CN105296249A - Transparent liquid soap with stable phase state structure obtained through changing soap base system - Google Patents
Transparent liquid soap with stable phase state structure obtained through changing soap base system Download PDFInfo
- Publication number
- CN105296249A CN105296249A CN201510740067.3A CN201510740067A CN105296249A CN 105296249 A CN105296249 A CN 105296249A CN 201510740067 A CN201510740067 A CN 201510740067A CN 105296249 A CN105296249 A CN 105296249A
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- China
- Prior art keywords
- acid
- phase
- soap
- transparent liquid
- liquid soap
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000344 soap Substances 0.000 title claims abstract description 99
- 239000007788 liquid Substances 0.000 title claims abstract description 46
- 239000000203 mixture Substances 0.000 claims abstract description 55
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 17
- 239000000194 fatty acid Substances 0.000 claims abstract description 17
- 229930195729 fatty acid Natural products 0.000 claims abstract description 17
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 11
- 238000000518 rheometry Methods 0.000 claims abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 239000003945 anionic surfactant Substances 0.000 claims description 17
- 239000013543 active substance Substances 0.000 claims description 15
- 239000002585 base Substances 0.000 abstract description 44
- 238000007127 saponification reaction Methods 0.000 abstract description 14
- 239000003513 alkali Substances 0.000 abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 12
- 239000002994 raw material Substances 0.000 abstract description 6
- 238000003756 stirring Methods 0.000 abstract description 5
- 238000002360 preparation method Methods 0.000 abstract description 4
- 239000003906 humectant Substances 0.000 abstract 3
- 239000002535 acidifier Substances 0.000 abstract 2
- 238000002156 mixing Methods 0.000 abstract 2
- 239000003755 preservative agent Substances 0.000 abstract 2
- 230000002335 preservative effect Effects 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 1
- 239000008367 deionised water Substances 0.000 abstract 1
- 229910021641 deionized water Inorganic materials 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000012071 phase Substances 0.000 description 42
- 239000002253 acid Substances 0.000 description 31
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 26
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 26
- -1 fatty acid salt Chemical class 0.000 description 26
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 24
- 150000002632 lipids Chemical class 0.000 description 22
- 239000005639 Lauric acid Substances 0.000 description 13
- 239000002131 composite material Substances 0.000 description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 235000011187 glycerol Nutrition 0.000 description 12
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 12
- 238000006386 neutralization reaction Methods 0.000 description 11
- 235000021355 Stearic acid Nutrition 0.000 description 9
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 9
- 239000008117 stearic acid Substances 0.000 description 9
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 8
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 8
- 239000004973 liquid crystal related substance Substances 0.000 description 8
- 230000008859 change Effects 0.000 description 7
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 7
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 229960003237 betaine Drugs 0.000 description 6
- 239000000976 ink Substances 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 6
- 238000007639 printing Methods 0.000 description 6
- 239000000080 wetting agent Substances 0.000 description 6
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 150000004671 saturated fatty acids Chemical class 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- CUBCNYWQJHBXIY-UHFFFAOYSA-N benzoic acid;2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O CUBCNYWQJHBXIY-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229960001631 carbomer Drugs 0.000 description 4
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 4
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 4
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 4
- 239000004310 lactic acid Substances 0.000 description 4
- 235000014655 lactic acid Nutrition 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 150000007524 organic acids Chemical group 0.000 description 4
- WQEPLUUGTLDZJY-UHFFFAOYSA-N pentadecanoic acid Chemical compound CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 4
- 238000010587 phase diagram Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 229920001282 polysaccharide Polymers 0.000 description 4
- 239000005017 polysaccharide Substances 0.000 description 4
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 4
- 229910052939 potassium sulfate Inorganic materials 0.000 description 4
- 235000011151 potassium sulphates Nutrition 0.000 description 4
- 244000215068 Acacia senegal Species 0.000 description 3
- 235000006491 Acacia senegal Nutrition 0.000 description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 3
- 229920002907 Guar gum Polymers 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 3
- UKANSAYWLOUHDZ-UHFFFAOYSA-M [Na+].CC=1C(=C(C=CC1)S(=O)(=O)[O-])C(CCCCCCCCCCC)=O Chemical compound [Na+].CC=1C(=C(C=CC1)S(=O)(=O)[O-])C(CCCCCCCCCCC)=O UKANSAYWLOUHDZ-UHFFFAOYSA-M 0.000 description 3
- BKDZVPVJIXZYBH-UHFFFAOYSA-N [Na].C(C)(=O)O.NC(=N)N Chemical compound [Na].C(C)(=O)O.NC(=N)N BKDZVPVJIXZYBH-UHFFFAOYSA-N 0.000 description 3
- 239000003125 aqueous solvent Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000665 guar gum Substances 0.000 description 3
- 235000010417 guar gum Nutrition 0.000 description 3
- 229960002154 guar gum Drugs 0.000 description 3
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000000230 xanthan gum Substances 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- 235000010493 xanthan gum Nutrition 0.000 description 3
- 229940082509 xanthan gum Drugs 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- YWWVWXASSLXJHU-AATRIKPKSA-N (9E)-tetradecenoic acid Chemical compound CCCC\C=C\CCCCCCCC(O)=O YWWVWXASSLXJHU-AATRIKPKSA-N 0.000 description 2
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 235000019325 ethyl cellulose Nutrition 0.000 description 2
- 229920001249 ethyl cellulose Polymers 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 150000002314 glycerols Chemical class 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- AMRBZKOCOOPYNY-QXMHVHEDSA-N 2-[dimethyl-[(z)-octadec-9-enyl]azaniumyl]acetate Chemical compound CCCCCCCC\C=C/CCCCCCCC[N+](C)(C)CC([O-])=O AMRBZKOCOOPYNY-QXMHVHEDSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- YWWVWXASSLXJHU-UHFFFAOYSA-N 9E-tetradecenoic acid Natural products CCCCC=CCCCCCCCC(O)=O YWWVWXASSLXJHU-UHFFFAOYSA-N 0.000 description 1
- JILQLJLJHXAERQ-UHFFFAOYSA-N C(CCCCCCCCCCCCCCC)C(N(C(C(=O)O)(C)CC(=O)O)C)(C)C Chemical compound C(CCCCCCCCCCCCCCC)C(N(C(C(=O)O)(C)CC(=O)O)C)(C)C JILQLJLJHXAERQ-UHFFFAOYSA-N 0.000 description 1
- SSPUHOCUIKUFAS-UHFFFAOYSA-N CC(N(C(C(=O)O)(C)CC(=O)O)C)C Chemical compound CC(N(C(C(=O)O)(C)CC(=O)O)C)C SSPUHOCUIKUFAS-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 240000004160 Capsicum annuum Species 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 230000018199 S phase Effects 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229960004232 linoleic acid Drugs 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229960002969 oleic acid Drugs 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Abstract
The invention discloses a transparent liquid soap with a stable phase state structure obtained through changing a soap base system. Raw materials for preparing the transparent liquid soap include fatty acid, alkali, a humectant, a surfactant, a rheology control agent, an acidifying agent, a preservative and deionized water. A preparation method comprises the steps of mixing the fatty acid, the humectant and the rheology control agent as a phase A, mixing the alkali and the water as a phase B, respectively heating the phase A and the phase B to 80-85 DEG C until the phase A is completely molten, adding the phase A serving as 80-DEG C water bath into the phase B under a stirring condition, stirring in a 80-DEG C constant-temperature water bath for 35-45 minutes, and adding the surfactant when saponification is complete; then, cooling the mixture to 40 DEG C, and adding the acidifying agent, the preservative and other components; and next, further stirring for 20 minutes to obtain the transparent liquid soap with the stable phase state structure obtained through changing the soap base system. The humectant, the surfactant and other components are added into the composition, so that the arrangement way of molecules in the soap base system is changed, furthermore, the phase state structure of the soap base system is changed, and the system range for forming the transparent liquid soap is widened.
Description
Technical field
The present invention relates to a kind of by changing the stable transparent liquid soap of soap base system Phase stracture, belonging to daily cosmetics field.
Background technology
The eighties in 20th century, the aqueous solution of liquid soap (softsoap) namely containing soap, composite with the appearance of the mixture of synthetic surfactant, amendment and finishing composition after the nineties, be intended to overcome in the high ph-values of fatty acid metal salt, large to skin irritation, rinsability difference and hard water the shortcoming forming floating quarrel.
Liquid soap is the technological innovation to perfumed soap, reaches the parent that skin nursing effect is subject to domestic and international human consumer and relies, occupy most of market of personal cleansing product with its convenient use-pattern freely and various added ingredients.
The liquid soap of current application is divided into transparent liquid soap and opaque liq soap, and transparent liquid soap is with the fully saponified soap base of lipid acid for matrix, composite with the mixture of tensio-active agent and amendment or other additives; Opaque liq soap is the product of the incomplete saponification of lipid acid and the mixture of tensio-active agent and other additives, mostly is emulsion form.
In soap base system owing to there is wetting ability and lipophilic group in its molecular structure in fatty acid salt surfactant molecule, can form diversified self-assembled structures.And the ordered aggregation that tensio-active agent is formed in water is relevant with its concentration, along with the increase of surfactant concentration, can have successively surfactant molecule monomer formed micella (spherical micelle, rod-shaped micelle), liquid crystal structure (layered liquid crystal, hexagonal liquid crystal, cubic liquid crystal) and other.Wherein, layered liquid crystal and hexagonal liquid crystal are anisotropy, have birefringence, and can observe polarisation texture, cubic liquid crystal is each side's same sex, cannot observe its polarisation texture.
In transparent liquid soap, between various tensio-active agent, compound proportion is different, and the phase structure of formation is also different, and the stability of system is difficult to control, and limits its application in daily cosmetics field.
Summary of the invention
An object of the present invention is the Phase stracture in order to be changed soap base system by added ingredients, increases the scope forming transparent soap.
Two of object of the present invention is to provide above-mentioned a kind of transparent liquid soap stable by change soap base system Phase stracture, and its preparation process has the features such as simple to operate.
Know-why of the present invention
After polyvalent alcohol joins in aqueous solvent, destroy the iceberg structure formed between water molecules, add the hydrogen bonded effect between soap molecule, the solubleness of soap in mixed solvent is increased.Appropriate tensio-active agent can change the arrangement mode of soap molecule in water, changes the Phase stracture of system, reaches the effect of stable soap base system.Rheology control agent is swelling in water, forms macromolecular network structure, also serves the effect of stable soap base system.
Technical scheme of the present invention
By changing the stable transparent liquid soap of soap base system Phase stracture, count by weight percentage, its raw material composition and content as follows:
Described lipid acid comprises saturated fatty acid and unsaturated fatty acids, wherein, saturated fatty acid includes but not limited to sad, capric acid, lauric acid, tetradecanoic acid, pentadecylic acid, palmitinic acid, margaric acid, stearic acid, Unimac 5680, nondecylic acid, eicosanoic acid, docosoic acid and analogue, and composition thereof.Unsaturated fatty acids includes but not limited to myristoleic acid, Zoomeric acid, oleic acid, linolic acid, linolenic acid and analogue, and composition thereof.Lipid acid scientific research residue animal tallow, such as, as tallow or be derived from vegetables oil, cocounut oil, chilli oil, palm-kernel oil, plam oil, Oleum Gossypii semen, soybean oil, peanut oil and composition thereof.
Described alkali comprises potassium hydroxide, salt of wormwood, sodium hydroxide and trolamine.Alkali number is to regulate in the scope of pH most about 9.5-12.0.Establish the upper limit of pH scope, gentle to guarantee user's skin, and establish the lower limit of pH value range, to guarantee neutralization or saponified fat acid.
Described wetting Agent for Printing Inks comprises polyvalent alcohol, and polyvalent alcohol includes but not limited to the mixture of one or more of glycerine, Glycerol dimer, polyoxyethylene glycol, propylene glycol, butyleneglycol.
Described tensio-active agent is anion surfactant, zwitterionics and nonionogenic tenside.Wherein anion surfactant includes, but are not limited to the mixture of one or more compositions in ammonium lauryl sulfate, laureth ammonium sulfate, laureth potassium sulfate, AESA salt, polyoxyethylenated alcohol sodium sulfate salt, sodium lauryl sulphate, dodecyl sulphate potassium, lauryl alcohol sulphonic acid sodium, lauryl alcohol potassium sulfate, methyl lauroyl benzene sulfonic acid sodium salt, Sodium dodecylbenzene sulfonate, lauryl both sexes guanidine-acetic acid sodium.Zwitterionics includes, but are not limited to coco dimethyl carboxymethyl trimethyl-glycine, cocamidopropyl betaine, coco betaine, oleyl betaine alkali, cetyl dimethyl carboxymethyl trimethyl-glycine, lauryl two-(2-hydroxyethyl) carboxymethyl betaine, stearyl be two-and (2-hydroxyethyl) carboxymethyl betaine, lauryl be two-and (2-hydroxypropyl)-carboxy-ethyl betaine, stearyl dimethyl hydroxypropyl trimethyl-glycine, lauryl dimethyl hydroxyethyl trimethyl-glycine, lauryl be two-(2-hydroxyethyl) azochlorosulfonate propyl lycine and composition thereof.Nonionogenic tenside includes, but are not limited to C16-C22 alkylphenol-alcoxyl oxide condensate, the condensation product of C8-C18 aliphatic series uncle or Zhong Zhilian or branching alcohol and oxyethane and the product made by reaction product and the condensation of alcoxyl ethane of propylene oxide and quadrol, one or more mixture of alkyl polysaccharide.And the content of anion surfactant is greater than the total content of zwitter-ion and nonionogenic tenside.
Described rheology control agent includes, but are not limited to the mixture of one or more compositions in carbomer, methylcellulose gum, ethyl cellulose, Walocel MT 20.000PV, Natvosol, hydroxypropylcellulose, guar gum, Sudan Gum-arabic, xanthan gum.
Described souring agent is selected from organic acid, mineral acid and composition thereof.
Described souring agent includes, but are not limited to the mixture of citric acid, acetic acid, Whitfield's ointment, lactic acid, oxyacetic acid, natural tartaric acid, hydrochloric acid, nitric acid, thionamic acid, one or more compositions of phosphoric acid.
Described sanitas is 1,3-dihydroxymethyl-5,5-T10, propylben or Kathon CG.
Above-mentioned a kind of preparation method, step is as follows:
First lipid acid, wetting Agent for Printing Inks, rheology control agent are mixed as A phase, alkali mixes with water as B phase, respectively A, B heat phase to 80 ~ 85 DEG C to A phase is all melted, with 80 DEG C of water-bath A phases, B phase is added under agitation condition, constant temperature 80 DEG C of stirring in water bath 35 ~ 45min, treat that saponification reaction is complete, add tensio-active agent, then this mixture is cooled to 40 DEG C, adding souring agent and sanitas and other compositions, then continue to stir 20min, obtaining a kind of by changing the stable transparent liquid soap of soap base system structure.
Result of the present invention shows, adds polyvalent alcohol wetting Agent for Printing Inks, tensio-active agent and other additives in system, by changing the Phase stracture of soap base system, can increase the scope of System forming transparent soap, improving soap base system stability.
Beneficial effect of the present invention
Of the present invention a kind of by changing the stable transparent liquid soap of soap base system Phase stracture, by the various lipid acid compound proportion scopes of phasor determination System forming transparent liquid soap, for soap base system provides reference in the application in daily cosmetics field.
Of the present invention a kind of by changing the stable transparent liquid soap of soap base system Phase stracture, by research polyvalent alcohol if glycerine is on the impact of system phase behavior, find that polyvalent alcohol can increase the scope of the formation transparent liquid soap of soap soap base system.
Of the present invention a kind of by changing the stable transparent liquid soap of soap base system Phase stracture, preparation technology is simple, workable.From the arrangement mode changed between soap base system Middle molecule, change the Micro-Structure of system, and then improve the stability of soap base system, the application of soap base system is had important practical significance.
Accompanying drawing explanation
Figure 1 shows that total fatty acid content is the phasor of the composite soap base system of different sorts lipid acid of 30% weight percent.Wherein Figure 1A is that the composite and lipid acid of 98% of lauric acid, tetradecanoic acid and palmitinic acid is by the soap base system phase diagram of saponification; Figure 1B is after interpolation 20% weight percent glycerine, and the composite and lipid acid of 98% of lauric acid, tetradecanoic acid and palmitinic acid is by the soap base system phase diagram of saponification; Fig. 1 C is that the composite and lipid acid of lauric acid, tetradecanoic acid and stearic acid is by fully saponified soap base system phase diagram; Fig. 1 D is after interpolation 20% weight percent glycerine, and the composite and lipid acid of lauric acid, tetradecanoic acid and stearic acid is by fully saponified soap base system phase diagram.
Embodiment
Below in conjunction with specific embodiment, the present invention is described further, but protection scope of the present invention is not limited in this.
Raw material specification used in various embodiments of the present invention and manufacturer are as table 1
embodiment 1
By changing the stable transparent liquid soap of soap base system Phase stracture, count by weight percentage, its raw material composition and content as follows:
Described lipid acid is selected from saturated fatty acid, comprises lauric acid, tetradecanoic acid and palmitinic acid.Wherein the ratio of lauric acid content is much larger than tetradecanoic acid and palmitinic acid, and concrete proportional range is shown in each lipid acid compound proportion of Liquid phase region in accompanying drawing 1B.
Described alkali selects potassium hydroxide.Alkali number calculates with neutralization or saponification 98% total fatty acid content.
Described wetting Agent for Printing Inks is selected from glycerine.The content of glycerine is with 20% weight.
Described tensio-active agent is selected from anion surfactant, zwitterionics and nonionogenic tenside.Wherein anion surfactant includes, but are not limited to the mixture of one or more compositions in laureth ammonium sulfate, laureth potassium sulfate, AESA salt, polyoxyethylenated alcohol sodium sulfate salt.Zwitterionics includes, but are not limited to cocamidopropyl betaine, coco betaine and composition thereof.Nonionogenic tenside includes, but are not limited to the mixture of one or more in C16-C22 alkylphenol-alcoxyl oxide condensate, alkyl polysaccharide.And the content of anion surfactant is greater than the total content of zwitter-ion and nonionogenic tenside.
Described rheology control agent includes, but are not limited to the mixture of one or more compositions in carbomer, methylcellulose gum, ethyl cellulose, Walocel MT 20.000PV, Natvosol.
Described souring agent is selected from organic acid.
Described souring agent includes, but are not limited to the mixture of citric acid, acetic acid, Whitfield's ointment, one or more compositions of lactic acid.
Described sanitas is Kathon CG.
embodiment 2
By changing the stable transparent liquid soap of soap base system Phase stracture, count by weight percentage, its raw material composition and content as follows:
Described lipid acid is selected from saturated fatty acid, comprises lauric acid, tetradecanoic acid and stearic acid.Wherein lauric content is greater than tetradecanoic acid and stearic acid, and concrete proportional range is as Fig. 1 D.
Described alkali selects potassium hydroxide.Alkali number is in neutralization or saponification 100% total fatty acid content.
Described wetting Agent for Printing Inks selects glycerine, and content is with 20% weight.
Described tensio-active agent is selected from anion surfactant, zwitterionics and nonionogenic tenside.Wherein anion surfactant includes, but are not limited to the mixture of one or more compositions in AESA salt, polyoxyethylenated alcohol sodium sulfate salt, methyl lauroyl benzene sulfonic acid sodium salt, Sodium dodecylbenzene sulfonate, lauryl both sexes guanidine-acetic acid sodium.Zwitterionics includes, but are not limited to cocamidopropyl betaine, lauryl two-(2-hydroxyethyl) carboxymethyl betaine, stearyl be two-(2-hydroxyethyl) carboxymethyl betaine, stearyl dimethyl hydroxypropyl trimethyl-glycine, lauryl dimethyl hydroxyethyl trimethyl-glycine and composition thereof.Nonionogenic tenside includes, but are not limited to the condensation product of C8-C18 aliphatic series uncle or Zhong Zhilian or branching alcohol and oxyethane and the product made by reaction product and the condensation of alcoxyl ethane of propylene oxide and quadrol, one or more mixture of alkyl polysaccharide.Wherein the content of anion surfactant is greater than the total content of zwitter-ion and nonionogenic tenside.
Described rheology control agent includes, but are not limited to the mixture of one or more compositions in carbomer, guar gum, Sudan Gum-arabic, xanthan gum.
Described souring agent is selected from organic acid.
Described souring agent includes, but are not limited to the mixture of one or more compositions in citric acid, acetic acid, Whitfield's ointment, lactic acid.
Described sanitas is 1,3-dihydroxymethyl-5,5-T10.
embodiment 3
By changing the stable transparent liquid soap of soap base system Phase stracture, count by weight percentage, its raw material composition and content as follows:
Described lipid acid is selected from saturated fatty acid, includes but not limited to lauric acid, tetradecanoic acid, pentadecylic acid, palmitinic acid, margaric acid, stearic acid, Unimac 5680, nondecylic acid, eicosanoic acid, docosoic acid and analogue, and composition thereof.And low carbon chain fatty acid content is greater than the content of Long carbon chain lipid acid.
Described alkali selects potassium hydroxide.Alkali number, in neutralization or saponification 98% total fatty acid content, regulates in the scope of pH most about 10.5-12.0.Establish the upper limit of pH scope, gentle to guarantee user's skin, and establish the lower limit of pH value range, to guarantee neutralization or saponified fat acid.
Described wetting Agent for Printing Inks is selected from polyvalent alcohol, and polyvalent alcohol includes but not limited to the mixture of one or more of glycerine, Glycerol dimer, polyoxyethylene glycol, propylene glycol, butyleneglycol.
Described tensio-active agent is selected from anion surfactant, zwitterionics and nonionogenic tenside.Wherein anion surfactant includes, but are not limited to the mixture of one or more compositions in laureth potassium sulfate, AESA salt, methyl lauroyl benzene sulfonic acid sodium salt, lauryl both sexes guanidine-acetic acid sodium.Zwitterionics includes, but are not limited to cocamidopropyl betaine, stearyl two-(2-hydroxyethyl) carboxymethyl betaine, stearyl dimethyl hydroxypropyl trimethyl-glycine and composition thereof.One or more mixture of the product that nonionogenic tenside includes, but are not limited to be made by reaction product and the condensation of alcoxyl ethane of propylene oxide and quadrol, alkyl polysaccharide.And the content of anion surfactant is greater than the total content of zwitter-ion and nonionogenic tenside.
Described rheology control agent includes, but are not limited to the mixture of one or more compositions in carbomer, guar gum, Sudan Gum-arabic, xanthan gum.
Described souring agent is selected from organic acid.
Described souring agent includes, but are not limited to the mixture of one or more compositions in citric acid, acetic acid, Whitfield's ointment, lactic acid.
Described sanitas is 1,3-dihydroxymethyl-5,5-T10.
Transparent liquid soap prepared by the embodiment of the present invention 1 is as Liquid region in Figure 1B, and Figure 1A is the phase behavior of soap base system prepared by the composite neutralization of lipid acid lauric acid, tetradecanoic acid and palmitinic acid or saponification 98% total fatty acid content, contrasts as Figure 1B.
Transparent liquid soap prepared by the embodiment of the present invention 2 is as Liquid region in Fig. 1 D, and Fig. 1 C is the phase behavior of soap base system prepared by the composite neutralization of lipid acid lauric acid, tetradecanoic acid and stearic acid or saponification 100% total fatty acid content, contrasts as Fig. 1 D.
In Figure 1A-B-C-D, be under the condition of 30% weight percentage at total fatty acid content, the ratio of three kinds of composite lipid acid is different, and the kind of lipid acid is different, and the phase behavior of the soap base system that neutralization or saponification are formed is different.Wherein, Liquid phase outward appearance is transparent liquid, and high/low temperature stability teaches other phases best; Liq+Lam phase is transparent liquid and layered liquid crystal coexisting phase, and physical properties is troubled liquor, anisotropy, system performance birefringence; Liq+Hex+Lam phase is three-phase transparent liquid phase, six side's phases and lamellar phase coexistence, and physical properties is half troubled liquor, each diversity, system surface birefringence; Cub phase is Emission in Cubic, and physical properties is transparent not flow-gel, isotropy; Liq+Crystal phase is transparent liquid and crystals coexist phase, and physical properties is the liquid or solid containing white precipitate.
From Figure 1A-B, glycerine can change the phase behavior of the soap base system of the composite neutralization of lauric acid, tetradecanoic acid and palmitinic acid or saponification formation, makes the Liquid phase region scope of System forming become large.In addition zwitter-ion and nonionogenic tenside can affect the transparency of system, anion surfactant affects less on the transparency of system within the specific limits, and the content of the anion surfactant therefore added is greater than the total content of zwitter-ion and nonionogenic tenside.
From Fig. 1 C-D, glycerine obviously can change the phase behavior of the soap base system of the composite neutralization of lauric acid, tetradecanoic acid and stearic acid or saponification formation, makes the Liquid phase region scope of System forming become large.The soap that the solubleness of stearate in water that stearic acid neutralization or saponification are formed is formed relative to other low carbon chain lipid acid is less, makes the Liq+Crystal phase region scope of System forming slightly large.
Figure 1A/B and C/D correlation data show, the polyvalent alcohols such as glycerine can change the arrangement mode between aqueous solvent and surfactant molecule, H-bonding capability strengthens, the Phase stracture of soap base system is changed, change the phase behavior of soap base system, make the three kinds of lipid acid compound proportion scopes forming transparent liquid soap Liquid phase in soap base system become large.
The result of the embodiment of the present invention 3 shows, total fatty acid content is lower, and when low carbon chain fatty acid content is higher than Long carbon chain fatty acid content, system easily forms transparent liquid soap.
In sum, of the present invention a kind of by changing the stable transparent liquid soap of soap base system Phase stracture, the phase behavior of the soap base system formed by the proportioning studying various composite lipid acid, polyvalent alcohol is if glycerine is on the impact of soap base system phase behavior, tensio-active agent is on the impact of soap base system phase behavior, result shows: polyvalent alcohol can by changing the arrangement mode between aqueous solvent and soap surfactant molecule, add lipid acid hydrochlorate molecule and the hydrogen bonded effect between polyvalent alcohol and water molecules, make the scope of System forming transparent liquid soap become large; Tensio-active agent be added beyond the transparency that certain limit can affect transparent liquid soap, within the specific limits, the adding the content that content is greater than zwitter-ion and nonionogenic tenside the transparency of system can be kept constant of anion surfactant.Other additives such as rheology control agent improves the stability of system by increasing spatial stability.
The above is only the citing of embodiments of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvement and modification, these improve and modification also should be considered as protection scope of the present invention.
Claims (6)
1., by changing the stable transparent liquid soap of soap base system Phase stracture, it is characterized in that described transparent liquid soap, the 90%-100% molar content of the fatty acid mixt of the 5-35% weight percentage of described liquid soap is neutralized to form soap.
2. transparent liquid soap according to claim 1, it comprises the 2-10% weight percentage surfactant mixture of described liquid soap further.
3. transparent liquid soap according to claim 2, wherein said tensio-active agent accounts for the total 25-100% weight percentage of the weight of described fatty acid mixt.
4. transparent liquid soap according to claim 2, described tensio-active agent is selected from anion surfactant, zwitterionics, nonionogenic tenside and surfactant mixture thereof, and wherein said anion surfactant total amount is greater than the total amount of described zwitterionics and nonionogenic tenside.
5. transparent liquid soap according to claim 1, it comprises the rheology control agent of described composition 0.05-8% weight percentage further.
6. transparent liquid soap according to claim 1, it comprises the polyvalent alcohol of described composition 5-35% weight percentage further.
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| CN107955764A (en) * | 2017-12-21 | 2018-04-24 | 四川同庆南风洗涤用品有限责任公司 | A kind of transparent soap lye of low temperature resistant low pour point and its preparation method and application |
| CN112812904A (en) * | 2021-02-08 | 2021-05-18 | 青岛杰纳勒尔生物有限公司 | Method for producing liquid soap |
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| CN101400772A (en) * | 2006-03-08 | 2009-04-01 | 路博润高级材料公司 | Stable soap based cleansing system |
| CN102481464A (en) * | 2008-10-21 | 2012-05-30 | 荷兰联合利华有限公司 | Soap-based liquid wash formulations with enhanced deposition |
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