CN101921673A - Detergent composition containing marine alkaloids - Google Patents
Detergent composition containing marine alkaloids Download PDFInfo
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- CN101921673A CN101921673A CN2009100530933A CN200910053093A CN101921673A CN 101921673 A CN101921673 A CN 101921673A CN 2009100530933 A CN2009100530933 A CN 2009100530933A CN 200910053093 A CN200910053093 A CN 200910053093A CN 101921673 A CN101921673 A CN 101921673A
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- detergent composition
- marine alkaloids
- alkyl
- fatty acid
- surfactant
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Abstract
The invention relates to a detergent composition containing marine alkaloids, which comprises marine alkaloids, anionic surfactant, amphoteric surfactant, non-ionic surfactant and de-ionized water. The raw materials are heated, stirred, dissolved and the like in proportion to obtain the detergent composition. Since marine alkaloids extracted from sea water are added, the detergent composition can effectively clear oil stains and dirt on the skin surface and clothing textiles, and rust and dirt on the surface of parts of metals, glass and ceramics in a washing mode of multistage degradation; the detergent composition is non-corrosive, does not hurt clothing or skin, and does not corrode the metal surface; the new detergent composition is environment-friendly and healthy; and due to the excellent biodegradability, the detergent composition can not generate pollution after being discharged into the environment.
Description
Technical field
The present invention relates to a kind of detergent composition, especially relate to a kind of detergent composition that contains marine alkaloids.This washing composition is applicable to as clothing, kitchen cleaning, vegetable and fruit, automobile, gold jewellery, even comprises various fields such as agricultural, fishing animal husbandry and industry, the article washing of various occasions.
Background of invention and prior art
The evolution of human washing composition technology and development can be divided into three phases: the fs is the petrochemical industry sanitising agent; The plant sanitising agent had appearred again afterwards; Present stage just flourish be exactly the marine organisms washing composition.
The petrochemical industry sanitising agent is to be succeeded in developing by the fritz the earliest, during the World War II, is refined in petroleum by-product by the U.S. again, successfully is developed as the commodity of universalness, and this technology has been introduced into Japan again after the war.Along with the universalness of washing machine, the sales volume of Japanese petrochemical industry sanitising agent soars, considerably beyond the usage quantity of soap.But the harm of petrochemical industry sanitising agent is very big.
Harm at first is embodied on its composition:
A. interfacial agent, its characteristic: (1). can reduce object surfaces tension force.(2). the inaccessiable place of porous water, so sanitising agent can be penetrated in the blood of clothes fiber and human body.
B. oil substance, last layer extracts and refines into senior oil product in the cracking of oil, and its tool carinogenicity is all known in the pitch whole world that the lowest layer manufactures, and oil rubbish can be extracted and manufactures various petrochemical industry goods, " plastic cement " is exactly product wherein.Plastic cement is not decomposed by the earth, and forms 10000 years rubbish, and the degree that it pollutes us is in so many words to feel.And have more toxic one deck oil rubbish down than plastic material, make the raw material of various " petrochemical industry sanitising agents " exactly.
C. the chemosynthesis material as formaldehyde, has the height clearing power, but also is the carcinogenic chemosynthesis element of the strong poison of tool.
D. fluorescent agent, its characteristic: (1). be the element (with the D.D.T. same nature) that belongs to " conservation of matter ", existence forever can not disappear because of position transfer.If enter in the human body then exist forever, and accumulate in the human body.(2). be proved at present and had toxicity really; Global personage has begun to pay attention to the fact of fluorescent agent to human body harm, and confirms that fluorescent agent is one of ten carcinogenic big reasons.(3). all skin wounds, fester, the mucous membrane place, fluorescent agent penetrates in the human body especially easily and causes disease.
E. phosphorus, its characteristic: be difficult for being decomposed by the earth, and the whole the earth ecotope of destruction that can be serious, and cause severe contamination.
The back appears in the plant sanitising agent once generally to be had an optimistic view of because of the characteristics of its environment protection health, but was not also developed preferably because be limited by the constraint of cost, starting material and preparation, extraction and synthetic technology.
Bigger development prospect appears in the marine organisms washing composition in recent years, its active ingredient comes from the marine organisms of this particular surroundings of ocean (high salt, high pressure, anoxic, lack illumination etc.), in its growth and metabolic process, produced and accumulated the material that has special chemical structure and tool special physiological activity and function in a large number.
Summary of the invention
The objective of the invention is to be to provide a kind of detergent composition that contains marine alkaloids in order to eliminate the existing existing problem of Betengent product.
A kind of detergent composition that contains marine alkaloids of the present invention, contain following composition (component and weight percent % thereof):
(A) 0.5-1.5% marine alkaloids;
(B) 9-13% surfactant system; Wherein
(B1) 2.5-4% anion surfactant
(B2) 2.5-3.5 amphoterics
(B3) 4-5.5% nonionogenic tenside
(C) add the deionized water of surplus to 100%.
Marine alkaloids
The present invention's notable attribute the most is to have added the marine alkaloids composition (A) that extracts from seawater.
Surfactant system
The present composition comprises surfactant system (B), and by anion surfactant (B1) commonly used in the washing composition, amphoterics (B2) and nonionogenic tenside (B3) are formed.
Anion surfactant
Basically, any anion surfactant that is used for washing purpose can both be included in this detergent composition.These comprise the anion sulfate acid root, sulfonate radical, the salt of hydroxy acid root and sarkosine root tensio-active agent (for example comprise sodium, potassium, ammonium and substituted ammonium salt as single-, two-and the trolamine salt).Anion sulfate and sulfosalt surfactant are preferred.More preferably polyoxyethylene ether sulfate herein, its chemical general formula is:
R
1O(CH
2CH
2O)n-SO
3Y
(in the formula, R
1The expression carbonatoms is 10～18 saturated or unsaturated alkyl; Y represents alkali metal atom, alkaline earth metal atom, alkanolamine, ammonium or basic aminoacids, n by the mole number mean value of adding oxyethane, the number of expression 0～5, preferred 1-3);
Amphoterics
Optionally amphoterics comprises coco betaine, oil-based betaine, lauroyl amido CAB, cocamidopropyl betaine, preferred herein AMONYL 380LC (CAB) Cocoamidopropyl Betaine, its chemical general formula is:
RCONH(CH2)3N+(CH3)2CH2COO-
Nonionogenic tenside
Optionally ionic surfactant pack is drawn together alkyl polyglycoside, polyoxyalkylene (optimal ethylene) alkyl or alkenyl ether, polyoxyalkylene sorbitol anhydride fatty acid fat, sorbitol anhydride fatty acid fat, polyoxyalkylene Sorbitol Powder fatty acid ester, polyoxyalkylene fatty acid glycerine fatty acid ester, polyglycerol fatty acid ester, fatty mono glyceride, cithrol, many glycosides of preferred alkyl herein, its chemical general formula is:
R
3O (C
nH
2nO)
t(glycosyl)
x
R wherein
3Be selected from the group of forming by following group: alkyl, alkyl phenyl, hydroxyalkyl, hydroxyalkyl phenyl and their mixture, wherein alkyl comprises 10 to 18, preferred 12 to 14 carbon atoms; N is 2 or 3, is preferably 2; T is 0 to 10, is preferably 0; X is 1.3 to 10, is preferably 1.3 to 3, most preferably 1.3 to 2.7; Described glycosyl is preferably derived from glucose; In order to prepare these compounds, at first form alcohol or alkyl polyethoxye alcohol, with glucose or source of glucose reaction, form glucoside (being connected the 1-position) then.Then, other glycosyl units can be connected they the 1-position and 2-, the 3-of aforementioned glycosyl units, 4-and or the 6-position between, preferably mainly in the 2-position.
Deionized water
The used thinner of the present composition is a deionized water, it manufactures process: water treating equipment are with after running water switch docks, open gac, zwitterion exchange bed switch when fetching boiling water treatment facility UV-lamp switch, the water that comes out bacterium, metal ion and specific conductivity after testing is deionized water after qualified, promptly can be used for producing.
Preparation method of the present invention
1. when the deionized water of stirring tank being heated to 80 ℃ amphoterics, nonionogenic tenside, anion surfactant are dropped into stirring tank by corresponding proportion, stirred 30 minutes while feeding intake, stirring tank is set 150 rev/mins;
2. the marine alkaloids that adds corresponding proportion when being cooled to 40 ℃ stirred while feeding intake 1 hour, and stirring tank is set 150 rev/mins;
3. raw material is slowly stirred, this moment, stirring tank was set 60 rev/mins, and restir is to be checked after 30 minutes when being cooled to 25 ℃;
The qualified back of inspection by sampling (inspecting standard is as follows) to put into hold-up vessel to be filled.
Inspecting standard
| Project | Technical requirements |
| Outward appearance | Transparent liquid, free from foreign meter |
| The pH value | 8.0-8.5 |
| Total plate count/(CFU/g) | ≤1000 |
| 40 ℃ of mm of foam | ≥50 |
| Working substance % | ≥5 |
| Excrement colibacillus group | Must not detect |
| Streptococcus aureus | Must not detect |
The present invention is applicable to the cleaning of various article, and the standard consumption and the cleaning method of article commonly used are as follows:
Standard consumption and cleaning method
| Clean article | The standard consumption | Cleaning method |
| Clothing | 3-5 spare clothes consumption 20ml | Cleaned up in 10 minutes with 5kg water logging bubble and to get final product |
| Gourd, fruit and vegetable | ?10ml/kg | Cleaned up in 5 minutes with 3kg water logging bubble and to get final product |
| Tableware | 15ml/5 spare | Cleaned up in 10 minutes with 5kg water logging bubble and to get final product |
| Office furniture | In right amount | The sprinkling body surface is cleaned and is got final product |
Characteristics of the present invention show: (1) the present invention can effectively remove oil stain, spot and part metals, glass, the rust stain of ceramic surface, the dirt of skin surface, clothing textiles with the mode of washing of multistage degraded.(2) non-corrosiveness of the present invention is not hindered clothing, does not hinder skin, not erode metallic surfaces.(3) the present invention is a novel environmental protection, healthy sanitising agent.(4) detergent composition of the present invention is because its fabulous biodegradability, can not produce pollution after entering environment.
Embodiment
Formulation Example 1-4:
Adopt aforesaid preparation method to produce detergent composition of the present invention (pressing wt%) by following prescription:
Certainly, those of ordinary skill in the art will be appreciated that, above embodiment is used for illustrating the present invention, and be not as limitation of the invention, as long as in essential scope of the present invention, all will drop in the scope of claims of the present invention variation, the modification of the above embodiment.
Claims (8)
1. detergent composition that contains marine alkaloids, contain following composition (component and weight percent % thereof):
(A) 0.5-1.5% marine alkaloids;
(B) 9-13% surfactant system; Wherein
(B1) 2.5-4% anion surfactant
(B2) 2.5-3.5 amphoterics
(B3) 4-5.5% nonionogenic tenside
(C) add the deionized water of surplus to 100%.
2. a kind of detergent composition that contains marine alkaloids according to claim 1 is characterized in that: added the marine alkaloids composition (A) that extracts from seawater.
3. a kind of detergent composition that contains marine alkaloids according to claim 1, comprise surfactant system (B), by anion surfactant (B1) commonly used in the washing composition, amphoterics (B2) and nonionogenic tenside (B3) are formed.
4. a kind of detergent composition that contains marine alkaloids according to claim 1, anion surfactant (B1) is the anion sulfate acid root, sulfonate radical, the salt of hydroxy acid root and sarkosine root tensio-active agent (for example comprises sodium, potassium, ammonium and substituted ammonium salt as single-, two-and the trolamine salt); Anion sulfate and sulfosalt surfactant are preferred; More preferably polyoxyethylene ether sulfate herein, its chemical general formula is:
R
1O(CH
2CH
2O)n-SO
3Y
(in the formula, R
1The expression carbonatoms is 10～18 saturated or unsaturated alkyl; Y represents alkali metal atom, alkaline earth metal atom, alkanolamine, ammonium or basic aminoacids, n by the mole number mean value of adding oxyethane, the number of expression 0～5, preferred 1-3).
5. a kind of detergent composition that contains marine alkaloids according to claim 1, amphoterics (B2) is a betaines, as coco betaine, oil-based betaine, lauroyl amido CAB, cocamidopropyl betaine; Preferred herein AMONYL 380LC.
6. a kind of detergent composition that contains marine alkaloids according to claim 1, nonionogenic tenside (B3) can adopt alkyl polyglycoside, polyoxyalkylene (optimal ethylene) alkyl or alkenyl ether, polyoxyalkylene sorbitol anhydride fatty acid fat, sorbitol anhydride fatty acid fat, polyoxyalkylene Sorbitol Powder fatty acid ester, polyoxyalkylene fatty acid glycerine fatty acid ester, polyglycerol fatty acid ester, fatty mono glyceride, cithrol, many glycosides of preferred alkyl herein, its chemical general formula is:
R
3O (C
nH
2nO)
t(glycosyl)
x
R wherein
3Be selected from the group of forming by following group: alkyl, alkyl phenyl, hydroxyalkyl, hydroxyalkyl phenyl and their mixture, wherein alkyl comprises 10 to 18, preferred 12 to 14 carbon atoms; N is 2 or 3, is preferably 2; T is 0 to 10, is preferably 0; X is 1.3 to 10, is preferably 1.3 to 3, most preferably 1.3 to 2.7; Described glycosyl is preferably derived from glucose; In order to prepare these compounds, at first form alcohol or alkyl polyethoxye alcohol, with glucose or source of glucose reaction, form glucoside (being connected the 1-position) then; Then, other glycosyl units can be connected they the 1-position and 2-, the 3-of aforementioned glycosyl units, 4-and or the 6-position between, preferably mainly in the 2-position.
7. a kind of detergent composition that contains marine alkaloids according to claim 1, used thinner is a deionized water, it manufactures process: water treating equipment are with after running water switch docks, open gac, zwitterion exchange bed switch when fetching boiling water treatment facility UV-lamp switch, the water that comes out bacterium, metal ion and specific conductivity after testing is deionized water after qualified, promptly can be used for producing.
8. a kind of detergent composition that contains marine alkaloids according to claim 1, its preparation method is:
(1). when the deionized water of stirring tank is heated to 80 ℃ amphoterics, nonionogenic tenside, anion surfactant are dropped into stirring tank by corresponding proportion, stirred 30 minutes while feeding intake, stirring tank is set 150 rev/mins;
(2). the marine alkaloids that adds corresponding proportion when being cooled to 40 ℃ stirred while feeding intake 1 hour, and stirring tank is set 150 rev/mins;
(3). raw material is slowly stirred, and this moment, stirring tank was set 60 rev/mins, and restir is to be checked after 30 minutes when being cooled to 25 ℃;
(4). it is to be filled to put into hold-up vessel after inspection by sampling is qualified.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100530933A CN101921673B (en) | 2009-06-16 | 2009-06-16 | Detergent composition containing marine alkaloids |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100530933A CN101921673B (en) | 2009-06-16 | 2009-06-16 | Detergent composition containing marine alkaloids |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101921673A true CN101921673A (en) | 2010-12-22 |
| CN101921673B CN101921673B (en) | 2012-07-25 |
Family
ID=43336891
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100530933A Active CN101921673B (en) | 2009-06-16 | 2009-06-16 | Detergent composition containing marine alkaloids |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101921673B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102936539A (en) * | 2012-01-06 | 2013-02-20 | 东莞市洛加斯润滑油有限公司 | Environment-friendly wax removing and oil removing cleaning agent |
| CN104419537A (en) * | 2013-08-23 | 2015-03-18 | 亚太轻合金(南通)科技有限公司 | Anti-ultraviolet glass cleaning agent |
| US20160046893A1 (en) * | 2014-08-18 | 2016-02-18 | Hongkai Zhang | Biotech Washing Agent |
| CN105802773A (en) * | 2016-04-14 | 2016-07-27 | 巢湖市荷花渔网有限公司 | Fishing net sterilization stain remover |
| CN105838521A (en) * | 2016-04-14 | 2016-08-10 | 巢湖市荷花渔网有限公司 | Detergent for fishing net |
| CN106137813A (en) * | 2015-04-03 | 2016-11-23 | 苏州聚和堂生物科技有限公司 | A kind of marine bioactivity detergent and preparation method thereof |
| CN114940925A (en) * | 2022-04-28 | 2022-08-26 | 广东丽臣奥威实业有限公司 | Environment-friendly surfactant composition |
-
2009
- 2009-06-16 CN CN2009100530933A patent/CN101921673B/en active Active
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102936539A (en) * | 2012-01-06 | 2013-02-20 | 东莞市洛加斯润滑油有限公司 | Environment-friendly wax removing and oil removing cleaning agent |
| CN104419537A (en) * | 2013-08-23 | 2015-03-18 | 亚太轻合金(南通)科技有限公司 | Anti-ultraviolet glass cleaning agent |
| US20160046893A1 (en) * | 2014-08-18 | 2016-02-18 | Hongkai Zhang | Biotech Washing Agent |
| US9783765B2 (en) * | 2014-08-18 | 2017-10-10 | Hongkai Zhang | Biotech washing agent |
| CN106137813A (en) * | 2015-04-03 | 2016-11-23 | 苏州聚和堂生物科技有限公司 | A kind of marine bioactivity detergent and preparation method thereof |
| CN105802773A (en) * | 2016-04-14 | 2016-07-27 | 巢湖市荷花渔网有限公司 | Fishing net sterilization stain remover |
| CN105838521A (en) * | 2016-04-14 | 2016-08-10 | 巢湖市荷花渔网有限公司 | Detergent for fishing net |
| CN114940925A (en) * | 2022-04-28 | 2022-08-26 | 广东丽臣奥威实业有限公司 | Environment-friendly surfactant composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101921673B (en) | 2012-07-25 |
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Owner name: SHANGHAI LIANGLIANG BIOTECHNOLOGY CO., LTD. Free format text: FORMER OWNER: ZHANG HONGKAI Effective date: 20130828 |
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Free format text: CORRECT: ADDRESS; FROM: 200240 HUANGPU, SHANGHAI TO: 201602 SONGJIANG, SHANGHAI |
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Effective date of registration: 20130828 Address after: 201602 Shanghai Songjiang District Sheshan Town Road No. 876 Tao Patentee after: Shanghai Liang Liang Bio-technology Co.,Ltd. Address before: 200240 room 5, No. 555, Lane 2601, Tibet South Road, Shanghai, Huangpu District Patentee before: Zhang Hongkai |
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Addressee: Patent of Shanghai Liangliang Biotechnology Co.,Ltd. The person in charge Document name: Payment Notice |
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