CN101875887B - Special plant vinegar solution-containing detergent for underwear - Google Patents
Special plant vinegar solution-containing detergent for underwear Download PDFInfo
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- CN101875887B CN101875887B CN2010102010705A CN201010201070A CN101875887B CN 101875887 B CN101875887 B CN 101875887B CN 2010102010705 A CN2010102010705 A CN 2010102010705A CN 201010201070 A CN201010201070 A CN 201010201070A CN 101875887 B CN101875887 B CN 101875887B
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Abstract
The invention provides special plant vinegar solution-containing detergent for underwear, belonging to the technical field of cleaning products. The detergent is characterized by comprising a plant vinegar solution accounting for 55 to 85 percent of the total weight, wherein the plant vinegar solution can be bamboo vinegar solution, wood vinegar solution or grass vinegar solution. The special plant vinegar solution-containing detergent for the underwear has the functions of disinfecting, sterilizing, cleaning, nursing skin, deodorizing, relieving itching and adding fragrant, has no phosphorus, is safe and environment-friendly for use, has small impact on environment and good cleaning effect, and is particularly suitable for cleaning the underwear. The detergent is generally manufactured into concentrate so as to reduce package and transportation cost.
Description
Technical field
The invention belongs to the articles for washing technical field, be specially a kind of special-purpose detergent for underclothes that contains plant vinegar liquid.
Background technology
Plant vinegar liquid is the brown liquid product that is condensed at normal temperatures by the gas that collection after vegetable material and the industrial wood waste pyrolysis thereof obtains, and contains nearly more than 300 kinds of compositions such as organic acid, phenols, ketone, aldehydes, alcohols and heterocyclic.Main application is bamboo vinegar liquid, wood vinegar and careless vinegar liquid at present; Bamboo vinegar liquid is the by product that bamboo surplus material of processing obtains through high temperature pyrolysis; Wood vinegar is the by product that wood machining residues obtains through high temperature pyrolysis, and careless vinegar liquid is meant the by product that herbage and crop stalk obtain through high temperature pyrolysis.Plant vinegar liquid can be used as a plurality of fields such as medical material, industrial chemicals, foodstuff additive, dyestuff mordant, reodorant, pesticides additive agent, soil improvement agent, root of hair promotor, Animal nutrition auxiliary agent.
Along with expanding economy, people's living standard improves, and the various washing composition of consumption are also increasing, and washing composition brings many cleanings, simultaneously easily in the life of giving people, and its discharge has also brought harm to environment.Along with the attention to environment protection, country more and more pays close attention to the influence of washing composition to environment, and has formulated laws and regulations and limited the influence of washing composition to ecology.Tensio-active agent is a most important component in the washing composition, and the security of its biological degradability and degraded product is directly connected to the ecotope of washing composition.Washing assistant is a basic raw material of producing washing composition; In traditional washing composition, add 20%～45% tripoly phosphate sodium STPP and made washing assistant; The annual phosphoric acid salt that will consume 60～700,000 tons; These phosphoric acid salt make body eutrophication along with washes has finally entered rivers,lakes and seas, finally cause organism in water mass mortality, water surrounding to be seriously damaged.Develop superior with use properties, as the tensio-active agent of eco-friendly to have been become tensio-active agent and detergent manufacturer substantial responsibility.By the look of development, use reproducible animal and plant resource, producing the degradable tensio-active agent will be the development trend of tensio-active agent.The effective measure that solve are exactly to ban use of phosphorus-containing detergent in the densely inhabited district that rivers,lakes and seas are arranged, and the many areas of China begin to prohibit phosphorus one after another, but the consequent also has the washing composition performance decrease.In order to guarantee and to improve performance of products; More external major companies have strengthened the research and development of functional additive; New variety continue to bring out, and float agent, anti-dyestuff migration agent and anti-soil dirt deposition agent etc. again like zymin, SYNTHETIC OPTICAL WHITNER, bleach-activating agent, bleaching catalyst and various novel white dyes, light; To no longer being phosphoric acid salt and 4A zeolite on the Application and Development of washing assistant, but turn on the better layered silicate of washing aid performance.Special purpose detergent guarantees on the basis of product original function, and the subsidiary function that also can add other strengthening the practicality of product, is washed the back fabric and had soft, anlistatig advantage as in fabric detergent, increasing softness, making; Increase bleaching, sterilizing function, the bleaching function can not only improve the washing composition detersive power, and has also given the function of effect product sterilization to a certain extent.
Many cleaning products all directly contact with human body, like hand with dish washing detergent, laundry detergent and other personal cleansing article; In addition, though some product does not directly contact with human body generally speaking,, then possibly damage, like highly acid detergent for toilet, scale remover and strong basicity cooking stove sanitising agent, dredging sewer agent etc. to human body if spattered because of carelessness.Therefore, to the pungency and the security of human body, just become the important indicator of these products.For obtaining gentle effect, each production firm extensively adopted low stimulation, to human temperature and tensio-active agent reduce the pungency of washing composition to skin, adopt the acid-basicity that reduces prescription to improve security of products.
Summary of the invention
For overcoming the problem that exists in the prior art, the objective of the invention is to design the technical scheme that a kind of without phosphorus special-purpose detergent for underclothes is provided, washing effect is good, and safe in utilization, environmental protection is little to environmental influence.
Described a kind of special-purpose detergent for underclothes that contains plant vinegar liquid is characterized in that containing the plant vinegar liquid of gross weight 55-85%, and described plant vinegar liquid is bamboo vinegar liquid, wood vinegar or careless vinegar liquid.
Described a kind of special-purpose detergent for underclothes that contains plant vinegar liquid is characterized in that also containing the sterilizing agent of gross weight 3-8%, and described sterilizing agent is RBA 777, phenylformic acid or Sodium Benzoate.
Described a kind of special-purpose detergent for underclothes that contains plant vinegar liquid; It is characterized in that also containing the emulsifying agent of gross weight 10-40%, described emulsifying agent is one or more the mixture among tea saponin, APG (APG), dodecyl phenenyl sulfate, X 2073, Witco 1298 Soft Acid or the OP-10.
Described a kind of special-purpose detergent for underclothes that contains plant vinegar liquid; It is characterized in that also containing the essence of gross weight 0.05-0.65%; Described essence is 2-nitroethyl alcohol, epoxy pentane, acetic acid hydrazides, LAURIC ACID 99 MIN, 2; 3-oxo-tetracosanoic acid methyl esters, 2,3-diacetyl propyl group laurate, 2-ethanoyl, 2, the mixture of one or more in the 4-dinitrobenzene ETHYLE ACETATE.
Described a kind of special-purpose detergent for underclothes that contains plant vinegar liquid; It is characterized in that also containing the sanitas of gross weight 0.04-0.1%; Described sanitas is kathan (card pine), oxaban, germall (outstanding horse), p-Hydroxybenzoate verivate (Ni Baijin ester class), benzylalcohol, butylene-chlorohydrin, 2,4-Dybenal, 2-phenoxyethyl alcohol, Whitfield's ointment, deoxidation acetate or Sorbic Acid.
Described a kind of special-purpose detergent for underclothes that contains plant vinegar liquid is characterized in that plant vinegar liquid content is 60-80%, preferred 70-80%, more preferably 75-80%.
Described a kind of special-purpose detergent for underclothes that contains plant vinegar liquid is characterized in that sterilizing agent content is 4-7%, preferred 5-6.5%, more preferably 5.5-6%.
Described a kind of special-purpose detergent for underclothes that contains plant vinegar liquid is characterized in that emulsifier content is 15-35%, preferred 18-35%, more preferably 25-30%.
Described a kind of special-purpose detergent for underclothes that contains plant vinegar liquid is characterized in that essence content is 0.1-0.6%, preferred 0.2-0.4%, more preferably 0.25-0.3%.
Described a kind of special-purpose detergent for underclothes that contains plant vinegar liquid is characterized in that antiseptic content is 0.05-0.08%, preferred 0.055-0.065%.
Also can adopt through the plant vinegar liquid distillate and the liquid concentrator that distill or rectification process obtains.
Above-mentioned a kind of special-purpose detergent for underclothes that contains plant vinegar liquid has sterilization, sterilization, washing, skin care, deodorizing, antipruritic, flavouring function, and not phosphorous, safe in utilization, environmental protection are little to environmental influence; Washing effect is good, and particularly suitable cleans underclothes.This washing composition is made generally in liquid concentrator, to reduce packing and transportation cost.
Percentage composition is the weight percentage of pure substance in the present specification.
Embodiment
Combine the embodiments of the invention and the test of pesticide effectiveness at present, further specify beneficial effect of the present invention.
Embodiment 1
In the 500L reaction kettle, drop into 400kg grass vinegar liquid, slowly drop into 25kg phenylformic acid and 75kg Witco 1298 Soft Acid again, stirring reaction 60 minutes promptly gets product.
Embodiment 2
In the 500L reaction kettle, drop into 20% the concentrated plant vinegar liquid that 296.5kg is concentrated to former plant vinegar liquid (100kg concentrates the mixed solution that bamboo vinegar liquid, 100kg concentrate wood vinegar and the concentrated careless vinegar liquid of 96.5kg), slowly drop into 25kg RBA 777 and 100kg tea saponin again, the 75kg Witco 1298 Soft Acid; Stirred 60 minutes, and slowly dropped into 2-ethanoyl, 2 again; 4-dinitrobenzene ETHYLE ACETATE and 2; Each 1.0kg of 3-diacetyl propyl group laurate slowly drops into the 0.5kg Whitfield's ointment again, promptly gets product.
Embodiment 3
In the 500L reaction kettle, drop into 299.75kg grass vinegar liquid; Slowly drop into 25kg RBA 777 and 50kg APG (APG) again, the 25kg dodecyl phenenyl sulfate stirred 60 minutes; Slowly drop into LAURIC ACID 99 MIN and 2 again; 3-oxo-each 0.5kg of tetracosanoic acid methyl esters slowly drops into the 0.25kg Sorbic Acid again, promptly gets product.
Embodiment 4
In the 500L reaction kettle, drop into 299.75kg plant vinegar liquid (mixed solution of 100kg bamboo vinegar liquid, 100kg wood vinegar and 99.75kg grass vinegar liquid); Slowly drop into 25kg RBA 777 and 50kg APG (APG) again, the 25kg dodecyl phenenyl sulfate stirred 60 minutes; Slowly drop into LAURIC ACID 99 MIN and 2 again; 3-oxo-each 0.5kg of tetracosanoic acid methyl esters slowly drops into 0.25kg kathan (card pine) again, promptly gets product.
Embodiment 5
In the 500L reaction kettle, drop into the refining plant vinegar liquid of 299.75kg (mixed solution of the refining careless vinegar liquid of 100kg refined bamboo vinegar, 100kg acetum pyrolignosum rectificatum liquid and 99.75kg), slowly drop into 25kg RBA 777 and 50kg tea saponin again, the 25kg Witco 1298 Soft Acid; Stirred 60 minutes, and slowly dropped into 2-ethanoyl, 2 again; 4-dinitrobenzene ETHYLE ACETATE and 2; Each 0.5kg of 3-diacetyl propyl group laurate slowly drops into the 0.25kg Whitfield's ointment again, promptly gets product.
Embodiment 6
In the 500L reaction kettle, drop into 399.5kg acetum pyrolignosum rectificatum liquid, slowly drop into 25kg RBA 777 and 75kg tea saponin again, stirred 60 minutes, slowly drop into 0.5kg 2-nitroethyl alcohol again, promptly get product.
Embodiment 7
In the 500L reaction kettle, drop into 399kg and concentrate bamboo vinegar liquid, slowly drop into 25kg Sodium Benzoate and 75kg APG (APG) again, stirred 60 minutes, slowly drop into 1.0kg 2 again, 4-dinitrobenzene ETHYLE ACETATE promptly gets product.
Embodiment 8
In the 500L reaction kettle, drop into 299.75kg acetum pyrolignosum rectificatum liquid, slowly drop into 25kg RBA 777 and 50kg tea saponin again, the 25kg Witco 1298 Soft Acid; Stirred 60 minutes; Slowly drop into the 2-ethanoyl again, 2,4-dinitrobenzene ETHYLE ACETATE and each 0.5kg of epoxy pentane; Slowly drop into the 0.25kg butylene-chlorohydrin again, promptly get product.
Embodiment 9
In the 500L reaction kettle, drop into 30% the concentrated bamboo vinegar liquid that 296.5kg is concentrated to the bamboo plant vinegar liquid, slowly drop into 25kg RBA 777 and 100kg tea saponin again, the 75kg Witco 1298 Soft Acid; Stirred 60 minutes; Slowly drop into the 2-ethanoyl again, acetic acid hydrazides and 2, each 1.0kg of 3-diacetyl propyl group laurate; Slowly drop into 0.5kg 2-phenoxyethyl alcohol again, promptly get product.
Below through its control effect of test explanation:
Table 1. embodiment 1-9 is to the BA effect (being diluted to 500mg/L, is standard with plant vinegar liquid concentration) of streptococcus aureus
Table 1 shows: embodiment 1-9 all has active preferably to killing of streptococcus aureus, wherein embodiment 2,7,9 is best, and embodiment 1,3,4 takes second place.
Table 2. embodiment 1-9 is to the BA effect (being diluted to 500mg/L) of Pseudomonas aeruginosa
Table 2 shows: embodiment 1-9 all has active preferably to killing of Pseudomonas aeruginosa, wherein embodiment 2,7,9 is best, and embodiment 1,3,4 takes second place.
Table 3. embodiment 1-9 is to the oidiomycetic BA effect of white (being diluted to 500mg/L)
Table 3 shows: embodiment 1-9 all has activity preferably to oidiomycetic the killing of white, and wherein embodiment 2,7,9 is best, and embodiment 1,3,4 takes second place.
Table 4. embodiment 1-9 is to colibacillary BA effect (being diluted to 500mg/L)
Annotate: the average bacterium number of positive controls: streptococcus aureus is the 2260000cfu/ sheet, and intestinal bacteria are the 705000cfu/ sheet, Candida albicans 810000cfu/ sheet.
Table 4 shows: embodiment 1-9 all has activity preferably to colibacillary killing, and wherein embodiment 2,7,9 is best, and embodiment 1,3,4 takes second place.
Claims (5)
1. special-purpose detergent for underclothes that contains plant vinegar liquid is characterized in that containing the plant vinegar liquid of gross weight 70-80%, and described plant vinegar liquid is wood vinegar or careless vinegar liquid; The sterilizing agent that also contains gross weight 3-8%, described sterilizing agent are RBA 777, phenylformic acid or Sodium Benzoate; The emulsifying agent that also contains gross weight 10-40%, described emulsifying agent are one or more the mixture among tea saponin, APG (APG), dodecyl phenenyl sulfate, X 2073, Witco 1298 Soft Acid or the OP-10; The essence that also contains gross weight 0.05-0.65%, described essence are 2-nitroethyl alcohol, epoxy pentane, acetic acid hydrazides, LAURIC ACID 99 MIN, 2,3-oxo-tetracosanoic acid methyl esters, 2, the mixture of one or more in the 3-diacetyl propyl group laurate; The sanitas that also contains gross weight 0.04-0.1%; Described sanitas is kathan (card pine), oxaban, germall (outstanding horse), p-Hydroxybenzoate verivate (Ni Baijin ester class), benzylalcohol, butylene-chlorohydrin, 2,4-Dybenal, 2-phenoxyethyl alcohol, Whitfield's ointment, deoxidation acetate or Sorbic Acid.
2. a kind of special-purpose detergent for underclothes that contains plant vinegar liquid as claimed in claim 1 is characterized in that sterilizing agent content is 4-7%.
3. a kind of special-purpose detergent for underclothes that contains plant vinegar liquid as claimed in claim 1 is characterized in that emulsifier content is 15-35%.
4. a kind of special-purpose detergent for underclothes that contains plant vinegar liquid as claimed in claim 1 is characterized in that essence content is 0.1-0.6%.
5. a kind of special-purpose detergent for underclothes that contains plant vinegar liquid as claimed in claim 1 is characterized in that antiseptic content is 0.05-0.08%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102010705A CN101875887B (en) | 2008-01-22 | 2008-01-22 | Special plant vinegar solution-containing detergent for underwear |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102010705A CN101875887B (en) | 2008-01-22 | 2008-01-22 | Special plant vinegar solution-containing detergent for underwear |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008100594381A Division CN101235343B (en) | 2008-01-22 | 2008-01-22 | Special-purpose detergent for underclothes |
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| Publication Number | Publication Date |
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| CN101875887A CN101875887A (en) | 2010-11-03 |
| CN101875887B true CN101875887B (en) | 2012-07-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2010102010705A Expired - Fee Related CN101875887B (en) | 2008-01-22 | 2008-01-22 | Special plant vinegar solution-containing detergent for underwear |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106010800A (en) * | 2016-05-31 | 2016-10-12 | 太仓协大申泰羊毛衫有限公司 | Bamboo vinegar liquid-containing antibacterial woolen sweater liquid detergent |
| CN107287603A (en) * | 2017-06-01 | 2017-10-24 | 杭州大家生物科技有限公司 | Soil preparations and its waste water utilization method are gone in a kind of multiple-effect derusting containing plant vinegar liquid |
| CN108467801A (en) * | 2018-02-13 | 2018-08-31 | 平南县亿翔环保能源有限公司 | A kind of detergent containing wood vinegar |
| CN108441359A (en) * | 2018-02-13 | 2018-08-24 | 平南县亿翔环保能源有限公司 | A kind of glass cleaner containing wood vinegar |
| CN111909803B (en) * | 2020-09-17 | 2021-11-30 | 广州市白云区大荣精细化工有限公司 | Clothes fragrance-retaining composition and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1547908A (en) * | 2003-05-07 | 2004-11-24 | 江 徐 | Prepn and application of natural bamboo vinegar disinfectant liquid |
| CN1778773A (en) * | 2005-10-17 | 2006-05-31 | 浙江林学院 | Liquid fertilizer with pyroligneous liquor and oxalacetic liquor and production thereof |
| CN1957896A (en) * | 2005-11-04 | 2007-05-09 | 杨国庭 | Nursing liquid for skin care of wood vinegar, and preparation method |
| CN101671953A (en) * | 2008-10-27 | 2010-03-17 | 浙江纺织服装科技有限公司 | Method for producing antibacterial fabric finished by bamboo vinegar liquor |
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2008
- 2008-01-22 CN CN2010102010705A patent/CN101875887B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1547908A (en) * | 2003-05-07 | 2004-11-24 | 江 徐 | Prepn and application of natural bamboo vinegar disinfectant liquid |
| CN1778773A (en) * | 2005-10-17 | 2006-05-31 | 浙江林学院 | Liquid fertilizer with pyroligneous liquor and oxalacetic liquor and production thereof |
| CN1957896A (en) * | 2005-11-04 | 2007-05-09 | 杨国庭 | Nursing liquid for skin care of wood vinegar, and preparation method |
| CN101671953A (en) * | 2008-10-27 | 2010-03-17 | 浙江纺织服装科技有限公司 | Method for producing antibacterial fabric finished by bamboo vinegar liquor |
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| CN101875887A (en) | 2010-11-03 |
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