CN113736576A - Washing gel bead and preparation method thereof - Google Patents
Washing gel bead and preparation method thereof Download PDFInfo
- Publication number
- CN113736576A CN113736576A CN202111228011.1A CN202111228011A CN113736576A CN 113736576 A CN113736576 A CN 113736576A CN 202111228011 A CN202111228011 A CN 202111228011A CN 113736576 A CN113736576 A CN 113736576A
- Authority
- CN
- China
- Prior art keywords
- alcohol
- sorbitol
- laundry
- polyoxyethylene ether
- stirring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011324 bead Substances 0.000 title claims abstract description 68
- 238000005406 washing Methods 0.000 title abstract description 49
- 238000002360 preparation method Methods 0.000 title abstract description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 93
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims abstract description 35
- 239000000600 sorbitol Substances 0.000 claims abstract description 35
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 34
- 238000003756 stirring Methods 0.000 claims abstract description 24
- 238000005202 decontamination Methods 0.000 claims abstract description 19
- 230000003588 decontaminative effect Effects 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 16
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 16
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims abstract description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 10
- 239000003755 preservative agent Substances 0.000 claims abstract description 8
- 230000002335 preservative effect Effects 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 238000007599 discharging Methods 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 238000004806 packaging method and process Methods 0.000 claims abstract description 4
- 235000011187 glycerol Nutrition 0.000 claims description 31
- 235000010356 sorbitol Nutrition 0.000 claims description 29
- 239000007788 liquid Substances 0.000 claims description 24
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 abstract description 6
- 239000000047 product Substances 0.000 description 32
- 238000009833 condensation Methods 0.000 description 21
- 230000005494 condensation Effects 0.000 description 21
- 230000000052 comparative effect Effects 0.000 description 20
- 230000000694 effects Effects 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 238000010521 absorption reaction Methods 0.000 description 7
- 239000012528 membrane Substances 0.000 description 7
- 238000011049 filling Methods 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 230000002950 deficient Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000011112 process operation Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- -1 sodium fatty alcohol Chemical class 0.000 description 2
- 238000013112 stability test Methods 0.000 description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 206010048962 Brain oedema Diseases 0.000 description 1
- 208000010412 Glaucoma Diseases 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 102100040396 Transcobalamin-1 Human genes 0.000 description 1
- 101710124861 Transcobalamin-1 Proteins 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 208000006752 brain edema Diseases 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 235000019533 nutritive sweetener Nutrition 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/043—Liquid or thixotropic (gel) compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a washing gel bead and a preparation method thereof, belonging to the technical field of clothes washing products, and comprising a decontamination component, glycerol, alcohol, sorbitol, a preservative and water; wherein, the content of the glycerol is 20.0 to 40.0 percent more than that of the sorbitol, and the content of the alcohol is 3.0 to 5.0 percent; putting fatty alcohol-polyoxyethylene ether sodium sulfate, sorbitol and glycerol in corresponding weight percentages into a reaction kettle, heating, uniformly stirring, and standing; (2) adding water with corresponding mass percentage, then stirring the mixture evenly again, cooling the mixture to normal temperature, and standing the mixture; (3) adding fatty alcohol-polyoxyethylene ether-9 and alcohol according to the corresponding mass percentage, slowly stirring at a low speed, fully and uniformly mixing, standing, discharging and packaging to obtain a finished product. The washing gel bead has proper viscosity, can keep stable viscosity and gram weight for a long time, and has simple and efficient preparation method.
Description
Technical Field
The invention relates to the technical field of clothes washing products, and particularly belongs to a washing gel bead and a preparation method thereof.
Background
With the improvement of living standard and quality, people have higher and higher requirements on the convenience degree of cleaning and washing clothes, and the traditional washing powder laundry detergent is difficult to meet the requirements of consumers, so that laundry beads, which are substitutes of the laundry detergent or the washing powder, are gradually produced in the market.
The washing condensation bead is different from the traditional washing powder or washing liquid, the concentrated liquid with a low water formula is arranged inside the washing condensation bead and is wrapped by an external mold, the outer membrane of the washing condensation bead can bear the weight of about 15 kilograms and can be dissolved when meeting water, and the concentrated liquid can be rapidly blended into the water, so that various types of clothes can be easily and cleanly washed by only half of the amount of the washing liquid, and one washing condensation bead can be conveniently and quantitatively added, and is convenient and rapid.
However, due to its special structure, the viscosity and the gram weight are required to be stable, for example, the viscosity is required to be not more than 200mPa · S, when the viscosity is too high, the liquid cannot be absorbed, the viscosity is higher than 200, the liquid can be drawn during filling, the line can be invaded, the outer film can not be sealed, the product can leak, when the viscosity is higher than 250, the filling opening can be blocked, the machine is easy to be damaged, and the viscosity of the finished product is too high, the liquid can be adhered to the inner wall of the film, and the quality and the appearance are affected. However, the viscosity can not be too low, the viscosity is lower than 150, liquid impacts the die during filling, so that liquid is splashed, the outer film can not be sealed, and the product leaks, so that the problems that the handling is difficult in the production process, defective products and leakage are easy to occur, even machine faults and the like are caused, and the production efficiency and the product quality are influenced.
In addition, even if the viscosity of the internal liquid of the washing condensation bead is controlled within the viscosity range of 150-200 mPas when the washing condensation bead is delivered from a factory, the property of the washing condensation bead on the market is generally not stable enough, and even if the viscosity is relatively proper when the washing condensation bead is delivered from the factory, the property is unstable, the viscosity changes after a period of time, most of the washing condensation beads have the situation that the viscosity is continuously increased, the viscosity is rapidly increased to be more than 200 mPas, the liquid is adhered to the inner wall of the membrane, the quality of the liquid is influenced, the appearance is also influenced, and the leakage can occur for a long time. In order to avoid adhesion, too complex components are added into the washing condensation beads, so that the decontamination effect is influenced, stimulation can be generated, the washing condensation beads are not suitable for washing of underwear, or the manufacturing process of the outer membrane of the washing condensation beads is improved, and higher energy and manufacturing guarantee cost are required, so that the price of the washing condensation beads must be increased, the popularization of the washing condensation beads is not facilitated, and the popularization of the washing condensation beads can be influenced without solving the problems. Therefore, the method becomes a technical problem which is very troublesome in the field and needs to be solved urgently.
Disclosure of Invention
Aiming at the defects and shortcomings in the background technology, the invention provides the washing gel bead and the preparation method thereof, wherein the washing gel bead has proper viscosity, can keep stable viscosity and gram weight for a long time, and is simple and efficient in preparation method.
In order to realize the purpose, the invention adopts the following technical scheme to realize the purpose:
a laundry bead comprises a detersive ingredient, glycerol, alcohol, sorbitol, a preservative and water;
wherein the content of glycerol is 20.0-40.0% more than that of sorbitol, and the content of alcohol is 3.0% -5.0%.
Further measures taken are: the decontamination component comprises fatty alcohol-polyoxyethylene ether sulfate sodium salt and fatty alcohol-polyoxyethylene ether-9.
Further measures taken are: comprises the following substances, by mass, 11.0-15.0% of a decontamination component, 42.0-58.0% of glycerol, 3.0-5.0% of alcohol, 18.0-28.0% of sorbitol, 0.1-1.0% of a preservative, and the balance of water added to 100%.
Further measures taken are: the mass percentage of the fatty alcohol-polyoxyethylene ether sulfate sodium salt is 9.0-13.0%; the mass percentage of the fatty alcohol-polyoxyethylene ether-9 is 1.0-3.0%.
Further measures taken are: the viscosity of the liquid inside the laundry beads was 165-185 mPaS.
Further measures taken are: the viscosity of the liquid inside the laundry beads was 180 mPaS.
Further measures taken are: also comprises trace pigment and essence.
A method for preparing laundry beads comprises the following steps,
(1) putting fatty alcohol-polyoxyethylene ether sodium sulfate, sorbitol and glycerol in corresponding weight percentages into a reaction kettle, heating, uniformly stirring, and then standing;
(2) adding water with corresponding mass percentage into the reaction kettle reacted in the step (1), then stirring again to be uniformly mixed, cooling to normal temperature, and standing;
(3) and (2) adding fatty alcohol-polyoxyethylene ether-9 and alcohol in corresponding mass percentage into the reaction kettle reacted in the step (1), slowly stirring at a low speed, fully mixing uniformly, standing, discharging and packaging to obtain a finished product.
Further measures taken are: the standing time in the step (1) and the step (2) is 15-25 minutes; the standing time in the step (3) is 24 hours.
Further measures taken are: the stirring speed in the step (1) and the step (2) is 280-300 revolutions per minute, and the stirring time is 8-10 minutes; the stirring speed in the step (3) is 160-180 r/min, and the stirring time is 40-60 min.
In order to control the cost, keep the ingredients simple and solve the problems of the background art under the condition that the raw materials are easy to obtain, the team of the invention finds that the glycerin, the alcohol and the sorbitol are added into the washing gel bead through long-term intensive research, the glycerin, the alcohol and the sorbitol are mutually coordinated, the viscosity of the liquid in the washing gel bead can be obviously improved, the proper viscosity and the proper gram weight can be kept for a long time, the washing gel bead can keep stable properties for a long time, the deterioration or the leakage is not easy to occur, and the production process is smoother.
Glycerin is traditionally used for filling and moisturizing; sorbitol is cheap and easily available, is white hygroscopic powder or crystalline powder, sheet or granule, is odorless, can be used as a nutritive sweetener and a wetting agent, is suitable for treating cerebral edema and glaucoma, is usually used as a sugar-free sweetener on food or is also usually used on toothpaste, but is never applied to laundry beads; while alcohol is generally used for disinfection or preservation. However, in the invention, the whole water absorption degree of the liquid in the washing gel bead is proper and stable through the interaction of the glycerol and the sorbitol, the softness and stability of the outer membrane of the washing gel bead can be kept, the adhesion between the liquid and the membrane can be avoided, the optimal absorption balance and viscosity requirement can be achieved through the adjustment of alcohol between the glycerol and the sorbitol, the whole body is kept in a slow and continuous water absorption state but not excessively large absorption, the gram weight is kept stable, the whole body of the washing gel bead has proper viscosity through the fusion and the mutual cooperation of the glycerol and the sorbitol, the production process is smooth and efficient, the whole quality is ensured, the defective product rate is obviously reduced, the properties such as the viscosity of the washing gel bead can be effectively kept stable for a long time, the quality reduction of the washing gel bead or the occurrence of liquid and membrane adhesion and the like can be avoided, and meanwhile, the dirt-removing capacity of the washing gel bead can not be influenced by the addition of the glycerol and the sorbitol, the invention has the advantages that the components are easy to obtain and cheap, the cost can be effectively controlled by using the three components under the condition that the price of the existing raw materials continuously rises, the production cost is reduced to a certain degree, the over-high finished product is avoided, and the beneficial effects are remarkable.
In addition, in the research process, the three substances are not just combined at once, and the proportional relationship between the glycerol and the sorbitol is required to be controlled, so that the content of the glycerol is 20.0-40.0% more than that of the sorbitol, and the content of the alcohol is strictly controlled, so that the content of the alcohol is 3.0-5.0%, so that the three substances can exert excellent effects in the laundry condensation beads, the whole laundry condensation beads cannot run out of water, the slow and continuous water absorption state can be kept, the absorption balance can be achieved, and the properties such as the viscosity, the gram weight and the like of the whole laundry condensation beads are kept stable. This was discovered by the present team after a long time of development, and was the reason why these three substances have been discovered by those skilled in the art.
In addition, the invention also selects sodium fatty alcohol polyoxyethylene ether sulfate (AES) and fatty alcohol polyoxyethylene ether-9 (AEO-9) as the decontamination components, so that the integral decontamination capability is extremely strong, and the integral decontamination effect is not influenced by the conflict between the actions of glycerol, alcohol, sorbitol and the like.
Through the formula matching and the proper preparation method, the viscosity of the liquid in the washing condensation bead can be controlled within the range of 165-185 mPa.S, and when the viscosity of the liquid in the washing condensation bead is 180 mPa.S, the optimal viscosity and gram weight can be achieved, and the washing condensation bead has stable overall property and strong decontamination effect. The preparation method is simple, can keep full reaction of all substances, has stable property, can improve the operation efficiency, operates smoothly and reduces complicated process operation steps.
Through the technical scheme, compared with the prior art, the invention has the following beneficial effects:
1. according to the invention, the glycerin, the alcohol and the sorbitol are added into the washing gel bead, and the proportion of the glycerin, the alcohol and the sorbitol is controlled, so that the glycerin, the alcohol and the sorbitol are coordinated with each other and supplement each other, the viscosity of liquid in the washing gel bead is obviously improved, the proper viscosity and gram weight can be kept for a long time, the washing gel bead can keep stable properties for a long time, the deterioration or the leakage is not easy to occur, and the production process is smoother.
2. The fatty alcohol-polyoxyethylene ether sodium sulfate and the fatty alcohol-polyoxyethylene ether-9 are added as the decontamination components, so that the integral decontamination capability is extremely strong, and the integral decontamination effect is not influenced by the conflict between the actions of glycerol, alcohol, sorbitol and the like.
2. The preparation method disclosed by the invention is simple in steps, can keep full reaction of all substances, is stable in property, can improve the operation efficiency, is smooth in operation, and reduces the complicated process operation steps.
Detailed Description
In order to clearly understand the technical solutions adopted by the present invention, the following description is made on the preferred embodiments of the present invention, and it should be understood that the embodiments described herein are only used for illustrating and explaining the present invention, and are not used to limit the present invention.
Example 1: the washing gel bead comprises, by mass, 13.0% of fatty alcohol-polyoxyethylene ether sulfate sodium salt, 93.0% of fatty alcohol-polyoxyethylene ether, 42.0% of glycerol, 5.0% of alcohol, 22.0% of sorbitol, 0.1% of a preservative, and the balance of water added to 100%.
Example 2: a washing gel bead comprises, by mass, 9.0% of fatty alcohol-polyoxyethylene ether sulfate sodium salt, 91.0% of fatty alcohol-polyoxyethylene ether, 50.0% of glycerol, 3.0% of alcohol, 28.0% of sorbitol, 1.0% of a preservative, trace pigments, trace essence and the balance of water to 100%.
Example 3: the washing gel bead comprises, by mass, 11.6% of fatty alcohol-polyoxyethylene ether sulfate sodium salt, 92.0% of fatty alcohol-polyoxyethylene ether, 48.4% of glycerol, 4.0% of alcohol, 25.0% of sorbitol, 0.2% of a preservative, and the balance of water added to 100%.
The above examples 1-3 were all prepared by the following preparation method, comprising the steps of:
(1) putting fatty alcohol-polyoxyethylene ether sodium sulfate, sorbitol and glycerol in corresponding weight percentages into a reaction kettle, heating, uniformly stirring, and then standing;
(2) adding water with corresponding mass percentage into the reaction kettle reacted in the step (1), then stirring again to be uniformly mixed, cooling to normal temperature, and standing;
(3) and (2) adding fatty alcohol-polyoxyethylene ether-9 and alcohol in corresponding mass percentage into the reaction kettle reacted in the step (1), slowly stirring at a low speed, fully mixing uniformly, standing, discharging and packaging to obtain a finished product.
Wherein, the standing time in the step (1) and the step (2) is 15-25 minutes; the standing time in the step (3) was 24 hours. The stirring speed in the step (1) and the step (2) is 280-300 revolutions per minute, and the stirring time is 8-10 minutes; the stirring speed in the step (3) is 160-180 r/min, and the stirring time is 40-60 min.
The performance index test of the finished laundry beads obtained in examples 1-3 of the present invention was performed according to the laundry detergent composition execution standard QB/T1224-:
1. appearance: transparent, has different colors, does not layer and has no obvious suspended substances or sediments.
The PH value is less than or equal to 10.5, and the actual measurement is 7.8-8.2.
3. And (3) investigating heat resistance stability: keeping the temperature at (40 +/-2) ℃ for 24 hours, and after the temperature is recovered to the room temperature, the temperature is not obviously changed from the room temperature before the test, and the heat resistance stability test is qualified.
4. And (3) cold resistance stability investigation: keeping the temperature at (-5 +/-2) DEG C for 24 hours, and after the temperature is recovered to the room temperature, no obvious change is caused between the temperature and the room temperature before the test, and the cold resistance stability test is qualified.
5. The total active substance is more than or equal to 15, and is actually measured to be 61.2-63.4.
6. The total phosphorus pentoxide proportion is less than or equal to 1.1, and the measured content is less than or equal to 0.1.
Comparative examples were also conducted in the present invention, and the following are the case of each comparative example, and the case of the control group.
Comparative example 1: the glycerin was replaced with coconut oil essence added to the conventional laundry beads, and the other ingredients, proportions and preparation methods were the same as those of example 3.
Comparative example 2: sorbitol was replaced with a stabilizer conventionally added to the laundry beads, and the other ingredients, proportions and preparation method were the same as in example 3.
Comparative example 3: the other components, ratios and preparation methods were the same as those of example 3 without adding alcohol.
Comparative example 4: the amount of alcohol added was 6.0%, and the other components, proportions and preparation method were the same as those of example 3.
Comparative example 5: the amount of sorbitol added was 8.0%, and other components, proportions and preparation methods were the same as those of example 3.
Control group 1: conventional qualified laundry bead products were prepared as control 1 products using formulations and formulations commonly used in the art.
And the finished products of comparative examples 1 to 5, comparative example 1, and the finished products obtained in examples of the present invention 1 to 3 were subjected to the following effect comparison tests.
(II) viscosity stability control test
The finished products of examples 1 to 3 of the present invention, the finished products of comparative examples 1 to 5, and the finished product of comparative example 1 were subjected to viscosity measurement at different times by using a viscosity measuring instrument, respectively, at the time of blending, after standing for 1 day, at the time of filling, after storing for 5 days, after storing for 15 days, and after storing for 30 days, and then the results were summarized as shown in table 1 below.
Table 1: viscosity stability contrast test detection result
As is apparent from the results in table 1 above, the finished products prepared in examples 1-3 have superior viscosity stability compared to the conventionally qualified products of control 1, so that the laundry beads can maintain stable viscosity for a long period of time, and prevent deterioration, leakage, or adhesion to the outer membrane. From the results of comparative examples 1 to 5, it can be seen that glycerin, alcohol and sorbitol, which act in concert with each other, play an important role in improving the viscosity of the liquid inside the laundry bead, and require strict control of the ratio and amount of addition to exert an excellent viscosity stability effect so that the viscosity is stably maintained within a more appropriate range.
Comparative test for grammage stability
The finished products of examples 1 to 3 of the present invention, the finished products of comparative examples 1 to 5, and the finished products of comparative example 1 were weighed using a weighing apparatus at different times, respectively, at the time of filling, after 5 days of storage, after 15 days of storage, and after 30 days of storage, and then weighing result data at different times were summarized, as shown in table 2 below.
Table 2: detection result of gram weight stability contrast test
From the data results in table 2 above, it can be seen that, compared with the conventionally qualified product of the control group 1, the finished products prepared in the embodiments 1 to 3 can maintain stable gram weight for a long time, without dropping the gram weight or increasing the gram weight, so that the gram weight of the product exceeds the standard or the product deteriorates. From the data results of comparative examples 1-5, it can be seen that glycerol, ethanol and sorbitol, which are the key components in maintaining the absorption balance and maintaining the gram weight stability, are all the less important in the case of a certain proportion.
(IV) comparative test for soil Release Effect
The finished products of examples 1-3, the finished products of comparative examples 1-5 and the finished products of comparative group 1 were tested for soil-release ability according to the laundry soil-release component standard QB/T1224-.
Table 3: test result of decontamination effect contrast test
From the data results in table 3 above, it can be seen that the carbon black R ratio, the protein R ratio, and the cortex R ratio of the finished products prepared in examples 1-3 are significantly better than those of the conventionally qualified product of control group 1, indicating that the finished products prepared in examples 1-3 have excellent detergency; the test results of comparative examples 1 to 5 are combined, and it can be seen that the synergistic effect of the glycerol, the alcohol and the sorbitol in a certain proportion does not affect the overall decontamination effect and can also improve the decontamination effect, however, when one of the glycerol, the alcohol and the sorbitol is absent, the effect is far away, and the overall balance can be affected, thereby affecting the decontamination effect.
By combining the above embodiments and the corresponding tests and results, it can be concluded that the laundry bead of the present invention can maintain stable viscosity and gram weight for a long time, has high decontamination efficiency, has simple overall components, is beneficial to controlling cost, and is suitable for popularization and application.
The above description is only for the purpose of illustrating the embodiments of the present invention and not for the purpose of limiting the same, and equivalent modifications and variations of the embodiments of the present invention will be apparent to those skilled in the art without departing from the overall spirit of the invention.
Claims (10)
1. A laundry bead, characterized by: comprises decontamination components, glycerin, alcohol, sorbitol, preservative and water;
wherein the content of glycerol is 20.0-40.0% more than that of sorbitol, and the content of alcohol is 3.0% -5.0%.
2. A laundry bead as claimed in claim 1, wherein: the decontamination component comprises fatty alcohol-polyoxyethylene ether sulfate sodium salt and fatty alcohol-polyoxyethylene ether-9.
3. A laundry bead as claimed in claim 1, wherein: comprises the following substances, by mass, 11.0-15.0% of a decontamination component, 42.0-58.0% of glycerol, 3.0-5.0% of alcohol, 18.0-28.0% of sorbitol, 0.1-1.0% of a preservative, and the balance of water added to 100%.
4. A laundry bead as claimed in claim 2, wherein: the mass percentage of the fatty alcohol-polyoxyethylene ether sulfate sodium salt is 9.0-13.0%; the mass percentage of the fatty alcohol-polyoxyethylene ether-9 is 1.0-3.0%.
5. A laundry bead as claimed in claim 1, wherein: the viscosity of the liquid inside the laundry beads was 165-185 mPaS.
6. A laundry bead as claimed in claim 5, wherein: the viscosity of the liquid inside the laundry beads was 180 mPaS.
7. A laundry bead as claimed in claim 1, wherein: also comprises trace pigment and essence.
8. A method for preparing laundry beads, comprising: comprises the following steps of (a) carrying out,
(1) putting fatty alcohol-polyoxyethylene ether sodium sulfate, sorbitol and glycerol in corresponding weight percentages into a reaction kettle, heating, uniformly stirring, and then standing;
(2) adding water with corresponding mass percentage into the reaction kettle reacted in the step (1), then stirring again to be uniformly mixed, cooling to normal temperature, and standing;
(3) and (2) adding fatty alcohol-polyoxyethylene ether-9 and alcohol in corresponding mass percentage into the reaction kettle reacted in the step (1), slowly stirring at a low speed, fully mixing uniformly, standing, discharging and packaging to obtain a finished product.
9. A method of making a laundry bead as claimed in claim 7, wherein: the standing time in the step (1) and the step (2) is 15-25 minutes; the standing time in the step (3) is 24 hours.
10. A method of making a laundry bead as claimed in claim 7, wherein: the stirring speed in the step (1) and the step (2) is 280-300 revolutions per minute, and the stirring time is 8-10 minutes; the stirring speed in the step (3) is 160-180 r/min, and the stirring time is 40-60 min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111228011.1A CN113736576A (en) | 2021-10-21 | 2021-10-21 | Washing gel bead and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111228011.1A CN113736576A (en) | 2021-10-21 | 2021-10-21 | Washing gel bead and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113736576A true CN113736576A (en) | 2021-12-03 |
Family
ID=78727007
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111228011.1A Pending CN113736576A (en) | 2021-10-21 | 2021-10-21 | Washing gel bead and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113736576A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115386435A (en) * | 2022-09-06 | 2022-11-25 | 湖北雅绿镓新材料科技有限公司 | Colorful deep sea crystal salt bacteriostatic decontamination fragrance-retaining washing gel bead and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106350271A (en) * | 2016-08-23 | 2017-01-25 | 余姚市德派日用品有限公司 | Color-protecting clothes washing condensate beads and preparation method thereof |
| CN106350268A (en) * | 2016-08-23 | 2017-01-25 | 余姚市德派日用品有限公司 | Laundry condensate bead and preparation method thereof |
| CN106381234A (en) * | 2016-08-23 | 2017-02-08 | 余姚市德派日用品有限公司 | Brightening laundry bead and preparation method thereof |
| CN111808694A (en) * | 2020-07-14 | 2020-10-23 | 福建恒安集团有限公司 | Stable long-acting fragrance-retaining washing gel bead and preparation method thereof |
-
2021
- 2021-10-21 CN CN202111228011.1A patent/CN113736576A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106350271A (en) * | 2016-08-23 | 2017-01-25 | 余姚市德派日用品有限公司 | Color-protecting clothes washing condensate beads and preparation method thereof |
| CN106350268A (en) * | 2016-08-23 | 2017-01-25 | 余姚市德派日用品有限公司 | Laundry condensate bead and preparation method thereof |
| CN106381234A (en) * | 2016-08-23 | 2017-02-08 | 余姚市德派日用品有限公司 | Brightening laundry bead and preparation method thereof |
| CN111808694A (en) * | 2020-07-14 | 2020-10-23 | 福建恒安集团有限公司 | Stable long-acting fragrance-retaining washing gel bead and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115386435A (en) * | 2022-09-06 | 2022-11-25 | 湖北雅绿镓新材料科技有限公司 | Colorful deep sea crystal salt bacteriostatic decontamination fragrance-retaining washing gel bead and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5964420B2 (en) | Gel, temperature-resistant gummy candy containing the gel, and method for preparing the gummy candy | |
| CN113736576A (en) | Washing gel bead and preparation method thereof | |
| CN1957732B (en) | Xylitol hard candy, and preparation method | |
| CN103564273A (en) | Composite food raising agent and applications thereof | |
| CN107996608A (en) | A kind of Camellia nitidissima cuttage seeding root-growing agent | |
| CN109369690A (en) | One kind containing Zn complex, containing Zn composite heat stabilizer and preparation method thereof, application | |
| CN101095473A (en) | Powder type composite cake emulsifying agent | |
| CN110204792A (en) | A kind of preparation method of monascorubin edible film against sunshine | |
| CN106124427A (en) | A kind of physics and chemistry screening technique being suitable for being processed into the rice special of rice noodle | |
| US20080253975A1 (en) | Composition for dyeing dental plaque for evaluating dental caries activity | |
| CN110857475B (en) | Hole sealing agent for aluminum alloy anodic oxide film, preparation method and sealing method | |
| CN111763587B (en) | Artificial pit mud for brewing and preparation method thereof | |
| JPS6015291B2 (en) | bread dough | |
| JP2015531599A (en) | Whitening agent for noodle products containing polysaccharide alcohol and use thereof | |
| KR960003887B1 (en) | Process for preparing noodles | |
| JP3013196B2 (en) | Manufacturing method of noodles | |
| CN102018155A (en) | Lotus seed paste mooncake modifier | |
| CN1974790B (en) | Method of preventing high fructose syrup from crystallizing | |
| CN109123601A (en) | It is a kind of to wrap Yoghourt fillings and preparation method thereof of ordering | |
| TWI700042B (en) | Process for preparing whey protein gel | |
| JP3535092B2 (en) | Manufacturing method of sake for sake brewing and sake | |
| CN115529989B (en) | Hydrogel type fruit mask containing humic acid and preparation method thereof | |
| JPS60203181A (en) | Composition for culture medium | |
| CN118872745A (en) | Cappuccino beverage and preparation method thereof | |
| JP2001253807A (en) | Pack agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20211203 |
|
| RJ01 | Rejection of invention patent application after publication |