CN105754737B - A kind of concentration liquid detergent and preparation method thereof for water-solubility membrane packaging - Google Patents
A kind of concentration liquid detergent and preparation method thereof for water-solubility membrane packaging Download PDFInfo
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- CN105754737B CN105754737B CN201410791952.XA CN201410791952A CN105754737B CN 105754737 B CN105754737 B CN 105754737B CN 201410791952 A CN201410791952 A CN 201410791952A CN 105754737 B CN105754737 B CN 105754737B
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Abstract
The invention belongs to detergent composition fields, and in particular to a kind of concentration liquid detergent and preparation method thereof for water-solubility membrane packaging.The raw material of the concentration liquid detergent includes: methyl ester ethoxylates, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic surfactant, 1,2-benzisothiazolin-3-one, glycerine, polyethylene glycol, propene carbonate and essence.Water-solubility membrane is not damaged according to the concentration liquid detergent that inventive formulation method produces, good water solubility, and foam is low, is easily rinsed；Highly concentrated, effective component is 4 ~ 5 times of ordinary liquid laundry detergent；And production is simple, preparation process is without heating.
Description
Technical field
The invention belongs to detergent composition field, in particular to it is a kind of for water-solubility membrane packaging concentration liquid detergent and
Preparation method.
Background technique
For household washing articles, the appearance of a variety of package metro-measuring modes is not any strange thing.The use of detergent
Amount directly affects washing effect, and the slurry of different hardness, different types of dirt and clothing decide used wash
Wash the optimum amount of agent.In recent years, laundry tablets, solidifying pearl of doing washing gradually listed in country variant, obtained certain success, were
Consumer brings convenience, while also putting forward new requirements for detergent research staff.
The liquid detergent of water-solubility membrane packaging is a kind of liquid detergent of new packaged form, and liquid detergent is packaged in PV water solubility
In film, the characteristics of with its own is unique " accurate washing " and " highly enriched ", in addition its environmentally protective novel package, it will
Occupy the manor of oneself on the market.Common PVA water-soluble plastic thin film be it is a kind of through special process processing, can pass through
The novel environment friendly packaging material that natural cause is degraded rapidly, it can pass through natural cause (H2O it) acts on, is voluntarily denaturalized rapidly, divides
It solves, be degraded to low molecular compound.The liquid detergent packed using PVA water soluble film has certain special want compared with ordinary liquid laundry detergent
Ask, in liquid detergent moisture and concentration have certain limitation, the general moisture and higher concentration required lower than 5%, currently,
The water-solubility membrane liquid detergent being commercially available is mostly based on 2 times of concentrations.
Summary of the invention
The concentration liquid detergent and preparation method thereof that the purpose of the present invention is to provide a kind of for water-solubility membrane；The detergent
Water-solubility membrane is not damaged, good water solubility is highly concentrated, strong detergency, and foam is low, easily rinses.
The purpose of the present invention is what is be achieved through the following technical solutions:
The raw material of a kind of concentration liquid detergent for water-solubility membrane packaging, the concentration liquid detergent includes: methyl esters ethyoxyl
Compound, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic surfactant, 1,2-benzisothiazolin-3-one, third
Triol, polyethylene glycol, propene carbonate and essence, the weight part ratio of each raw material are as follows:
Methyl ester ethoxylates 10 ~ 20
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 3~5
Nonionic surfactant 45~60
1,2-benzisothiazolin-3-one 0.1~0.3
Glycerine 1~5
Polyethylene glycol 5 ~ 10
Propene carbonate 10 ~ 25
Essence 0.2~0.4.
Further, the nonionic surfactant is aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy
(7) one or more of ether, aliphatic alcohol polyethenoxy (9) ether mix.
It is another object of the present invention to what is be achieved through the following technical solutions:
A kind of preparation method of the concentration liquid detergent for water-solubility membrane packaging, the raw material of the concentration liquid detergent include:
Methyl ester ethoxylates, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic surfactant, 1,2- benzisothiazole
Quinoline -3- ketone, glycerine, polyethylene glycol, propene carbonate and essence, the weight part ratio of each raw material are as follows:
Methyl ester ethoxylates 10 ~ 20
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 3~5
Nonionic surfactant 45~60
1,2-benzisothiazolin-3-one 0.1~0.3
Glycerine 1~5；
Polyethylene glycol 5 ~ 10
Propene carbonate 10 ~ 25
Essence 0.2~0.4；
Preparation step are as follows:
A, the polyethylene glycol, glycerine, propene carbonate is taken to be added in material kettle according to above-mentioned weight proportion, then
The methyl ester ethoxylates, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic are sequentially added according to said ratio respectively
Surfactant obtains mixed liquor A to being completely dissolved；
B, 1,2-benzisothiazolin-3-one, essence then are sequentially added according to said ratio respectively, obtains mixed liquid B；
C, it by above-mentioned mixed liquid B, is handled with 200 mesh filter-cloth filterings, obtains the concentration liquid detergent.
The present invention has the advantages that compared with prior art
1) present invention in the preparation, without heating, can operate at room temperature.
2) present invention is Concentrated formulations, so that under extremely low concentration, reaches washing standard requirements, and good water solubility,
Foam is few, easy rinsing, nontoxic non-stimulated；Effective content of the present invention is higher than 4-5 times of conventional detergent.
3) present invention is Concentrated formulations, can save raw material and packing cost, and production and transport cost is conducive to energy-saving；
The present invention more has its advantage on economizing on resources, can save the production cost, packing cost, transport of one third or more at
This, the purchase cost of such consumer can also be greatly reduced, and have high economic benefit and social benefit.
4) present invention can be used for water-solubility membrane packaging, and prompt band is convenient, easy to use, dosage more saves.
Specific embodiment
Embodiment 1
The raw material of a kind of concentration liquid detergent for water-solubility membrane packaging, the concentration liquid detergent includes: methyl esters ethyoxyl
Compound, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic surfactant, 1,2-benzisothiazolin-3-one, third
Triol, polyethylene glycol, propene carbonate and essence, the weight part ratio of each raw material are as follows:
Methyl ester ethoxylates 10 ~ 20
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 3~5
Nonionic surfactant 45~60
1,2-benzisothiazolin-3-one 0.1~0.3
Glycerine 1~5
Polyethylene glycol 5 ~ 10
Propene carbonate 10 ~ 25
Essence 0.2~0.4；
The nonionic surfactant is aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether, fat
The mixing of one or more of alcohol polyoxyethylene (9) ether.
Unit of weight used in the present embodiment is gram, or kilogram；
Each raw material described in the present embodiment is technical grade；
Each raw material described in the present embodiment is the conventional products sold in the market；
In the present embodiment, each raw material in described can in the ratio range provided flexible combination, it is different herein
One enumerates.
The present embodiment liquid detergent specific is concentrated the preparation method comprises the following steps:
A, the polyethylene glycol, glycerine, propene carbonate is taken to be added in material kettle according to above-mentioned weight proportion, then
The methyl ester ethoxylates, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic are sequentially added according to said ratio respectively
Surfactant obtains mixed liquor A to being completely dissolved；
B, 1,2-benzisothiazolin-3-one, essence then are sequentially added according to said ratio respectively, obtains mixed liquid B；
C, by above-mentioned mixed liquid B, filtration treatment obtains the concentration liquid detergent.
It is easy to operate in entire production technology, it is cold to match.First solvent is added in kettle, is convenient for various surfactants
Quickly dissolution mixes.In above-mentioned process for preparation, it should be noted that whole operation clean environment is hygienic, dust-proof.
Product of the present invention, after 5 times of dilution, clean effect reaches the requirement of GB/T 13174-2008.
Embodiment 2
The present embodiment is preferred embodiment on that basis of example 1, quality and 1 phase of embodiment of raw materials used (component)
Together, the weight fraction ratio of each raw material of the concentration liquid detergent are as follows:
Methyl ester ethoxylates 15
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 3
Aliphatic alcohol polyethenoxy (3) ether 35
Aliphatic alcohol polyethenoxy (7) ether 15
1,2-benzisothiazolin-3-one 0.2
Glycerine 5
Polyethylene glycol 6.5
Propene carbonate 20
Essence 0.3；
Unit of weight used in the present embodiment is gram, or kilogram；
The preparation method of the concentration liquid detergent of this example is referring to embodiment 1.
Product of the present invention, after 5 times of dilution, clean effect reaches the requirement of GB/T 13174-2008.
Embodiment 3
The present embodiment is preferred embodiment on that basis of example 1, quality and 1 phase of embodiment of raw materials used (component)
Together, the weight fraction ratio of each raw material of the concentration liquid detergent are as follows:
Methyl ester ethoxylates 10
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 5
Aliphatic alcohol polyethenoxy (3) ether 40
Aliphatic alcohol polyethenoxy (7) ether 15
Aliphatic alcohol polyethenoxy (9) ether 5
1,2-benzisothiazolin-3-one 0.2
Glycerine 5
Polyethylene glycol 5
Propene carbonate 14.5
Essence 0.3；
Unit of weight used in the present embodiment is gram, or kilogram；
The preparation method of the concentration liquid detergent of this example is referring to embodiment 1.
Product of the present invention, after 5 times of dilution, clean effect reaches the requirement of GB/T 13174-2008.
Embodiment 4
The present embodiment is preferred embodiment on that basis of example 1, quality and 1 phase of embodiment of raw materials used (component)
Together, the weight fraction ratio of each raw material of the concentration liquid detergent are as follows:
Methyl ester ethoxylates 10
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 5
Aliphatic alcohol polyethenoxy (3) ether 30
Aliphatic alcohol polyethenoxy (7) ether 15
1,2-benzisothiazolin-3-one 0.3
Glycerine 5
Polyethylene glycol 10
Propene carbonate 24.5
Essence 0.2；
Unit of weight used in the present embodiment is gram, or kilogram；
The preparation method of the concentration liquid detergent of this example is referring to embodiment 1.
Product of the present invention, after 5 times of dilution, clean effect reaches the requirement of GB/T 13174-2008.
Embodiment 5
The present embodiment is preferred embodiment on that basis of example 1, quality and 1 phase of embodiment of raw materials used (component)
Together, the weight fraction ratio of each raw material of the concentration liquid detergent are as follows:
Methyl ester ethoxylates 10
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 5
Aliphatic alcohol polyethenoxy (3) ether 35
Aliphatic alcohol polyethenoxy (7) ether 15
1,2-benzisothiazolin-3-one 0.3
Glycerine 5
Polyethylene glycol 10
Propene carbonate 19.5
Essence 0.2；
Unit of weight used in the present embodiment is gram, or kilogram；
The preparation method of the concentration liquid detergent of this example is referring to embodiment 1.
Product of the present invention, after 5 times of dilution, clean effect reaches the requirement of GB/T 13174-2008.
Claims (6)
1. a kind of concentration liquid detergent for water-solubility membrane packaging, it is characterised in that: the raw material of the concentration liquid detergent are as follows: methyl esters
Ethoxylate, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic surfactant, 1,2- benzisothiazole -3-
Ketone, glycerine, polyethylene glycol, propene carbonate and essence, the weight part ratio of each raw material are as follows:
Methyl ester ethoxylates 10~20
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 3~5
Nonionic surfactant 45~60
1,2-benzisothiazolin-3-one 0.1~0.3
Glycerine 1~5
Polyethylene glycol 5~10
Propene carbonate 10~25
Essence 0.2~0.4；
The nonionic surfactant is aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether, poly alkyl alcohol
The mixing of one or more of ethylene oxide (9) ether.
2. the concentration liquid detergent according to claim 1 for water-solubility membrane packaging, it is characterised in that: each raw material
Weight fraction ratio are as follows:
Methyl ester ethoxylates 15
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 3
Aliphatic alcohol polyethenoxy (3) ether 35
Aliphatic alcohol polyethenoxy (7) ether 15
1,2-benzisothiazolin-3-one 0.2
Glycerine 5
Polyethylene glycol 6.5
Propene carbonate 20
Essence 0.3.
3. the concentration liquid detergent according to claim 1 for water-solubility membrane packaging, it is characterised in that: each raw material
Weight fraction ratio are as follows:
Methyl ester ethoxylates 10
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 5
Aliphatic alcohol polyethenoxy (3) ether 40
Aliphatic alcohol polyethenoxy (7) ether 15
Aliphatic alcohol polyethenoxy (9) ether 5
1,2-benzisothiazolin-3-one 0.2
Glycerine 5
Polyethylene glycol 5
Propene carbonate 14.5
Essence 0.3.
4. the concentration liquid detergent according to claim 1 for water-solubility membrane packaging, it is characterised in that: each raw material
Weight fraction ratio are as follows:
Methyl ester ethoxylates 10
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 5
Aliphatic alcohol polyethenoxy (3) ether 30
Aliphatic alcohol polyethenoxy (7) ether 15
1,2-benzisothiazolin-3-one 0.3
Glycerine 5
Polyethylene glycol 10
Propene carbonate 24.5
Essence 0.2.
5. the concentration liquid detergent according to claim 1 for water-solubility membrane packaging, it is characterised in that: each raw material
Weight fraction ratio are as follows:
Methyl ester ethoxylates 10
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 5
Aliphatic alcohol polyethenoxy (3) ether 35
Aliphatic alcohol polyethenoxy (7) ether 15
1,2-benzisothiazolin-3-one 0.3
Glycerine 5
Polyethylene glycol 10
Propene carbonate 19.5
Essence 0.2.
6. a kind of preparation method of the concentration liquid detergent for water-solubility membrane packaging, it is characterised in that: the concentration liquid detergent
Raw material are as follows: methyl ester ethoxylates, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, nonionic surfactant, 1,2- benzo
Isothiazoline -3- ketone, glycerine, polyethylene glycol, propene carbonate and essence, the weight part ratio of each raw material are as follows:
Methyl ester ethoxylates 10~20
Aliphatic alcohol polyethenoxy (2) ether sodium sulfate 3~5
Nonionic surfactant 45~60
1,2-benzisothiazolin-3-one 0.1~0.3
Glycerine 1~5
Polyethylene glycol 5~10
Propene carbonate 10~25
Essence 0.2~0.4；
The nonionic surfactant is aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether, poly alkyl alcohol
The mixing of one or more of ethylene oxide (9) ether；
The preparation method comprises the following steps:
A. it takes the polyethylene glycol, glycerine, propene carbonate to be added in material kettle according to above-mentioned weight proportion, then distinguishes
The methyl ester ethoxylates, aliphatic alcohol polyethenoxy (2) ether sodium sulfate, non-ionic surface are sequentially added according to said ratio
Activating agent obtains mixed liquor A to being completely dissolved；
B. and then respectively according to sequentially adding 1,2-benzisothiazolin-3-one, essence in the said ratio first mixed liquor A,
Obtain mixed liquid B；
C. it by above-mentioned mixed liquid B, is handled with 200 mesh filter-cloth filterings, obtains the concentration liquid detergent.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410791952.XA CN105754737B (en) | 2014-12-19 | 2014-12-19 | A kind of concentration liquid detergent and preparation method thereof for water-solubility membrane packaging |
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| CN201410791952.XA CN105754737B (en) | 2014-12-19 | 2014-12-19 | A kind of concentration liquid detergent and preparation method thereof for water-solubility membrane packaging |
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| CN105754737A CN105754737A (en) | 2016-07-13 |
| CN105754737B true CN105754737B (en) | 2019-03-01 |
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5427697A (en) * | 1993-12-17 | 1995-06-27 | The Procter & Gamble Company | Clear or translucent, concentrated fabric softener compositions |
| WO1999066016A1 (en) * | 1998-06-12 | 1999-12-23 | Henkel Kommanditgesellschaft Auf Aktien | Use of 1,3-dioxolane-2-ones in detergents |
| CN102159692A (en) * | 2008-08-14 | 2011-08-17 | 麦莱琉卡有限公司 | Ultra concentrated liquid laundry detergent |
| CN102186962A (en) * | 2008-10-15 | 2011-09-14 | 方法产品有限公司 | Liquid cleaning compositions |
| CN102242022A (en) * | 2011-06-15 | 2011-11-16 | 于文 | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof |
| CN102618398A (en) * | 2012-02-15 | 2012-08-01 | 中国日用化学工业研究院 | Concentrated fabric liquid detergent containing fatty acid methyl ester sulfonate and preparation method of concentrated fabric liquid detergent |
| CN102643725A (en) * | 2012-04-25 | 2012-08-22 | 中国日用化学工业研究院 | Hyper-concentrated liquid detergent and preparation technique thereof |
| CN103298920A (en) * | 2011-01-12 | 2013-09-11 | 宝洁公司 | Method for controlling the plasticization of a water soluble film |
-
2014
- 2014-12-19 CN CN201410791952.XA patent/CN105754737B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5427697A (en) * | 1993-12-17 | 1995-06-27 | The Procter & Gamble Company | Clear or translucent, concentrated fabric softener compositions |
| WO1999066016A1 (en) * | 1998-06-12 | 1999-12-23 | Henkel Kommanditgesellschaft Auf Aktien | Use of 1,3-dioxolane-2-ones in detergents |
| CN102159692A (en) * | 2008-08-14 | 2011-08-17 | 麦莱琉卡有限公司 | Ultra concentrated liquid laundry detergent |
| CN102186962A (en) * | 2008-10-15 | 2011-09-14 | 方法产品有限公司 | Liquid cleaning compositions |
| CN103298920A (en) * | 2011-01-12 | 2013-09-11 | 宝洁公司 | Method for controlling the plasticization of a water soluble film |
| CN102242022A (en) * | 2011-06-15 | 2011-11-16 | 于文 | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof |
| CN102618398A (en) * | 2012-02-15 | 2012-08-01 | 中国日用化学工业研究院 | Concentrated fabric liquid detergent containing fatty acid methyl ester sulfonate and preparation method of concentrated fabric liquid detergent |
| CN102643725A (en) * | 2012-04-25 | 2012-08-22 | 中国日用化学工业研究院 | Hyper-concentrated liquid detergent and preparation technique thereof |
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| CN105754737A (en) | 2016-07-13 |
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Address after: 100094 block B, building 1, yard 2, Yongcheng North Road, Yongfeng Industrial base, Haidian District, Beijing Patentee after: Beijing green umbrella Technology Co., Ltd Address before: 100094 block B, building 1, yard 2, Yongcheng North Road, Yongfeng Science Park, Haidian District, Beijing Patentee before: Beijing lvsan Chemical Co., Ltd |