CN104452284B - A kind of fabric antistatic additive and preparation method thereof and Fabrid care composition - Google Patents
A kind of fabric antistatic additive and preparation method thereof and Fabrid care composition Download PDFInfo
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- CN104452284B CN104452284B CN201410635225.4A CN201410635225A CN104452284B CN 104452284 B CN104452284 B CN 104452284B CN 201410635225 A CN201410635225 A CN 201410635225A CN 104452284 B CN104452284 B CN 104452284B
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Abstract
The invention discloses a kind of fabric antistatic additive and preparation method thereof and Fabrid care composition.Said composition contains：(a) 0.05~20.0% antistatic additive with formula (I) chemical formula；R1 represents the straight or branched alkyl of C6~C18 in formula；R2, R3 represent the straight or branched alkylidene of C2~C4；R4 represents the straight or branched alkyl of C1~C4；M is anion, and it is in electroneutral to make compound；M, n is 0~5；(b) 0.7 90% carrier, the carrier select liquid-carrier or solid carrier, any one in water, alcohols solvent, ether solvent, inorganic salts solid carrier or two or more compositions according to the mode of appearance of final product.Said composition has the antistatic property for being obviously improved fabric especially chemical ＆ blended fabric.
Description
Technical field
The present invention relates to a kind of Fabrid care composition, belongs to daily use chemicals fabric care product technical field, more particularly to
A kind of Fabrid care composition that can significantly improve fabric antistatic property.
Background technology
In dry winter, usual people are installed with the clothing of various material with it, such as down jackets, sweater, cotton clothes, poly-
Ester chemical fibre clothes, meeting rubs mutually can produce electrostatic, the fabric table of poorly conductive between clothing when the body movement of people
Face can accumulate electrostatic, and not only easily absorption dirt pollutes for the accumulation of electrostatic on the fabric, and electrostatic can also when human body discharges
People is allowed to have the sensation of electric shock pain, in specific place, electrostatic is also possible to cause the accidents such as burning, explosion, therefore exploitation has
The fabric care product of anti-static function disclosure satisfy that consumer demand, have a vast market prospect.
Modern science is taught that：Any object is all by atomic building, and atom is by the atomic nucleus and band of positively charged
The electron institute composition of negative electricity, electronics is around atom nuclear motion.Under normal conditions, the positive changes of atomic nucleus band are with electron outside nucleus
The negative electrical charge number of band is equal, and atom is not aobvious electrical, so whole object is neutral.Positive charge quantity is difficult to change in atomic nucleus
Become, and electron outside nucleus can break away from nuclear constraint, be transferred on another object, so that the negative electrical charge number of electron outside nucleus band
Mesh changes.When object loses electronics, the negative electrical charge sum of its electronic band is fewer than nuclear positive charge, just shows band just
Electricity；On the contrary, it was neutral object originally, when obtaining electronics, it just shows negatively charged.
During two object rubs mutuallies, because the ability of the atomic nucleus constraint electron outside nucleus of different objects is different, its
In there is an object to lose some electronics so as to positively charged, another object obtains unnecessary electronics so as to negatively charged.Such as people
The clothes of unlike material is worn because body kinematics generation electrostatic, terylene material fabric and wool clothes friction, electronics on wool
It is transferred on terylene, wool positively charged, dacron is negatively charged.
How much institute is powered on fabric in same environment depends on two factors：First, play capacitance between unlike material fabric
Easy degree, determines the difference of charge confinement by the frictional force and different fabric textures of fabric；Second, the electric conductivity of fabric
That is resistance sizes, resistance is bigger, and electric conductivity is poorer, the easier accumulation of electrostatic.In various clothing common materials, terylene etc. is changed
The fabric antistatic property of fine material is poor, is on the one hand terylene material easily and animal hair friction produces electrostatic；Other one
Aspect, the resistance of terylene is very big, not easy conductive, and electrostatic is easily accumulated on the fabric.Therefore, in general, the antistatic skill of fabric
Art primarily directed to chemical ＆ blended fabrics such as terylene for.
Antistatic additive mechanism is that hydroaropic substance is knitted so as to change on the fabric by Van der Waals force or electrostatic force absorption
The property on thing surface, can with reduce fabric face friction coefficient so as to play reduce triboelectrification probability, such as softener, separately
Outer hydrophilic substance absorption can reduce the sheet resistance of fabric in fabric face.Usual electrostatic adsorption force can cause antistatic additive more
Add and be firmly adsorbed on fabric, therefore fabric antistatic additive is mostly cation.Presently commercially available fabric softener declares have more
There is anti-static function, the main component of softening agent is the quaternary ammonium salt cationic containing hydrophobic chain, and the cation of positively charged can be more
Fabric face is deposited on well, and hydrophobic chain can assign fabric smooth effect.
101935949 B of Chinese patent CN disclose a kind of fabric softener, which contains 4%~6% double oxen
Ester group ethoxycarbonyl hydroxyethyl methyl sulfate methyl ammonium；103541220 A of Chinese patent CN disclose a kind of fabric softener, should
Softener contains 5%~8% Dialkyl dimethyl quaternary ammonium salt；103669000 A of Chinese patent CN disclose a kind of antistatic
Fabric softener and preparation method thereof, the softener contain 0.1 part to 0.5 part of ester based quaternary ammonium salt.Also formula engineer opens
The detergent with antistatic compliance function has been sent out, that is, two-in-one concept is protected in popular washing, such detergent is also
Generally use has the quaternary ammonium salt cationic of hydrophobic chain as antistatic additive, Akzo Nobel NV patent CN
101454433 B disclose a kind of aqueous laundry detergent compositions with improved softening and antistatic property, the combination
Thing includes at least one amido alkyl amine quarternary ammonium salt compound.102676314 A of Chinese patent CN disclose a kind of antistatic
Detergent, its used antistatic additive are trihydroxyethyl methyl quaternary ammonium methyl sulfate.
The antistatic additive of the above-mentioned prior art is the quaternary ammonium salt cationic containing hydrophobic chain, it has been found that above-mentioned is anti-
The antistatic property of electrostatic agent is unsatisfactory because absorption the antistatic additive of fabric face hydrophobic group cannot produce it is good
Electric conductivity.
The content of the invention
In order to solve the above-mentioned problems of the prior art, it is an object of the invention to provide a kind of fabric antistatic additive and
Fabrid care composition containing the anti-static agent, said composition have the antistatic property for being obviously improved fabric especially chemical ＆ blended fabric
Energy.
Summary of the invention
It is mostly cation that tradition, which applies to fabric nursing to be used to lift fabric antistatic property and the material of softness, should
Cation is mostly the compound being made of hydrophobic chain and quaternary ammonium salt, is used in real consumption person and experiment test shows, this knot
The cationic antistatic performance of structure is not fully up to expectations.It is it has been surprisingly found that antistatic after alkyl quaternary ammonium salts introducing hydrophilic radical
Performance is significantly improved.
The purpose of the present invention is realized by following technical proposals：
A kind of fabric antistatic additive, the antistatic additive have following chemical formula：
R1 represents the straight or branched alkyl of C6~C18 in formula；R2, R3 represent the straight or branched alkylidene of C2~C4；
R4 represents the straight or branched alkyl of C1~C4；M is anion, and it is in electroneutral to make compound；M, n is 0~5.
A kind of Fabrid care composition, said composition by weight percentage, are made of following ingredients：
A) 0.05~20.0% antistatic additive, the antistatic additive have following chemical formula：
R1 represents the straight or branched alkyl of C6~C18 in formula；R2, R3 represent the straight or branched alkylidene of C2~C4；
R4 represents the straight or branched alkyl of C1~C4；M is anion, and it is in electroneutral to make compound；M, n is 0~5.
B) the carrier of 0.7-90%, according to the mode of appearance of the final product of fabric care product select liquid-carrier or
Solid carrier, any one in water, alcohols solvent, ether solvent, inorganic salts solid carrier or two or more combinations
Thing.
Detailed description of the invention
A kind of Fabrid care composition the present invention provides antistatic additive and containing the antistatic additive, the fabric nursing group
Compound contains the poly- ammonium salt antistatic additive of hydrophilic modifying alkyl of 0.05~20.0% percentage by weight, and 0.7-90% weight percents
The carrier of ratio.
The each key element for forming the present invention is explained in detail below.
Antistatic additive
Antistatic additive of the present invention is different from conventional antistatic additive, is a kind of hydrophilic modifying alkyl quaternary ammonium salts, has
Following chemical structural formula：
R in upper chemical structural formula1It is C10~C16 straight chained alkyls；R2, R3 are selected from ethylidene, propylidene；m+n≤6；M is
Water soluble anion, its any one in cl anion, bromine anions, iodine anion, Methylsulfate.
The process of preparing of above-mentioned antistatic additive, comprises the following steps：
1) N, N- dihydroxy ethyl alkylamine synthesize
By haloalkyl and diethanol amine according to molar ratio 0.8:1 to 1.6:Homogeneous forms lotion in 1 ratio disperse water,
Reacted under the alkaline condition of pH value 9.0 to 12.0, reaction temperature is 50~90 DEG C, removes the aqueous solution containing impurity, obtains
To crude product；Crude product is evaporated under reduced pressure at a certain temperature, removes the impurity such as moisture removal and diethanol amine, is obtained faint yellow
Thick liquid, as N, N- dihydroxy ethyl alkylamines；
2) epoxy N, N- dihydroxy ethyl alkylamine
Will the N as made from step 1), N- dihydroxy ethyls alkylamine add reactor in, add water be dispersed with stirring uniformly, add
Enter 0.2% to 5.0% potassium hydroxide, be heated to 70~85 DEG C, purged with nitrogen, remove the moisture in reactor, vacuumize, lead to
Enter ethylene oxide or propylene oxide into reactor, ethylene oxide or the molar ratio of propylene oxide and N, N- dihydroxy ethyl alkylamine
For 1:1 to 6:1, reaction a period of time, vacuumize, remove escaping gas, obtain epoxy N, N- dihydroxy ethyl alkylamine；
3) ethoxylation N, N- dihydroxy ethyl alkylamine quaternary aminesization are reacted
By ethoxylation N made from step 2), N- dihydroxy ethyls alkylamine carries out quaterisation using known method,
Formed and containing any cl anion, bromine anions, iodine anion, the quaternary ammonium salt of Methylsulfate, that is, obtain the antistatic additive.
A kind of Fabrid care composition containing the above-mentioned antistatic additive of the present invention, contains：
A) the antistatic additive of 0.05~20.0% percentage by weight, the antistatic additive have following chemical formula：
R1 represents the straight or branched alkyl of C6~C18 in formula；R2, R3 represent the straight or branched alkylidene of C2~C4；
R4 represents the straight or branched alkyl of C1~C4；M is anion, and it is in electroneutral to make compound；M, n is 0~5.
B) the carrier of 0.7-90%, liquid-carrier or solid carrier, choosing are selected according to the mode of appearance of final product
From any one in water, alcohols solvent, ether solvent, inorganic salts solid carrier or two or more compositions.
Composition of the present invention contains the antistatic additive described in 0.1~10.0% percentage by weight；Further preferably
Ground, said composition contain the antistatic additive that 0.5~5.0% percentage by weight is stated；It is further preferred that said composition contains 1.0
The antistatic additive of~3.0% percentage by weight.
The Fabrid care composition, it can also live containing the cationic surface of 0.5~20.0% percentage by weight
Property agent, can prepare the fabric softener kind fabric care product with anti-static function.
Cationic surfactant
Composition of the present invention also contains 0.5~20.0% percentage by weight cationic surfactant, suitable
Cationic surfactant is selected from：Dialkyl quaternary ammonium salt, triethanolamine-type ester based quaternary ammonium salt, di-ester-base quaternary ammonium salts, methyl
In diethanol amine type Biester quarternary ammoniumsalt, bisamide ethoxyl quaternary ammonium salt, acid amides ester based quaternary ammonium salt, amide imidazoline type quaternary ammonium salt
Any one or two or more compositions.
The Fabrid care composition, it can also the non-ionic surface active containing 0.5~15% percentage by weight
Agent and the anion surfactant of 0.5~25% percentage by weight, can be prepared into the laundry detergent compositions with anti-static function
Product.
Nonionic surfactant and anion surfactant
Composition of the present invention also containing 0.5~15% percentage by weight nonionic surfactant and 0.5~
25% anion surfactant.
The nonionic surfactant is selected from：The fatty alcohol polyoxyethylene ether of C12~C18, C12~C14 alkyl glycosides,
Appointing in the condensation product of C12~C18 alcohol and ethylene oxide/propylene oxide block copolymer, C8~C20 branched-chain alcoho polyoxyethylene ether
The composition for one or more of anticipating.
The anion surfactant is selected from：C12~C18 fatty acid soaps, C11~C18 alkylbenzenesulfonates (LAS),
Any one in C12~C18 alkyl alkoxy sulfates (AES), C14~C18 fatty acid methyl ester sulfonate (MES) or two kinds
Composition above.
The Fabrid care composition, in order to make formula have more preferable detergency or other additional functions, it is also
Can the auxiliary agent containing 0.5-50% percentage by weights.
Auxiliary agent
The auxiliary agent is selected from：In water softener, bleaching agent, bleach activator, enzyme preparation, essence, pigment any one or
Two or more compositions.
The water softener in 4A zeolites, sodium silicate, composition silicate, citrate, carbonate any one or
Two or more compositions.
The bleaching agent is selected from hydrogen peroxide, sodium perborate monohydrate, sodium perborate tetrahydrate, SODIUM PERCARBONATE, overfocus
Any one in sodium phosphate, urea peroxyhydrate, sodium peroxide or two or more compositions.
The bleach-activating is selected from tetra acetyl ethylene diamine (TAED), decyloxy benzoic acid (DOBA), caprinoyl epoxide benzene
Any one or two or more compositions of sodium sulfonate (DOBS).
The enzyme preparation in protease, lipase, cellulase, peroxidase any one or it is two or more
Composition.
The antistatic additive of the present invention and the Fabrid care composition containing the antistatic additive have the following advantages that and beneficial to effects
Fruit：
1) compared with traditional antistatic additive, the present invention introduces epoxy alkyl on the basis of traditional alkyl quaternary ammonium salts, when
The antistatic additive of the present invention is adsorbed when on clothing by electrostatic interaction, using the teaching of the invention it is possible to provide good hydrophilic effect, so as to carry
For excellent antistatic property；
2) antistatic additive is soluble easily in water, is adapted to apply in various fabric nursing formulas.
Embodiment
Produced below by way of fabric nursing of the specific preferred embodiment to the antistatic additive of the present invention and containing the antistatic additive
Product are described in further detail, but the present invention is not limited in following embodiment.
Embodiment 1
The synthetic method of antistatic additive A, comprises the following steps that：
A) N, N- dihydroxy ethyl dodecyl amine synthesize
300ml deionized waters are added into the three-necked flask of 500mL, add 120g bromododecanes, homogeneous is formed for 5 minutes
Bromododecane lotion.And warming-in-water is carried out to system, when temperature is increased to 90 DEG C, 44g diethanol amine is slowly added dropwise
Into reaction system, constant temperature stirring 0.5h.Then 2g NaOH are added, within this temperature range quick stirring reaction certain time.
Reaction solution is poured in the separatory funnel of 500mL and stands 2h, be separated off the aqueous solution containing impurity such as NaBr, slightly produced
Product.Crude product is evaporated under reduced pressure at a certain temperature, removes the impurity such as moisture removal and diethanol amine, obtains faint yellow viscous fluid
Body, as N, N- dihydroxy ethyl lauryl amines.
B)5EO ethoxylations N, N- dihydroxy ethyl dodecyl amine
200g deionized waters are added into reactor, are added as A) N made from step, N- dihydroxy ethyl lauryl amines
120g, stirs evenly, and adds 8g potassium hydroxide, is heated to 70~85 DEG C, is purged three times with nitrogen, removes the water in reactor
Point, temperature of reactor is increased to 120 DEG C, is vacuumized, the reaction pressure for being passed through 300g ethylene oxide to reactor reaches
800KPa, open stirring stirring 4 it is small when after vacuumize, remove escaping gas, obtain buff thick liquid, be 5EO
Ethoxylation N, N- dihydroxy ethyl dodecyl amine.
C)Ethoxylation N, N- dihydroxy ethyl dodecyl amine quaterisation
Weigh as B) made from ethoxylation N, N- dihydroxy ethyl dodecyl amine 100g be added in 250ml three-necked flasks,
23 grams of progress quaterisations of dimethyl suflfate are slowly added dropwise under the conditions of being stirred at reflux, reaction completes postcooling, removes volatilization
Thing is to obtain the antistatic additive.
Embodiment 2
The synthetic method of antistatic agent B, comprises the following steps that：
A) N, N- dihydroxy ethyl cetylamine synthesize
300ml deionized waters are added into the three-necked flask of 500mL, add 120g bromohexadecanes, homogeneous is formed for 5 minutes
Bromohexadecane lotion.And warming-in-water is carried out to system, when temperature is increased to 90 DEG C, 40g diethanol amine is slowly added dropwise
Into reaction system, constant temperature stirring 0.5h.Then 2g NaOH are added, within this temperature range quick stirring reaction certain time.
Reaction solution is poured in the separatory funnel of 500mL and stands 2h, be separated off the aqueous solution containing impurity such as NaBr, slightly produced
Product.Crude product is evaporated under reduced pressure at a certain temperature, removes the impurity such as moisture removal and diethanol amine, obtains faint yellow viscous fluid
Body, as N, N- dihydroxy ethyl hexadecylamines.
B)5PO propoxylations N, N- dihydroxy ethyl cetylamine
200g deionized waters are added into reactor, are added as A) N obtained by step, N- dihydroxy ethyl hexadecylamines
120g, stirs evenly, and adds 7g potassium hydroxide, is heated to 70~85 DEG C, is purged three times with nitrogen, removes the water in reaction pot
Point, temperature of reactor is increased to 120 DEG C, is vacuumized, the reaction pressure for being passed through 291g propylene oxide to reactor reaches
800KPa, open stirring stirring 4 it is small when after vacuumize, remove escaping gas, obtain buff thick liquid.As 5PO third
Epoxide N, N- dihydroxy ethyl cetylamine.
C)Ethoxylation N, N- dihydroxy ethyl cetylamine quaterisation
Weigh as B) made from ethoxylation N, N- dihydroxy ethyl cetylamine 100g be added in 250ml three-necked flasks,
21.5 grams of progress quaterisations of dimethyl suflfate are slowly added dropwise under the conditions of being stirred at reflux, postcooling is completed in reaction, and removing is waved
Stimulating food is to obtain the antistatic additive.
Comparative example 1, embodiment 3~6
Embodiment 3~6 is that and comparative example 1 is to correspond containing antistatic additive softener product of the present invention
The softener product without antistatic additive.
1 comparative example of table, 3~6 submissive agent prescription of embodiment
Above-mentioned anti-softener recipe configuration technique is as follows：
(1) deionized water is proportionally added into, stirring is opened, temperature is increased to 50 DEG C；
(2) TEP-88 is heated to 50 DEG C keeps liquid condition to be then slowly added in water, stirs 10 minutes；
(3) treat that batch temperature is down to 45 DEG C, add antistatic additive, essence, preservative；
Comparative example 2, embodiment 7~10
Embodiment 7~10 is the fabric liquid detergent embodiment containing antistatic additive of the present invention, and comparative example 2
It is the corresponding liquid fabric detergent compositions without the antistatic additive.
2 comparative example 2 of table, the formula of 7~10 liquid detergent of embodiment
The formula preparing process of above-mentioned fabric liquid detergent is as follows：
(1) soft water, sodium hydroxide are proportionally added, Las is added and carries out neutralization reaction with aliphatic acid；
(2) after the completion of reaction to be neutralized, 50 DEG C are warming up to, is proportionally added into APG, AEO7, AES, 445N, citric acid respectively
Sodium, propane diols, Boratex, calcium chloride, brightening agent CBS, sodium formate, stir to above-mentioned substance and are completely dissolved；
(3) start to be cooled to 45 DEG C of ＜, protease, amylase, cellulase, mannosan are added according to formula rate
Enzyme, essence, preservative, stirring can discharge after ten minutes.
Comparative example 3, embodiment 11~14
Embodiment 11~14 is the washing powder embodiment containing antistatic additive of the present invention, and comparative example 3 is therewith
The corresponding washing powder formula without the antistatic additive.
3 comparative example 3 of table, 11~14 washing powder formula composition of embodiment are than row
The production technology of washing powder formula is as follows in form 3：
(2) process water is added in ingredients pot, 32% liquid caustic soda, sulfonic acid progress neutralization reaction is added, then sequentially adds increasing
White agent CBS-X, fatty acid soaps, sodium citrate, soda ash, sodium metasilicate, sodium sulphate, 4A zeolites, Acusol445N, stir evenly, always
Change, be then pipelined to spray tower and dust；
(2) the original washing powder wind of gained of dusting is sent to rear match system, rear with adding antistatic additive A, AEO7, essence, TAED, cross carbon
Sour sodium, enzyme preparation are uniformly mixed.
Antistatic property is evaluated
(1) test method of electrostatic pressure half-life period
With reference to the standard of standard GB/T/T 12703.1, this hair is evaluated by testing the electrostatic pressure half-life period of textile
Bright embodiment softener, liquid fabric detergent, the antistatic property of washing powder.
Sample-pretreating method
Knitted polyester cloth is cut into 1m × 1m, 4 kilograms of roller washing machines is then placed in and is washed.
The antistatic property evaluation washing machine of softener is only rinsed, dehydration, and softener adds 120ml to laundry
In machine, evaluation fabric is taken out after rinsing, dehydration procedure and is dried, circular treatment 3 times.
The evaluation washing machine of liquid detergent is washed, rinsed, dehydration procedure, and liquid detergent adds 60ml to laundry
In machine, evaluation fabric is taken out by washing, rinse, after dehydration procedure and is dried, circular treatment 3 times.
The test condition of electrostatic pressure half-life period
Test air environmental condition be：Temperature (20 ± 2) DEG C, relative humidity (35 ± 5) %, ambient wind velocity ＜ 0.1m/
s。
The above-mentioned knitted polyester cloth by pre-treatment is cut into 4.5cm × 4.5cm, is then advised according to GB/T 12703.1
Fixed instrument is tested.
Test result
4 comparative example 1 of table, the submissive agent prescription electrostatic pressure half-life period evaluation result of embodiment 3~6
| Electrostatic potential (unit V) | Half-life period (unit s) | |
| Comparative example 1 | 2500 | 60 |
| Embodiment 3 | 2200 | 20 |
| Embodiment 4 | 1800 | 2 |
| Embodiment 5 | 1500 | 1.6 |
| Embodiment 6 | 1810 | 2.2 |
From the point of view of table 4, relative to comparative example 1, the electrostatic potential of the formula of softener and half-life period after antistatic additive are added
Significantly decrease, antistatic property is improved, and with the increase of antistatic additive additive amount, antistatic effect is got over
It is good.
5 comparative example 2 of table, 7~10 liquid fabric detergent compositions electrostatic pressure half-life period evaluation result of embodiment
| Electrostatic potential (unit V) | Half-life period (unit s) |
| Comparative example 2 | 3000 | 100 |
| Embodiment 7 | 2600 | 50 |
| Embodiment 8 | 1900 | 10 |
| Embodiment 9 | 1700 | 8 |
| Embodiment 10 | 1300 | 6 |
From the point of view of table 5, the fabric after liquid detergent processing is bigger than the fabric half-life period that softener is handled, and adds anti-quiet
The electrostatic potential of the formula of liquid fabric detergent is same with half-life period after electric agent decreases drastically, and antistatic property obtains
Lifting, as the increase of antistatic additive additive amount, antistatic effect are better.
6 comparative example 3 of table, 11~14 washing powder of embodiment formula electrostatic pressure half-life period evaluation result
| Electrostatic potential (unit V) | Half-life period (unit s) | |
| Comparative example 3 | 3300 | 200 |
| Embodiment 11 | 2800 | 120 |
| Embodiment 12 | 2500 | 60 |
| Embodiment 13 | 2000 | 50 |
| Embodiment 14 | 1800 | 35 |
From the point of view of table 6, the electrostatic pressure half-life period relative to washing powder formula after the addition antistatic additive of comparative example 3 has substantially
Decline, antistatic property is improved, as the increase of antistatic additive additive amount, antistatic effect are better.
(2) simulation actual use fabric care product application method assessment antistatic property
Consumer in life with the electrostatic that produces of fabric number mainly determined by two factors：First, fabric
Friction produces the easy degree of electrostatic；Second, the degree of the stop accumulation of electrostatic on the fabric.In order to evaluate the embodiment of the present invention
In each fabric care product actual antistatic property, we devise simulation actual use antistatic property appraisal procedure.
Sample-pretreating method
Knitted polyester cloth is cut into 1m × 1m, 4 kilograms of roller washing machines is then placed in and is washed.
The antistatic property evaluation washing machine of softener is only rinsed, dehydration, and softener adds 120ml to laundry
In machine, evaluation fabric is taken out after rinsing, dehydration procedure and is dried, circular treatment 3 times.
The evaluation washing machine of liquid detergent is washed, rinsed, dehydration procedure, and liquid detergent adds 60ml to laundry
In machine, evaluation fabric is taken out by washing, rinse, after dehydration procedure and is dried, circular treatment 3 times.
Fabric by circular treatment 3 times is put into 70 DEG C of baking ovens places 4 hours and be then placed in containing the close of drier
Close in container.
Test condition
Test air environmental condition be：Temperature (20 ± 2) DEG C, relative humidity (35 ± 5) %, ambient wind velocity ＜ 0.1m/
s。
The above-mentioned knitted polyester cloth by pre-treatment is cut into 4.5cm × 4.5cm, then fabric according to fixed side
Formula and hair friction, then with the carried charge in simca FMX-003 electrostatic field tester test fabrics, one was tested every 30 seconds
It is secondary.
7 comparative example 1 of table, 3~6 submissive agent prescription of embodiment simulation actual use antistatic property assessment (unit K V)
| Initially | 30S | 60S | |
| Comparative example 1 | -6.7 | -5.0 | -4.5 |
| Embodiment 3 | -4.5 | -2.6 | -2.2 |
| Embodiment 4 | -4.4 | -1.4 | -1.0 |
| Embodiment 5 | -3.5 | -1.2 | -0.9 |
| Embodiment 6 | -4.3 | -1.5 | -0.9 |
In terms of the data of table 7, produced by the antistatic property for the submissive agent prescription that antistatic additive is added relative to comparative example 1
Electrostatic pressure absolute value decrease, electrostatic fabric decay also faster, it is antistatic with the increase of antistatic additive additive amount
It is better notable.
8 comparative example 2 of table, 7~10 liquid detergent of embodiment simulation actual use antistatic property assessment (unit K V)
| Initially | 30S | 60S | |
| Comparative example 2 | -9.5 | -6.5 | -5.5 |
| Embodiment 7 | -6.5 | -4.5 | -4.0 |
| Embodiment 8 | -5.8 | -2.0 | -1.6 |
| Embodiment 9 | -4.6 | -1.6 | -1.4 |
| Embodiment 10 | -2.5 | -1.0 | -0.4 |
In terms of the data of table 8, the antistatic property institute of the liquid detergent formula of antistatic additive is added relative to comparative example 1
The electrostatic pressure absolute value of generation decreases, electrostatic fabric decay also faster, with the increase of additive amount, antistatic effect
It is more preferably notable.
9 comparative example 3 of table, 11~13 washing powder formula of embodiment simulation actual use antistatic property assessment (unit K V)
| Initially | 30S | 60S | |
| Comparative example 1 | -10.3 | -8.2 | -7.5 |
| Embodiment 11 | -7.4 | -5.5 | -4.5 |
| Embodiment 12 | -5.8 | -4.2 | -2.8 |
| Embodiment 13 | -4.6 | -2.9 | -2.0 |
| Embodiment 15 | -3.8 | -2.0 | -1.8 |
In terms of the data of table 9, produced by the antistatic property for the washing powder formula that antistatic additive is added relative to comparative example 1
Electrostatic pressure absolute value decrease, electrostatic fabric decay also faster, with the increase of additive amount, antistatic effect is more preferably
Significantly.
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention and from above-described embodiment
Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (7)
- A kind of 1. Fabrid care composition, it is characterised in that：By weight percentage, said composition is composed of the following components：A) 0.05~20.0% antistatic additive, the antistatic additive have following chemical formula：R in formula1Represent the straight or branched alkyl of C6~C18；R2、R3Represent the straight or branched alkylidene of C2~C4；R4Represent The straight or branched alkyl of C1~C4；M is anion, and it is in electroneutral to make compound；M, n is 0~5, m+n≤6；M, when n is different For 0；B) 0.5~20.0% cationic surfactant, suitable cationic surfactant are selected from dialkyl quaternary ammonium salt, three Ethanol amine type ester based quaternary ammonium salt, di-ester-base quaternary ammonium salts, methyl diethanolamine type Biester quarternary ammoniumsalt, bisamide ethoxy season Any one in ammonium salt, acid amides ester based quaternary ammonium salt, amide imidazoline type quaternary ammonium salt or two or more compositions；C) the carrier of 0.7-90%, the carrier select liquid-carrier or solid to carry according to the mode of appearance of final product Body, any one in water, alcohols solvent, ether solvent, inorganic salts solid carrier or two or more compositions；Each group / and satisfaction 100%.
- 2. Fabrid care composition according to claim 1, it is characterised in that：Said composition contains 0.1~10.0% weight Measure the antistatic additive of percentage.
- 3. Fabrid care composition according to claim 2, it is characterised in that：Said composition contains 0.5~5.0% weight Antistatic additive described in percentage.
- 4. Fabrid care composition according to claim 3, it is characterised in that：Said composition contains 1.0~3.0% weight Antistatic additive described in percentage.
- 5. Fabrid care composition according to claim 1, it is characterised in that：Wherein R1It is C10~C16 straight chained alkyls.
- 6. Fabrid care composition according to claim 1, it is characterised in that：Wherein R2、R3Arbitrarily selected from ethylidene, Asia Propyl group.
- 7. Fabrid care composition according to claim 1, it is characterised in that：Wherein M is water soluble anion, it is any Selected from cl anion, bromine anions, iodine anion, Methylsulfate.
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| CN106631841A (en) * | 2016-12-05 | 2017-05-10 | 广州天赐高新材料股份有限公司 | Ester-based quaternary ammonium salt as well as preparation method and application thereof |
| CN107325898A (en) * | 2017-06-28 | 2017-11-07 | 太仓大唐化纤厂 | A kind of detergent for improving chemical fibre pliability |
| CN108342185B (en) * | 2018-01-03 | 2020-09-01 | 浙江绿岛科技有限公司 | Antistatic aerosol based on cationic surfactant and preparation method thereof |
| CN111944198A (en) * | 2020-07-24 | 2020-11-17 | 江苏海云花新材料有限公司 | Cationic quaternary ammonium salt antistatic agent |
| CN112142608A (en) * | 2020-10-09 | 2020-12-29 | 杭州临安德昌静电科技有限公司 | Antistatic agent and preparation method thereof |
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| US5994285A (en) * | 1999-06-14 | 1999-11-30 | Colgate-Palmolive Co. | Liquid laundry detergent composition containing ethoxylated amine quaternary surfactant |
| CN100569932C (en) * | 2006-07-26 | 2009-12-16 | 广州立白企业集团有限公司 | Fabric detergent |
| CN101812381B (en) * | 2009-06-08 | 2012-10-10 | 广州立白企业集团有限公司 | Washing and softening laundry detergent composition |
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