CN101165151A - Natural, mild and green cleaning agent - Google Patents
Natural, mild and green cleaning agent Download PDFInfo
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- CN101165151A CN101165151A CNA2007100466444A CN200710046644A CN101165151A CN 101165151 A CN101165151 A CN 101165151A CN A2007100466444 A CNA2007100466444 A CN A2007100466444A CN 200710046644 A CN200710046644 A CN 200710046644A CN 101165151 A CN101165151 A CN 101165151A
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Abstract
The natural mild green detergent consists of composite surfactant 1 (in weight portions, the same below), sodium carbonate 15-21.428, mirabilite 17-24.28, sodium percarbonate 6-8.58, sodium metasilicate 15-21.428, citric acid 10-14.28, sodium carboxymethyl ellulose 2-2.86, EDTA 2-2.86, stuffing 10-14.28 and water 3-4.28. It has the advantages of environment friendship, no pollution to underground water, high detergency, no harm to skin, natural sterilizing capacity and no toxicity.
Description
Technical field
The present invention relates to a kind of natural, gentle, green sanitising agent, can be applied to washedly, do not damage fabric, can wash woman, baby's underwear; Wash vegetable and fruit, clean pesticide residue; The chopsticks of washing the dishes, easy cleaning, noresidue belongs to washing composition technical field in the fine chemistry industry.
Background technology
The sanitising agent composition mainly contains two major parts:
1. activeconstituents, as active ingredient is tensio-active agent;
2. ancillary component, as auxiliary component auxiliary agent, anti-sludging agent, weighting agent etc. are arranged, to strengthen and to improve various usefulness such as tensio-active agent washing.
The maximum tensio-active agent of sanitising agent (washing composition) consumption that various places, the world today produce is a sodium alkyl benzene sulfonate, also is the main preparation composition of various brand washing powder more than 90% on the market.
Auxiliary agent generally is meant carbonate, vitriol, silicate, phosphoric acid salt.The nearly in the world washing composition more than 60% all contains phosphoric acid salt, and tripoly phosphate sodium STPP is the inorganic assistant agent of consumption maximum in the washing powder, and general washing powder also adds white dyes in order to improve whitening effect simultaneously.
There is following shortcoming in the washing composition of being made by components such as sodium alkyl benzene sulfonate, phosphoric acid salt, fluorescent agents:
1, biological degradability is poor, and environment is polluted
Sodium alkyl benzene sulfonate is because industrialization automatic production degree is higher, inexpensive, detersive power is stronger, so usage quantity is very big, but its biological degradability is relatively poor, residual quantity is big, and alkane benzene petroleum chemicals all have toxicity, form certain dispersion colloid particle with other pollutents together, materialization, biochemical to waste water have a significant impact, and cause environmental pollution;
2, has toxicity
General alkane benzene washing composition all has certain toxicity; toxic to human body, animal; corrosion skin; destroy skin surface secretion oiliness protective layer, cause anaphylaxis, contact dermatitis; infringement liver in the life-time service accumulation body; the infringement function of immune system all has certain infringement to blood circulation and neural system in addition, and life-time service can produce the symptom of haemolysis, dizziness.
3, water body is endangered
The transmission speed of oxygen makes water hypoxia in the meeting degraded water body, and smelly corruption is made auxiliary agent with phosphoric acid salt, and its content Gao Shihui causes body eutrophication, and many countries such as current Europe ban use phosphoric acid salt;
4, contain fluorescent agent, phosphoric acid salt, zeolite etc., be difficult for dissolving and remove, destroy the Nature ecology
In recent years each state all very to pay close attention to washing composition inharmonious to environment, seek the new way new variety and carry biological degradability, to obtain and ecological, environmental harmony.
Summary of the invention
The purpose of this invention is to provide natural, gentle, green sanitising agent a kind of and the environmentally compatible close friend.
For realizing above purpose, technical scheme of the present invention provides a kind of natural, gentle, green sanitising agent, it is characterized in that, form: 3～4.28 parts in 1 part of compound surfactant, 15～21.428 parts of soda ash, 17～24.28 parts in saltcake, 6～8.58 parts of SPC-D, 15～21.428 parts of Starsos, 10～14.28 parts of citric acids, 2～2.86 parts of Xylo-Mucines, 2～2.86 parts of the dead acetate of quadrol, 10～14.28 parts of stopping composition and water by following composition by weight raw material.
Described compound surfactant is made up of alkyl glycoside, Fatty acid methyl ester sodium sulfonate, acyl glutamate, and its ratio is 1.5: 0.4-0.6: 0.1-0.3, wherein active matter content is 14～20.
Described acyl glutamate is acyl glutamic acid sodium, trolamine; Described stopping composition is an attapulgite.
The present invention adopts compound surfactant, wherein alkyl glycoside APG raw material is from natural, the glucose of being made by corn or potato starch, the coconut oleyl alcohol that Oleum Cocois makes are made, its biological degradation is complete, be the environment-friendly product, nontoxic, gentle, non-stimulated to human body, uniquely in the world can be become nontoxic level kind, have stronger broad spectrum antibiotic activity, can form best tensio-active agent with any kind surfactant compound.
Fatty acid methyl ester sulfonate MES extracts in a kind of natural fats and oils to play a role in low temperature and height hard water; Therefore acyl glutamate AGA is a kind of character gentleness, and the excellent property amino acid surfactant is made up of alkyl glycoside, Fatty acid methyl ester sulfonate, acyl glutamate and can be formed best tensio-active agent.
It is that organic sequestering agent replaces tripoly phosphate sodium STPP that the present invention adopts citric acid, the dead acetate EDTA of quadrol, reaches without phosphorus, can not cause eutrophication by polluted-water.
The present invention adopts SPC-D and Starso as activator, and without white dyes, human body is not had harm, and ecology is not had influence.
Advantage of the present invention is:
1. natural formula, environment-friendly type, green product
Without phosphorus, no benzene, nontoxic, no enzyme, no fluorescent agent, nuisanceless pollution; Coordinate with environmental friendliness, underground water zero pollutes, and ensures that drinking-water is healthy;
2. multi-functional, comprehensive
Bubble is smeared few, and washing force is strong,
3. healthy, safety
Protection skin, natural disinfection, sterilization, toxicological harmless;
4. good and cheap, best in quality.
Embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment 1
A kind of natural, gentle, green sanitising agent is made up of following composition by weight raw material: 3 parts in 1 part of compound surfactant, 15 parts of soda ash, 17 parts in saltcake, 6 parts of SPC-D, 15 parts of Starsos, 10 parts of citric acids, 2 parts of Xylo-Mucines, 2 parts of the dead acetate of quadrol, 10 parts of attapulgites and water.
Described compound surfactant is made up of alkyl glycoside, Fatty acid methyl ester sodium sulfonate, acyl glutamic acid sodium, and its ratio is 1.5: 0.4: 0.1.
Embodiment 2
A kind of natural, gentle, green sanitising agent is made up of following composition by weight raw material: 3.5 parts in 1 part of compound surfactant, 18 parts of soda ash, 20 parts in saltcake, 7 parts of SPC-D, 18 parts of Starsos, 12 parts of citric acids, 2.4 parts of Xylo-Mucines, 2.4 parts of the dead acetate of quadrol, 12 parts of attapulgites and water.
Described compound surfactant is made up of alkyl glycoside, Fatty acid methyl ester sodium sulfonate, trolamine, and its ratio is 1.5: 0.5: 0.2.
Embodiment 3
A kind of natural, gentle, green sanitising agent is made up of following composition by weight raw material: 4 parts in 1 part of compound surfactant, 21 parts of soda ash, 24 parts in saltcake, 8.5 parts of SPC-D, 21 parts of Starsos, 14 parts of citric acids, 2.86 parts of Xylo-Mucines, 2.86 parts of the dead acetate of quadrol, 14 parts of attapulgites and water.
Described compound surfactant is made up of alkyl glycoside, Fatty acid methyl ester sodium sulfonate, acyl glutamic acid sodium, and its ratio is 1.5: 0.6: 0.3.
A kind of natural, gentle, the preparation method of green sanitising agent adopts the mixing moulding dry mix, the steps include:
The first step. component takes by weighing each raw material by weight;
Second step. at normal temperatures solid material in the recipe ingredient, promptly compound surfactant, soda ash, saltcake, Xylo-Mucine are put into the pulverizer pulverizing, and mix by ribbon blender;
The 3rd step. make liquid starting material
Starso, citric acid, ethylenediamine tetraacetic acid (EDTA) and water are made liquid at the frequency conversion liquid stirrers, and frequency conversion liquid stirrers rotating speed is 500/ minute, and churning time is 30 minutes;
The 4th step. with after join material, promptly stopping composition, SPC-D add and fully mix, are 4 hours during stirring.
The 5th step. the post curing one day of sieving, packing and finished product warehouse-in.
Check data of the present invention:
1. the station survey report is experienced in product toxicity quality surveillance in Shanghai City
| Sequence number | Test item | Index name | Standard-required | Embodiment 1-3 | Conclusion |
| 1 | Acute toxicity | Per os LD50mg/kg | ≥500 | 5300-5400 | Qualified |
| 2 | Skin irritation | Divide rate | ≤0.4 | 0.2-0.3 | Qualified |
| 3 | Eye stimulates | Integral exponential | ≤5 | 0 | Qualified |
| 4 | Sensitization of skin | Sensitization rate % | ≤8 | 5-7 | Qualified |
Inspection technology foundation: DB31/121-93 " requirement of dairy industry product safety hygienic quality current techique " inspection content: toxicity---acute oral toxicity, skin irritation, eye stimulate, sensitization of skin
Check conclusion: this inspection content meets the DB31/121-93 standard-required.
2. Guangzhou Product Quality Testing Institute's Entrustment Inspection report
| Interventions Requested | Unit | Standard-required | Embodiment 1-3 | Individual event is estimated |
| Relative standard's powder is to the decontamination ratio of greasy dirt cloth | ≥1.0 | 1.2-1.4 | Qualified | |
| White dyes | Must not detect | Do not detect | Qualified | |
| Methyl alcohol | Mg/kg | ≤1 | Do not detect | Qualified |
| Lead content (in 1% solution) | Mg/kg | ≤1 | ＜0.01 | Qualified |
| Arsenic content (in 1% solution) | Mg/kg | ≤0.05 | ＜0.01 | Qualified |
3, Shenzhen health and epidemic prevention station survey report
Interventions Requested: sterilisation effect test.
Brief summary: after testing, the multi-functional cleaning agent extension rate of submitted sample is 1: 10 o'clock, acts on 10 minutes, and to colibacillary killing rate 50.98%, minimal inhibitory concentration is 1: 160.
4, Shenzhen City, Guangdong Province health and epidemic prevention station sanitary inspection document
Test item: bacterium, inspectionization index
Detected result:
Total plate count [individual/g]: 0
Coliform [individual/100]:＜3
Pathogenic bacterium: do not detect
Plumbous [10
-6]: 0.75
Arsenic [10
-6]: 0.060
White dyes 365mm is long: do not detect
Result of use of the present invention
(1) nontoxic:
This product actives raw material is natural, and plant-sourced (corn, potato, Oleum Cocois) is unique in the world can be described as " nontoxic level " tensio-active agent.Through Shanghai City product toxicity quality monitoring testing station detected result " real genus is nontoxic ", because make acute toxicity test in mice with 1: 10 times of diluent of this product---per os LD
50National standard requires medium lethal dose 〉=500mg/kg, and this product 〉=5000mg/kg proof is nontoxic.The peasant also sprays the blade face result with 1000 times of its dilutions and also obtains to improve output.
The flourishing cowpea test-results in Anhui: table 1
The place: Yongfeng, Lian Qun village, the San Shan of Fanchang County town group plum name is unit: kilogram
| Time | ① | It is happy together to execute the four seasons | ② | The fertilising 70%+ four seasons are happy together | ③ | Do not execute contrast | |||||
| Month | Day | Area | Quantity | 0.1 per mu yield | Area | Output | Area | Output | |||
| 5 5 5 5 5 | 12 15 18 20 22 | 0.4 0.4 0.4 0.4 0.4 | 6 23 89 78 181 | 1.5 6 22 20 46 | 0.1 0.1 0.1 0.1 0.1 | 1 4 20 18 47 | 0.1 0.1 0.1 0.1 0.1 | / 3 11 14 35 | |||
| 5 5 5 5 6 | 25 27 29 31 2 | 0.4 0.4 0.4 0.4 0.4 | 101 105 93 82 65 | 25 26 24 20 16 | 0.1 0.1 0.1 0.1 0.1 | 24 25 21 17 15 | 0.1 0.1 0.1 0.1 0.1 | 21 23 19 15 13 | |||
| 6 6 6 6 6 | 4 6 8 10 12 | 0.4 0.4 0.4 0.4 0.4 | 51 48 42 40 35 | 14 12 11 10 9 | 0.1 0.1 0.1 0.1 0.1 | 12 13 9 10 8 | 0.1 0.1 0.1 0.1 0.1 | 9 11 7 8 6 | |||
| Summation | 1039 | 262.5 | 244 | 195 | |||||||
| 6 6 6 | 14 16 18 | The bottom is played upwards main climing inflorescence and is continued to bloom and bear pods | Serious early ageing, leaf look Huang is withered, come off and rare inflorescence continues to bloom | ||||||||
| Per mu yield | ① | 2597.5 kilogram/mu | ② | 2440 kilograms/mu | ③ | 1950 kilograms/mu | |||||
Pudong New District's north Cai's cowpea test-results: table 2 unit: jin
See its root growth, grow all well, confirmed the not only nontoxic effect that promotes the plant healthy growth in addition.Its actives raw material of present 90% above washing composition is that petrochemical complex is paid in the product to refine and formed---sodium alkyl benzene sulfonate, to human body and all toxic effect of animal, long-term contact not only contains corrosion skin, contact dermatitis, also can infiltrate behind the human body because its blood dissolubility is very strong, cause the variation of blood red amount easily, cause anemia.Wear the literary composition report according to Chinese washing composition website, stomach cancer cell is cultivated in artificial experiment, inject the deterioration of sodium alkyl benzene sulfonate after-acceleration cancer cells, according to washing weekly report, carrying out toxicity test tests with the mung bean germination, be immersed in 1: 10 times " dab hand " " carving board " " white cat " " upright white " diluent 10 minutes with 50 mung beans, take out its germination situation of sight, its result " dab hand " is only germinateed 3 after 36 hours, " carving board " germinates 5, germinate 20 " upright white ", " white cat " germinates 35 and with germinate 50 of water logging from the beginning, as seen general washing powder is poisoned and has been suppressed germination, percentage of germination is low, and its bean sprouts flavescence of its epidermis, show epidermis and young shoot base portion tissue damaged, growth retardation, these washing composition have big toxic action to seed, do the equal conditions test with this product, its germination is 49, bean sprouts than water logging from the beginning is thicker, in vain, strong, another proves that this product is harmless to plant, can promote growth.
(2) pollution-free, environmentfriendly products
For handling 1, the Yong Tang town is for handling 2, table 3 in Wuwei County, Anhui mud fork town
The auxiliary agent of this product mainly is to extract soda ash from seawater, and is not phosphorous, without tripoly phosphate sodium STPP, without fluorescent agent, to water nonpollution, waterplant and fishes and shrimps do not had harm, can make the water conditioner of fishpond, to the fishes and shrimps promotes growth.
Usually with phosphoric acid salt and fluorescent agents such as detergent use tripoly phosphate sodium STPPs, cause water pollution, report according to chemical institute doctor Guo of Beijing, phosphorus 16.1% is from washing composition in the water body, 1 gram phosphorus entry can make growth blue-green algae 100 grams in the water, cause the surface water eutrophication, blue-green algae grows in the water, dead back is smelly, a large amount of oxygen makes fish death by suffocation in the consume water, the phosphorus-containing detergent turnout is about 2,000,000 tons/year at present, has every year 320000 tons of P contained compounds to be discharged in the surface water, and visible water body is big to hydrocoles harm.
(3) experimental studies results
In the tributary, Jia Lingjiang River, gather free of contamination river, carp, algae, river snail, river sand are made artificial ecosystem, and establish control group and experimental group, in addition concentration is that 1/10000 to 5/10000 washing powder and concentration are 1/100000 to 5/100000 washing powder respectively, observes the affected situation of the ecosystem.
(1) washing powder concentration is 1/10000 to 5/10000 experimental result (seeing Table 4)
| Item compared | No. 1 ecosystem | No. 2 ecosystems | No. 3 ecosystems | No. 4 ecosystems | No. 5 ecosystems | No. 6 ecosystems | ||
| Washing powder concentration | 1/10000 | 2/10000 | 3/10000 | 4/10000 | 5/10000 | Pollution-free | ||
| Water quality | Color | Transparent | 1 day | 1 day | 1 day | 1 day | 1 day | 3 days |
| Opaque | 2 days | 2 days | 2 days | 2 days | 2 days | |||
| Mean P H value | 6.86 | 6.62 | 6.70 | 6.77 | 6.98 | 6.82 | ||
| Medial temperature | 1 ℃ | 1 ℃ | 1 ℃ | 1 ℃ | 1 ℃ | 1 ℃ | ||
| Algae | The frond green | 1 day | 1 day | 1 day | 1 day | 1 day | 3 days | |
| A small amount of blackout | 2 days | 2 days | 2 days | 1 day | 1 day | |||
| A large amount of blackouts | 1 day | 1 day | ||||||
| Fish | Normal fate | 151 minutes | 103 minutes | 63 minutes | 46 minutes | 30 minutes | 3 days | |
| River snail | Normal fate | 12 hours | 12 hours | 12 hours | 7 hours | 2 hours | 3 days | |
| Remarks | Be 3 days observing time: No. 6 ecosystems are control group. | |||||||
(2) washing powder concentration is 1/100000 to 5/100000 experimental result (seeing Table 5)
| Item compared | No. 1 ecosystem | No. 2 ecosystems | No. 3 ecosystems | No. 4 ecosystems | No. 5 ecosystems | No. 6 ecosystems | ||
| Washing powder concentration | 1/100000 | 2/100000 | 3/100000 | 4/100000 | 5/100000 | Pollution-free | ||
| Water quality | Color | Transparent | 33 days | 33 days | 29 days | 25 days | 23 days | 35 days |
| Opaque | 2 days | 2 days | 6 days | 10 days | 12 days | |||
| Mean P H value | 7.00 | 6.67 | 7.00 | 7.17 | 7.00 | 7.00 | ||
| Medial temperature | 8 ℃ | 8 ℃ | 8 ℃ | 8 ℃ | 8 ℃ | 8 ℃ | ||
| Algae | The frond green | 22 days | 22 days | 19 days | 11 days | 11 days | 34 days | |
| A small amount of blackout | 13 days | 13 days | 16 days | 17 days | 14 days | 1 day | ||
| A large amount of blackouts | 7 days | 10 days | ||||||
| Fish | Normal fate | 35 days | 31 days | 30 days | 28 days | 27 days | 35 days | |
| River snail | Normal fate | 35 days | 35 days | 35 days | 33 days | 35 days | 35 days | |
| Remarks | Be 35 days observing time: No. 6 ecosystems are control group. | |||||||
By the data of table 4 and table 5 as can be known:
1. the primary factor that influences aquatic ecosystem is that washing powder pollutes;
2. washing powder concentration is 1/10000 between 5/10000 the time, and is very big to the direct influence of aquatic ecosystem: and washing powder concentration is 1/100000 between 5/100000 the time, is not very big to the direct influence of aquatic ecosystem;
When 3. washing powder concentration was excessive, the human consumer in the aquatic ecosystem (animal) at first was affected;
4. after aquatic ecosystem was destroyed, its water quality also was affected.
Can form the sanitising agent natural, nontoxic, that mild is green from above this product as can be seen, meet the effect of environmental protection, health, safety fully.
Claims (4)
- One kind natural, gentle, green sanitising agent, it is characterized in that, form: 3～4.28 parts in 1 part of compound surfactant, 15～21.428 parts of soda ash, 17～24.28 parts in saltcake, 6～8.58 parts of SPC-D, 15～21.428 parts of Starsos, 10～14.28 parts of citric acids, 2～2.86 parts of Xylo-Mucines, 2～2.86 parts of the dead acetate of quadrol, 10～14.28 parts of stopping composition and water by following composition by weight raw material.
- 2. according to claim 1 a kind of natural, gentle; green sanitising agent; it is characterized in that; described compound surfactant is made up of alkyl glycoside, Fatty acid methyl ester sodium sulfonate, acyl glutamate; its ratio is 1.5: 0.4-0.6: 0.1-0.3, wherein active matter content is 14～20.
- 3. according to claim 2 a kind of natural, gentle, green sanitising agent is characterized in that described acyl glutamate is acyl glutamic acid sodium, trolamine.
- 4. according to claim 1 a kind of natural, gentle, green sanitising agent is characterized in that described stopping composition is an attapulgite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710046644A CN101165151B (en) | 2007-09-29 | 2007-09-29 | Natural, mild and green cleaning agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710046644A CN101165151B (en) | 2007-09-29 | 2007-09-29 | Natural, mild and green cleaning agent |
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| Publication Number | Publication Date |
|---|---|
| CN101165151A true CN101165151A (en) | 2008-04-23 |
| CN101165151B CN101165151B (en) | 2010-05-19 |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101831660A (en) * | 2010-05-28 | 2010-09-15 | 大连克林尔化学品科技有限公司 | Steel surface treating agent and production method |
| CN102876468A (en) * | 2011-07-14 | 2013-01-16 | 黄登成 | Cleaning agent composition |
| WO2014085883A1 (en) * | 2012-12-07 | 2014-06-12 | Wfabrill Indústria E Comércio Ltda. - Epp | Cleaning product formulations |
| CN103966032A (en) * | 2013-01-30 | 2014-08-06 | 石家庄菠莉亚日用化工有限公司 | Environment-friendly concentrated sheet-shaped neutral detergent |
| CN105695120A (en) * | 2016-03-07 | 2016-06-22 | 苏州龙腾万里化工科技有限公司 | Decontaminative protective water-based cleaning agent |
| CN106190671A (en) * | 2016-07-04 | 2016-12-07 | 李汉辉 | Tableware dipping powder |
| CN107304383A (en) * | 2016-04-21 | 2017-10-31 | 沈阳汉威科技有限公司 | A kind of net formula of environmental protection clothing leaching |
| CN111040884A (en) * | 2019-12-31 | 2020-04-21 | 濮阳绿洁新材料科技有限公司 | Toilet bowl water tank cleaning agent and preparation method thereof |
| CN111218349A (en) * | 2018-11-26 | 2020-06-02 | 环球科诗美集团有限公司 | Liquid laundry detergent |
| CN111454788A (en) * | 2020-04-24 | 2020-07-28 | 谷雨河生物科技有限公司 | Energy-saving water-saving low-foam pregnant woman and infant laundry detergent production process and formula |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1030341A (en) * | 1987-07-09 | 1989-01-18 | 广东省煤炭工业研究所 | Permanently-effective toilet-cleaning agent |
| CN1240226A (en) * | 1998-06-18 | 2000-01-05 | 湖南丽臣实业有限公司 | Synthetic washing powder |
| EP1354938A1 (en) * | 2002-04-18 | 2003-10-22 | Unilever N.V. | Laundry tablets with improved dissolution behaviour |
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2007
- 2007-09-29 CN CN200710046644A patent/CN101165151B/en active Active
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101831660B (en) * | 2010-05-28 | 2015-04-22 | 大连克林尔化学品科技有限公司 | Steel surface treating agent and production method |
| CN101831660A (en) * | 2010-05-28 | 2010-09-15 | 大连克林尔化学品科技有限公司 | Steel surface treating agent and production method |
| CN102876468A (en) * | 2011-07-14 | 2013-01-16 | 黄登成 | Cleaning agent composition |
| WO2014085883A1 (en) * | 2012-12-07 | 2014-06-12 | Wfabrill Indústria E Comércio Ltda. - Epp | Cleaning product formulations |
| CN103966032B (en) * | 2013-01-30 | 2017-11-24 | 石家庄菠莉亚日用化工有限公司 | The neutral concentration detergent tablet of environment-friendly type |
| CN103966032A (en) * | 2013-01-30 | 2014-08-06 | 石家庄菠莉亚日用化工有限公司 | Environment-friendly concentrated sheet-shaped neutral detergent |
| CN105695120A (en) * | 2016-03-07 | 2016-06-22 | 苏州龙腾万里化工科技有限公司 | Decontaminative protective water-based cleaning agent |
| CN107304383A (en) * | 2016-04-21 | 2017-10-31 | 沈阳汉威科技有限公司 | A kind of net formula of environmental protection clothing leaching |
| CN106190671A (en) * | 2016-07-04 | 2016-12-07 | 李汉辉 | Tableware dipping powder |
| CN111218349A (en) * | 2018-11-26 | 2020-06-02 | 环球科诗美集团有限公司 | Liquid laundry detergent |
| US11365377B2 (en) | 2018-11-26 | 2022-06-21 | Global Cosmed Group spolka akcyjna | Liquid laundry detergent comprising lauryl ether sulfate and bicarbonate/metasilicate mixture |
| CN111040884A (en) * | 2019-12-31 | 2020-04-21 | 濮阳绿洁新材料科技有限公司 | Toilet bowl water tank cleaning agent and preparation method thereof |
| CN111454788A (en) * | 2020-04-24 | 2020-07-28 | 谷雨河生物科技有限公司 | Energy-saving water-saving low-foam pregnant woman and infant laundry detergent production process and formula |
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