CN105567454A - Antibacterial liquid laundry detergent, preparation method and applications thereof - Google Patents
Antibacterial liquid laundry detergent, preparation method and applications thereof Download PDFInfo
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- CN105567454A CN105567454A CN201511031469.2A CN201511031469A CN105567454A CN 105567454 A CN105567454 A CN 105567454A CN 201511031469 A CN201511031469 A CN 201511031469A CN 105567454 A CN105567454 A CN 105567454A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1206—Water-insoluble compounds free metals, e.g. aluminium grit or flakes
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/187—Hydrocarbons aromatic
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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Abstract
The invention belongs to the field of daily chemicals, and specifically relates to an antibacterial liquid laundry detergent, a preparation method and applications thereof. The antibacterial liquid laundry detergent comprises the following components in percentage by weight: 0.3 to 0.9% of composite antibacterial agent, 5 to 20% of anionic surfactant, 5 to 20% of nonionic surfactant, 0.05 to 0.5% of fluorescent whitening agent, 0.05 to 5% of chelating agent, 0 to 1% of pH adjuster, 0.1 to 1% of essence, and the balance being water. The composite antibacterial agent is prepared according to a mass ratio of 1:1-5 of nano silver to a plant origin antibacterial agent. The nano silver and plant origin antibacterial agent can generate a synergetic effect, the antibacterial activity is largely improved, and thus the bacteria can be effectively removed. Furthermore, the raw materials are easily available, the preparation technology is simple, the cost is low, and the preparation method can be applied to industrial production. The prepared antibacterial liquid laundry detergent is nontoxic, nonirritant, and environment-friendly and can be easily degraded by organisms.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of antimicrobial laundry liquid and preparation method thereof and application.
Background technology
Washing liquid is common clothes or textile washing articles for use.Washing liquid commercially available at present generally only has following function: washing, submissive and arrangement function, seldom there is antibiotic and sterilizing function, the requirement of comprehensive cleaning clothes can not be met, especially the textiles and clothing etc. of the public place such as hotel, hotel, generally also need additionally to add sterilizing agent when washing, this is very inconvenient when washing.
(application number: 200810101768.2) disclose a kind of bactericidal liquid detergent adopts subtilis CGMCC2294 fermentation broth extract to be sterilant to Chinese patent.Chinese patent (application number 201310613125.7) discloses a kind of sterilization and disinfection laundry liquid formulation, adopts the extract of the leaf of bamboo and mulberry leaf as disinfection solution; Chinese patent (application number: 201110369026.X) discloses a kind of clothing degerming liquid and preparation method thereof, have employed mesoporous silicate loading nano silvery suspension as antiseptic-germicide.But nanometer silver price is high, antimicrobial spectrum is narrower, especially poor to the inhibition of mould, be difficult to the object reaching effective antibiotic and sterilizing, be also unfavorable for suitability for industrialized production.
Summary of the invention
In order to overcome the deficiencies in the prior art and shortcoming, primary and foremost purpose of the present invention is to provide a kind of antimicrobial laundry liquid, (1:5) ~ (1:1) is formulated in mass ratio by nanometer silver and plant-source antibacterial agent for one of component of this antimicrobial laundry liquid complex antimicrobials, due to the antibacterial synergistic effect of nanometer silver and natural plant antiseptic-germicide, its anti-microbial activity significantly improves, there is has a broad antifungal spectrum, feature that antimicrobial efficiency is high, can effectively kill common bacteria as intestinal bacteria, streptococcus aureus etc.
Another object of the present invention is to the preparation method that above-mentioned antimicrobial laundry liquid is provided.
Another object of the present invention is the application providing above-mentioned antimicrobial laundry liquid.
Object of the present invention is achieved through the following technical solutions:
A kind of antimicrobial laundry liquid, comprises following component by mass percentage:
Described antimicrobial laundry liquid, preferably comprises following component by mass percentage:
Described complex antimicrobials comprises nanometer silver and natural plant antiseptic-germicide;
The mass ratio of described nanometer silver and natural plant antiseptic-germicide is preferably (1:5) ~ (1:1);
Described nanometer silver is at least one in monomer nano silver and complex state nanometer silver;
Described monomer nano silver Ag mean particle size is preferably 100nm; Described complex state nanometer silver Ag mean particle size is preferably 0.5nm;
Described natural plant antiseptic-germicide is preferably at least one in Aloe extract and citron extract;
The effective solid content of described Aloe extract is preferably 5%;
The effective solid content of described citron extract is preferably 2.5%;
Described anion surfactant is at least one in sodium alkyl benzene sulfonate, sodium alkyl sulfate, poly alkyl alcohol ether sodium sulfate, a-sodium olefin sulfonate and methyl sodiosul foaliphatate;
Described nonionogenic tenside is at least one in fatty alcohol-polyoxyethylene ether, isomery alcohol polyoxyethylenated alcohol, fatty acid methyl ester ethoxylate, cocounut oil acyl diglycollic amide and APG;
Described white dyes is double styrene-biphenyl type whitening agent and at least one in two triazinyl diphenyl ethylene derivatives;
The described sequestrant at least one that to be sequestrant be in disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate and Trisodium Citrate;
Described pH adjusting agent be preferably in citric acid and sodium hydroxide any one;
The preparation method of described antimicrobial laundry liquid, comprises following steps:
Heat water to 60 DEG C ~ 70 DEG C, add anion surfactant, nonionogenic tenside, white dyes and sequestrant, mixing rear pH value regulator adjust ph is 7.5 ~ 8.5, reduce temperature to 30 DEG C ~ 40 DEG C, add essence and complex antimicrobials mixes, obtain antimicrobial laundry liquid;
The application of described antimicrobial laundry liquid in household chemicals field;
The present invention has following advantage and effect relative to prior art:
(1) the present invention adopts using nanometer silver and the natural plant antiseptic-germicide mixture that (1:5) ~ (1:1) prepares in mass ratio as antiseptic-germicide, due to the antibacterial synergistic effect of nanometer silver and natural plant antiseptic-germicide, its anti-microbial activity significantly improves, effectively can remove intestinal bacteria, the bacteriums such as streptococcus aureus.
(2) raw material of the present invention is easy to get, and preparation technology is simple, and cost is low, can be applicable to industrialized production.The antimicrobial efficiency of the antimicrobial laundry liquid prepared is high, nontoxic, non-stimulated, environmental friendliness, readily biodegradable.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited thereto.
100nm monomer nano silver in embodiment and 0.5nm complex state nanometer silver are purchased from Li Yuan Chemical Co., Ltd. of Foshan City; The buying of Aloe extract (effective solid content is 5%), citron extract (effective solid content is 2.5%), old ginger extract and Fructus Canrii Albi extract is from Huzhou Jiamei Biochemical Products Co., Ltd..
Embodiment 1
A kind of antimicrobial laundry liquid, comprises following component by mass percentage:
The preparation method of above-mentioned antimicrobial laundry liquid, comprises following steps:
(1) nanometer silver 0.3% and citron extract 0.6% are mixed all obtain complex antimicrobials;
(2) deionized water 68.5% is added in reactor, by its heating temperatures to 60 DEG C, add sodium alkyl benzene sulfonate 10%, poly alkyl alcohol ether sodium sulfate 10%, fatty alcohol-polyoxyethylene ether 5%, APG 5%, double styrene-biphenyl type whitening agent 0.1% and disodium ethylene diamine tetraacetate 0.1% successively, be 7.5 by citric acid adjust ph after stirring, reduce temperature to 30 DEG C, add essence 0.3% and complex antimicrobials 0.9%, then obtain antimicrobial laundry liquid after stirring.
Embodiment 2
A kind of antimicrobial laundry liquid, comprises following component by mass percentage:
The preparation method of above-mentioned antimicrobial laundry liquid, comprises following steps:
(1) nanometer silver 0.3% and Aloe extract 0.4% are mixed all obtain complex antimicrobials;
(2) deionized water 67.9% is added in reactor, by its heating temperatures to 65 DEG C, add sodium alkyl benzene sulfonate 5%, poly alkyl alcohol ether sodium sulfate 10%, methyl sodiosul foaliphatate 5%, fatty alcohol-polyoxyethylene ether 5%, isomery alcohol polyoxyethylenated alcohol 5%, double styrene-biphenyl type whitening agent 0.1% and Trisodium Citrate 1% successively, after stirring, adjust ph is 8.0, reduce temperature to 35 DEG C, add essence 0.3% and complex antimicrobials 0.7%, then obtain antimicrobial laundry liquid after stirring.
Embodiment 3
A kind of antimicrobial laundry liquid, comprises following component by mass percentage:
The preparation method of above-mentioned antimicrobial laundry liquid, comprises following steps:
(1) nanometer silver 0.2% and citron extract 0.3% are mixed all obtain complex antimicrobials;
(2) deionized water 68.75% is added in reactor, by its heating temperatures to 70 DEG C, add sodium alkyl benzene sulfonate 10%, poly alkyl alcohol ether sodium sulfate 5%, a-sodium olefin sulfonate 5%, fatty alcohol-polyoxyethylene ether 5%, fatty acid methyl ester ethoxylate 5%, two triazines diphenyl ethylene derivatives 0.3% and tetrasodium ethylenediamine tetraacetate 0.1% successively, be 8.5 by citric acid adjust ph after stirring, reduce temperature to 40 DEG C, add essence 0.3% and complex antimicrobials 0.5%, then obtain antimicrobial laundry liquid after stirring.
Embodiment 4
A kind of antimicrobial laundry liquid, comprises following component by mass percentage:
The preparation method of above-mentioned antimicrobial laundry liquid, comprises following steps:
(1) nanometer silver 0.2% and Aloe extract 0.2% are mixed all obtain complex antimicrobials;
(2) deionized water 68.79% is added in reactor, by its heating temperatures to 70 DEG C, add sodium alkyl benzene sulfonate 5%, poly alkyl alcohol ether sodium sulfate 10%, methyl sodiosul foaliphatate 5%, fatty acid methyl ester ethoxylate 5%, APG 5%, two triazines diphenyl ethylene derivatives 0.2% and disodium ethylene diamine tetraacetate 0.1% successively, be 7.5 by citric acid adjust ph after stirring, reduce temperature extremely lower than 30 DEG C, add essence 0.5% and complex antimicrobials 0.4%, then obtain antimicrobial laundry liquid after stirring.
Embodiment 5
A kind of antimicrobial laundry liquid, comprises following component by mass percentage:
The preparation method of above-mentioned antimicrobial laundry liquid, comprises following steps:
(1) nanometer silver 0.1% and citron extract 0.5% are mixed all obtain complex antimicrobials;
(2) deionized water 62.9% is added in reactor, by its heating temperatures to 60 DEG C, add poly alkyl alcohol ether sodium sulfate 10%, methyl sodiosul foaliphatate 10%, fatty alcohol-polyoxyethylene ether 8%, fatty acid methyl ester ethoxylate 8%, double styrene-biphenyl type whitening agent 0.1% and disodium ethylene diamine tetraacetate 0.1% successively, be 7.5 by sodium hydroxide adjust ph after stirring, reduce temperature extremely lower than 40 DEG C, add essence 0.3%, complex antimicrobials 0.6%, then obtain antimicrobial laundry liquid after stirring.
Embodiment 6
A kind of antimicrobial laundry liquid, comprises following component by mass percentage:
The preparation method of above-mentioned antimicrobial laundry liquid, comprises following steps:
(1) nanometer silver 0.1% and Aloe extract 0.4% are mixed all obtain complex antimicrobials;
(2) deionized water 69% is added in reactor, by its heating temperatures to 60 DEG C, add sodium alkyl benzene sulfonate 10%, poly alkyl alcohol ether sodium sulfate 10%, fatty alcohol-polyoxyethylene ether 7%, cocounut oil acyl diglycollic amide 3%, double styrene-biphenyl type whitening agent 0.1% and disodium ethylene diamine tetraacetate 0.1% successively, be 7.5 by citric acid adjust ph after stirring, reduce temperature extremely lower than 40 DEG C, add essence 0.3% and complex antimicrobials 0.5%, then obtain antimicrobial laundry liquid after stirring.
Embodiment 7
A kind of antimicrobial laundry liquid, comprises following component by mass percentage:
The preparation method of above-mentioned antimicrobial laundry liquid, comprises following steps:
(1) nanometer silver 0.1% and citron extract 0.3% are mixed all obtain complex antimicrobials;
(2) deionized water 69.05% is added in reactor, by its heating temperatures to 70 DEG C, add sodium alkyl benzene sulfonate 10%, poly alkyl alcohol ether sodium sulfate 10%, fatty alcohol-polyoxyethylene ether 10%, double styrene-biphenyl type whitening agent 0.1% and disodium ethylene diamine tetraacetate 0.1% successively, be 7.5 by citric acid adjust ph after stirring, reduce temperature extremely lower than 30 DEG C, add essence 0.3% and complex antimicrobials 0.4%, then obtain antimicrobial laundry liquid after stirring.
Embodiment 8
A kind of antimicrobial laundry liquid, comprises following component by mass percentage:
The preparation method of above-mentioned antimicrobial laundry liquid, comprises following steps:
(1) nanometer silver 0.1% and Aloe extract 0.2% are mixed all obtain complex antimicrobials;
(2) deionized water 74.05% is added in reactor, by its heating temperatures to 60 DEG C, add sodium alkyl benzene sulfonate 10%, poly alkyl alcohol ether sodium sulfate 5%, fatty alcohol-polyoxyethylene ether 5%, alkyl polysaccharide 5%, double styrene-biphenyl type whitening agent 0.2% and disodium ethylene diamine tetraacetate 0.1% successively, be 7.5 by citric acid adjust ph after stirring, reduce temperature extremely lower than 30 DEG C, add essence 0.3% and complex antimicrobials 0.3%, then obtain antimicrobial laundry liquid after stirring.
Comparative example 1
Preparation technology is with embodiment 1, and difference is only to adopt mass percent to be that the nanometer silver (100nm monomer nano silver) of 0.3% is as antiseptic-germicide in step (1).
Comparative example 2
Preparation technology is with embodiment 1, and difference is only to adopt mass percent to be that the nanometer silver (100nm monomer nano silver) of 0.2% is as antiseptic-germicide in step (1).
Comparative example 3
Preparation technology is with embodiment 1, and difference is only to adopt mass percent to be that the nanometer silver (0.5nm complex state nanometer silver) of 0.1% is as antiseptic-germicide in step (1).
Comparative example 4
Preparation technology is with embodiment 1, and difference is only to adopt mass percent to be that the citron extract of 0.5% is as antiseptic-germicide in step (1).
Comparative example 5
Preparation technology is with embodiment 1, and difference is only to adopt mass percent to be that the Aloe extract of 0.4% is as antiseptic-germicide in step (1).
Comparative example 6
Preparation technology with embodiment 1, difference be only to adopt in step (1) mass percent be 0.1% nanometer silver (0.5nm complex state nanometer silver) and mass percent be that the mixture of the old ginger extract of 0.4% is as complex antimicrobials.
Comparative example 7
Preparation technology with embodiment 1, difference be only to adopt in step (1) mass percent be 0.1% nanometer silver (0.5nm complex state nanometer silver) and mass percent be that the mixture of the Fructus Canrii Albi extract of 0.4% is as complex antimicrobials.
Effect example
The antimicrobial laundry liquid obtained to embodiment 1 ~ 8 carries out detersive power and sterilizing ability test.
Detergency test:
The detergency test of antimicrobial laundry liquid sample carries out with reference to GB/T13174-2008 " mensuration of dress material washing composition detersive power and circulation cleaning performance ", experimental result shows, the ratio of antimicrobial laundry liquid to carbon black oil soiled cotton, albumen soiled cotton, sebum soiled cotton decontamination value and standard washing liquid decontamination value that embodiment 1 ~ 8 obtains is as shown in table 1.
The detergency ability test effect of table 1 antimicrobial laundry liquid
Antibacterial ability is tested:
The antibacterial ability test of antimicrobial laundry liquid sample is carried out with reference to QB/T2738-2012 " evaluation method of the antibacterial and fungistatic effect of daily chemical products ", activity 1:100,20 minutes action time, experimental result shows, embodiment 1 ~ 8 and the sterilizing rate of comparative example's all samples to intestinal bacteria ATCC25922 and staphylococcus glucose bacterium ATCC6538 as shown in table 2.
The anti-microbial property test effect of table 2 antimicrobial laundry liquid
Above-described embodiment is the present invention's preferably embodiment; but embodiments of the present invention are not restricted to the described embodiments; change, the modification done under other any does not deviate from spirit of the present invention and principle, substitute, combine, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (10)
1. an antimicrobial laundry liquid, is characterized in that comprising following component by mass percentage:
Described complex antimicrobials comprises nanometer silver and natural plant antiseptic-germicide.
2. antimicrobial laundry liquid according to claim 1, is characterized in that comprising following component by mass percentage:
3. antimicrobial laundry liquid according to claim 1 and 2, is characterized in that:
The mass ratio of described nanometer silver and natural plant antiseptic-germicide is (1:5) ~ (1:1).
4. antimicrobial laundry liquid according to claim 1 and 2, is characterized in that:
Described nanometer silver is at least one in monomer nano silver and complex state nanometer silver.
5. antimicrobial laundry liquid according to claim 1 and 2, is characterized in that:
Described natural plant antiseptic-germicide is at least one in Aloe extract and citron extract.
6. antimicrobial laundry liquid according to claim 1 and 2, is characterized in that:
Described anion surfactant is at least one in sodium alkyl benzene sulfonate, sodium alkyl sulfate, poly alkyl alcohol ether sodium sulfate, a-sodium olefin sulfonate and methyl sodiosul foaliphatate.
7. antimicrobial laundry liquid according to claim 1 and 2, is characterized in that:
Described nonionogenic tenside is at least one in fatty alcohol-polyoxyethylene ether, isomery alcohol polyoxyethylenated alcohol, fatty acid methyl ester ethoxylate, cocounut oil acyl diglycollic amide and APG.
8. antimicrobial laundry liquid according to claim 1 and 2, is characterized in that:
Described white dyes is double styrene-biphenyl type whitening agent and at least one in two triazinyl diphenyl ethylene derivatives.
9. the preparation method of the antimicrobial laundry liquid described in any one of claim 1 ~ 8, comprises following steps:
The component water of the antimicrobial laundry liquid described in any one of claim 1 ~ 8 is heated to 60 DEG C ~ 70 DEG C, add anion surfactant, nonionogenic tenside, white dyes and sequestrant, mixing rear pH value regulator adjust ph is 7.5 ~ 8.5, reduce temperature to 30 DEG C ~ 40 DEG C, add essence and complex antimicrobials mixes, obtain antimicrobial laundry liquid.
10. the application of the antimicrobial laundry liquid described in any one of claim 1 ~ 8 in household chemicals field.
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Application publication date: 20160511 |