CN105754737A - Concentrated laundry liquid for water-soluble membrane packaging and preparing method thereof - Google Patents
Concentrated laundry liquid for water-soluble membrane packaging and preparing method thereof Download PDFInfo
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- CN105754737A CN105754737A CN201410791952.XA CN201410791952A CN105754737A CN 105754737 A CN105754737 A CN 105754737A CN 201410791952 A CN201410791952 A CN 201410791952A CN 105754737 A CN105754737 A CN 105754737A
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- aliphatic alcohol
- alcohol polyethenoxy
- ether
- liquid detergent
- water
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Abstract
The invention belongs to the field of washing agent compositions, and particularly relates to concentrated laundry liquid for water-soluble membrane packaging and a preparing method thereof. Raw materials of the concentrated laundry liquid comprise methyl ester ethoxylate, fatty alcohol polyoxyethylene (2) ether sodium sulphate, a nonionic surfactant, 1,2-benzisothiazolin-3-one, glycerol, polyethylene glycol, propylene carbonate and essence. The concentrated laundry liquid prepared through the method is free of damage to water-soluble membranes, good in water solubility, low in foam, easy to rinse, and highly concentrated. The content of effective components of the concentrated laundry liquid is 4-5 times of the content of effective components of common laundry liquid. Preparation of the concentrated laundry liquid is simple, and a preparing process does not need heating.
Description
Technical field
The invention belongs to composition of detergent field, particularly to a kind of concentration liquid detergent for water-solubility membrane packaging and preparation method thereof.
Background technology
For household washing articles for use, the appearance of multiple package metro-measuring mode has not been any strange thing.The consumption of detergent directly affects clean result, and the slurry of different hardness, different types of dirt and medicated clothing decide the optimum amount of detergent used.In recent years, laundry tablets, the solidifying pearl of laundry listed at country variant gradually, it is thus achieved that certain success, brought facility for consumer, also proposed new requirement for detergent research staff simultaneously.
The liquid detergent of water-solubility membrane packaging is the liquid detergent of a kind of new packaged form, liquid detergent is packaged in PV water-solubility membrane, with the feature of " accurately the washing " and " highly enriched " of himself uniqueness, add the novel package of its environmental protection, will commercially occupy the manor of oneself.Conventional PVA water-soluble plastic thin film be a kind of through special process processing, the novel environment friendly packaging material that natural cause be degraded rapidly can be passed through, it can pass through natural cause (H2O) effect, degeneration voluntarily rapidly, decomposes, is degraded to low molecular compound.The liquid detergent using PVA water soluble film packaging has certain particular/special requirement compared with ordinary liquid laundry detergent, moisture in liquid detergent and concentration there is certain restriction, generally requiring the moisture lower than 5% and higher concentration, at present, the water-solubility membrane liquid detergent being commercially available is many based on 2 times of concentrations.
Summary of the invention
It is an object of the invention to provide a kind of concentration liquid detergent for water-solubility membrane and preparation method thereof；Water-solubility membrane is not damaged by this detergent, good water solubility, high enrichment, strong detergency, and foam is low, easily rinses.
It is an object of the invention to be achieved through the following technical solutions:
A kind of concentration liquid detergent for water-solubility membrane packaging, the raw material of described concentration liquid detergent includes: FMEE, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic surfactant, 1,2-benzisothiazole-3-ketone, glycerol, Polyethylene Glycol, Allyl carbonate and essence, the ratio of weight and number of described each raw material is:
FMEE 10 ~ 20
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 3～5
Nonionic surfactant 45～60
BIT 0.1～0.3
Glycerol 1～5
Polyethylene Glycol 5 ~ 10
Allyl carbonate 10 ~ 25
Essence 0.2～0.4.
Further, described nonionic surfactant is one or more mixing in aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether.
It is another object of the present invention to be achieved through the following technical solutions:
A kind of preparation method of the concentration liquid detergent for water-solubility membrane packaging, the raw material of described concentration liquid detergent includes: FMEE, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic surfactant, 1,2-benzisothiazole-3-ketone, glycerol, Polyethylene Glycol, Allyl carbonate and essence, the ratio of weight and number of described each raw material is:
FMEE 10 ~ 20
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 3～5
Nonionic surfactant 45～60
BIT 0.1～0.3
Glycerol 1～5；
Polyethylene Glycol 5 ~ 10
Allyl carbonate 10 ~ 25
Essence 0.2～0.4；
Preparation process is:
A, take described Polyethylene Glycol according to above-mentioned weight proportion, glycerol, Allyl carbonate add in material still, then it is sequentially added into described FMEE, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic surfactant to being completely dissolved according to said ratio respectively, obtains mixed liquor A；
B, then it is sequentially added into BIT, essence according to said ratio respectively, obtains mixed liquid B；
C, by above-mentioned mixed liquid B, with 200 order filter-cloth filterings process, obtain described concentration liquid detergent.
The present invention has the advantages that compared to existing technology
1) present invention is in the preparation, it is not necessary to heating, operable under room temperature.
2) present invention is Concentrated formulations so that under extremely low concentration, reaches washing standard-required, and the rinsing few, easy of good water solubility, foam, nontoxic non-stimulated；Effective content of the present invention is higher than 4-5 times of conventional detergent.
3) present invention is Concentrated formulations, can economize in raw materials and packing cost, and production and transport cost is beneficial to energy-saving and cost-reducing；The present invention more has its advantage on economizing on resources, it is possible to the production cost of saving more than 1/3rd, packing cost, cost of transportation, the purchase cost of such consumer also can be greatly reduced, and has higher economic benefit and social benefit.
4) present invention can be used for water-solubility membrane packaging, and prompt band is convenient, easy to use, consumption is more economized.
Detailed description of the invention
Embodiment 1
A kind of concentration liquid detergent for water-solubility membrane packaging, the raw material of described concentration liquid detergent includes: FMEE, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic surfactant, 1,2-benzisothiazole-3-ketone, glycerol, Polyethylene Glycol, Allyl carbonate and essence, the ratio of weight and number of described each raw material is:
FMEE 10 ~ 20
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 3～5
Nonionic surfactant 45～60
BIT 0.1～0.3
Glycerol 1～5
Polyethylene Glycol 5 ~ 10
Allyl carbonate 10 ~ 25
Essence 0.2～0.4；
Described nonionic surfactant is one or more mixing in aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether.
Unit of weight used by the present embodiment is gram, it is also possible to for kilogram；
Each raw material described in the present embodiment is technical grade；
Each raw material described in the present embodiment be on market sell conventional products；
In the present embodiment, each raw material in described can in the ratio range provided flexible combination, do not enumerate one by one at this.
The concrete preparation method of the present embodiment concentration liquid detergent is:
A, take described Polyethylene Glycol according to above-mentioned weight proportion, glycerol, Allyl carbonate add in material still, then it is sequentially added into described FMEE, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic surfactant to being completely dissolved according to said ratio respectively, obtains mixed liquor A；
B, then it is sequentially added into BIT, essence according to said ratio respectively, obtains mixed liquid B；
C, by above-mentioned mixed liquid B, filtration treatment, obtain described concentration liquid detergent.
In whole production technology, simple to operate, cold join.First solvent is added in still, it is simple to various surfactants dissolve mixing quickly.In above-mentioned process for preparation, it should be noted that whole clean operation environment health, dust-proof.
Product of the present invention, after diluting 5 times, clean effect reaches the requirement of GB/T13174-2008.
Embodiment 2
The present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the ratio of weight and number of each raw material of this concentration liquid detergent is:
FMEE 15
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 3
Aliphatic alcohol polyethenoxy (3) ether 35
Aliphatic alcohol polyethenoxy (7) ether 15
BIT 0.2
Glycerol 5
Polyethylene Glycol 6.5
Allyl carbonate 20
Essence 0.3；
Unit of weight used by the present embodiment is gram, it is also possible to for kilogram；
The preparation method of the concentration liquid detergent of this example is referring to embodiment 1.
Product of the present invention, after diluting 5 times, clean effect reaches the requirement of GB/T13174-2008.
Embodiment 3
The present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the ratio of weight and number of each raw material of this concentration liquid detergent is:
FMEE 10
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 5
Aliphatic alcohol polyethenoxy (3) ether 40
Aliphatic alcohol polyethenoxy (7) ether 15
Aliphatic alcohol polyethenoxy (9) ether 5
BIT 0.2
Glycerol 5
Polyethylene Glycol 5
Allyl carbonate 14.5
Essence 0.3；
Unit of weight used by the present embodiment is gram, it is also possible to for kilogram；
The preparation method of the concentration liquid detergent of this example is referring to embodiment 1.
Product of the present invention, after diluting 5 times, clean effect reaches the requirement of GB/T13174-2008.
Embodiment 4
The present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the ratio of weight and number of each raw material of this concentration liquid detergent is:
FMEE 10
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 5
Aliphatic alcohol polyethenoxy (3) ether 30
Aliphatic alcohol polyethenoxy (7) ether 15
BIT 0.3
Glycerol 5
Polyethylene Glycol 10
Allyl carbonate 24.5
Essence 0.2；
Unit of weight used by the present embodiment is gram, it is also possible to for kilogram；
The preparation method of the concentration liquid detergent of this example is referring to embodiment 1.
Product of the present invention, after diluting 5 times, clean effect reaches the requirement of GB/T13174-2008.
Embodiment 5
The present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the ratio of weight and number of each raw material of this concentration liquid detergent is:
FMEE 10
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 5
Aliphatic alcohol polyethenoxy (3) ether 35
Aliphatic alcohol polyethenoxy (7) ether 15
BIT 0.3
Glycerol 5
Polyethylene Glycol 10
Allyl carbonate 19.5
Essence 0.2；
Unit of weight used by the present embodiment is gram, it is also possible to for kilogram；
The preparation method of the concentration liquid detergent of this example is referring to embodiment 1.
Product of the present invention, after diluting 5 times, clean effect reaches the requirement of GB/T13174-2008.
Claims (7)
1. the concentration liquid detergent for water-solubility membrane packaging, it is characterized in that: the raw material of described concentration liquid detergent includes: FMEE, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic surfactant, 1,2-benzisothiazole-3-ketone, glycerol, Polyethylene Glycol, Allyl carbonate and essence, the ratio of weight and number of described each raw material is:
FMEE 10～20
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 3～5
Nonionic surfactant 45～60
BIT 0.1～0.3
Glycerol 1～5
Polyethylene Glycol 5～10
Allyl carbonate 10～25
Essence 0.2～0.4.
2. the concentration liquid detergent for water-solubility membrane packaging according to claim 1, it is characterised in that: described nonionic surfactant is one or more mixing in aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether.
3. the concentration liquid detergent for water-solubility membrane packaging according to claim 2, it is characterised in that: the ratio of weight and number of described each raw material is:
FMEE 15
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 3
Aliphatic alcohol polyethenoxy (3) ether 35
Aliphatic alcohol polyethenoxy (7) ether 15
BIT 0.2
Glycerol 5
Polyethylene Glycol 6.5
Allyl carbonate 20
Essence 0.3.
4. the concentration liquid detergent for water-solubility membrane packaging according to claim 2, it is characterised in that: the ratio of weight and number of described each raw material is:
FMEE 10
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 5
Aliphatic alcohol polyethenoxy (3) ether 40
Aliphatic alcohol polyethenoxy (7) ether 15
Aliphatic alcohol polyethenoxy (9) ether 5
BIT 0.2
Glycerol 5
Polyethylene Glycol 5
Allyl carbonate 14.5
Essence 0.3.
5. the concentration liquid detergent for water-solubility membrane packaging according to claim 2, it is characterised in that: the ratio of weight and number of described each raw material is:
FMEE 10
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 5
Aliphatic alcohol polyethenoxy (3) ether 30
Aliphatic alcohol polyethenoxy (7) ether 15
BIT 0.3
Glycerol 5
Polyethylene Glycol 10
Allyl carbonate 24.5
Essence 0.2.
6. the concentration liquid detergent for water-solubility membrane packaging according to claim 2, it is characterised in that: the ratio of weight and number of described each raw material is:
FMEE 10
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 5
Aliphatic alcohol polyethenoxy (3) ether 35
Aliphatic alcohol polyethenoxy (7) ether 15
BIT 0.3
Glycerol 5
Polyethylene Glycol 10
Allyl carbonate 19.5
Essence 0.2.
7. the preparation method for the concentration liquid detergent of water-solubility membrane packaging, it is characterized in that: the raw material of described concentration liquid detergent includes: FMEE, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic surfactant, 1,2-benzisothiazole-3-ketone, glycerol, Polyethylene Glycol, Allyl carbonate and essence, the ratio of weight and number of described each raw material is:
FMEE 10～20
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 3～5
Nonionic surfactant 45～60
BIT 0.1～0.3
Glycerol 1～5
Polyethylene Glycol 5～10
Allyl carbonate 10～25
Essence 0.2～0.4；
Described preparation method comprises the following steps:
A. take described Polyethylene Glycol according to above-mentioned weight proportion, glycerol, Allyl carbonate add in material still, then it is sequentially added into described FMEE, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic surfactant to being completely dissolved according to said ratio respectively, obtains mixed liquor A；
B. then it is sequentially added into BIT, essence according in said ratio first described mixed liquor A respectively, obtains mixed liquid B；
C. by above-mentioned mixed liquid B, process with 200 order filter-cloth filterings, obtain described concentration liquid detergent.
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| CN201410791952.XA CN105754737B (en) | 2014-12-19 | 2014-12-19 | A kind of concentration liquid detergent and preparation method thereof for water-solubility membrane packaging |
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|---|---|---|---|
| CN201410791952.XA CN105754737B (en) | 2014-12-19 | 2014-12-19 | A kind of concentration liquid detergent and preparation method thereof for water-solubility membrane packaging |
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| CN105754737A true CN105754737A (en) | 2016-07-13 |
| CN105754737B CN105754737B (en) | 2019-03-01 |
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5427697A (en) * | 1993-12-17 | 1995-06-27 | The Procter & Gamble Company | Clear or translucent, concentrated fabric softener compositions |
| WO1999066016A1 (en) * | 1998-06-12 | 1999-12-23 | Henkel Kommanditgesellschaft Auf Aktien | Use of 1,3-dioxolane-2-ones in detergents |
| CN102159692A (en) * | 2008-08-14 | 2011-08-17 | 麦莱琉卡有限公司 | Ultra concentrated liquid laundry detergent |
| CN102186962A (en) * | 2008-10-15 | 2011-09-14 | 方法产品有限公司 | Liquid cleaning compositions |
| CN102242022A (en) * | 2011-06-15 | 2011-11-16 | 于文 | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof |
| CN102618398A (en) * | 2012-02-15 | 2012-08-01 | 中国日用化学工业研究院 | Concentrated fabric liquid detergent containing fatty acid methyl ester sulfonate and preparation method of concentrated fabric liquid detergent |
| CN102643725A (en) * | 2012-04-25 | 2012-08-22 | 中国日用化学工业研究院 | Hyper-concentrated liquid detergent and preparation technique thereof |
| CN103298920A (en) * | 2011-01-12 | 2013-09-11 | 宝洁公司 | Method for controlling the plasticization of a water soluble film |
-
2014
- 2014-12-19 CN CN201410791952.XA patent/CN105754737B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5427697A (en) * | 1993-12-17 | 1995-06-27 | The Procter & Gamble Company | Clear or translucent, concentrated fabric softener compositions |
| WO1999066016A1 (en) * | 1998-06-12 | 1999-12-23 | Henkel Kommanditgesellschaft Auf Aktien | Use of 1,3-dioxolane-2-ones in detergents |
| CN102159692A (en) * | 2008-08-14 | 2011-08-17 | 麦莱琉卡有限公司 | Ultra concentrated liquid laundry detergent |
| CN102186962A (en) * | 2008-10-15 | 2011-09-14 | 方法产品有限公司 | Liquid cleaning compositions |
| CN103298920A (en) * | 2011-01-12 | 2013-09-11 | 宝洁公司 | Method for controlling the plasticization of a water soluble film |
| CN102242022A (en) * | 2011-06-15 | 2011-11-16 | 于文 | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof |
| CN102618398A (en) * | 2012-02-15 | 2012-08-01 | 中国日用化学工业研究院 | Concentrated fabric liquid detergent containing fatty acid methyl ester sulfonate and preparation method of concentrated fabric liquid detergent |
| CN102643725A (en) * | 2012-04-25 | 2012-08-22 | 中国日用化学工业研究院 | Hyper-concentrated liquid detergent and preparation technique thereof |
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Address after: 100094 block B, building 1, yard 2, Yongcheng North Road, Yongfeng Industrial base, Haidian District, Beijing Patentee after: Beijing green umbrella Technology Co., Ltd Address before: 100094 block B, building 1, yard 2, Yongcheng North Road, Yongfeng Science Park, Haidian District, Beijing Patentee before: Beijing lvsan Chemical Co., Ltd |
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