CN108034522A - A kind of non-phosphate liquid laundry detergent - Google Patents

A kind of non-phosphate liquid laundry detergent Download PDF

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Publication number
CN108034522A
CN108034522A CN201711486914.3A CN201711486914A CN108034522A CN 108034522 A CN108034522 A CN 108034522A CN 201711486914 A CN201711486914 A CN 201711486914A CN 108034522 A CN108034522 A CN 108034522A
Authority
CN
China
Prior art keywords
parts
sodium
polyoxyethylene ether
fatty alcohol
laundry detergent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711486914.3A
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Chinese (zh)
Inventor
何倩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201711486914.3A priority Critical patent/CN108034522A/en
Publication of CN108034522A publication Critical patent/CN108034522A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/162—Organic compounds containing Si
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers

Abstract

The invention belongs to daily chemical product field, more particularly to a kind of non-phosphate liquid laundry detergent.A kind of non-phosphate liquid laundry detergent, mainly include following parts by weight ingredient to form, 9 15 parts of fatty alcohol polyoxyethylene ether sulfate, 25 parts of neopelex, 25 parts of fatty alcohol polyoxyethylene ether, 0.5 1 parts of sodium carboxymethylcellulose, 6 10 parts of ethanol, 26 parts of sodium chloride, 5 15 parts of sodium metasilicate, 13 parts of sodium hypochlorite, 13 parts of coconut oleyl alcohol diglycollic amide, 0.1 0.5 parts of silicone antifoams agent.

Description

A kind of non-phosphate liquid laundry detergent
Technical field
The invention belongs to daily chemical product field, more particularly to a kind of non-phosphate liquid laundry detergent.
Background technology
Laundry, the most flat thing in life.For in the product of clothes washing, washing powder to account for main always Status.But careful people can realize, liquid detergent main component is nonionic surfactant, and dirt-removing power is strong, and can Go deep into playing cleaning function inside clothes fiber, decontamination is more thorough.Washing powder can not be completely dissolved in use, residual Thing is easy to cause clothing damage, and is not easy to rinse；And liquid detergent can be completely dissolved and dissolution velocity is fast, easily float it is washable, no Skin and clothing can be injured.(PH is more than 12) of the general strong basicity of washing powder, need to wear gloves in use, with reduction pair The stimulation of skin；And liquid detergent pH value partial neutral, formula are not hurt hands gently.The technology content higher of liquid detergent, it is each easy to add Kind active ingredient, washing can make clothing fluffy, soft, smooth glossy, and have the effect of degerming and lasting lasting.Use synthesis Cost is low, is just widely received by people.The waste liquid that washing powder produces is in difficult (the particularly branched alkyl of nature degraded Benzene sulfonic acid sodium salt), water pollution is caused, very big destruction is caused to ecology；And then opposite degraded is more complete for liquid detergent, environment is made It is smaller into going bad.
Phosphorus is often to contain anything in liquid detergent, everybody may hear " body eutrophication ", and a fish pond is Example, in the event of " body eutrophication ", then the microbes amount reproduction such as algae first in fish pond, then in water Oxygen can be greatly decreased, then fishes and shrimps can anoxic and it is dead ... the disruption of ecological balance in whole fish pond, eventually becomes a pond stagnant water." phosphorus " In this process, equivalent to the nutritional ingredient for stimulating microorganism to grow, to the very harmful of environment.In addition phosphorus can also influence people Body causes osteomalacia etc to calcareous absorption.It is because to remove phosphorus matter in clothes rinse cycle without using Powdered Detergent Containing Phosphate It is not easy very much for health, you go to rinse with more water, more times.
The content of the invention
For this reason, the present invention provides a kind of non-phosphate liquid laundry detergent.
To achieve the above object, the present invention adopts the following technical scheme that：
A kind of non-phosphate liquid laundry detergent, mainly forms including following parts by weight ingredient,
9-15 parts of fatty alcohol polyoxyethylene ether sulfate,
2-5 parts of neopelex,
2-5 parts of fatty alcohol polyoxyethylene ether,
0.5-1 parts of sodium carboxymethylcellulose,
6-10 parts of ethanol,
2-6 parts of sodium chloride,
5-15 parts of sodium metasilicate,
1-3 parts of sodium hypochlorite,
1-3 parts of coconut oleyl alcohol diglycollic amide,
0.1-0.5 parts of silicone antifoams agent.
The technical program further optimizes, and further includes plus deionized water adds to 100%.
The technical program further optimizes, including following parts by weight ingredient composition,
9 parts of fatty alcohol polyoxyethylene ether sulfate,
3 parts of neopelex,
2 parts of fatty alcohol polyoxyethylene ether,
0.5 part of sodium carboxymethylcellulose,
7 parts of ethanol,
2 parts of sodium chloride,
5 parts of sodium metasilicate,
1 part of sodium hypochlorite,
1 part of coconut oleyl alcohol diglycollic amide,
0.1 part of silicone antifoams agent.
The technical program further optimizes, including following parts by weight ingredient composition,
15 parts of fatty alcohol polyoxyethylene ether sulfate,
5 parts of neopelex,
5 parts of fatty alcohol polyoxyethylene ether,
1 part of sodium carboxymethylcellulose,
9 parts of ethanol,
5 parts of sodium chloride,
14 parts of sodium metasilicate,
3 parts of sodium hypochlorite,
2 parts of coconut oleyl alcohol diglycollic amide,
0.5 part of silicone antifoams agent.
Not phosphorous in a kind of liquid detergent proposed by the present invention, more environmentally-friendly, safety, user also feels more relieved.
Embodiment
To describe the technology contents of technical solution, construction feature, the objects and the effects in detail, below in conjunction with specific reality Example is applied to be explained in detail.
A kind of non-phosphate liquid laundry detergent, mainly forms including following parts by weight ingredient,
9-15 parts of fatty alcohol polyoxyethylene ether sulfate,
2-5 parts of neopelex,
2-5 parts of fatty alcohol polyoxyethylene ether,
0.5-1 parts of sodium carboxymethylcellulose,
6-10 parts of ethanol,
2-6 parts of sodium chloride,
5-15 parts of sodium metasilicate,
1-3 parts of sodium hypochlorite,
1-3 parts of coconut oleyl alcohol diglycollic amide,
0.1-0.5 parts of silicone antifoams agent.
Embodiment one
A kind of non-phosphate liquid laundry detergent, mainly forms including following parts by weight ingredient,
9 parts of fatty alcohol polyoxyethylene ether sulfate,
3 parts of neopelex,
2 parts of fatty alcohol polyoxyethylene ether,
0.5 part of sodium carboxymethylcellulose,
7 parts of ethanol,
2 parts of sodium chloride,
5 parts of sodium metasilicate,
1 part of sodium hypochlorite,
1 part of coconut oleyl alcohol diglycollic amide,
0.1 part of silicone antifoams agent.
Embodiment two
A kind of non-phosphate liquid laundry detergent, mainly forms including following parts by weight ingredient,
15 parts of fatty alcohol polyoxyethylene ether sulfate,
5 parts of neopelex,
5 parts of fatty alcohol polyoxyethylene ether,
1 part of sodium carboxymethylcellulose,
9 parts of ethanol,
5 parts of sodium chloride,
14 parts of sodium metasilicate,
3 parts of sodium hypochlorite,
2 parts of coconut oleyl alcohol diglycollic amide,
0.5 part of silicone antifoams agent.
It should be noted that herein, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to Non-exclusive inclusion, so that process, method, article or terminal device including a series of elements not only include those Key element, but also including other elements that are not explicitly listed, or further include as this process, method, article or end The intrinsic key element of end equipment.In the absence of more restrictions, limited by sentence " including ... " or " including ... " Key element, it is not excluded that also there are other key element in the process including the key element, method, article or terminal device.This Outside, herein, " being more than ", " being less than ", " exceeding " etc. are interpreted as not including this number；" more than ", " following ", " within " etc. understand It is to include this number.
Although the various embodiments described above are described, those skilled in the art once know basic wound The property made concept, then can make these embodiments other change and modification, so the foregoing is merely the embodiment of the present invention, Not thereby the scope of patent protection of the present invention, every equivalent structure made using present specification or equivalent are limited Flow converts, and is directly or indirectly used in other related technical areas, is similarly included in the patent protection model of the present invention Within enclosing.

Claims (4)

  1. A kind of 1. non-phosphate liquid laundry detergent, it is characterised in that mainly it is made of following parts by weight ingredient,
    9-15 parts of fatty alcohol polyoxyethylene ether sulfate,
    2-5 parts of neopelex,
    2-5 parts of fatty alcohol polyoxyethylene ether,
    0.5-1 parts of sodium carboxymethylcellulose,
    6-10 parts of ethanol,
    2-6 parts of sodium chloride,
    5-15 parts of sodium metasilicate,
    1-3 parts of sodium hypochlorite,
    1-3 parts of coconut oleyl alcohol diglycollic amide,
    0.1-0.5 parts of silicone antifoams agent.
  2. 2. a kind of non-phosphate liquid laundry detergent as claimed in claim 1, it is characterised in that add deionized water to add to 100%.
  3. A kind of 3. non-phosphate liquid laundry detergent as claimed in claim 1, it is characterised in that mainly it is made of following parts by weight ingredient,
    9 parts of fatty alcohol polyoxyethylene ether sulfate,
    3 parts of neopelex,
    2 parts of fatty alcohol polyoxyethylene ether,
    0.5 part of sodium carboxymethylcellulose,
    7 parts of ethanol,
    2 parts of sodium chloride,
    5 parts of sodium metasilicate,
    1 part of sodium hypochlorite,
    1 part of coconut oleyl alcohol diglycollic amide,
    0.1 part of silicone antifoams agent.
  4. A kind of 4. non-phosphate liquid laundry detergent as claimed in claim 1, it is characterised in that mainly it is made of following parts by weight ingredient,
    15 parts of fatty alcohol polyoxyethylene ether sulfate,
    5 parts of neopelex,
    5 parts of fatty alcohol polyoxyethylene ether,
    1 part of sodium carboxymethylcellulose,
    9 parts of ethanol,
    5 parts of sodium chloride,
    14 parts of sodium metasilicate,
    3 parts of sodium hypochlorite,
    2 parts of coconut oleyl alcohol diglycollic amide,
    0.5 part of silicone antifoams agent.
CN201711486914.3A 2017-12-29 2017-12-29 A kind of non-phosphate liquid laundry detergent Pending CN108034522A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711486914.3A CN108034522A (en) 2017-12-29 2017-12-29 A kind of non-phosphate liquid laundry detergent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711486914.3A CN108034522A (en) 2017-12-29 2017-12-29 A kind of non-phosphate liquid laundry detergent

Publications (1)

Publication Number Publication Date
CN108034522A true CN108034522A (en) 2018-05-15

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711486914.3A Pending CN108034522A (en) 2017-12-29 2017-12-29 A kind of non-phosphate liquid laundry detergent

Country Status (1)

Country Link
CN (1) CN108034522A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108865491A (en) * 2018-07-19 2018-11-23 中国日用化学研究院有限公司 A kind of efficiently stripping oil type industrial greasy dirt cleaning agent and preparation method
CN111073758A (en) * 2019-11-27 2020-04-28 悦奈诗(浙江)生物科技有限公司 Environment-friendly laundry detergent and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104450269A (en) * 2014-05-08 2015-03-25 南京正亮医药科技有限公司 Underwear laundry detergent
CN104560450A (en) * 2013-10-19 2015-04-29 王慧 Phosphorus-free laundry detergent
CN104893849A (en) * 2015-06-15 2015-09-09 马建剑 Novel environment-friendly laundry detergent for blending clothes and preparation method thereof
CN106479736A (en) * 2016-09-22 2017-03-08 长兴净安环保科技有限公司 A kind of liquid detergent and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104560450A (en) * 2013-10-19 2015-04-29 王慧 Phosphorus-free laundry detergent
CN104450269A (en) * 2014-05-08 2015-03-25 南京正亮医药科技有限公司 Underwear laundry detergent
CN104893849A (en) * 2015-06-15 2015-09-09 马建剑 Novel environment-friendly laundry detergent for blending clothes and preparation method thereof
CN106479736A (en) * 2016-09-22 2017-03-08 长兴净安环保科技有限公司 A kind of liquid detergent and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108865491A (en) * 2018-07-19 2018-11-23 中国日用化学研究院有限公司 A kind of efficiently stripping oil type industrial greasy dirt cleaning agent and preparation method
CN111073758A (en) * 2019-11-27 2020-04-28 悦奈诗(浙江)生物科技有限公司 Environment-friendly laundry detergent and preparation method thereof

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Application publication date: 20180515