CN114940925A - Environment-friendly surfactant composition - Google Patents
Environment-friendly surfactant composition Download PDFInfo
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- CN114940925A CN114940925A CN202210470781.5A CN202210470781A CN114940925A CN 114940925 A CN114940925 A CN 114940925A CN 202210470781 A CN202210470781 A CN 202210470781A CN 114940925 A CN114940925 A CN 114940925A
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- surfactant
- ammonium salt
- sulfonate
- alkyl
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- 239000004094 surface-active agent Substances 0.000 title claims abstract description 38
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- -1 alkyl quaternary ammonium salt Chemical class 0.000 claims abstract description 27
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 9
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 9
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 9
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 9
- 229930013930 alkaloid Natural products 0.000 claims abstract description 7
- 229930182470 glycoside Natural products 0.000 claims abstract description 7
- 239000002562 thickening agent Substances 0.000 claims abstract description 7
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims abstract description 6
- 229940069521 aloe extract Drugs 0.000 claims abstract description 6
- 229960003237 betaine Drugs 0.000 claims abstract description 6
- 239000001913 cellulose Substances 0.000 claims abstract description 6
- 229920002678 cellulose Polymers 0.000 claims abstract description 6
- 235000006708 antioxidants Nutrition 0.000 claims description 8
- 150000003863 ammonium salts Chemical group 0.000 claims description 7
- KWGRBVOPPLSCSI-WPRPVWTQSA-N (-)-ephedrine Chemical compound CN[C@@H](C)[C@H](O)C1=CC=CC=C1 KWGRBVOPPLSCSI-WPRPVWTQSA-N 0.000 claims description 6
- WNGSUWLDMZFYNZ-UHFFFAOYSA-N Leonurine Chemical compound COC1=CC(C(=O)OCCCCN=C(N)N)=CC(OC)=C1O WNGSUWLDMZFYNZ-UHFFFAOYSA-N 0.000 claims description 6
- IAKHMKGGTNLKSZ-INIZCTEOSA-N (S)-colchicine Chemical compound C1([C@@H](NC(C)=O)CC2)=CC(=O)C(OC)=CC=C1C1=C2C=C(OC)C(OC)=C1OC IAKHMKGGTNLKSZ-INIZCTEOSA-N 0.000 claims description 4
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 4
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 4
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 4
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 4
- 229940077388 benzenesulfonate Drugs 0.000 claims description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 4
- 244000269722 Thea sinensis Species 0.000 claims description 3
- FENRSEGZMITUEF-ATTCVCFYSA-E [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] FENRSEGZMITUEF-ATTCVCFYSA-E 0.000 claims description 3
- KWGRBVOPPLSCSI-UHFFFAOYSA-N d-ephedrine Natural products CNC(C)C(O)C1=CC=CC=C1 KWGRBVOPPLSCSI-UHFFFAOYSA-N 0.000 claims description 3
- 229960002179 ephedrine Drugs 0.000 claims description 3
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 3
- 235000013824 polyphenols Nutrition 0.000 claims description 3
- 229940083982 sodium phytate Drugs 0.000 claims description 3
- 235000013616 tea Nutrition 0.000 claims description 3
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 2
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- 229920000896 Ethulose Polymers 0.000 claims description 2
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 claims description 2
- 240000004670 Glycyrrhiza echinata Species 0.000 claims description 2
- 235000001453 Glycyrrhiza echinata Nutrition 0.000 claims description 2
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 claims description 2
- 235000017382 Glycyrrhiza lepidota Nutrition 0.000 claims description 2
- QAQJMLQRFWZOBN-LAUBAEHRSA-N L-ascorbyl-6-palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](O)[C@H]1OC(=O)C(O)=C1O QAQJMLQRFWZOBN-LAUBAEHRSA-N 0.000 claims description 2
- 239000011786 L-ascorbyl-6-palmitate Substances 0.000 claims description 2
- 244000082204 Phyllostachys viridis Species 0.000 claims description 2
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 2
- 229930003427 Vitamin E Natural products 0.000 claims description 2
- 125000005227 alkyl sulfonate group Chemical group 0.000 claims description 2
- 235000010385 ascorbyl palmitate Nutrition 0.000 claims description 2
- 239000011425 bamboo Substances 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 229960001338 colchicine Drugs 0.000 claims description 2
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 claims description 2
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims description 2
- 229940094952 green tea extract Drugs 0.000 claims description 2
- 235000020688 green tea extract Nutrition 0.000 claims description 2
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 2
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 2
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 2
- 229940010454 licorice Drugs 0.000 claims description 2
- 150000004702 methyl esters Chemical group 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 235000010388 propyl gallate Nutrition 0.000 claims description 2
- 239000000473 propyl gallate Substances 0.000 claims description 2
- 229940075579 propyl gallate Drugs 0.000 claims description 2
- 229940092258 rosemary extract Drugs 0.000 claims description 2
- 235000020748 rosemary extract Nutrition 0.000 claims description 2
- 239000001233 rosmarinus officinalis l. extract Substances 0.000 claims description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 235000019165 vitamin E Nutrition 0.000 claims description 2
- 229940046009 vitamin E Drugs 0.000 claims description 2
- 239000011709 vitamin E Substances 0.000 claims description 2
- 230000015556 catabolic process Effects 0.000 abstract description 3
- 238000006731 degradation reaction Methods 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 239000003599 detergent Substances 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 2
- 229930182478 glucoside Natural products 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 239000004530 micro-emulsion Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 230000002535 lyotropic effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2096—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/362—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Abstract
The invention provides an environment-friendly surfactant composition, which comprises the following components in parts by weight: 30-50 parts of sulfonate surfactant, 20-30 parts of alkyl quaternary ammonium salt cationic surfactant, 10-20 parts of alkyl glycoside, 10-20 parts of betaine, 1-5 parts of cellulose thickener, 0.3-0.8 part of organic amine alkaloid, 0.03-0.1 part of aloe extract and 0.01-0.05 part of antioxidant; the sulfonate surfactant, the alkyl quaternary ammonium salt cationic surfactant and the alkyl glycoside are all in straight-chain structures. The surfactant composition disclosed by the invention is easy to degrade, high in degradation speed and small in environmental pollution.
Description
Technical Field
The invention relates to the technical field of surfactants, and particularly relates to an environment-friendly surfactant composition.
Background
The surfactant is a substance which can obviously reduce the interfacial tension when the addition amount is small, and the molecule of the surfactant has a unique structure: one end is a hydrophilic polar group and the other end is a lipophilic non-polar group, also known as an amphiphile. Can spontaneously form stable and orderly arranged association structures such as micelles, lyotropic liquid crystals, microemulsions, vesicles, vermicular micelles, microemulsion gels and the like in a solution. The surfactant is commonly applied to the field of washing and care, a plurality of surfactants are combined into a detergent, the wastewater with the surfactant is usually directly discharged into rivers after the cleaning is finished, and the partial surfactant composition is generally difficult to degrade or has slow degradation speed, so that the water quality is seriously polluted.
Disclosure of Invention
Aiming at the problems, the invention provides the surfactant composition which is environment-friendly, is easy to degrade, has high degradation speed and small environmental pollution.
In order to achieve the purpose, the invention is solved by the following technical scheme:
an environment-friendly surfactant composition comprises the following components in parts by weight: 30-50 parts of sulfonate surfactant, 20-30 parts of alkyl quaternary ammonium salt cationic surfactant, 10-20 parts of alkyl glycoside, 10-20 parts of betaine, 1-5 parts of cellulose thickener, 0.3-0.8 part of organic amine alkaloid, 0.03-0.1 part of aloe extract and 0.01-0.05 part of antioxidant;
the sulfonate surfactant, the alkyl quaternary ammonium salt cationic surfactant and the alkyl glycoside are all in straight-chain structures.
Specifically, the sulfonate surfactant is selected from one of alkyl benzene sulfonate, secondary alkyl sulfonate, olefin sulfonate and methyl ester sulfonate.
Specifically, the alkyl quaternary ammonium salt cationic surfactant is selected from one of N-dodecyl biquaternary ammonium salt, mono-octadecyl quaternary ammonium salt and octadecyl biquaternary ammonium salt.
Specifically, the organic amine alkaloid is one selected from ephedrine, leonurine and colchicine.
Specifically, the antioxidant is selected from one or more of tea polyphenol, vitamin E, bamboo leaf antioxidant, sodium phytate, ascorbyl palmitate, licorice antioxidant, rosemary extract, propyl gallate and green tea extract.
Specifically, the cellulose thickener is one selected from hydroxyethyl cellulose, hydroxypropyl methyl cellulose, carboxymethyl cellulose and ethyl hydroxyethyl cellulose.
The beneficial effects of the invention are:
1. the surfactant composition provided by the invention takes the straight-chain sulfonate surfactant, the alkyl quaternary ammonium salt cationic surfactant, the alkyl glycoside and the betaine as main components, and the detergent, the oil removal and the foaming performances are excellent after the surfactant composition is combined, and the four components are all in straight-chain structures, so that the surfactant composition is more easily biodegraded compared with a branched molecular structure, is discharged into rivers, is fast in biodegradation speed and is environment-friendly;
2. the viscosity of the system is adjusted by adopting the cellulose thickener, and the cellulose thickener is easy to degrade and has small influence on the environment;
3. organic amine alkaloid is used as a pH conditioner to adjust the pH value of the system, and compared with the traditional sodium hydroxide, the organic amine alkaloid is extracted from plants and is extremely easy to biodegrade;
4. the aloe extract is used as an antibacterial agent, has good antibacterial property, and can prevent and inhibit the growth of bacteria and ensure that the surfactant composition is not easy to putrefy.
Detailed Description
The present invention will be described in further detail with reference to specific embodiments in order to provide a further understanding of the nature and technical means of the invention, as well as the specific objects and functions attained by the invention.
Example 1
The embodiment discloses an environment-friendly surfactant composition, which comprises the following components in parts by weight: 40 parts of straight-chain alkyl benzene sulfonate, 25 parts of straight-chain N-dodecyl biquaternary ammonium salt, 15 parts of straight-chain alkyl glucoside, 15 parts of straight-chain betaine, 2 parts of hydroxyethyl cellulose, 0.5 part of ephedrine, 0.05 part of aloe extract and 0.02 part of sodium phytate.
And (3) testing: the detergency of the surfactant was measured by a test method of GB/T13174-2008. evaluation of detergency and circulating detergency of a detergent for clothing, and the record is as shown in Table 1 below.
Example 2
The embodiment discloses an environment-friendly surfactant composition, which comprises the following components in parts by weight: 50 parts of straight-chain alkyl benzene sulfonate, 20 parts of straight-chain N-dodecyl biquaternary ammonium salt, 20 parts of straight-chain alkyl glucoside, 15 parts of straight-chain betaine, 2 parts of hydroxyethyl cellulose, 0.3 part of leonurine, 0.08 part of aloe extract and 0.03 part of tea polyphenol.
And (3) testing: the detergency of the surfactant was measured by a test method of GB/T13174-2008. evaluation of detergency and circulating detergency of a detergent for clothing, and the record is as shown in Table 1 below.
TABLE 1 test results
| Example 1 | Example 2 | |
| Stain removal value | 1.98 | 1.76 |
As can be seen from table 1 above, the surfactant compositions of examples 1-2 both have a stain removal value greater than 1.7, and the conventional laundry detergent has a stain removal value of about 1.5, indicating that the surfactant system of the present invention has good stain removal effect.
The above examples only show 2 embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (6)
1. The environment-friendly surfactant composition is characterized by comprising the following components in parts by weight: 30-50 parts of sulfonate surfactant, 20-30 parts of alkyl quaternary ammonium salt cationic surfactant, 10-20 parts of alkyl glycoside, 10-20 parts of betaine, 1-5 parts of cellulose thickener, 0.3-0.8 part of organic amine alkaloid, 0.03-0.1 part of aloe extract and 0.01-0.05 part of antioxidant;
the sulfonate surfactant, the alkyl quaternary ammonium salt cationic surfactant and the alkyl glycoside are all straight-chain structures.
2. The environmentally friendly surfactant composition of claim 1, wherein the sulfonate surfactant is selected from the group consisting of alkyl benzene sulfonate, secondary alkyl sulfonate, olefin sulfonate, and methyl ester sulfonate.
3. The environmentally friendly surfactant composition of claim 1, wherein the alkyl quaternary ammonium salt cationic surfactant is selected from one of N-dodecyl biquaternary ammonium salt, monostearyl biquaternary ammonium salt and octadecyl biquaternary ammonium salt.
4. The composition of claim 1, wherein the organic amine alkaloid is selected from the group consisting of ephedrine, leonurine, and colchicine.
5. The environmentally friendly surfactant composition of claim 1, wherein the antioxidant is selected from one or more of tea polyphenols, vitamin E, bamboo leaf antioxidant, sodium phytate, ascorbyl palmitate, licorice antioxidant, rosemary extract, propyl gallate, and green tea extract.
6. The environmentally friendly surfactant composition of claim 1, wherein the cellulosic thickener is selected from the group consisting of hydroxyethyl cellulose, hydroxypropyl methylcellulose, carboxymethyl cellulose, and ethyl hydroxyethyl cellulose.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921673A (en) * | 2009-06-16 | 2010-12-22 | 张红凯 | Detergent composition containing marine alkaloids |
| CN102242023A (en) * | 2011-05-31 | 2011-11-16 | 廊坊乐万家联合家化有限公司 | Laundry liquid with washing and caring functions |
| CN102517164A (en) * | 2011-12-06 | 2012-06-27 | 江南大学 | Sterilizing laundry detergent containing hairyvein agrimony extract |
| CN104513740A (en) * | 2013-09-27 | 2015-04-15 | 天津普范科技开发有限公司 | Plant type anti-color fading liquid laundry detergent |
| CN104531383A (en) * | 2014-12-15 | 2015-04-22 | 广州立白企业集团有限公司 | Liquid detergent composition and method for adjusting rheological property of liquid detergent composition |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921673A (en) * | 2009-06-16 | 2010-12-22 | 张红凯 | Detergent composition containing marine alkaloids |
| CN102242023A (en) * | 2011-05-31 | 2011-11-16 | 廊坊乐万家联合家化有限公司 | Laundry liquid with washing and caring functions |
| CN102517164A (en) * | 2011-12-06 | 2012-06-27 | 江南大学 | Sterilizing laundry detergent containing hairyvein agrimony extract |
| CN104513740A (en) * | 2013-09-27 | 2015-04-15 | 天津普范科技开发有限公司 | Plant type anti-color fading liquid laundry detergent |
| CN104531383A (en) * | 2014-12-15 | 2015-04-22 | 广州立白企业集团有限公司 | Liquid detergent composition and method for adjusting rheological property of liquid detergent composition |
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