CN103242973A - Three-effect liquid laundry detergent composition and preparation method thereof - Google Patents
Three-effect liquid laundry detergent composition and preparation method thereof Download PDFInfo
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- CN103242973A CN103242973A CN2013101864783A CN201310186478A CN103242973A CN 103242973 A CN103242973 A CN 103242973A CN 2013101864783 A CN2013101864783 A CN 2013101864783A CN 201310186478 A CN201310186478 A CN 201310186478A CN 103242973 A CN103242973 A CN 103242973A
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Abstract
The invention relates to the field of detergents and particularly relates to a three-effect liquid laundry detergent composition and a preparation method thereof. The three-effect liquid laundry detergent composition has the three effects of washing, softness and puffiness and comprises the following components: 0.02-15% of cationic softener, 0.01-10% of modified silicon oil, 2-50% of nonionic surfactant, 0.02-6% of enzymic preparation and 0.01-12% of enzymic preparation stabilizer. The preparation method comprises the following steps of: adding the nonionic surfactant into the heated deionized water, adding the enzymic preparation stabilizer, stirring while adding, and heating the mixture to 55-65 DEG C; adding the pre-molten cationic softener, stirring until the pre-molten cationic softener is completely dispersed and the system is uniform, and cooling to 45-55 DEG C; adding the modified silicon oil, stirring and uniformly dispersing, and cooling to 30-40 DEG C; adding the enzymic preparation, stirring to dissolve the enzymic preparation until the system is uniform; and complementing the deionized water, and uniformly stirring the mixture.
Description
Technical field
The present invention relates to detergent applications, particularly a kind of triple effect unification washing liquid composition and preparation method.
Background technology
In the clothes washing field, people are little by little from using washing powder to develop into the use washing liquid.Because washing liquid has milder ground washing, to advantages such as skin irritation are little, enjoy user's trust.
The problem that exists: common washing liquid mainly has washing and dirt-removing functions, fabric there is not soft effect, but at the higher northern area of the water hardness, use after common washing liquid repeatedly washs clothing, the reaction of some compositions and hard water can generate the throw out-calcium soap of indissoluble in the washing liquid, can be deposited on the clothing, thereby make the clothing through repeatedly washing harden.Thereby, can re-use softener at rinse stage during the common washing clothes of people and remedy, could make fabric soft fluffy more.So not only increase the expense of human consumer's washing clothes, also make and wash that to protect the housework of separately doing washing loaded down with trivial details more time-consuming.
Summary of the invention
The object of the present invention is to provide a kind of triple effect unification washing liquid composition, can keep fabric sofetening fluffy.
Another object of the present invention is to provide above-mentioned triple effect unification washing liquid preparation of compositions method.
Purpose of the present invention is achieved through the following technical solutions:
Triple effect unification washing liquid composition in mass fraction, comprises following composition:
Cationic softener 0.02%～15%;
Modified silicon oil 0.01%～10%;
Nonionogenic tenside 2%～50%;
Zymin 0.02%～6%;
Zymin stablizer 0.01%～12%;
Surplus is deionized water.
Triple effect unification washing liquid preparation of compositions method specifically may further comprise the steps:
In the deionized water of heating, add described nonionogenic tenside, add the zymin stablizer, stir while adding, and be heated to 55 ℃～65 ℃;
The described cationic softener that adds fritting is stirred to and disperses complete system even, is cooled to 45 ℃～55 ℃;
Add described modified silicon oil, dispersed with stirring is even, is cooled to 30～40 ℃;
Add described zymin, stirring and dissolving is even to system;
Supply deionized water, stir.
In the triple effect unification washing liquid composition provided by the invention, cationic softener wherein is the quaternary ammonium salt product, and its dispersion thing in water is adsorbed on electronegative fabric face and plays softness and antistatic effect.The molecular backbone chain of modified silicon oil is that the Si-O key with excellent flexibility is formed, and has introduced the amino of different structure on the side chain according to different amino silicane coupling agents, and amino has chemical propertys such as stronger polarity, adsorptivity.
Modified silicon oil and cationic softener are composite, make the performance of the two can well work in coordination with enhancing, thereby effectively improve wetting ability, water absorbability, smooth feeling and the soft fluffy of fabric fibre.
Described nonionogenic tenside biological degradation is thorough rapidly, has good synergistic function with the tensio-active agent of other type.
Described zymin selectivity is strong, action temperature and, remove various household stains, the filoplume of removing fabric face improves flexibility, also make fabric face brighter and cleaner, be difficult for advantage such as balling-up when evenly reaching wearing process and washing.So triple effect unification washing liquid composition provided by the invention and preparation method can make fabric still keep soft fluffy behind repetitive scrubbing.
Description of drawings
Fig. 1 is the schematic flow sheet that the invention provides the washing liquid preparation method of embodiment 1;
Fig. 2 is the schematic flow sheet that the invention provides the washing liquid preparation method of embodiment 2;
Fig. 3 is the schematic flow sheet that the invention provides the washing liquid preparation method of embodiment 3;
Fig. 4 is the schematic flow sheet that the invention provides the washing liquid preparation method of embodiment 4.
Embodiment
Below will carry out clear, complete description to the technical scheme of various embodiments of the present invention, obviously, described embodiment only is a part of embodiment of the present invention, rather than whole embodiment.Based on the embodiment among the present invention, those of ordinary skills are resulting all other embodiment under the prerequisite of not making creative work, all belong to the scope that the present invention protects.
Embodiment 1
Triple effect unification washing liquid composition in mass fraction, comprises following composition:
Cationic softener 0.02%～15%;
Modified silicon oil 0.01%～10%;
Nonionogenic tenside 2%～50%;
Zymin
0.02%～6%;
Zymin stablizer 0.01%～12%;
Surplus is deionized water.
As shown in Figure 1: the triple effect unification washing liquid preparation of compositions method that present embodiment provides specifically may further comprise the steps:
101. in the deionized water of heating, add described nonionogenic tenside, add the zymin stablizer, stir while adding, and be heated to 55 ℃～65 ℃;
102. add the described cationic softener of fritting, be stirred to and disperse complete system even, be cooled to 45 ℃～55 ℃;
103. add described modified silicon oil, dispersed with stirring is even, is cooled to 30 ℃～40 ℃;
104. add described zymin, stirring and dissolving is even to system;
105. supply deionized water, stir.
Triple effect provided by the invention is imitated in the unification washing liquid, and cationic softener wherein is the quaternary ammonium salt product, and its dispersion thing in water is adsorbed on electronegative fabric face and plays softness and antistatic effect.The molecular backbone chain of modified silicon oil is that the Si-O key with excellent flexibility is formed, and has introduced the amino of different structure on the side chain according to different amino silicane coupling agents, and amino has chemical propertys such as stronger polarity, adsorptivity.
Modified silicon oil and cationic softener are composite, make the performance of the two can well work in coordination with enhancing, thereby effectively improve wetting ability, water absorbability, smooth feeling and the soft fluffy of fabric fibre.
Described nonionogenic tenside biological degradation is thorough rapidly, has good synergistic function with the tensio-active agent of other type.
Described zymin selectivity is strong, action temperature and, remove various household stains, the filoplume of removing fabric face improves flexibility, also make fabric face brighter and cleaner, be difficult for advantage such as balling-up when evenly reaching wearing process and washing.So triple effect unification washing liquid composition provided by the invention and preparation method can make fabric still keep soft fluffy behind repetitive scrubbing.
Embodiment 2:
Triple effect unification washing liquid composition in mass fraction, comprises following composition:
Cationic softener 0.8%;
Modified silicon oil 0.1%;
Cardanol polyoxyethylene ether surface active agent 9.0%;
Fatty alcohol-polyoxyethylene ether tensio-active agent 8.0%;
Alkyl glucoside surfactant 5.0%;
Borax 3.0%
Proteinase-10 .4%;
Cellulase 0.2%;
Surplus is deionized water.
As shown in Figure 2: the triple effect unification washing liquid preparation of compositions method that present embodiment provides specifically may further comprise the steps:
201. in the deionized water of heating, add cardanol polyoxyethylene ether surface active agent, fatty alcohol-polyoxyethylene ether tensio-active agent and alkyl glucoside surfactant, add borax, stir while adding, and be heated to 55 ℃～65 ℃;
202. add the described cationic softener of fritting, be stirred to and disperse complete system even, be cooled to 45 ℃～55 ℃;
203. add described modified silicon oil, dispersed with stirring is even, is cooled to 30 ℃～40 ℃;
204. add described proteolytic enzyme, cellulase, stirring and dissolving is even to system;
205. supply deionized water, stir.
Described cationic softener is the quaternary ammonium salt product, its dispersion thing in water is adsorbed on electronegative fabric face and plays softness and antistatic effect, be divided into four types of alkyl methyl ammonium chlorides, imidazoline quaternary ammonium salt, acid amides quaternary ammonium salt, ester based quaternary ammonium salt according to different fat-based, the present invention selects for use in imidazoline quaternary ammonium salt, acid amides quaternary ammonium salt, the ester based quaternary ammonium salt one or more composite, is preferably ester based quaternary ammonium salt or acid amides quaternary ammonium salt.
The two ethyl palmitate base hydroxyethyl methylsulfuric acid ammoniums of STEPANTEX SP-90() structural formula as the formula (1),
SP-90 is that to derive from plant reproducible, is easy to biodegradable cationic softener, and fabric is had excellent flexibility and splendid advantages such as rewetting, namely is repeatedly that repetitive scrubbing can not cause the xanthochromia of fabric yet or turn grey phenomenon.
Described modified silicon oil is modified dimethyl polysiloxane, is preferably amino modified polydimethylsiloxane.
SLM FC202(or DC2-8035) fabric of organosilicon nursing agent emulsion, be a kind of crosslinkable amino modified polydimethylsiloxane, be about to amido functional group and introduce siloxane backbone.Because amino polarity, make silicone oil can with interactions such as the hydroxyl of fiber surface, carbonyl, make the siloxane main chain oriented adsorption in fiber surface.Bond angle between silicon-oxygen-silicon bound big and in the shape of a spiral shape arrange, make that reactive force weakens between molecular linkage, thereby reduced the frictional coefficient between the fiber, reach good softness, crease-resistant, easily scald effect.Also because amido functional group has certain wetting ability, help to improve the hydrophilicity of fabric.
The molecular backbone chain of modified silicon oil is that the Si-O key with excellent flexibility is formed, and has introduced the amino of different structure on the side chain according to different amino silicane coupling agents, and amino has chemical propertys such as stronger polarity, adsorptivity.
Described nonionogenic tenside is one or more in cardanol Soxylat A 25-7, fatty alcohol-polyoxyethylene ether tensio-active agent or the alkyl glucoside surfactant
Described cardanol Soxylat A 25-7 is to be raw material with reproducible natural cashew nut shell oil, the of new generation gentle safety that the cardanol that forms through the modern technique refining refinement is produced, green natural, environmentally friendly nonionogenic tenside, biological degradation is thorough rapidly, itself and anion surfactant be composite good synergistic effects, has surfactant properties such as good low bubble, wetting power, perviousness, emulsification dispersion and decontamination.
The chemical structure of cardanol Soxylat A 25-7 is represented that by following general formula phenyl ring one end is the unsaturated straight chain that contains 15 C, is polyoxyethylene chain on the position, wherein n=12-14.
Described fatty alcohol-polyoxyethylene ether (being called for short AEO) tensio-active agent is the condenses of Fatty Alcohol(C12-C14 and C12-C18) and oxyethane, and wherein the mol ratio of Fatty Alcohol(C12-C14 and C12-C18) and oxyethane is 1:(3～15), be preferably 1:(3～10); The alkyl chain of Fatty Alcohol(C12-C14 and C12-C18) is the straight or branched alkyl that contains 8～20 carbon atoms, is preferably the composite of the branched-chain alkyl that contains 8～20 carbon atoms.
Described alkyl glycoside (APG for short) tensio-active agent is the condensation product of carbohydrate and high fatty alcohol, its structure as the formula (2),
Wherein, R is the Fatty Alcohol(C12-C14 and C12-C18) alkyl carbon chain of carbonatoms 8-14, is preferably 12～14 Fatty Alcohol(C12-C14 and C12-C18) alkyl carbon chain, and n represents the mean number of glycoside units on every alkyl carbon chain, and namely mean polymerisation degree (DP value) is used for the better with 1.3～1.8 of washing composition.
The raw material that condensation reaction is used is plant renewable resources starch and grease and derivative glucose and natural fatty alcohol.Described alkyl glycoside be a new generation adopt renewable natural matter production, performance gentleness, can quick and complete biodegradable " environmental protection " type nonionogenic tenside, have the characteristic of common nonionic and anion surfactant concurrently, has good detersive power, no cloud point, gel-free phenomenon, can with any kind tensio-active agent synergy, and can reduce the pungency of other tensio-active agent, and has the performance of thickening property and stabilising system preferably.Especially be fit to be applied to liquid washing agent.
Described zymin is one or more mixtures in proteolytic enzyme, cellulase, hemicellulase, peroxidase, M-Zyme, amylase, glucoamylase, lipase, oxydase or the Starch debranching enzyme, is preferably one or more mixtures in proteolytic enzyme, cellulase, lipase or the amylase.
The proteolytic enzyme selectivity is strong, action temperature and, can effectively remove and contain the protein spot in the life, improve the detersive power of GB albumen soiled cotton.
Cellulase is that a class can be the general name of the polycomponent enzyme system of glucose with cellulose degradation, and their synergy decomposition of cellulose produce oligosaccharides and cellobiose, finally are hydrolyzed to glucose.
In textile industry, utilize cellulase to carry out decrement treatment and biopolishing etc. to fabric and optimize processing, improve softness, elasticity and the drape of fabric.Decrement treatment can be divided into chemical decrement and physics decrement, and chemical decrement mechanism is that cellulase catalytic hydrolysis Mierocrystalline cellulose becomes glucose and makes fabric reach decrement, and the physics decrement is the decrement that non-chemical catalysis hydrolysis (surface fiber is peeled off) causes.Reduction rate control just can make fabric that soft hand feeling is arranged 3%～5%, makes the brute force of fabric keep constant substantially again.Biopolishing dominant mechanism is to utilize cellulase to remove the slight fiber that fabric face stretches out, and removes the filoplume of fabric face, makes surface smoothing gloss bright-coloured, also can improve whiteness and the flexibility of fabric, improves fabric feeling.Thereby make fabric face brighter and cleaner, evenly reach wearing process and washing the time all is difficult for balling-up, protect look, protect advantages such as the new time is long.
Embodiment 3:
Triple effect unification washing liquid composition in mass fraction, comprises following composition:
Cationic softener 0.6%;
Modified silicon oil 0.3%;
Cardanol polyoxyethylene ether surface active agent 9.0%;
Fatty alcohol-polyoxyethylene ether tensio-active agent 8.0%;
Alkyl glucoside surfactant 5.0%;
Proteinase-10 .4%;
Cellulase 0.2%;
Borax 2.0%;
Sodium Citrate, usp, Dihydrate Powder 1.0%;
Polyacrylic acid (OP301) 0.3%;
Pigment is an amount of;
Sanitas (KF88) 0.1%;
Essence 0.2%;
Surplus is deionized water.
As shown in Figure 3: the triple effect unification washing liquid preparation of compositions method that present embodiment provides specifically may further comprise the steps:
301. in the deionized water of heating, add cardanol polyoxyethylene ether surface active agent, fatty alcohol-polyoxyethylene ether tensio-active agent and alkyl glucoside surfactant, add borax, Sodium Citrate, usp, Dihydrate Powder, stir while adding, and be heated to 55 ℃～65 ℃;
302. add the described cationic softener of fritting, be stirred to and disperse complete system even, be cooled to 45 ℃～55 ℃;
303. add described modified silicon oil, dispersed with stirring is even, is cooled to 30～40 ℃;
304. add described proteolytic enzyme, cellulase, stirring and dissolving is even to system;
305. add the polyacrylic acid (OP301) with deionized water (1:1) dilution, after stirring and dissolving is even to system, add pigment, sanitas (KF88) and essence successively, it is even to be stirred to system;
306. supply deionized water, stir.
In the present embodiment, described zymin stablizer is one or more mixtures in borax, propylene glycol, glycerine, Sodium Citrate, usp, Dihydrate Powder or the calcium chloride, is preferably one or more mixtures in borax, propylene glycol or the Sodium Citrate, usp, Dihydrate Powder.Described opalizer is polyacrylic acid (OP301).Account for 0～5% of composition total weight, preferred 0.1～3%.Sanitas, essence and pigment can add according to individual sexual demand.
Embodiment 4:
Triple effect unification washing liquid composition in mass fraction, comprises following composition:
Cationic softener 0.7%;
Modified silicon oil 0.2%;
Cardanol polyoxyethylene ether surface active agent 11.0%;
Fatty alcohol-polyoxyethylene ether tensio-active agent 7.0%;
Cocounut oil CAB tensio-active agent 6.0%;
Proteinase-10 .3%;
Cellulase 0.3%;
Borax 1.0%;
Propylene glycol 2.0%
Polyacrylic acid (OP301) 0.5%;
Pigment is an amount of;
Sanitas (KF88) 0.1%;
Essence 0.2%;
Surplus is deionized water.
As shown in Figure 4, the triple effect unification washing liquid preparation of compositions method that present embodiment provides specifically may further comprise the steps:
401. in the deionized water of heating, add cardanol polyoxyethylene ether surface active agent, fatty alcohol-polyoxyethylene ether tensio-active agent and cocounut oil CAB tensio-active agent, add borax, propylene glycol, stir while adding, be heated to 55 ℃～65 ℃;
402. add the described cationic softener of fritting, be stirred to and disperse complete system even, be cooled to 45 ℃～55 ℃;
403. add described modified silicon oil, dispersed with stirring is even, is cooled to 30 ℃～40 ℃;
404. add described proteolytic enzyme, cellulase, stirring and dissolving is even to system;
405. add the polyacrylic acid (OP301) with deionized water (1:1) dilution, after stirring and dissolving is even to system, add pigment, sanitas (KF88) and essence successively, it is even to be stirred to system;
406. supply deionized water, stir.
Described amphoterics is one or more mixtures in trimethyl-glycine or the tetrahydroglyoxaline, is preferably trimethyl-glycine, more preferably cocounut oil CAB (CAB-30).Account for 0～15% of composition total weight, preferred 0～10%.
The cocounut oil CAB is from the production of reproducible natural matter Oleum Cocois, readily biodegradable, mild amphoterics with better flexibility, auxiliary stabilized enzyme formulations function can reduce the pungency of other tensio-active agent with other surfactant compounds.
So, add the cocounut oil CAB in the amphoterics in the present embodiment, can make the washing liquid that makes have flexibility better.
The soft fluffy evaluation test method of triple effect unification washing liquid composition of the present invention is as follows:
1 test sample
Triple effect unification washing liquid composition example 3 of the present invention, example 4, market contrast common washing liquid and standard washing liquid, and wherein the prescription of standard washing liquid, raw material specification and preparation require with reference to table one.
Table one standard washing liquid prescription and raw material specification
The compound method of above-mentioned standard washing liquid: various compositions are added in a certain amount of deionized water successively, stirring and dissolving (heating in case of necessity), regulating pH with sodium hydroxide is 8.5～9.0, supplies amount of deionized water and gets final product.
2 reagent and instrument
2.1 standard hard water: press GB/T13174-2008 method preparation 250ppm hard water.
2.2 towel: newly buy with producer with batch (specification is the white cotton textiles of 35cm * 70cm) the thick towels that become mildewed.
2.3 washing machine: two Taiwan Straits that godling spiral shell XPB56-21SK(or two other identical brand washing machines)
2.4 electronic balance: precision 0.01g, maximum range 3000g
2.5 ruler: precision 0.1cm, maximum range 30cm
2.6 clothes hanger, washbowl (the about 22cm of base diameter, about deeply 10cm)
3 tests are prepared
3.1 towel pre-treatment
Towel in 2.2 is placed in the washing machine of regulation and dries after still with the tap water washing, select identical standby.
3.2 recover the measurement of thickness
Every towel is divided, stack after the smooth doubling is (for reducing testing error one by one, by same people's operation, and keep whole process gimmick, firmly parallel), put one flat plate at the towel of stack then, require the dull and stereotyped towel that just all covers doubling, weight (dull and stereotyped and weight weighs 1.5kg altogether) is placed in dull and stereotyped center, the maintenance level pressed down 3 minutes, upwards remove weight and flat board, towel left standstill 2 minutes, used ruler (2.5) to measure the thickness of towel (keeping a decimal) again, was recovery thickness.
3.3 soft fluffy assessment of performance
3.3.1 fluffy assessment of performance: under prescribed condition, wash towel with washing machine, dry naturally, measure and recover thickness.It is more big more fluffy to recover thickness.Recovery thickness difference before and after the carrying out washing treatment is more big, and the towel after washing composition is washed is more fluffy.
3.3.2 softness evaluation: by the mode that several testers touch with feel, wash the towel that dries naturally the back to two groups simultaneously and carry out Blind Test, the flexibility of comparative evaluation's towel.
4 testing sequences
4.1 fluffy performance test
Wash preceding towel recovery thickness (X1) 4.1.1 measure
Choose 24 pretreated towels (3.1), per 12 one group, carry out number record, measure two groups of towels then respectively and wash preceding recovery thickness (3.2).
4.1.2 washing test
In a washing machine (2.3), put into one group of towel (4.1.1), the setting water yield is 30L, add 30g washing liquid of the present invention, soak 15min after, program for washing in accordance with regulations (washing time 15min, rinsing time 2 each 3min, each 15min dewaters) washs.Simultaneously, in the washing machine of another same size model, put into another group towel (4.1.1), wash under the same conditions with the reference washing liquid and to contrast.After washing finishes, take out towel, the hand-power whipping towel with suitable as far as possible intensity fully launches every towel, and flat hanging on the clothes hanger dried it naturally, notes not stretching towel.
Wash back towel recovery thickness (X2) 4.1.3 measure
According to (3.2) method, measure two groups of recovery thickness of washing back towel (4.1.2) respectively.
4.2 softness test
4.2.1 take by weighing 10g washing liquid of the present invention in the 150ml beaker, wash to washbowl (2.6) with 2kg hard water (2.1), and be stirred to abundant dissolving, put into a pretreated towel (3.1), soak and wash 30 times by rubbing with the hands after soaked again 2 minutes, (control wet towel weight is about 3 times of dry towel weight) wrung out in taking-up, uses 2kg hard water (2.1) rinsing once (immerse wash 30 times in the basin by rubbing with the hands with towel) again, takes out to wring out back (by the method for 4.1.2) and dry.Test before towel after drying repeats repeats 3 times altogether.Similarity condition is done controlled trial with an other pretreated towel (3.1) with the reference washing liquid.
4.2.2 softness evaluation
According to the 3.3.2 method, two towels that dry among the 4.2.1 are carried out the softness evaluation.
5 results judge
5.1 fluffy test-results is judged
According to the fluffy effect of the difference judgement towel that washs front and back towel recovery thickness, it is more big to recover thickness difference, and towel is more fluffy.The results are shown in Table two.
Table two: fluffy performance test evaluation result
From table two data as seen, towel with triple effect unification washing liquid cleaning compositions of the present invention, recover thickness difference before and after the washing than about one times of the towel of using the common washing liquid washing in standard washing liquid and market, show that triple effect unification washing liquid composition of the present invention has good fluffy performance to fabric.
5.2 soft test-results is judged
Touch contrast judge flexibility by many people to washing the back towel, add up whole people's evaluating data.The results are shown in Table three.
Table three: softness test evaluation result
According to contrast test, through 120 bit test personnel Blind Test samples (touching relatively with hand), it is more soft with the towel of the common washing liquid washing of standard washing liquid and market with the towel ratio of triple effect unification washing liquid cleaning compositions of the present invention that most testers think.
6. detergency test
The detergency test method is with reference to the QB/T1224 standard.Detergency test the results are shown in Table shown in four.
Table four: detergency test result
As can be seen from Table IV, the triple effect of preparation unification washing liquid composition among the embodiment of the invention 3 and the embodiment 4, its soil removability also is higher than the common washing liquid in market far above the standard washing liquid, and is especially fine to the clean effect of albumen soiled cotton.
Triple effect of the present invention unification washing liquid composition has the advantage of washing soft fluffy, and is easy to use, cost is low, environmental protection.Be main tensio-active agent with nonionogenic tenside in the triple effect of the present invention unification washing liquid composition, and composite amphoterics, guarantee that composition has good detersive power and moderate spumescence; Preferred cationic softening agent and modified silicon oil are composite, and add the plurality of enzymes preparation, guarantee that composition has excellent soft fluffy, make fabric wash back flatiron easily, and feel is smooth to be difficult for balling-up, and it is long to protect the Se Baoxin time.
Triple effect of the present invention unification washing liquid composition efficiently solves common washing liquid not to be possessed soft fluffy to fabric and repeatedly makes the harden defective of roughen of fabric behind the repetitive scrubbing; Have the following advantages:
(1) triple effect unification washing liquid composition of the present invention has the advantage of washing soft fluffy triple effect unification.Not only has good washing detersive power; Also have excellent soft fluffy, make fabric wash back flatiron easily, feel is smooth to be difficult for balling-up, and it is long to protect the Se Baoxin time.The human consumer is washed and nurse clothing and once finish, not only cut down expenses, also alleviate housework.
(2) triple effect unification washing liquid composition of the present invention has green environmental protection.Adopt green reproducible raw material production, add intelligent activeconstituents biological enzyme formulation, but fast degraded biologically not only, with environmental friendliness; And gentle safety, not skin irritation.
(3) triple effect unification washing liquid composition of the present invention has good anti-hard water.Also can bring into play good decontamination washing effect in the high hardness water area, wash that to protect clothing time saving and energy saving.
(4) triple effect unification washing liquid composition production technology of the present invention is simple, and product cost is low, the cost performance height.
Various embodiment provided by the invention can be as required combination mutually in any way, the technical scheme that obtains by this combination is also in protection scope of the present invention.
Obviously, those skilled in the art can carry out various changes and modification to the present invention and not break away from the spirit and scope of the present invention.Like this, if of the present invention these are revised and modification belongs within the scope of claim of the present invention and equivalent technologies thereof, then the present invention also comprises these changes and modification interior.
Claims (9)
1. triple effect unification washing liquid composition is characterized in that, by percentage to the quality, comprises following composition:
Cationic softener 0.02%～15%;
Modified silicon oil 0.01%～10%;
Nonionogenic tenside 2%～50%;
Zymin 0.02%～6%;
Zymin stablizer 0.01%～12%;
Surplus is deionized water.
2. triple effect unification washing liquid composition according to claim 1 is characterized in that,
Described cationic softener is any one or more the mixture in imidazoline quaternary ammonium salt, acid amides quaternary ammonium salt, the ester based quaternary ammonium salt;
Described modified silicon oil is modified dimethyl polysiloxane.
3. triple effect unification washing liquid composition according to claim 1 is characterized in that,
Described nonionogenic tenside is: the mixture of any one or more in cardanol Soxylat A 25-7, fatty alcohol-polyoxyethylene ether tensio-active agent or the alkyl glucoside surfactant.
4. triple effect unification washing liquid composition according to claim 1 is characterized in that,
Described zymin is: one or more mixtures in proteolytic enzyme, cellulase, hemicellulase, peroxidase, M-Zyme, amylase, glucoamylase, lipase, oxydase or the Starch debranching enzyme.
5. triple effect unification washing liquid composition according to claim 1 is characterized in that,
Described zymin stablizer is: one or more mixtures in borax, propylene glycol, glycerine, Trisodium Citrate or the calcium chloride.
6. triple effect unification washing liquid composition according to claim 1 is characterized in that,
Comprise that also mass fraction is 0～15% amphoterics;
Described amphoterics is trimethyl-glycine or tetrahydroglyoxaline, perhaps the mixture of the two.
7. triple effect unification washing liquid composition according to claim 1 is characterized in that,
Comprise that also mass fraction is 0～5% opalizer;
Also comprise in sanitas, essence or the pigment etc. one or more.
8. according to each described triple effect unification washing liquid preparation of compositions method of claim 1-7, it is characterized in that, specifically may further comprise the steps:
In the deionized water of heating, add described nonionogenic tenside, add the zymin stablizer, stir while adding, and be heated to 55 ℃～65 ℃;
The described cationic softener that adds fritting is stirred to and disperses complete system even, is cooled to 45 ℃～55 ℃;
Add described modified silicon oil, dispersed with stirring is even, is cooled to 30 ℃～40 ℃;
Add described zymin, stirring and dissolving is even to system;
Supply deionized water, stir.
9. triple effect unification washing liquid preparation of compositions method according to claim 8 is characterized in that,
Add described zymin, stirring and dissolving also comprises to the uniform step of system:
Adding opalizer stirs;
In adding pigment, sanitas and the essence one or more are supplied deionized water, stir.
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| CN103449984A (en) * | 2013-09-24 | 2013-12-18 | 浙江皇马科技股份有限公司 | Anacardol polyoxyethylene ether and preparation method thereof |
| CN103451922A (en) * | 2013-08-21 | 2013-12-18 | 吴江市七都镇庙港雅迪针织制衣厂 | Softening detergent for woolen clothes and preparation method thereof |
| CN104060471A (en) * | 2014-06-19 | 2014-09-24 | 宁波市川宁环保科技有限公司 | Softener composition and application of composition |
| CN104987961A (en) * | 2015-07-20 | 2015-10-21 | 徐文欢 | Anti-pilling laundry powder for clothes and preparation method thereof |
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| CN106083948A (en) * | 2016-06-16 | 2016-11-09 | 常熟耐素生物材料科技有限公司 | Two phenol polyethenoxy ether base glucosides and its preparation method and application between pentadecane (alkene) base |
| CN106083947A (en) * | 2016-06-16 | 2016-11-09 | 常熟耐素生物材料科技有限公司 | Phenol polyethenoxy ether glucoside and its preparation method and application between pentadecane (alkene) base |
| CN107287059A (en) * | 2016-04-01 | 2017-10-24 | 安徽绿微康生物科技有限公司 | Baby's children's clothes thing bio-enzyme cleaning agent |
| WO2018050047A1 (en) * | 2016-09-13 | 2018-03-22 | Novozymes A/S | Detergent composition, use of detergent composition and method for laundering textile |
| CN108384673A (en) * | 2018-05-08 | 2018-08-10 | 罗彦明 | Environment friendly laundry liquid |
| CN108468053A (en) * | 2018-06-21 | 2018-08-31 | 东北大学 | The aluminum or aluminum alloy mordant and its preparation method of the cardanol polyoxyethylene ether containing saturation |
| WO2019000350A1 (en) * | 2017-06-29 | 2019-01-03 | 黄玉倩 | Stabilizer for laundry detergent |
| CN110964605A (en) * | 2019-12-05 | 2020-04-07 | 广州立白企业集团有限公司 | Soft liquid detergent composition |
| CN111019768A (en) * | 2019-11-29 | 2020-04-17 | 南京市检捷生物信息科技有限公司 | Anti-pilling laundry detergent |
| US10731143B2 (en) | 2014-10-28 | 2020-08-04 | Agrivida, Inc. | Methods and compositions for stabilizing trans-splicing intein modified proteases |
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| CN103451922A (en) * | 2013-08-21 | 2013-12-18 | 吴江市七都镇庙港雅迪针织制衣厂 | Softening detergent for woolen clothes and preparation method thereof |
| CN103449984A (en) * | 2013-09-24 | 2013-12-18 | 浙江皇马科技股份有限公司 | Anacardol polyoxyethylene ether and preparation method thereof |
| CN104060471A (en) * | 2014-06-19 | 2014-09-24 | 宁波市川宁环保科技有限公司 | Softener composition and application of composition |
| US10731143B2 (en) | 2014-10-28 | 2020-08-04 | Agrivida, Inc. | Methods and compositions for stabilizing trans-splicing intein modified proteases |
| US11066657B2 (en) | 2014-10-28 | 2021-07-20 | Agrivida, Inc | Methods and compositions for stabilizing trans-splicing intein modified proteases |
| CN104987960A (en) * | 2015-07-13 | 2015-10-21 | 于文 | Fabric fiber care type bio-enzyme laundry detergent and preparation method thereof |
| CN104987961A (en) * | 2015-07-20 | 2015-10-21 | 徐文欢 | Anti-pilling laundry powder for clothes and preparation method thereof |
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| CN107287059A (en) * | 2016-04-01 | 2017-10-24 | 安徽绿微康生物科技有限公司 | Baby's children's clothes thing bio-enzyme cleaning agent |
| CN107287059B (en) * | 2016-04-01 | 2019-11-19 | 安徽绿微康生物科技有限公司 | Baby's children's clothes object bio-enzyme cleaning agent |
| CN105861183A (en) * | 2016-04-28 | 2016-08-17 | 山西勇宁记科技有限公司 | Efficient compound cellulase for detergent |
| CN105925399A (en) * | 2016-04-28 | 2016-09-07 | 山西勇宁记科技有限公司 | High-efficiency complex lipase for detergents |
| CN105907484A (en) * | 2016-05-25 | 2016-08-31 | 深圳市洁王精细化工科技有限公司 | Detergent as stain removal pen and preparation method of detergent |
| CN106083947A (en) * | 2016-06-16 | 2016-11-09 | 常熟耐素生物材料科技有限公司 | Phenol polyethenoxy ether glucoside and its preparation method and application between pentadecane (alkene) base |
| CN106083948A (en) * | 2016-06-16 | 2016-11-09 | 常熟耐素生物材料科技有限公司 | Two phenol polyethenoxy ether base glucosides and its preparation method and application between pentadecane (alkene) base |
| WO2018050047A1 (en) * | 2016-09-13 | 2018-03-22 | Novozymes A/S | Detergent composition, use of detergent composition and method for laundering textile |
| WO2019000350A1 (en) * | 2017-06-29 | 2019-01-03 | 黄玉倩 | Stabilizer for laundry detergent |
| CN108384673A (en) * | 2018-05-08 | 2018-08-10 | 罗彦明 | Environment friendly laundry liquid |
| CN108468053B (en) * | 2018-06-21 | 2019-06-11 | 东北大学 | The aluminum or aluminum alloy mordant and its preparation method of the cardanol polyoxyethylene ether containing saturation |
| CN108468053A (en) * | 2018-06-21 | 2018-08-31 | 东北大学 | The aluminum or aluminum alloy mordant and its preparation method of the cardanol polyoxyethylene ether containing saturation |
| CN111019768A (en) * | 2019-11-29 | 2020-04-17 | 南京市检捷生物信息科技有限公司 | Anti-pilling laundry detergent |
| CN110964605A (en) * | 2019-12-05 | 2020-04-07 | 广州立白企业集团有限公司 | Soft liquid detergent composition |
| CN110964605B (en) * | 2019-12-05 | 2022-06-28 | 广州立白企业集团有限公司 | Soft liquid detergent composition |
| CN111518630A (en) * | 2020-05-13 | 2020-08-11 | 杭州炫墨生物科技有限公司 | Laundry detergent with antibacterial function and preparation method thereof |
| CN113493724A (en) * | 2021-06-22 | 2021-10-12 | 广东菁萃生物科技有限公司 | Efficient decontamination laundry detergent and preparation method thereof |
| CN113980745A (en) * | 2021-08-19 | 2022-01-28 | 广州南顺清洁用品有限公司 | Color-locking care laundry detergent and preparation method thereof |
| CN115725372A (en) * | 2022-11-21 | 2023-03-03 | 广州立白企业集团有限公司 | Liquid detergent with softening function |
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