CN1071376C - High-molecular active solid detergent composition and making method thereof - Google Patents
High-molecular active solid detergent composition and making method thereof Download PDFInfo
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- CN1071376C CN1071376C CN98100615A CN98100615A CN1071376C CN 1071376 C CN1071376 C CN 1071376C CN 98100615 A CN98100615 A CN 98100615A CN 98100615 A CN98100615 A CN 98100615A CN 1071376 C CN1071376 C CN 1071376C
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Abstract
The present invention relates to a high-molecular active solid detergent composition which is prepared by mixing active solid granules A and B prepared by different formulations according to a proportion of 2:1, and the high-molecular active solid detergent composition is filled in a container, wherein the granules are prepared by mixing high-molecular active substances which can be easily degraded with inorganic substances. The high-molecular active solid detergent composition is put in a laundry machine in use to make the active solid granules flow in water and continuously release active substances to change pH values of the water; simultaneously, dirt is wetted and emulsified to be separated from fabrics, and clothes washing effects can be achieved. The granular product of the present invention has the advantages of small use quantity (release) every time, repeated use for many times, no need of adding other synthetic detergents, easy bleaching and favorable environmental protection benefits.
Description
The present invention relates to a kind of high-molecular active solid detergent composition and manufacture method thereof, refer to a kind of active solid particle of making according to specific proportioning by macromolecular compound and mineral compound especially, be a kind of can reusable detergent composition.
Existing result of study confirms that the biological degradability of the main raw material sodium branched alkyl benzene sulfonate (ABS) in the synthetic detergent, linear alkylbenzene sulphonic acid (LAB) and sodium alkyl benzene sulfonate (SAS) is relatively poor, and especially ABS is difficult to realize biological degradation especially.When they are constantly entered in the rivers and lakes, promptly be one of root that forms red tide and other pollutions.In addition, produce for using synthetic detergent (washing powder) allergic, the blood cell index decreased, the case that women's hemopathy increases is quite a few.In washing machine fixed washing time, synthetic detergent (washing powder) dissolving is (perhaps excessive formation state of saturation) not exclusively, just have quite a few in the drainage procedure of washing machine, drained together with waste water, this part washing composition that does not play a role (washing powder) had both caused waste, also formed the pollution to water quality; Worldwide calculate, annual consumption synthetic detergent is with hundred million tons of calculating, and like this, a large amount of harmful chemical elements all forms source of pollution with waste water.
Traditional synthetic detergent, in light weight, volume is big, consumption is big, is all increasing social burden and pressure aspect packing, storage and the transportation.
At present, the seriousness of the problems referred to above is subjected to the attention of washing composition and environmental protection industry day by day, so some washing composition without phosphorus, low-phosphorous and concentrated or hyperconcentration all come out in succession.In recent years, it is raw material that Japan has also occurred with inorganic mineral (silicate), replaces the physics laundry product of washing composition, but because it can not clean dirt effectively, so embarrass people to accept.Inventor according to the said products claims, when using this kind product, must add the synthetic detergent (washing powder) of usual amounts 1/4 simultaneously, and the historical facts or anecdotes border will increase many troubles on the contrary when using, and its penetration and promotion ought more difficultly be reached.
Main purpose of the present invention is to provide a kind of high-molecular active solid detergent composition that is repeatedly used.
Another object of the present invention is to provide a kind of method of making above-mentioned high-molecular active solid detergent composition.
The said high-molecular active solid detergent composition of the present invention, mainly be with sodium lauryl sulfate, fatty alcohol-polyoxyethylene ether 9, Xylo-Mucine, ethylenediamine tetraacetic acid (EDTA), white dyes, metasilicate pentahydrate sodium, yellow soda ash, epoxy resin E-44, low molecule pa resin 6101, red iron oxide (iron oxide red), macromolecular compound such as zeolite and essence and mineral compound are raw material, prepare two kinds of active solid particles respectively with special formulation, by specified proportion it is loaded in mixture into a saturating empty receptacle again, insert in the washing machine during use, making the active solid particle form in water flows, and lasting release of active agent and change pH value in the water, simultaneously wetting, the emulsification dirt, make dirt break away from fabric, reach the clothing cleaning performance.
The composition of said two kinds of active solid particle A of the present invention and B and the weight percent of adding are as follows: A, (1), sodium lauryl sulfate (Sodium Laury Sulfate) 10～90%
(2), fatty alcohol-polyoxyethylene ether 9 (Fatty Alcohol Polyoxyethylene (9) Ether (AEO-9)) 1～17%
(3), Xylo-Mucine (CMC) 0.01～5%
(4), ethylenediamine tetraacetic acid (EDTA) (EDTA) 0.01～5%
(5), white dyes (Fluorescent Whitening Agent) 0.01～5%
(6), metasilicate pentahydrate sodium (Na
2SiO
3.5H
2O) 0.50～15%
(7), yellow soda ash (Na
2CO
3) 5～50%
(8), epoxy resin E-44 (Epoxy Resin) 0.50～20%
(9), low molecule pa resin 6101 (Polyamide Resin) 0.50～20%
(10), red iron oxide (Red Iron Oxide) 0.01～5%
(11), zeolite (Zeolite A) 0.01～30%
B:(1), sodium lauryl sulfate (Sodium Laury Sulfate) 8～80%
(2), fatty alcohol-polyoxyethylene ether 9 (Fatty Alcohol Polyoxyethylene (9) Ether (AEO-9)) 1～17%
(3), Xylo-Mucine (CMC) 0.01～5%
(4), ethylenediamine tetraacetic acid (EDTA) (EDTA) 0.01～5%
(5), white dyes (Fluorescent Whitening Agent) 0.01～5%
(6), metasilicate pentahydrate sodium (Na
2SiO
35H
2O) 0.50～15%
(7), yellow soda ash (Na
2CO
3) 5～50%
(8), epoxy resin E-44 (Epoxy Resin) 0.50～20%
(9), low molecule pa resin 6101 (Polyamide Resin) 0.50～20%
(10), zeolite (Zelite A) 0.01～30%
Above-mentioned solid particulate A and B load in mixture into a saturating empty receptacle with 2: 1 ratios, are composition product of the present invention.
Product of the present invention is made up of highly enriched active particle, and sodium lauryl sulfate is realized decontamination and washing as anion surfactant by wetting, emulsification, and wool, cotton, linen are had best washing effect; And the nonionogenic tenside fatty alcohol-polyoxyethylene ether is suitable for removing greasy dirt, sebum, sweat stain etc., also have the clean effect of highly significant during low temperature, two kinds of raw materials share, mix other auxiliary agents again, to have good laundry effect, and as highly enriched particulate product, insert washing machine and stir the use of flowing, making the active solid particle form in water flows, and lasting release of active agent and change pH value in the water, wetting, emulsification dirt makes dirt break away from fabric simultaneously, reaches the clothing cleaning performance.Each usage quantity (burst size) seldom can need not added other synthetic detergents fully for repeatedly using repeatedly, and rinsing is easy, and the fabric feeling after washing is good, need not to use softener.Product of the present invention at room temperature uses, and by 20 minutes (use in washing machine) of normal laundry, 45 gram products can be done washing about 60 times, to cotton, fiber crops, wool tool best effect.
Another characteristics of the present invention are being human body and environmentally friendly raw material of composite formula employing, as anion surfactant sodium lauryl sulfate and nonionogenic tenside fatty alcohol-polyoxyethylene ether, its biological degradability is all more than 90%, and do not contain hard-degraded substances such as sodium polyphosphate and Sodium peroxoborate in the product, each usage quantity (burst size) seldom, need not add other synthetic detergents (washing powder) during repeated use fully, can reduce blowdown, so can not cause contaminate environment and harm humans, has environmental benefit, and this active solid particulate volume is little, the convenient storage, need not take a large amount of storage areas and transport capacity, reduce social pressure widely yet, save human consumer's expenditure yet.
Two kinds of particulate making processes of product of the present invention are identical, finish as follows:
(1), with Xylo-Mucine, ethylenediamine tetraacetic acid (EDTA), white dyes, metasilicate pentahydrate sodium and yellow soda ash, separately by after the prescription weighing, promptly pour the mixed cylinder that band stirs into and stir evenly, and pour fatty alcohol-polyoxyethylene ether 9 into and impose and mix, pour sodium lauryl sulfate again into and mix;
(2), with epoxy resin E-44, low molecule pa resin 6101 and red iron oxide impose mix after, pour in said process (one's) the mixture again and give and stir evenly (active solid particle B is the redfree iron oxide composition then);
(3), pour above-mentioned mixed material into plodder, the uniform and smooth bar in surface is made in the press strip moulding;
(4), the bar of above-mentioned compression moulding is placed air-conditioned room, its envrionment temperature adjustment is set in about 25 ℃, and this bar is sent into make round particle in the nodulizer;
(5), above-mentioned round particle is put into temperature is that 70～80 ℃ baker is dried, take out until the particle hardening beginning;
(6), get an amount of essence and add to impose in the talcum powder (or lime carbonate) and rub with the hands evenly, and then again this powder is sprinkled in the particle, airtight being stored in the bucket can be treated for charging.
By above-mentioned specified mix and specific this made two kinds of active solid particle A and B of production stage thereof, bestow the mixing empty receptacle of packing in 2: 1 ratio in the when filling with substance particle.The saturating empty receptacle that two kinds of active solid particles like this are loaded can provide laundry to use.
The Anionic Active sodium lauryl sulfate that the present invention is used, purity can be 92%, when using the raw material of different purity, can determine its usage quantity by converting.
The bar of compression moulding is 25 ℃ of viscosity with the most suitable granulation, granulates with this understanding and can avoid in the pelletization sticking machine to greatest extent or produce a large amount of fines when granulating, and reaches optimum producting capacity.
The consumption of essence in two kinds of particles can be 0.5～10% (weight percent).
Used zeolite in the composition of raw materials of above-mentioned manufacturing processed, effect is the intensity that strengthens particle, cooperates with other component simultaneously, can strengthen the friction between particle and the water molecules, makes the easier impact spot of water molecules, with greasiness removal.The effect of red iron oxide is to improve granule strength and painted, distinguishes when being beneficial to packing, and makes particle have certain rigidity, the impact of water-fast stream.Two kinds of particulate prescriptions are different, and performance is also different, then can obtain ideal effect so mix to use.
Embodiment
Two kinds of particulate prescriptions following (weight %):
A, (1), sodium lauryl sulfate 40%
(2), fatty alcohol-polyoxyethylene ether 9 4%
(3), Xylo-Mucine 1.5%
(4), ethylenediamine tetraacetic acid (EDTA) 3%
(5), white dyes 1.5%
(6), metasilicate pentahydrate sodium 8%
(7), yellow soda ash 16%
(8), epoxy resin E-44 7%
(9), low molecule pa resin 6,101 10%
(10), red iron oxide 2%
(11), zeolite 7%
B:(1), sodium lauryl sulfate 25%
(2), fatty alcohol-polyoxyethylene ether 9 10%
(3), Xylo-Mucine 2.5%
(4), ethylenediamine tetraacetic acid (EDTA) 1%
(5), white dyes 1.5%
(6), metasilicate pentahydrate sodium 10%
(7), yellow soda ash 10%
(8), epoxy resin E-44 12%
(9), low molecule pa resin 6,101 15%
(10), zeolite 13%
Two kinds of particulate preparation process are identical, and promptly above-mentioned raw materials is made particle by following steps:
(1), with Xylo-Mucine, ethylenediamine tetraacetic acid (EDTA), white dyes, metasilicate pentahydrate sodium and yellow soda ash, separately by after the prescription weighing, promptly pour the mixed cylinder that band stirs into and stir evenly, and pour fatty alcohol-polyoxyethylene ether 9 into and impose and mix, pour sodium lauryl sulfate again into and mix;
(2), with epoxy resin E-44, low molecule pa resin 6101 and red iron oxide impose mix after, pour in said process (one's) the mixture again and give and stir evenly (active solid particle B is the redfree iron oxide composition then);
(3), pour above-mentioned mixed material into plodder, the uniform and smooth bar in surface is made in the press strip moulding;
(4), the bar of above-mentioned compression moulding is placed air-conditioned room, its envrionment temperature adjustment is set in about 25 ℃, and this bar is put into nodulizer make round particle;
(5), above-mentioned round particle is put into temperature is that 70～80 ℃ baker is dried, take out until the particle hardening beginning;
(6), get zeolite and an amount of essence and add to impose in the talcum powder (or lime carbonate) and rub with the hands evenly, the essence amount is 0.8% (weight percent) and then this powder is sprinkled in the particle again, airtight being stored in the bucket can be treated for charging.Two kinds of active solid particle A and B bestow the mixing empty receptacle of packing in 2: 1 ratio.
Claims (4)
1, a kind of high-molecular active solid detergent composition is characterized in that being formed with 2: 1 mixed by two kinds of active solid particle A that make with different ingredients and B, and the saturating empty receptacle of packing into;
The weight percent of said two kinds of active solid particulate compositions and adding is as follows:
A:(1), sodium lauryl sulfate 10～90%
(2), fatty alcohol-polyoxyethylene ether 9 1～17%
(3), Xylo-Mucine 0.01～5%
(4), ethylenediamine tetraacetic acid (EDTA) 0.01～5%
(5), white dyes 0.01～5%
(6), metasilicate pentahydrate sodium 0.50～15%
(7), yellow soda ash 5～50%
(8), epoxy resin E-44 0.50～20%
(9), low molecule pa resin 6,101 0.50～20%
(10), red iron oxide 0.01～5%
(11), zeolite 0.01～30%
B:(1), sodium lauryl sulfate 8～80%
(2), fatty alcohol-polyoxyethylene ether 9 1～17%
(3), Xylo-Mucine 0.01～5%
(4), ethylenediamine tetraacetic acid (EDTA) 0.01～5%
(5), white dyes 0.01～5%
(6), metasilicate pentahydrate sodium 0.50～15%
(7), yellow soda ash 5～50%
(8), epoxy resin E-44 0.50～20%
(9), low molecule pa resin 6,101 0.50～20%
(10), zeolite 0.01～30%.
2, high-molecular active solid detergent composition according to claim 1 is characterized in that the weight percent of the compositing formula of said two kinds of particle A and B and adding is as follows:
A, (1), sodium lauryl sulfate 40%
(2), fatty alcohol-polyoxyethylene ether 94%
(3), Xylo-Mucine 1.5%
(4), ethylenediamine tetraacetic acid (EDTA) 3%
(5), white dyes 1.5%
(6), metasilicate pentahydrate sodium 8%
(7), yellow soda ash 16%
(8), epoxy resin E-44 7%
(9), low molecule pa resin 6,101 10%
(10), red iron oxide 2%
(11), zeolite 7%
B:(1), sodium lauryl sulfate 25%
(2), fatty alcohol-polyoxyethylene ether 9 10%
(3), Xylo-Mucine 2.5%
(4), ethylenediamine tetraacetic acid (EDTA) 1%
(5), white dyes 1.5%
(6), metasilicate pentahydrate sodium 10%
(7), yellow soda ash 10%
(8), epoxy resin E-44 12%
(9), low molecule pa resin 6,101 15%
(10), zeolite 13%.
3, a kind of manufacture method of high-molecular active solid detergent composition as claimed in claim 1 is characterized in that preparing particle A and B respectively by following same steps as:
(1), with Xylo-Mucine, ethylenediamine tetraacetic acid (EDTA), white dyes, metasilicate pentahydrate sodium and yellow soda ash, separately by after the prescription weighing, promptly pour the mixed cylinder that band stirs into and stir evenly, and pour fatty alcohol-polyoxyethylene ether 9 into and impose and mix, pour sodium lauryl sulfate again into and mix;
(2), with epoxy resin E-44, low molecule pa resin 6101 and red iron oxide impose mix after, pour in said process (one's) the mixture again and give and stirring evenly, wherein active solid particle B redfree iron oxide composition;
(3), pour above-mentioned mixed material into plodder, impose the press strip moulding, make the uniform and smooth bar in surface;
(4), the bar of above-mentioned compression moulding is placed air-conditioned room, its envrionment temperature adjustment is set in about 25 ℃, and this bar is sent into make round particle in the nodulizer;
(5), above-mentioned round particle is put into temperature is that 70～80 ℃ baker is dried, take out until the particle hardening beginning;
(6), get zeolite and an amount of essence and add to impose in talcum powder or the lime carbonate and rub with the hands evenly, and then again this powder is sprinkled in the particle, airtight being stored in the bucket can be treated for charging.
Two kinds of active solid particle A and B bestow mixing and the empty receptacle of packing in 2: 1 ratio.
4, the manufacture method of high-molecular active solid detergent composition according to claim 3 when it is characterized in that making two kinds of particles, adds the essence of 0.5～10 weight % respectively.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98100615A CN1071376C (en) | 1998-02-13 | 1998-02-13 | High-molecular active solid detergent composition and making method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98100615A CN1071376C (en) | 1998-02-13 | 1998-02-13 | High-molecular active solid detergent composition and making method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1225940A CN1225940A (en) | 1999-08-18 |
| CN1071376C true CN1071376C (en) | 2001-09-19 |
Family
ID=5216135
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98100615A Expired - Fee Related CN1071376C (en) | 1998-02-13 | 1998-02-13 | High-molecular active solid detergent composition and making method thereof |
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| Country | Link |
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| CN (1) | CN1071376C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101457185B (en) * | 2008-12-23 | 2010-10-13 | 深圳市成为生物科技有限公司 | Environment friendly washing granule and preparation method thereof |
| CN101585608B (en) * | 2009-06-09 | 2011-06-01 | 深圳市成为生物科技有限公司 | Water quality softening ball and prepartion method thereof |
| CN102071112B (en) * | 2011-01-31 | 2012-07-04 | 北京凯迪威机电设备有限公司 | Stubborn stain decomposer |
| CN104450263A (en) * | 2014-12-04 | 2015-03-25 | 周莉莉 | Environment-friendly air conditioner detergent and preparation method thereof |
| KR102313268B1 (en) * | 2016-04-26 | 2021-10-19 | 바스프 에스이 | Thermoplastic Polyamide Particles |
| CN113136266A (en) * | 2021-04-30 | 2021-07-20 | 东莞市合信新材料有限公司 | Solid laundry detergent ball and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5949299A (en) * | 1982-09-14 | 1984-03-21 | 株式会社 サクラクレパス | Solid cleaner composition |
| CN1048726A (en) * | 1989-07-14 | 1991-01-23 | 徐云英 | Detergent for water closet |
| US5658870A (en) * | 1996-09-26 | 1997-08-19 | Leu; Shiow Jiuan Freida | Composition of super molecule active solid cleaning agent |
-
1998
- 1998-02-13 CN CN98100615A patent/CN1071376C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5949299A (en) * | 1982-09-14 | 1984-03-21 | 株式会社 サクラクレパス | Solid cleaner composition |
| CN1048726A (en) * | 1989-07-14 | 1991-01-23 | 徐云英 | Detergent for water closet |
| US5658870A (en) * | 1996-09-26 | 1997-08-19 | Leu; Shiow Jiuan Freida | Composition of super molecule active solid cleaning agent |
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| Publication number | Publication date |
|---|---|
| CN1225940A (en) | 1999-08-18 |
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