CN102851131A - Detergent with functions of decontamination, sterilization and fabric softening - Google Patents

Detergent with functions of decontamination, sterilization and fabric softening Download PDF

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CN102851131A
CN102851131A CN2012103201889A CN201210320188A CN102851131A CN 102851131 A CN102851131 A CN 102851131A CN 2012103201889 A CN2012103201889 A CN 2012103201889A CN 201210320188 A CN201210320188 A CN 201210320188A CN 102851131 A CN102851131 A CN 102851131A
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fabric
detergent
sterilization
functions
present
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CN102851131B (en
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胡艳霞
罗文姗
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HUNAN DAILY CHEMICAL SCIENCE RESEARCH INSTITUTE CO LTD
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HUNAN DAILY CHEMICAL SCIENCE RESEARCH INSTITUTE CO LTD
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Abstract

The invention relates to a detergent with functions of decontamination, sterilization and fabric softening. The detergent comprises the following components, by weight, 18-26% of C16-18 polyoxypropylene polyoxyethylene aliphatic alcohol ether, 10-20% of isomeric C13 fatty alcohol ether, 0.2-0.8% of glycol mono stearate, 2-4% of sodium citrate, 5-20% of nanometer silver, 6-10% of 2-methyl-2,4-pentadiol, 6-15% of diester dimethyl tert-butyl ether ammonium chloride, 0.5-1% of EDTA-4Na, 0.1-0.5% of essence, 0.1-0.5% of a dye, and 20-30% of deionized water. The detergent of the present invention is a detergent with functions of effective removal of stains on the fabric, killing of bacteria and fungi on the fabric, and fabric softening.

Description

The washing composition of a kind of stain removal bactericidal and compliant fabric
Technical field
The invention belongs to daily use chemicals washing field, be specifically related to a kind of washing composition that is applicable to industry and domestic fabric washing.
Background technology
Clothing, textiles cleaning are one of human lives's problems from start to finish, raising along with people's living standard, the enhancing of the consciousness of sanitation and hygiene, the human consumer is more and more higher to the requirement of cleaning, namely cleaning is not only to remove the visible dirt such as greasy dirt dust, also should remove even kill harmful germ, wash simultaneously rear fabric sofetening comfortable.
General cleaning can only decontamination, but can not sterilization also have the effect of compliant fabric, so people will carry out sterilization again with special sterilant, or special softener comes compliant fabric.Sterilant and softener all will use separately, bring very large inconvenience to the human consumer.Really can decontamination, sterilization, again can compliant fabric, and the good consumer acceptance's of cost performance the simultaneously product of the sterilization softening laundry liquid of disinfecting and decontaminating compliant fabric there is not yet.
Chinese patent application 200710179670.4 discloses antimicrobial laundry liquid of a kind of simultaneously disinfecting and decontaminating and preparation method thereof.Secondly adopt two arc classes, diquaternary amine salt as sterilizing agent in the washing liquid prescription, sterilization effect is limited, and this washing liquid only has the disinfecting and decontaminating performance to there is no submissive effect.The present invention adopts nanometer silver as sterilant, and the measured result of its sterilization effect is up to state standards, and the simultaneously submissive successful of washing liquid of disinfecting and decontaminating compliant fabric described in the present invention.
Summary of the invention
The purpose of this invention is to provide and a kind ofly can effectively remove spot on the fabric, kill simultaneously bacterium, fungi on the fabric, and washing composition that can compliant fabric.
The washing composition of stain removal bactericidal provided by the invention and compliant fabric is comprised of following weight percent composition:
Figure BDA00002081971600011
Figure BDA00002081971600021
Nanometer silver nanometer silver particle diameter in the above-mentioned component is 15~25nm.
Washing composition provided by the invention, obtain by the preferred component of repetition test, washing composition uses Trisodium Citrate as the complexing agent of the metal ions such as calcium or magnesium, effective softening washing water, and to the effect that pH has adjusting and buffering, make washing composition can satisfy the pH value area requirement of the chemical stabilities such as tensio-active agent and emulsifying agent; Washing composition has adopted the C of long carbochain 16-18Aliphatic alcohol polyethenoxy polyoxypropylene ether surface active agent, this tensio-active agent have high, the anti-hard water of surfactivity and low bubble performance, and can be dissolved in well the formation highly efficiency compositional washing composition such as auxiliary agent, emulsifying agent, have better washability; Adopt environmentally friendly solvent 2-methyl-2,4 pentanediol (Hexasol) to increase isomery polyoxyethylenated alcohol and the dispersiveness of isomery fatty alcohol-ether in water of long carbochain, nontoxic, security is good; In compound system, utilize the C of the active reactive group of compound 16-18Directly introduce nano silver material on the aliphatic alcohol polyethenoxy polyoxypropylene macromolecular chain, the tens of kinds of pathogenic microorganisms such as intestinal bacteria, streptococcus aureus, Candida albicans, gonococcus, chlamydia trachomatis are had strong inhibition and killing action and do not produce resistance, and in conjunction with the germicidal action of dibasic acid esters fat base dimethyl tertbutyl ether ammonium chloride, make bactericidal property more effective lasting; The in addition stable effect of also playing compliant fabric of the softness of dibasic acid esters fat base dimethyl tertbutyl ether ammonium chloride; Whole detergent formulation is for fabric safety, health, comfortable softness after the washing of fabric.
Washing composition germicidal action experimental test of the present invention, by the effect of 2min to intestinal bacteria, streptococcus aureus and Candida albicans, average bactericidal rate is respectively 100.00%, 100.00%, 100.00%.
The submissive Experiment on Function test of washing composition of the present invention is by the fabric rewetting, in the capillary effect time; The fabric antistatic property is in surface specific resistance logarithmic difference value difference.
Effect of the present invention: by repeatedly experiment, selected two kinds of strong detergency readily biodegradables and the good tensio-active agent of compatibility, i.e. C 16-18Aliphatic alcohol polyethenoxy polyethenoxy ether, isomery C 13Fatty alcohol-ether composite reaches efficient clean effect; Simultaneously add especially people's nanometer silver as fabric sterilization and disinfection component in prescription, the present invention has not only played the intensity that has strengthened sterilization and disinfection by the adding of dibasic acid esters fat base dimethyl tertbutyl ether ammonium chloride in addition, and further compliant fabric.Guarantee the health of fabric and human consumer's health by effective proportioning of the present invention, make clean, sanitary, the comfortable softness of fabric.
Embodiment
Following examples are to further specify of the present invention, rather than limit the scope of the invention.
For different washing requirements, above-mentioned prescription can be made suitable adjustment in summary of the invention scope of the present invention.Unit all is weight percentage among the embodiment.
Embodiment 1:
Fill a prescription 1 as follows:
Figure BDA00002081971600031
Experimental data:
1) sterilizing ability:
We have carried out the sterilization contrast experiment to have germicidal action washings and the washing composition of the present invention on the market, and find after testing: commercially available desinfactant detergent has certain bactericidal and bacteriostatic effect, but the sterilization effect difference is larger.Washing composition bactericidal range of the present invention is wider, can play germicidal action to bacterium, the fungi of carrying in coat, outer trousers, underwear, underpants, socks and the rag respectively, and sterilization effect is obvious, and sterilization is thorough.
Washing composition effect of the present invention is respectively 100.00%, 100.00%, 100.00% by 2min to the average bactericidal rate of intestinal bacteria, streptococcus aureus and Candida albicans.
2) submissive ability:
A, fabric rewetting: the rewetting of the present embodiment take (capillary effect time) as 25s
Rewetting (in the capillary effect time) the average out to 78s of present other related productss, i.e. the present invention is three times of existing products in markets effect.
B, fabric antistatic property: antistatic property (in the surface specific resistance logarithmic difference value difference △ lg ρ) average out to 2.5 of the static resistance of the present embodiment take (surface specific resistance logarithm value difference △ lg ρ) as 4.82 present other related productss, i.e. the present invention is two times of existing products in markets effect.
Embodiment 2:
Be used for the demanding situation of fabric softening:
The static of the fabric effect not only depends on the static content of its generation, more depends on static charge dissipation ability, and fabric face resistance is the physical quantity that characterizes the static of the fabric rate of decay.Present method is under prescribed condition, with mylar fabric conditioner testing liquid immersion treatment, decide the surface resistivity that mylar is processed front and back with the ultra-high resistance instrumentation, lower the quality of △ ρ or surface specific resistance logarithmic value reduction △ lg ρ evaluation fabric softening antistatic property with surface specific resistance.
The submissive stoste of table 1 bactericidal nano-silver and commercially available related products static resistance detect Data Comparison
Figure BDA00002081971600042
Rewetting
Because long carbochain cats product is bringing to fabric submissive, the anlistatig while, has also reduced the water absorbing properties of clothing, makes the rewetting degradation of clothing.
The submissive liquid of table 2 bactericidal nano-silver and commercially available related products are to fabric rewetting performance test result relatively
Figure BDA00002081971600043
Embodiment 3:
Be used for the demanding situation of sterilization and disinfection:
The suspension quantitative disinfecting test
Get the submissive liquid stoste of bactericidal nano-silver 5ml and contrast liquid (PBS (0.2% Sulfothiorine, 1.0% sodium-chlor, 2.0% tween-80,0.3% Yelkin TTS)) and put in the sterilizing test tubes of radiator valve, get above-mentioned bacteria suspension 100 μ l mixings.Draw 0.5ml bacterium liquid mixed solution when being applied to respectively 2min, 5min, 10min, 20min and add the in vitro mixing that contains 4.5mlPBS, do suitably dilution after, draw respectively the 1.0ml ware that inclines and do the viable bacteria enumeration.Test repeats 3 times.
The submissive liquid of table 3 bactericidal nano-silver is to the sterilization effect of streptococcus aureus
Figure BDA00002081971600052
The submissive liquid of table 4 bactericidal nano-silver is to the sterilization effect of Candida albicans
Figure BDA00002081971600061
The submissive liquid of table 5 bactericidal nano-silver is to colibacillary sterilization effect
Figure BDA00002081971600062
Under 20 ℃ ± 1 ℃ water bath condition, test repeats 3 times.The submissive stoste effect of bactericidal nano-silver 2min is 100.00% to streptococcus aureus, Candida albicans and colibacillary average bactericidal rate.

Claims (2)

1. the washing composition of a stain removal bactericidal and compliant fabric is characterized in that, comprises that following weight percent forms:
2. washing composition according to claim 1 is characterized in that, described nanometer silver particle diameter is 15~25nm.
CN201210320188.9A 2012-08-31 2012-08-31 Detergent with functions of decontamination, sterilization and fabric softening Active CN102851131B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105623868A (en) * 2015-12-28 2016-06-01 广东都市丽人实业有限公司 Nano-silver washing solution and preparation method thereof
CN105670823A (en) * 2015-12-30 2016-06-15 广州市南大实业有限公司 Antibiosis detergent powder, and preparation method and application thereof
CN109762678A (en) * 2019-03-21 2019-05-17 福建省纯杰绿色科技有限公司 A kind of plant cleaning agent for animal origin cleaning
CN109868191A (en) * 2019-03-21 2019-06-11 福建省纯杰绿色科技有限公司 A kind of plant cleaning agent for human secretion cleaning
CN109897736A (en) * 2019-04-01 2019-06-18 合肥亚太日化有限公司 A kind of antibacterial cleanser and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102242023A (en) * 2011-05-31 2011-11-16 廊坊乐万家联合家化有限公司 Laundry liquid with washing and caring functions
CN102604764A (en) * 2012-02-24 2012-07-25 福建省金鹿日化股份有限公司 Special underwear washing and caring solution

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102242023A (en) * 2011-05-31 2011-11-16 廊坊乐万家联合家化有限公司 Laundry liquid with washing and caring functions
CN102604764A (en) * 2012-02-24 2012-07-25 福建省金鹿日化股份有限公司 Special underwear washing and caring solution

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105623868A (en) * 2015-12-28 2016-06-01 广东都市丽人实业有限公司 Nano-silver washing solution and preparation method thereof
CN105670823A (en) * 2015-12-30 2016-06-15 广州市南大实业有限公司 Antibiosis detergent powder, and preparation method and application thereof
CN109762678A (en) * 2019-03-21 2019-05-17 福建省纯杰绿色科技有限公司 A kind of plant cleaning agent for animal origin cleaning
CN109868191A (en) * 2019-03-21 2019-06-11 福建省纯杰绿色科技有限公司 A kind of plant cleaning agent for human secretion cleaning
CN109897736A (en) * 2019-04-01 2019-06-18 合肥亚太日化有限公司 A kind of antibacterial cleanser and preparation method thereof

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