CN106047522A - Hyperconcentration anhydrous laundry detergent as well as preparation method and laundry beads thereof - Google Patents
Hyperconcentration anhydrous laundry detergent as well as preparation method and laundry beads thereof Download PDFInfo
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- CN106047522A CN106047522A CN201610503126.XA CN201610503126A CN106047522A CN 106047522 A CN106047522 A CN 106047522A CN 201610503126 A CN201610503126 A CN 201610503126A CN 106047522 A CN106047522 A CN 106047522A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/8305—Mixtures of non-ionic with anionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/043—Liquid or thixotropic (gel) compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
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Abstract
The invention discloses a hyperconcentration anhydrous laundry detergent as well as a preparation method and laundry beads thereof. The hyperconcentration anhydrous laundry detergent comprises the following components in parts by mass: 1 part of cardanol polyoxyethylene ether, 0.2-1.0 part of coconut diethanol amide, 0.2-1.0 part of AES, 0.2-1.0 part of AEO-10 and 1.0-2.0 parts of polyethylene glycol. In the invention, the cardanol polyoxyethylene ether, coconut diethanol amide, AES and AEO-10 are used as main active ingredients, and the surfactants have good compatibility; meanwhile, by adopting the polyethylene glycol with washing performance as a solvent, the washing performance of the hyperconcentration anhydrous laundry detergent is further improved; the adopted surfactants are plant-based green surfactants or polyether natural product derivatives which are nontoxic to human and livestock and pollution-free to the environment and have good biological compatibility; moreover, the hyperconcentration anhydrous laundry detergent is easy to transport and store, and the transport cost is greatly reduced.
Description
Technical field
The present invention relates to a kind of daily detergent, be specifically related to a kind of anhydrous liquid detergent of ultra concentration type and preparation method thereof and
The solidifying pearl of laundry.
Background technology
Along with integration and the development of trade globalization of World Economics, culture give strength, technical merit and environmental regulation by
Gradually becoming three large driving forces of articles for washing development of globalization, the articles for washing in the whole world would tend to variation, but energy-conservation, joint
Water, efficient, gentle, easy to use and to meet the product of safety and environmental requirement will be the development of current and following cleaning product
Main flow direction.
Due to containing the brightest without the filler unit of any cleaning function in traditional detergent (including non-phosphide detergent)
Powder, its mass fraction >=40%, in terms of resource and the energy, all cause waste greatly, the most also can cause powder
Dustiness contaminates, and is unfavorable for environmental conservation.
Liquid detergent instead of Matrii Sulfas Exsiccatus with aboundresources and inexpensive water, and uses biodegradable surfactant to make
For main component and be aided with that phosphorus-free adjuvant is compounding to be formed.Owing to possessing, equipment investment is few, production technology is easy, performance is gentle stingless
Swashing, be prone to dissolve and the feature such as easy to use, liquid detergent is gradually accepted by people.
The water content of general liquid detergent is 80～90%, in order to pursue higher clean power, reduction cost of transportation, reduce and wash
Clothing liquid usage amount, market occurs in that substantial amounts of concentrated type laundry liquid product, also occurs in that some anhydrous laundry liquid product simultaneously.
As the Chinese invention patent application of Publication No. CN 104818167 A discloses a kind of anhydrous liquid detergent, with percentage by weight
Meter, this anhydrous liquid detergent includes: polyoxyethylenated alcohol sodium sulfate 8～12%, nonionic surfactant 16～24%,
Fatty acid potassium soap 2～6%, enzyme 0.1～0.5%, anhydrous citric acid sodium 0.1～0.3%, essence 0.1～0.5%, preservative
0.02～0.12%, pigment 0.03～0.14%, solvent 57～73%.Wherein, described nonionic surfactant is fat
At least one in acid FMEE, aliphatic alcohol polyethenoxy (9) ether and aliphatic alcohol polyethenoxy (7) ether.
This anhydrous liquid detergent is disadvantageous in that: (1) its active component (polyoxyethylenated alcohol sodium sulfate, non-from
Subtype surfactant, fatty acid potassium soap) content is between 26～42%, and the content of active component is still the highest, solvent
Higher, cost of transportation is the highest；
(2) containing fatty acid methyl ester ethoxylate in its nonionic surfactant used, and fatty acid methyl ester
One of raw material of ethoxylate fatty acid methyl ester does not contains active hydrogen, it is difficult to ethoxylation occurs, at fatty acid methyl ester
In the production process of ethoxylate, the production technology that major part manufacturer uses is to use water as raising ethoxylation productivity
Solvent, therefore the product of technical grade all contains more moisture, it is impossible to obtain the fatty acid methyl ester ethoxylate of high-load,
High purity product can only be obtained by low-pressure distillation, as reagent grade (medicine analysis is pure) can accomplish the content of more than 99%,
This not only substantially increases the production cost of fatty acid methyl ester ethoxylate, also substantially increases the production of this anhydrous liquid detergent
Cost；
(3) fatty acid methyl ester ethoxylate returns back out existing phenomenon muddy, opaque at low ambient temperatures, thus affects anhydrous
Liquid detergent detergency ability at low ambient temperatures.
Summary of the invention
The invention provides a kind of anhydrous liquid detergent of ultra concentration type, solve active component in the anhydrous liquid detergent of prior art
The problem that low, production cost is high.
A kind of anhydrous liquid detergent of ultra concentration type, according to the mass fraction, including:
The present invention is with cardanol polyoxyethylene ether, cocoanut fatty acid diethanolamide, fatty alcohol-polyoxyethylene ether sulphuric acid
Sodium and fatty alcohol-polyoxyethylene ether, as main active, the most also use the Polyethylene Glycol conduct equally with scourability
Solvent, in the case of Polyethylene Glycol is only used as solvent, the content minimum 44%, up to more than 80% of active component,
Active component content is high, has good compatibility between each component, and Polyethylene Glycol, not only as solvent but also as active component, enters
One step improves the scourability of the anhydrous liquid detergent of ultra concentration type of the present invention so that the anhydrous liquid detergent of ultra concentration type of the present invention is prone to fortune
Defeated with store, greatly reduce cost of transportation.
The present invention is using cardanol polyoxyethylene ether and cocoanut fatty acid diethanolamide as main nonionic table
Face activating agent, both nonionic surfactant are all plant base green surfactants, not only have excellent chemistry
Character, and nontoxic to human body, domestic animal, the mankind are relied in the environmental nonpollution of existence, the bio-compatibility of its emission
Good, can quickly be biodegradable.
Wherein, cardanol polyoxyethylene ether is the straight chained alkyl phenol polyethenoxy ether with Cardanol as raw material production, not only
Production cost is low, yield is high, and Cardanol is a kind of natural phenol of reproducible environment-friendly type, can substitute or part substitutes benzene
Phenol；One of raw material of cocoanut fatty acid diethanolamide is also natural Oleum Cocois, can substitute alkyl quaternaries sun from
Sub-surface activating agent；It is thus possible on the premise of ensureing heavy duty wash performance, it is to avoid use conventional petroleum based raw material to be produced
Environmental pollution, human body zest problem.
Further, polyoxyethylenated alcohol sodium sulfate and fatty alcohol-polyoxyethylene ether be polyethers natural product derive
Thing, the advantage being likewise supplied with easily biological-degradable and non-environmental-pollution.
Owing to cardanol polyoxyethylene ether, fatty alcohol-polyoxyethylene ether and fatty alcohol-polyoxyethylene ether are nonionic
Surfactant, and polyoxyethylenated alcohol sodium sulfate is anionic surfactant, two class surfactants are in water
Dissolubility differ greatly.In order to ensure that the anhydrous liquid detergent system of the present invention is homogeneous, balance, stable, as preferably, described waist
Really the hydrophile-lipophile balance value (HLB value) of phenol polyethenoxy ether is 9～25；As preferably, described fatty alcohol-polyoxyethylene ether is
Fatty alcohol-polyoxyethylene ether AEO-7, AEO-9, AEO-10, AEO-15 or AEO-20；As preferably, described coco-nut oil fatty acid two
Glycollic amide is cocoanut fatty acid diethanolamide 6501,6502 or 6503.
As preferably, described Polyethylene Glycol is Polyethylene Glycol 100, polyethylene glycol 200, PEG400, Polyethylene Glycol
600 or polyethylene glycol-800；More preferably PEG400.
As preferably, according to the mass fraction, the described anhydrous liquid detergent of ultra concentration type includes:
Under this proportioning, the active component of the anhydrous liquid detergent of ultra concentration type is high, the compatibility between each component more preferably, system
Stable, more preferably, shelf life of products is longer for scourability.
As preferably, according to the mass fraction, the described anhydrous liquid detergent of ultra concentration type also includes:
As further preferably, according to the mass fraction, the described anhydrous liquid detergent of ultra concentration type also includes:
Wherein, there was added of antistatic additive is beneficial to the medicated clothing after making washing and keeps fluffy, is not likely to produce electrostatic.Hard water resistance dose
There was added beneficially chelating water in calcium ions and magnesium ions, prevent calcium ions and magnesium ions from affecting the scourability of liquid detergent.Alkaline protease
There was added and beneficially improve the anhydrous liquid detergent of ultra concentration type of the present invention to the clean result of protein stain on medicated clothing.
As preferably, according to the mass fraction, the anhydrous liquid detergent of ultra concentration type of the present invention includes:
Under this formula, the active component content of the anhydrous liquid detergent of ultra concentration type of the present invention is up to 88%, washing performance
Can reach optimal.
As preferably, described antistatic additive is at least one in oleic acid, Petiolus Trachycarpi oil and lauric acid.Used in the present invention
Antistatic additive is natural product composition, and bio-compatibility is good, injury non-stimulated to human body.
As further preferably, described antistatic additive is oleic acid.Oleic acid, in addition to as antistatic additive, is also equipped with certain
Scourability, it is possible to increase the clean result of liquid detergent.
As preferably, described hard water resistance dose be in anhydrous citric acid sodium, citric acid and disodiumedetate at least
A kind of.
As further preferably, described hard water resistance dose is anhydrous citric acid sodium.Anhydrous citric acid sodium not only excellent performance, and
And as a kind of natural product composition, there is excellent bio-compatibility.
As preferably, described preservative is at least one in Kazon, germall and matrine.
As further preferably, described preservative is matrine.
Present invention also offers the preparation method of a kind of described anhydrous liquid detergent of ultra concentration type, this preparation method includes:
(1) under room temperature, by preset mass fraction, by cardanol polyoxyethylene ether, cocoanut fatty acid diethanolamide,
Polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether and antistatic additive are dissolved in Polyethylene Glycol, and stirring is to the most molten
25～80 DEG C it are slowly heated to, it is thus achieved that thickness settled solution I after solution；
Be heated to 25～80 DEG C be in order to improve hard water resistance dose of follow-up addition (anhydrous citric acid sodium), alkaline protease,
Preservative and the dissolution velocity of pigment, the solution temperature of these materials, between 0～100 DEG C, does not the most heat and also is able to delay
Slow dissolving.Preferably, optimal solution temperature is 60 DEG C.At such a temperature, each material can rapid solution, also can prevent alkalescence
There is degeneration at relatively high temperatures in protease.
(2) by preset mass fraction, add in described thickness settled solution I hard water resistance dose, preservative, basic protein
Enzyme and pigment, stir at 25～80 DEG C and be cooled to room temperature after being completely dissolved, add essence, stirs to solution clarification, it is thus achieved that
Settled solution II；
(3) in described settled solution II, deicer, dried sucking filtration, it is thus achieved that described ultra concentration type is without water washing are added
Liquid.
The addition of deicer desirably prevents a small amount of moisture carried in raw material or a small amount of water brought in preparation process
Dividing the performance affecting final products, deicer is dried about 1h after adding can completely remove the moisture in product, after being dried
Sucking filtration removes deicer.
As preferably, described deicer is anhydrous sodium sulfate, anhydrous magnesium sulfate, molecular sieve or silica gel.More preferably molecule
Sieve.
As preferably, according to the mass fraction, the addition of described deicer is 0.05～0.5 part, more preferably 0.1～
0.3 part, most preferably 0.2 part.
Present invention also offers the solidifying pearl of a kind of laundry, this laundry is coagulated pearl and is included water soluble film layer and sealed by described water soluble film layer
The liquid detergent of parcel, described liquid detergent is the anhydrous liquid detergent of ultra concentration type of the present invention.
Compared with prior art, the invention have the benefit that
(1) present invention is with cardanol polyoxyethylene ether, cocoanut fatty acid diethanolamide, fatty alcohol-polyoxyethylene ether sulfur
Acid sodium and fatty alcohol-polyoxyethylene ether are as main active, wherein, and cardanol polyoxyethylene ether and coco-nut oil fatty acid two
Glycollic amide is all plant base green surfactant, not only has excellent chemical property, and to human body, the nontoxic nothing of domestic animal
The mankind are relied in the environmental nonpollution of existence by evil, and the bio-compatibility of its emission is good, can quickly be biodegradable, fatty alcohol
Polyethenoxy ether sodium sulfate and fatty alcohol-polyoxyethylene ether are polyethers natural product derivant, are likewise supplied with easily biological-degradable
Advantage with non-environmental-pollution；
(2) between each surfactant used in the present invention, there is good compatibility, the most also use and have equally
The Polyethylene Glycol of scourability, as solvent, improves the scourability of the anhydrous liquid detergent of ultra concentration type of the present invention further so that
The anhydrous liquid detergent of ultra concentration type of the present invention is prone to transport and stores, and greatly reduces cost of transportation；
(3) according to GB QB/T1224-2012 " dress material washes agent by liquid " to the ultra concentration type of the present invention without water washing
Liquid carries out quality testing, and indices all meets the requirements, and wherein, gross activity thing accounting 88%, pH6.8, total phosphorus pentoxide accounts for
Ratio is less than 0.1%, at high temperature ((40 ± 2) DEG C, recover to room temperature after 24h), low temperature ((-5 ± 2) DEG C, recover to room temperature after 24h)
It is respectively provided with good stability under environment, is 0 in standard liquid detergent test concentrations, 2%, before sample test concentration is 0.1%
Putting and carry out detergency detection, the detergency of the anhydrous liquid detergent of ultra concentration type of the present invention is all higher than standard liquid detergent, detergency
Up to 1.7 times of standard liquid detergent.
Detailed description of the invention
Use detailed description of the invention that technical scheme is described in further detail below.
Embodiment 1
The present embodiment one anhydrous liquid detergent of ultra concentration type, its preparation method includes:
(1) under room temperature, by 100.0g cardanol polyoxyethylene ether (HLB is 18), 30.0g coco-nut oil fatty acid diethanol acyl
Amine (6501), 30.0g polyoxyethylenated alcohol sodium sulfate (AES), 45.0g fatty alcohol-polyoxyethylene ether (AEO-10) and 5.0g
Oleic acid is dissolved in 150mL PEG400, and stirring, to being completely dissolved, is heated slowly to 60 DEG C, obtains thickness settled solution I；
(2) in gained thickness settled solution I, anhydrous citric acid sodium 15.0g, alkaline protease 20.0g, matrine are added
2.5g and pigment light blue 0.36g, solution temperature is maintained at 60 DEG C, stirs after dissolving to solid, and stirring is cooled to room temperature, adds Cape jasmine
Sub-extrait 20.0g, stirs and clarifies to liquid, obtain settled solution II；
(3) in gained settled solution II, add molecular sieve 20.0g, be dried 1.0h, sucking filtration, obtain the ultra concentration of the present embodiment
Type anhydrous liquid detergent 401.2g.
Embodiment 2
The present embodiment one anhydrous liquid detergent of ultra concentration type, its preparation method includes:
(1) under room temperature, by 100.0g cardanol polyoxyethylene ether (HLB is 20), 20.0g coco-nut oil fatty acid diethanol acyl
Amine (6501), 100.0g polyoxyethylenated alcohol sodium sulfate (AES), 20.0g fatty alcohol-polyoxyethylene ether (AEO-20) and
2.0g Petiolus Trachycarpi oil is dissolved in 100mL Polyethylene Glycol 100, and stirring, to being completely dissolved, is heated slowly to 60 DEG C, obtains thickness settled solution
Ⅰ；
(2) in gained thickness settled solution I, citric acid 10.0g, alkaline protease 30.0g, Kazon 1.0g and color are added
Element light blue 0.1g, solution temperature is maintained at 60 DEG C, stirs after dissolving to solid, and stirring is cooled to room temperature, adds jasmine flower essence
8.0g, stirs and clarifies to liquid, obtain settled solution II；
(3) in gained settled solution II, add anhydrous sodium sulfate 10.0g, be dried 1.0h, sucking filtration, obtain the super of the present embodiment
Concentrated type anhydrous liquid detergent 386.1g.
Embodiment 3
The present embodiment one anhydrous liquid detergent of ultra concentration type, its preparation method includes:
(1) under room temperature, by 100.0g cardanol polyoxyethylene ether (HLB is 9), 80.0g coco-nut oil fatty acid diethanol acyl
Amine (6502), 30.0g polyoxyethylenated alcohol sodium sulfate (AES), 50.0g fatty alcohol-polyoxyethylene ether (AEO-9) and 6.0g
Lauric acid is dissolved in 180mL polyethylene glycol 200, and stirring, to being completely dissolved, is heated slowly to 60 DEG C, obtains thickness settled solution I；
(2) in gained thickness settled solution I, EDTA 18.0g, alkaline protease 10.0g, germall 2.5g and pigment are added
Light blue 0.5g, solution temperature is maintained at 60 DEG C, stirs after dissolving to solid, and stirring is cooled to room temperature, adds Flos Rosae Rugosae essence
30.0g, stirs and clarifies to liquid, obtain settled solution II；
(3) in gained settled solution II, add anhydrous magnesium sulfate 30.0g, be dried 1.0h, sucking filtration, obtain the super of the present embodiment
Concentrated type anhydrous liquid detergent 500.3g.
Embodiment 4
The present embodiment one anhydrous liquid detergent of ultra concentration type, its preparation method includes:
(1) under room temperature, by 100.0g cardanol polyoxyethylene ether (HLB is 25), 30.0g coco-nut oil fatty acid diethanol acyl
Amine (6501), 60.0g polyoxyethylenated alcohol sodium sulfate (AES), 30.0g fatty alcohol-polyoxyethylene ether (AEO-7) and 4.0g
Oleic acid is dissolved in 120mL Macrogol 600, and stirring, to being completely dissolved, obtains thickness settled solution I；
(2) in gained thickness settled solution I, anhydrous citric acid sodium 25.0g, alkaline protease 15.0g, matrine are added
1.5g and pigment light blue 0.2g, stirs after dissolving to solid, and stirring is cooled to room temperature, adds lavandula angustifolia essence 10.0g, and stirring is extremely
Liquid is clarified, and obtains settled solution II；
(3) in gained settled solution II, add silica gel 20.0g, be dried 1.0h, sucking filtration, obtain the ultra concentration type of the present embodiment
Anhydrous liquid detergent 388.1g.
Embodiment 5
The present embodiment one anhydrous liquid detergent of ultra concentration type, its preparation method includes:
(1) under room temperature, by 100.0g cardanol polyoxyethylene ether (HLB is 15), 100.0g coco-nut oil fatty acid diethanol
Amide (6503), 20.0g polyoxyethylenated alcohol sodium sulfate (AES), 100.0g fatty alcohol-polyoxyethylene ether (AEO-15) and
10.0g oleic acid is dissolved in 200mL polyethylene glycol-800, and stirring, to being completely dissolved, is heated slowly to 80 DEG C, obtains thickness settled solution
Ⅰ；
(2) in gained thickness settled solution I, anhydrous citric acid sodium 12.0g, alkaline protease 50.0g, matrine are added
3.0g and pigment light blue 1.0g, solution temperature is maintained at 80 DEG C, stirs after dissolving to solid, and stirring is cooled to room temperature, adds thin
Lotus essence 50.0g, stirs and clarifies to liquid, obtain settled solution II；
(3) in gained settled solution II, add anhydrous sodium sulfate 50.0g, be dried 1.0h, sucking filtration, obtain the super of the present embodiment
Concentrated type anhydrous liquid detergent 625.1g.
Comparative example 1
This comparative example one anhydrous liquid detergent of ultra concentration type, its preparation method includes:
(1) under room temperature, by 100.0g cardanol polyoxyethylene ether (HLB is 18), 30.0g coco-nut oil fatty acid diethanol acyl
Amine (6501), 30.0g polyoxyethylenated alcohol sodium sulfate (AES), 45.0g fatty alcohol-polyoxyethylene ether (AEO-10) and 5.0g
Oleic acid is dissolved in 150mL D-panthenol, and stirring, to being completely dissolved, is heated slowly to 60 DEG C, obtains thickness settled solution I；
(2) in gained thickness settled solution I, anhydrous citric acid sodium 15.0g, alkaline protease 20.0g, matrine are added
2.5g and pigment light blue 0.36g, solution temperature is maintained at 60 DEG C, stirs after dissolving to solid, and stirring is cooled to room temperature, adds osmanthus
Extrait 20.0g, stirs and clarifies to liquid, obtain settled solution II；
(3) in gained settled solution II, add molecular sieve 20.0g, be dried 1.0h, sucking filtration, obtain the ultra concentration of the present embodiment
Type anhydrous liquid detergent 401.5g.
Comparative example 2
This comparative example one anhydrous liquid detergent of ultra concentration type, its preparation method includes:
(1) under room temperature, by 110.0g cardanol polyoxyethylene ether (HLB is 18), 40.0g fatty alcohol-polyoxyethylene ether sulphuric acid
Sodium (AES), 55.0g fatty alcohol-polyoxyethylene ether (AEO-10) and 5.0g oleic acid are dissolved in 150mL PEG400, and stirring is extremely
It is completely dissolved, is heated slowly to 60 DEG C, obtain thickness settled solution I；
(2) in gained thickness settled solution I, anhydrous citric acid sodium 15.0g, alkaline protease 20.0g, matrine are added
2.5g and pigment light blue 0.36g, solution temperature is maintained at 60 DEG C, stirs after dissolving to solid, and stirring is cooled to room temperature, adds Cape jasmine
Sub-extrait 20.0g, stirs and clarifies to liquid, obtain settled solution II；
(3) in gained settled solution II, add molecular sieve 20.0g, be dried 1.0h, sucking filtration, obtain the ultra concentration of the present embodiment
Type anhydrous liquid detergent 402.2g.
Comparative example 3
This comparative example one anhydrous liquid detergent of ultra concentration type, its preparation method includes:
(1) under room temperature, by 110.0g cardanol polyoxyethylene ether (HLB is 18), 40.0g coco-nut oil fatty acid diethanol acyl
Amine (6501), 55.0g fatty alcohol-polyoxyethylene ether (AEO-10) and 5.0g oleic acid are dissolved in 150mL PEG400, and stirring is extremely
It is completely dissolved, is heated slowly to 60 DEG C, obtain thickness settled solution I；
(2) in gained thickness settled solution I, anhydrous citric acid sodium 15.0g, alkaline protease 20.0g, matrine are added
2.5g and pigment light blue 0.36g, solution temperature is maintained at 60 DEG C, stirs after dissolving to solid, and stirring is cooled to room temperature, adds water
Honey peach essence 20.0g, stirs and clarifies to liquid, obtain settled solution II；
(3) in gained settled solution II, add molecular sieve 20.0g, be dried 1.0h, sucking filtration, obtain the ultra concentration of the present embodiment
Type anhydrous liquid detergent 401.8g.
Comparative example 4
This comparative example one anhydrous liquid detergent of ultra concentration type, its preparation method includes:
(1) under room temperature, by 110.0g cocoanut fatty acid diethanolamide (6501), 40.0g fatty alcohol-polyoxyethylene ether
Sodium sulfate (AES), 55.0g fatty alcohol-polyoxyethylene ether (AEO-10) and 5.0g oleic acid are dissolved in 150mL PEG400, stir
Mix to being completely dissolved, be heated slowly to 60 DEG C, obtain thickness settled solution I；
(2) in gained thickness settled solution I, anhydrous citric acid sodium 15.0g, alkaline protease 20.0g, matrine are added
2.5g and pigment light blue 0.36g, solution temperature is maintained at 60 DEG C, stirs after dissolving to solid, and stirring is cooled to room temperature, adds lemon
Lemon orange essence 20.0g, stirs and clarifies to liquid, obtain settled solution II；
(3) in gained settled solution II, add molecular sieve 20.0g, be dried 1.0h, sucking filtration, obtain the ultra concentration of the present embodiment
Type anhydrous liquid detergent 402.4g.
Test case
According to GB QB/T1224-2012 " dress material washes agent by liquid " to above-described embodiment 1～5, comparative example 1～4 system
The anhydrous liquid detergent of ultra concentration type obtained carries out quality testing, and testing result is shown in Tables 1 and 2.
The quality measurements of the table 1 embodiment 1 anhydrous liquid detergent of ultra concentration type
Note: (a) standard liquid detergent test concentrations is 0.2%, sample test concentration is 0.1%, lower same.
Table 2 embodiment 2～5, the quality measurements of the comparative example 1～4 anhydrous liquid detergent of ultra concentration type
Note: (b) detection project each with table 1 is identical, and identical detection project has identical sequence number；S2～S5 represents real
Executing example 2～5, D1～D4 represents comparative example 1～4.
From Tables 1 and 2, the indices of the anhydrous liquid detergent of ultra concentration type of embodiment 1～5 all meets the requirements, its
In, gross activity thing accounting all more than 80%, pH6.8, total phosphorus pentoxide accounting is respectively less than 0.1%, high temperature (40 ± 2 DEG C,
Recover to room temperature after 24h), be respectively provided with good stability, in standard under low temperature (-5 ± 2 DEG C, recover to room temperature after 24h) environment
Liquid detergent test concentrations is 0,2%, sample test concentration be to carry out detergency detection on the premise of 0.1%, embodiment 1～5
The detergency of the anhydrous liquid detergent of ultra concentration type is all higher than standard liquid detergent, wherein the anhydrous liquid detergent of ultra concentration type of embodiment 1
The detection of JB-03 detergency is 1.7 times of standard liquid detergent.
From table 2, the outward appearance of comparative example 1～4, abnormal smells from the patient, stability, gross activity thing content, pH and total five oxidations two
Phosphorus content all meets the requirements, but standard liquid detergent test concentrations is 0, and 2%, on the premise of sample test concentration is 0.1%, contrast
The detergency index of each anhydrous liquid detergent of ultra concentration type of example 1～4 is slightly inferior to standard liquid detergent.
Claims (10)
1. the anhydrous liquid detergent of ultra concentration type, it is characterised in that according to the mass fraction, including:
2. the anhydrous liquid detergent of ultra concentration type as claimed in claim 1, it is characterised in that the parent of described cardanol polyoxyethylene ether
Hydrophile-lipophile balance value is 9～25.
3. the anhydrous liquid detergent of ultra concentration type as claimed in claim 1, it is characterised in that described fatty alcohol-polyoxyethylene ether is fat
Fat polyoxyethylenated alcohol AEO-7, AEO-9, AEO-10, AEO-15 or AEO-20.
4. the anhydrous liquid detergent of ultra concentration type as claimed in claim 1, it is characterised in that described coco-nut oil fatty acid diethanol acyl
Amine is cocoanut fatty acid diethanolamide 6501,6502 or 6503.
5. the anhydrous liquid detergent of ultra concentration type as claimed in claim 1, it is characterised in that described Polyethylene Glycol is Polyethylene Glycol
100, polyethylene glycol 200, PEG400, Macrogol 600 or polyethylene glycol-800.
6. the anhydrous liquid detergent of ultra concentration type as claimed in claim 1, it is characterised in that according to the mass fraction, including:
7. the anhydrous liquid detergent of ultra concentration type as described in as arbitrary in claim 1～6, it is characterised in that according to the mass fraction, also wrap
Include:
8. the anhydrous liquid detergent of ultra concentration type as claimed in claim 7, it is characterised in that described antistatic additive is oleic acid, Petiolus Trachycarpi
At least one in oil and lauric acid.
9. the preparation method of the anhydrous liquid detergent of ultra concentration type as described in as arbitrary in claim 7～8, it is characterised in that including:
(1) under room temperature, by the mass fraction preset, by cardanol polyoxyethylene ether, cocoanut fatty acid diethanolamide, fat
Polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether and antistatic additive are dissolved in Polyethylene Glycol, stir to after being completely dissolved
It is slowly heated to 25～80 DEG C, it is thus achieved that thickness settled solution I；
(2) by preset mass fraction, add in described thickness settled solution I hard water resistance dose, preservative, alkaline protease and
Pigment, stirs at 25～80 DEG C and is cooled to room temperature after being completely dissolved, add essence, stirs to solution clarification, it is thus achieved that clarification
Solution II；
(3) in described settled solution II, deicer, dried sucking filtration, it is thus achieved that the described anhydrous liquid detergent of ultra concentration type are added.
10. the solidifying pearl of laundry, including water soluble film layer with by the liquid detergent of described water soluble film layer sealed envelope, it is characterised in that
Described liquid detergent be as arbitrary in claim 1～8 as described in the anhydrous liquid detergent of ultra concentration type.
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| CN109679778B (en) * | 2018-12-03 | 2021-05-04 | 常熟耐素生物材料科技有限公司 | Low-foam low-viscosity laundry detergent and preparation method thereof |
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| CN111117795A (en) * | 2019-12-31 | 2020-05-08 | 长沙如洋环保科技有限公司 | Environment-friendly concentrated laundry detergent with sterilization and mite removal functions and preparation method thereof |
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