulates washing liquid pH value to be 7.0 ~ 10.0;
Described sanitas is isothiazolinone derivatives, BIT, phenylformic acid/sodium, Sorbic Acid/potassium sorbate, Triclosan or parachlormetaxylenol;
Wherein, isothiazolinone derivatives is the mixture of CMIT and MIT.
The present invention has the following advantages:
1, a kind of fabric fibre nursing type biological enzyme washing liquid provided by the invention, adopt in washing liquid, add cellulase and superpolymer care component in specific proportions, both synergies, not only improve the soil-removing action of washing liquid, and provide the nursing role to fabric fibre.The present invention has the advantages that consumption is few, usefulness is high, significantly improves the clean decontamination of fabric, whiteness maintenance, anti-ash, anti-to fade, the fabric care effect of anti pilling.
2, a kind of fabric fibre nursing type biological enzyme washing liquid provided by the invention, carrying out detergency test by GB soiled cotton proves to promote detersive power; By proving to promote whiteness maintenance effect with white pure cotton cloth built-in testing.
3, a kind of fabric fibre nursing type biological enzyme washing liquid provided by the invention, have that detergency ability is good, biological degradability is good, environmental protection, simultaneously concentrated efficient, save and the effect of consumption of alternative exhibiting high surface promoting agent, there is excellent washing cleaning effect, energy-saving and emission-reduction, reduce the wasting of resources.
Accompanying drawing explanation
Fig. 1 is that washing liquid promotes detersive power effect comparison.
Fig. 2 is the whiteness effect comparison that washing liquid promotes white pure cotton cloth.
Embodiment
Below in conjunction with embodiment, the present invention will be described in detail.
The fabric fibre nursing type biological enzyme washing liquid that the present invention relates to, is prepared by the component of following mass parts:
Nonionogenic tenside 1.0 ~ 40.0 parts;
Anion surfactant 1.0 ~ 40.0 parts;
Cellulase 0.001 ~ 2.0 part;
Superpolymer nursing agent 0.001 ~ 5.0 part;
PH value regulator 0.01 ~ 5.0 part;
Water surplus;
Add up to 100 parts.
Also comprise the component of following mass parts:
Zwitterionics is not more than 40.0 parts;
Water-soluble solvent is not more than 20.0 parts;
Sanitas is not more than 1.0 parts;
Essence is not more than 0.5 part.
In formula:
Described nonionogenic tenside is fatty alcohol-polyoxyethylene ether, alkyl-glucoside, lauric acid amide of ethanol, alkyl dimethyl amine oxide, dodecanamide propyl amine oxide or sorbitan mono-laurate Soxylat A 25-7 20;
Wherein, fatty alcohol-polyoxyethylene ether has following chemical structure:
C nh 2n+1o (CH 2cH 2o) 7-10h, wherein n=8-16;
Wherein, alkyl-glucoside has following chemical structure:
, wherein R=C 8-18alkyl, n=1-3;
Wherein, fatty diglycollic amide has following chemical structure:
RCON(CH 2CH 2OH) 2；
Wherein, alkyl dimethyl amine oxide has following chemical structure:
R-N (CH 3) 2o, R=C 12-18straight chained alkyl;
Wherein, dodecanamide propyl amine oxide has following chemical structure:
C 11H 23CO-NH(CH 2) 3-N(CH 3) 2O；
Wherein, sorbitan mono-laurate Soxylat A 25-7 20 has following chemical structure:
C 11H 25COOC 6H 11O 4(CH 2CH 2O) 20H。
Described anion surfactant is polyoxyethylenated alcohol sodium sulfate, Seconary Alkane Sulphonate Sodium, alkyl sulfuric ester sodium, α-sodium olefin sulfonate, methyl sodiosul foaliphatate, soap or Sodium dodecylbenzene sulfonate;
Wherein, polyoxyethylene alkyl ether sulfate sodium has following chemical structure:
C nh 2n+1-(CH 2cH 2o) 2-3sO 4na, wherein n=8-16;
Wherein, Seconary Alkane Sulphonate Sodium has following chemical structure:
R 1-CH (R 2) SO 3na, wherein R 1+ R 2=C 11-17alkyl;
Wherein, alkyl sulfuric ester sodium has following chemical structure:
C nh 2n+1oSO 3na, wherein n=8-16;
Wherein, α-sodium olefin sulfonate has following chemical structure:
RCH=CH (CH 2) SO 3na and RCHOH (CH 2) nsO 3na, wherein R=C 10-16straight chained alkyl;
Wherein, methyl sodiosul foaliphatate has following chemical structure:
RCH (SO 3na) COOCH 3, wherein R=C12-18 alkyl;
Wherein, soap has following chemical structure:
C nh 2n+1-COONa, wherein n=11-17;
Wherein, Sodium dodecylbenzene sulfonate has following chemical structure:
C 12h 25-C 6h 5-SO 3na, wherein R=C 12-18straight chained alkyl.
Described zwitterionics is empgen BB or AMONYL 380LC;
Wherein, empgen BB has following chemical structure:
C 12H 25-N +(CH 3) 2CH 2COO -；
Wherein, AMONYL 380LC has following chemical structure:
C 11H 23CO-NH(CH 2) 3-N +(CH 3) 2CH 2CH 2COO -。
Described cellulase is endo-glucanase cellulase or cellobiohydrolase.
Described superpolymer nursing agent is acrylate copolymer sodium salt, vinylformic acid/maleic acid sodium salt, maleic acid sodium salt or polyvinylpyrrolidone.
Described water-soluble solvent is ethanol, Virahol, 1,2-PD, butyl glycol ether, glycol propyl ether, propandiol butyl ether, diethylene glycol ether, butyl, dipropylene glycol propyl ether or dipropylene;
Described pH value regulator is sodium hydroxide, potassium hydroxide, trolamine, diethanolamine, monoethanolamine, sodium carbonate, sodium bicarbonate, citric acid or its soluble salt, regulates washing liquid pH value to be 7.0 ~ 10.0;
Described sanitas is isothiazolinone derivatives, BIT, phenylformic acid/sodium, Sorbic Acid/potassium sorbate, Triclosan or parachlormetaxylenol;
Wherein, isothiazolinone derivatives is the mixture of CMIT and MIT.
The preparation method of above-mentioned fabrics fabric care type biological enzyme washing liquid, comprises the following steps:
Step one: prepare raw material by following mass parts formula:
Nonionogenic tenside 1.0 ~ 40.0 parts;
Anion surfactant 1.0 ~ 40.0 parts;
Zwitterionics 0 ~ 40.0 part;
Cellulase 0.001 ~ 2.0 part;
Superpolymer nursing agent 0.001 ~ 5.0 part;
Water-soluble solvent 0 ~ 20.0 part;
PH value regulator 0.01 ~ 5.0 part;
Sanitas 0 ~ 1.0 part;
0 ~ 0.5 part, essence;
Water surplus;
Add up to 100 parts.
Step 2: nonionogenic tenside, anion surfactant are placed in mixing tank, selectivity adds zwitterionics and water-soluble solvent, is heated to 55 DEG C ~ 60 DEG C, is stirred to dissolving, is uniformly dispersed, and stops heating;
Step 3: add under agitation 55 DEG C ~ 60 DEG C water to dissolving completely, evenly;
Step 4: add cellulase under agitation, adds superpolymer nursing agent;
Step 5: add pH value regulator under agitation, controls and adjust ph is 7.0 ~ 10.0;
Step 6: under agitation, treat that liquid material temperature is down to less than 35 DEG C, selectivity adds sanitas and essence, is stirred to evenly;
Step 7: sampling Detection, finished product packing.
The cellulase that the present invention adopts is inner cellulose enzyme or outer fiber element enzyme and respective hemicellulase.Superpolymer nursing agent is with acrylate copolymer, vinylformic acid/maleic acid sodium salt, maleic acid sodium salt, polyvinylpyrrolidone, one or more mixtures composition wherein.Both are according to 1:(1-20) ratio use, cleaning-nursing effect is better.
Embodiment 1:
Nonionogenic tenside 1.0 parts;
Anion surfactant 40.0 parts;
Cellulase 0.001 part;
Superpolymer nursing agent 0.02;
Water-soluble solvent 20.0 parts;
PH value regulator 0.01 part;
Water surplus;
Add up to 100 parts.
In formula, each compositional selecting is with above-mentioned.
The preparation method of above-mentioned fabrics fabric care type biological enzyme washing liquid, comprises the following steps:
Step one: prepare raw material by above-mentioned formula;
Step 2: nonionogenic tenside, anion surfactant and water-soluble solvent are placed in mixing tank, is heated to 55 DEG C, is stirred to dissolving, is uniformly dispersed, and stops heating;
Step 3: add under agitation 60 DEG C of water to dissolving completely, evenly;
Step 4: add cellulase under agitation, adds superpolymer nursing agent;
Step 5: add pH value regulator under agitation, controls and adjust ph is 7.0;
Step 6: under agitation, treats that liquid material temperature is down to less than 35 DEG C;
Step 7: sampling Detection, finished product packing.
Embodiment 2:
Nonionogenic tenside 10.0 parts;
Anion surfactant 30.0 parts;
Cellulase 0.5 part;
Superpolymer nursing agent 5.0 parts;
PH value regulator 0.2 part;
Water surplus;
Add up to 100 parts.
Also comprise the component of following mass parts:
Zwitterionics 20.0 parts;
Water-soluble solvent 15.0 parts;
In formula, each component is chosen with above-mentioned.
The preparation method of above-mentioned fabrics fabric care type biological enzyme washing liquid, comprises the following steps:
Step one: prepare raw material by above-mentioned formula;
Step 2: nonionogenic tenside, anion surfactant and water-soluble solvent are placed in mixing tank, add zwitterionics, is heated to 60 DEG C, is stirred to dissolving, is uniformly dispersed, and stops heating;
Step 3: add under agitation 55 DEG C of water to dissolving completely, evenly;
Step 4: add cellulase under agitation, adds superpolymer nursing agent;
Step 5: add pH value regulator under agitation, controls and adjust ph is 8.0;
Step 6: under agitation, treats that liquid material temperature is down to less than 35 DEG C, is stirred to evenly;
Step 7: sampling Detection, finished product packing.
Embodiment 3:
Nonionogenic tenside 20.0 parts;
Anion surfactant 20.0 parts;
Cellulase 1.0 parts;
Superpolymer nursing agent 5.0 parts;
PH value regulator 4.0 parts;
Water surplus;
Add up to 100 parts.
Also comprise the component of following mass parts:
Zwitterionics 40.0 parts;
Water-soluble solvent 10.0 parts.
In formula, each compositional selecting is with above-mentioned.
The preparation method of above-mentioned fabrics fabric care type biological enzyme washing liquid, comprises the following steps:
Step one: prepare raw material by above-mentioned formula;
Step 2: nonionogenic tenside, anion surfactant and water-soluble solvent are placed in mixing tank, add zwitterionics, be heated to 55 DEG C DEG C, is stirred to dissolving, is uniformly dispersed, and stops heating;
Step 3: add under agitation 60 DEG C of water to dissolving completely, evenly;
Step 4: add cellulase under agitation, adds superpolymer nursing agent;
Step 5: add pH value regulator under agitation, controls and adjust ph is 9.0;
Step 6: under agitation, treats that liquid material temperature is down to less than 35 DEG C, is stirred to evenly;
Step 7: sampling Detection, finished product packing.
Embodiment 4:
Nonionogenic tenside 30.0 parts;
Anion surfactant 10.0 parts;
Cellulase 1.5 parts;
Superpolymer nursing agent 2.0 parts;
PH value regulator 4.0 parts;
Water surplus;
Add up to 100 parts.
Also comprise the component of following mass parts:
Zwitterionics 20.0 parts;
Water-soluble solvent 5 parts;
Sanitas 1.0 parts;
In formula, each compositional selecting is with above-mentioned.
The preparation method of above-mentioned fabrics fabric care type biological enzyme washing liquid, comprises the following steps:
Step one: prepare raw material by above-mentioned formula;
Step 2: nonionogenic tenside, anion surfactant and water-soluble solvent are placed in mixing tank, add zwitterionics, is heated to 60 DEG C, is stirred to dissolving, is uniformly dispersed, and stops heating;
Step 3: add under agitation 55 DEG C of water to dissolving completely, evenly;
Step 4: add cellulase under agitation, adds superpolymer nursing agent;
Step 5: add pH value regulator under agitation, controls and adjust ph is 10.0;
Step 6: under agitation, treats that liquid material temperature is down to less than 35 DEG C, adds sanitas, is stirred to evenly;
Step 7: sampling Detection, finished product packing.
Embodiment 5:
Nonionogenic tenside 40.0 parts;
Anion surfactant 1.0 parts;
Cellulase 2.0 parts;
Superpolymer nursing agent 5.0 parts;
PH value regulator 5.0 parts;
Water surplus;
Add up to 100 parts.
Also comprise the component of following mass parts:
Zwitterionics 40.0 parts;
Sanitas 1.0 parts;
0.5 part, essence.
In formula, each compositional selecting is with above-mentioned.
The preparation method of above-mentioned fabrics fabric care type biological enzyme washing liquid, comprises the following steps:
Step one: prepare raw material by above-mentioned formula;
Step 2: nonionogenic tenside, anion surfactant are placed in mixing tank, add zwitterionics, is heated to 55 DEG C, is stirred to dissolving, is uniformly dispersed, and stops heating;
Step 3: add under agitation 60 DEG C of water to dissolving completely, evenly;
Step 4: add cellulase under agitation, adds superpolymer nursing agent;
Step 5: add pH value regulator under agitation, controls and adjust ph is 7.0;
Step 6: under agitation, treats that liquid material temperature is down to less than 35 DEG C, adds sanitas and essence, is stirred to evenly;
Step 7: sampling Detection, finished product packing.
A kind of fabric fibre nursing type biological enzyme washing liquid provided by the invention, adopt in washing liquid, add cellulase and superpolymer care component in specific proportions, both synergies, not only improve the soil-removing action of washing liquid, and the nursing role provided fabric fibre, concrete effect comparison is see Figure of description 1 and 2.
Content of the present invention is not limited to cited by embodiment, and the conversion of those of ordinary skill in the art by reading specification sheets of the present invention to any equivalence that technical solution of the present invention is taked, is claim of the present invention and contains.

Claims (10)

1. fabric fibre nursing type biological enzyme washing liquid, is characterized in that:
Prepared by the component of following mass parts:
Nonionogenic tenside 1.0 ~ 40.0 parts;
Anion surfactant 1.0 ~ 40.0 parts;
Cellulase 0.001 ~ 2.0 part;
Superpolymer nursing agent 0.001 ~ 5.0 part;
PH value regulator 0.01 ~ 5.0 part; ;
Water surplus;
Add up to 100 parts.
2. fabric fibre nursing type biological enzyme washing liquid according to claim 1, is characterized in that:
Also comprise the component of following mass parts:
Zwitterionics is not more than 40.0 parts;
Water-soluble solvent is not more than 20.0 parts;
Sanitas is not more than 1.0 parts;
Essence is not more than 0.5 part.
3. fabric fibre nursing type biological enzyme washing liquid according to claim 2, is characterized in that:
Described nonionogenic tenside is fatty alcohol-polyoxyethylene ether, alkyl-glucoside, lauric acid amide of ethanol, alkyl dimethyl amine oxide, dodecanamide propyl amine oxide or sorbitan mono-laurate Soxylat A 25-7 20;
Wherein, fatty alcohol-polyoxyethylene ether has following chemical structure:
C nh 2n+1o (CH 2cH 2o) 7-10h, wherein n=8-16;
Wherein, alkyl-glucoside has following chemical structure:
, wherein R=C 8-18alkyl, n=1-3;
Wherein, fatty diglycollic amide has following chemical structure:
RCON(CH 2CH 2OH) 2；
Wherein, alkyl dimethyl amine oxide has following chemical structure:
R-N (CH 3) 2o, R=C 12-18straight chained alkyl;
Wherein, dodecanamide propyl amine oxide has following chemical structure:
C 11H 23CO-NH(CH 2) 3-N(CH 3) 2O；
Wherein, sorbitan mono-laurate Soxylat A 25-7 20 has following chemical structure:
C 11H 25COOC 6H 11O 4(CH 2CH 2O) 20H。
4. fabric fibre nursing type biological enzyme washing liquid according to claim 3, is characterized in that:
Described anion surfactant is polyoxyethylenated alcohol sodium sulfate, Seconary Alkane Sulphonate Sodium, alkyl sulfuric ester sodium, α-sodium olefin sulfonate, methyl sodiosul foaliphatate, soap or Sodium dodecylbenzene sulfonate;
Wherein, polyoxyethylene alkyl ether sulfate sodium has following chemical structure:
C nh 2n+1-(CH 2cH 2o) 2-3sO 4na, wherein n=8-16;
Wherein, Seconary Alkane Sulphonate Sodium has following chemical structure:
R 1-CH (R 2) SO 3na, wherein R 1+ R 2=C 11-17alkyl;
Wherein, alkyl sulfuric ester sodium has following chemical structure:
C nh 2n+1oSO 3na, wherein n=8-16;
Wherein, α-sodium olefin sulfonate has following chemical structure:
RCH=CH (CH 2) SO 3na and RCHOH (CH 2) nsO 3na, wherein R=C 10-16straight chained alkyl;
Wherein, methyl sodiosul foaliphatate has following chemical structure:
RCH (SO 3na) COOCH 3, wherein R=C12-18 alkyl;
Wherein, soap has following chemical structure:
C nh 2n+1-COONa, wherein n=11-17;
Wherein, Sodium dodecylbenzene sulfonate has following chemical structure:
C 12h 25-C 6h 5-SO 3na, wherein R=C 12-18straight chained alkyl.
5. fabric fibre nursing type biological enzyme washing liquid according to claim 4, is characterized in that:
Described zwitterionics is empgen BB or AMONYL 380LC;
Wherein, empgen BB has following chemical structure:
C 12H 25-N +(CH 3) 2CH 2COO -；
Wherein, AMONYL 380LC has following chemical structure:
C 11H 23CO-NH(CH 2) 3-N +(CH 3) 2CH 2CH 2COO -。
6. fabric fibre nursing type biological enzyme washing liquid according to claim 5, is characterized in that:
Described cellulase is endo-glucanase cellulase or cellobiohydrolase.
7. fabric fibre nursing type biological enzyme washing liquid according to claim 6, is characterized in that:
Described superpolymer nursing agent is acrylate copolymer sodium salt, vinylformic acid/maleic acid sodium salt, maleic acid sodium salt or polyvinylpyrrolidone.
8. fabric fibre nursing type biological enzyme washing liquid according to claim 7, is characterized in that:
Described water-soluble solvent is ethanol, Virahol, 1,2-PD, butyl glycol ether, glycol propyl ether, propandiol butyl ether, diethylene glycol ether, butyl, dipropylene glycol propyl ether or dipropylene;
Described pH value regulator is sodium hydroxide, potassium hydroxide, trolamine, diethanolamine, monoethanolamine, sodium carbonate, sodium bicarbonate, citric acid or its soluble salt, regulates washing liquid pH value to be 7.0 ~ 10.0;
Described sanitas is isothiazolinone derivatives, BIT, phenylformic acid/sodium, Sorbic Acid/potassium sorbate, Triclosan or parachlormetaxylenol;
Wherein, isothiazolinone derivatives is the mixture of CMIT and MIT.
9. the preparation method of fabric fibre nursing type biological enzyme washing liquid, is characterized in that:
Comprise the following steps:
Step one: prepare raw material by following mass parts formula:
Nonionogenic tenside 1.0 ~ 40.0 parts;
Anion surfactant 1.0 ~ 40.0 parts;
Zwitterionics 0 ~ 40.0 part;
Cellulase 0.001 ~ 2.0 part;
Superpolymer nursing agent 0.001 ~ 5.0 part;
Water-soluble solvent 0 ~ 20.0 part;
PH value regulator 0.01 ~ 5.0 part;
Sanitas 0 ~ 1.0 part;
0 ~ 0.5 part, essence;
Water surplus;
Add up to 100 parts;
Step 2: nonionogenic tenside, anion surfactant are placed in mixing tank, selectivity adds zwitterionics and water-soluble solvent, is heated to 55 DEG C ~ 60 DEG C, is stirred to dissolving, is uniformly dispersed, and stops heating;
Step 3: add under agitation 55 DEG C ~ 60 DEG C water to dissolving completely, evenly;
Step 4: add cellulase under agitation, adds superpolymer nursing agent;
Step 5: add pH value regulator under agitation, controls and adjust ph is 7.0 ~ 10.0;
Step 6: under agitation, treat that liquid material temperature is down to less than 35 DEG C, selectivity adds sanitas and essence, is stirred to evenly;
Step 7: sampling Detection, finished product packing.
10. the preparation method of fabric fibre nursing type biological enzyme washing liquid according to claim 9, is characterized in that:
Described nonionogenic tenside is fatty alcohol-polyoxyethylene ether, alkyl-glucoside, lauric acid amide of ethanol, alkyl dimethyl amine oxide, dodecanamide propyl amine oxide or sorbitan mono-laurate Soxylat A 25-7 20;
Wherein, fatty alcohol-polyoxyethylene ether has following chemical structure:
C nh 2n+1o (CH 2cH 2o) 7-10h, wherein n=8-16;
Wherein, alkyl-glucoside has following chemical structure:
, wherein R=C 8-18alkyl, n=1-3;
Wherein, fatty diglycollic amide has following chemical structure:
RCON(CH 2CH 2OH) 2；
Wherein, alkyl dimethyl amine oxide has following chemical structure:
R-N (CH 3) 2o, R=C 12-18straight chained alkyl;
Wherein, dodecanamide propyl amine oxide has following chemical structure:
C 11H 23CO-NH(CH 2) 3-N(CH 3) 2O；
Wherein, sorbitan mono-laurate Soxylat A 25-7 20 has following chemical structure:
C 11H 25COOC 6H 11O 4(CH 2CH 2O) 20H；
Described anion surfactant is polyoxyethylenated alcohol sodium sulfate, Seconary Alkane Sulphonate Sodium, alkyl sulfuric ester sodium, α-sodium olefin sulfonate, methyl sodiosul foaliphatate, soap or Sodium dodecylbenzene sulfonate;
Wherein, polyoxyethylene alkyl ether sulfate sodium has following chemical structure:
C nh 2n+1-(CH 2cH 2o) 2-3sO 4na, wherein n=8-16;
Wherein, Seconary Alkane Sulphonate Sodium has following chemical structure:
R 1-CH (R 2) SO 3na, wherein R 1+ R 2=C 11-17alkyl;
Wherein, alkyl sulfuric ester sodium has following chemical structure:
C nh 2n+1oSO 3na, wherein n=8-16;
Wherein, α-sodium olefin sulfonate has following chemical structure:
RCH=CH (CH 2) SO 3na and RCHOH (CH 2) nsO 3na, wherein R=C 10-16straight chained alkyl;
Wherein, methyl sodiosul foaliphatate has following chemical structure:
RCH (SO 3na) COOCH 3, wherein R=C12-18 alkyl;
Wherein, soap has following chemical structure:
C nh 2n+1-COONa, wherein n=11-17;
Wherein, Sodium dodecylbenzene sulfonate has following chemical structure:
C 12h 25-C 6h 5-SO 3na, wherein R=C 12-18straight chained alkyl;
Zwitterionics is empgen BB or AMONYL 380LC;
Wherein, empgen BB has following chemical structure:
C 12H 25-N +(CH 3) 2CH 2COO -；
Wherein, AMONYL 380LC has following chemical structure:
C 11H 23CO-NH(CH 2) 3-N +(CH 3) 2CH 2CH 2COO -；
Described cellulase is endo-glucanase cellulase or cellobiohydrolase;
Described superpolymer nursing agent is acrylate copolymer sodium salt, vinylformic acid/maleic acid sodium salt, maleic acid sodium salt or polyvinylpyrrolidone;
Described water-soluble solvent is ethanol, Virahol, 1,2-PD, butyl glycol ether, glycol propyl ether, propandiol butyl ether, diethylene glycol ether, butyl, dipropylene glycol propyl ether or dipropylene;
Described pH value regulator is sodium hydroxide, potassium hydroxide, trolamine, diethanolamine, monoethanolamine, sodium carbonate, sodium bicarbonate, citric acid or its soluble salt, regulates washing liquid pH value to be 7.0 ~ 10.0;
Described sanitas is isothiazolinone derivatives, BIT, phenylformic acid/sodium, Sorbic Acid/potassium sorbate, Triclosan or parachlormetaxylenol;
Wherein, isothiazolinone derivatives is the mixture of CMIT and MIT.
CN201510407687.5A 2015-07-13 2015-07-13 Fabric fiber care type bio-enzyme laundry detergent and preparation method thereof Pending CN104987960A (en)

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