CN109096925A - A kind of environmentally protective scratch resistance aqua type lapping liquid and preparation method thereof - Google Patents
A kind of environmentally protective scratch resistance aqua type lapping liquid and preparation method thereof Download PDFInfo
- Publication number
- CN109096925A CN109096925A CN201810707632.XA CN201810707632A CN109096925A CN 109096925 A CN109096925 A CN 109096925A CN 201810707632 A CN201810707632 A CN 201810707632A CN 109096925 A CN109096925 A CN 109096925A
- Authority
- CN
- China
- Prior art keywords
- lapping liquid
- environmentally protective
- scratch resistance
- aqua type
- boric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/04—Aqueous dispersions
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Organic Chemistry (AREA)
- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of environmentally protective scratch resistance aqua type lapping liquids and preparation method thereof.The lapping liquid includes the raw material of following weight percent: alkyl diethanolamide 1-5%, linear alkyl benzene sulfonic acid 5-15%, scratching resistant 1-5%, boric acid 0.5-1%, deionized water surplus, is prepared according to the following steps: alkyl diethanolamide and linear alkyl benzene sulfonic acid are mixed；Under 100 DEG C of heating water baths, deionized water is mixed with boric acid solid, prepares boric acid solution；Obtained boric acid solution is added in the mixture prepared；It is sufficiently stirred, adds the sodium hydroxide solution that mass concentration is 30% and liquid environment is adjusted to 8.00-10.00, scratching resistant is added thereto after shady place is placed 12 hours；PH is adjusted to 5.50 using the citric acid solution that mass concentration is 50%；Up to environmentally protective scratch resistance aqua type lapping liquid after standing.The advantages that present invention has adhesion strength high, stablizes, biodegradable, environmentally protective, and preparation method is simple, meets the demand of industrial mass production.
Description
Technical field
The invention belongs to be machined cleaning technique field, ground more particularly to a kind of environmentally protective scratch resistance aqua type
Liquid and preparation method thereof.
Background technique
In grinding process technique, lapping liquid plays the role of vital.Lapping liquid can make to grind during the grinding process
Mill abrasive material is uniformly distributed, lubrication, and forms oxide film in workpiece surface, thus accelerate process of lapping, it can also be in gold
Degreasing, antirust, the effects of cleaning and add lustre to are played after belonging to material mechanical processing.Earliest lapping liquid organic oil, kerosene, lard
Deng.But it is gradually substituted since above-mentioned lapping liquid permeability is strong, inflammable, volatile, environmental pollution is serious.
The existing general main component of lapping liquid are as follows: thickener, dispersing agent, pH adjusting agent, surfactant and chelating
Agent etc..In order to make product have good compatibility and stable appearance, what the lapping liquid produced on the market was added to mostly contains
Substance, such as patent CN102311718B, TW1623612B is complexed in phosphoric acid salt；In order to improve the rustless property of lapping liquid, meeting
Add the substances such as sodium nitrite, such as patent CN103450848A, CN102250581B；However, being added in lapping liquid phosphorous
Substance or sodium nitrite is complexed in Barbiturates, and the discharge of subsequent lapping liquid waste water will cause waters eutrophication, promotes algae numerous
It grows, water oxygen level is made to decline and cause water quality deterioration, be unsatisfactory for the needs of environmental protection.
In addition, there is scratch when being easy to cause grinding there is also the problem inadequate to abrasive material dispersibility in existing lapping liquid,
Subsequent processing is difficult, influences product quality；The problem of some lapping liquid stability is inadequate, is easy to appear a point water, precipitating.
Therefore, based on defect existing for above-mentioned existing lapping liquid, the present invention develops a kind of environment-friendly and green, is suitable for metal
The lapping liquid of material.For the lapping liquid while meeting grinding effect, adhesion strength is high, and property is stablized, biodegradable, green
Colour circle is protected, and the grinding liquid and preparation method thereof is simple, meets the demand of industrial mass production.
Summary of the invention
The purpose of the present invention is to provide a kind of environmentally protective scratch resistance aqua type lapping liquids and preparation method thereof.The present invention
With adhesion strength height, property is stablized, biodegradable, environmentally protective, and the grinding liquid and preparation method thereof is simple, meets industry
The advantages that demand of large-scale production.
To achieve the above object, the present invention takes following technical scheme:
A kind of environmentally protective scratch resistance aqua type lapping liquid, which includes the raw material of following weight percent:
The alkyl diethanolamide that the present invention uses is a kind of nonionic surfactant, and linear alkyl benzene sulfonic acid is a kind of
Anionic surfactant, surfactant is many kinds of in the prior art, which kind of surface used actually for certain system
Activating agent is proper, and efficiency highest also lacks theoretical direction at present.The present invention is living by above two different types of surface
Property agent compounding, according to the HLB value of two kinds of surfactants by many experiments determine both optimum content, when aqua type grind
The weight percent of alkyldiethanolamine is 1-5% in liquid, and linear alkyl benzene sulfonic acid weight percent can rise when being 5-15%
To optimal effect, there can not only be preferable dispersibility to abrasive material, so that it is not easy scratch occur in subsequent process of lapping, and
And stable system, transparent clear lapping liquid can be made.
Meanwhile linear alkyl benzene sulfonic acid can also play the role of oiliness improver and antirust agent, especially the present invention is used as one
Kind aqua type lapping liquid, the presence of linear alkyl benzene sulfonic acid can significantly reduce lapping liquid of the present invention for during metal grinding
The problem of caused metal erosion, instead of conventional use of antirust agent such as nitrite.The discharge of nitrite can cause water
Matter eutrophication, or react with other additives and generate carcinogenicity ammonium nilrite, and the present invention passes through linear alkylbenzene (LAB)
The use of sulfonic acid overcomes the above problem caused by nitrite.
In above-mentioned aqua type lapping liquid, it is preferred that the alkyl diethanolamide is coco-nut oil fatty acid diethanol acyl
Amine.
In above-mentioned aqua type lapping liquid, it is preferred that the linear alkyl benzene sulfonic acid is dodecyl benzene sulfonic acid.
In above-mentioned aqua type lapping liquid, it is preferred that the scratching resistant is calcium stearate, aluminum stearate, oleic acid surface
One or more of line borate of modification.
In above-mentioned aqua type lapping liquid, it is preferred that the sodium hydroxide solution and/or quality that addition mass concentration is 30%
The citric acid solution that concentration is 50%.The present invention add sodium hydroxide and/or citric acid solution be in order to the pH to lapping liquid into
Row adjustment.It is furthermore preferred that the pH=5.5 of above-mentioned water base lapping liquid.It is a discovery of the invention that having when lapping liquid pH is 5.5 best
Physicochemical property, cleaning performance and grinding performance.Lapping liquid has excellent stability between 0 DEG C -70 DEG C, can keep product
Stablize not stratified.It is tested using moisture film method, the moisture film that product leaves the formation of water surface rear surface after grinding can uniformly take whole tables
Face.It is ground with plastic cement abrasive material, up to 0.2 μm, lapped face micro- can only be distinguished the surface roughness Ra of product after grinding
Processing direction.
In above-mentioned aqua type lapping liquid, it is preferred that further comprise the raw material of following weight percent:
The present invention also provides a kind of preparation methods of environmentally protective scratch resistance aqua type lapping liquid, which includes following
The raw material of weight percent:
It is prepared according to the following steps to obtain:
(1) alkyl diethanolamide and linear alkyl benzene sulfonic acid are mixed；
(2) under 100 DEG C of heating water baths, deionized water is mixed with boric acid solid, prepares boric acid solution；
(3) boric acid solution for obtaining step (2) is added in step (1) prepared mixture；
(4) said mixture matter is sufficiently stirred, adds the sodium hydroxide solution that mass concentration is 30% for Breakup of Liquid Ring
Border is adjusted to 8.00-10.00, places 12 hours in shady place, and after white foam disappearance, scratching resistant is added thereto；This
Sodium hydroxide is added in place, and appearance uniform is consistent from preparing, not stratified technological design.
(5) pH is adjusted to 5.50 using the citric acid solution that mass concentration is 50%；Up to environmentally protective anti-after standing
Scratch aqua type lapping liquid.
The present invention has following technical characterstic:
1) present invention uses alkyldiethanolamine and the two distinct types of surfactant compound of linear alkyl benzene sulfonic acid,
There can not only be preferable dispersibility to abrasive material, so that being not easy scratch, and stable system, energy occur in subsequent process of lapping
Transparent clear lapping liquid is enough made.
2) linear alkyl benzene sulfonic acid of the present invention has Corrosion Protection, can significantly reduce lapping liquid for metal grinding mistake
In journey the problem of caused metal erosion.
3) present invention has excellent grinding performance and cleaning performance.It is tested using moisture film method, product leaves water after grinding
The moisture film that face rear surface is formed can uniformly take all surfaces.It is ground with plastic cement abrasive material, the surface of product after grinding
For roughness Ra up to 0.2 μm, lapped face micro- can only distinguish processing direction.
4) present invention employs the scratching resistants such as the line borate of calcium stearate, aluminum stearate and oleic acid surface modification, increase
The wear-resistant and antifriction performance of lapping liquid.
5) lapping liquid each component of the invention has good biodegradable ability, is a kind of environmentally protective aqua type
Lapping liquid.
Specific embodiment
Following specific embodiments are the further explanations to method provided by the invention and technical solution, but are not construed as
Limitation of the present invention.
Embodiment 1: aqua type lapping liquid is prepared, each raw material weight is as follows: cocoanut fatty acid diethanolamide 50g, ten
Dialkyl benzene sulfonic acids 150g, calcium stearate 50g, boric acid 10g, deionized water 740g；Preparation steps are as follows:
(1) cocoanut fatty acid diethanolamide and linear alkyl benzene sulfonic acid are mixed；
(2) under 100 DEG C of heating water baths, deionized water is mixed with boric acid solid, prepares boric acid solution；
(3) boric acid solution for obtaining step (2) is added in step (1) prepared mixture；
(4) said mixture matter is sufficiently stirred, adds the sodium hydroxide solution that mass concentration is 30% for Breakup of Liquid Ring
Border is adjusted to 8.00-10.00, places 12 hours in shady place, and after white foam disappearance, stearate is added thereto；
(5) pH is adjusted to 5.50 using the citric acid solution that mass concentration is 50%；Up to environmentally protective anti-after standing
Scratch aqua type lapping liquid.
The resulting aqua type lapping liquid stability of the present embodiment is strong, is uniformly mixed in 120 hours, no precipitating.By the water
Property lapping liquid mixed with plastic abrasive according to mass ratio 1:20, stainless iron 430 is ground, after grinding find product surface
0.2 μm of roughness Ra, lapped face micro- can only distinguish processing direction.
Embodiment 2: aqua type lapping liquid is prepared, each raw material weight is as follows: cocoanut fatty acid diethanolamide 40g, ten
Dialkyl benzene sulfonic acids 100g, aluminum stearate 50g, boric acid 5g, deionized water 805g；Preparation steps are as follows:
(1) cocoanut fatty acid diethanolamide and linear alkyl benzene sulfonic acid are mixed；
(2) under 100 DEG C of heating water baths, deionized water is mixed with boric acid solid, prepares boric acid solution；
(3) boric acid solution for obtaining step (2) is added in step (1) prepared mixture；
(4) said mixture matter is sufficiently stirred, adds the sodium hydroxide solution that mass concentration is 30% for Breakup of Liquid Ring
Border is adjusted to 8.00-10.00, places 12 hours in shady place, and after white foam disappearance, aluminum stearate is added thereto；
(5) pH is adjusted to 5.50 using the citric acid solution that mass concentration is 50%；Up to environmentally protective anti-after standing
Scratch aqua type lapping liquid.
The resulting aqua type lapping liquid stability of the present embodiment is strong, is uniformly mixed in 120 hours, no precipitating.By the water
Property lapping liquid mixed with abrasive material according to mass ratio 1:18, brass H65 is ground, after grinding find product surface roughness
0.1 μm of Ra, lapped face trace can only be recognized by lustrous surface.
Embodiment 3: aqua type lapping liquid is prepared, each raw material weight is as follows: cocoanut fatty acid diethanolamide 40g, ten
Dialkyl benzene sulfonic acids 100g, the line borate 50g of oleic acid surface modification, boric acid 5g, deionized water 805g；Preparation steps are as follows:
(1) cocoanut fatty acid diethanolamide and linear alkyl benzene sulfonic acid are mixed；
(2) under 100 DEG C of heating water baths, deionized water is mixed with boric acid solid, prepares boric acid solution；
(3) boric acid solution for obtaining step (2) is added in step (1) prepared mixture；
(4) said mixture matter is sufficiently stirred, adds the sodium hydroxide solution that mass concentration is 30% for Breakup of Liquid Ring
Border is adjusted to 8.00-10.00, places 12 hours in shady place, and after white foam disappearance, oleic acid surface modification is added thereto
Line borate；
(5) pH is adjusted to 5.50 using the citric acid solution that mass concentration is 50%；Up to environmentally protective anti-after standing
Scratch aqua type lapping liquid.
The resulting aqua type lapping liquid stability of the present embodiment is strong, is uniformly mixed in 120 hours, no precipitating.By the water
Property lapping liquid and aluminium oxide ceramics abrasive material mixed according to 1:20 ratio, stainless steel 304 is ground, product is found after grinding
0.2 μm of surface roughness Ra, lapped face micro- can only distinguish processing direction.
Embodiment 4: aqua type lapping liquid is prepared, each raw material weight is as follows: cocoanut fatty acid diethanolamide 10g, ten
Dialkyl benzene sulfonic acids 50g, calcium stearate 5g, 5 grams of aluminum stearate, boric acid 5g, deionized water 925g；Preparation steps are as follows:
(1) cocoanut fatty acid diethanolamide and linear alkyl benzene sulfonic acid are mixed；
(2) under 100 DEG C of heating water baths, deionized water is mixed with boric acid solid, prepares boric acid solution；
(3) boric acid solution for obtaining step (2) is added in step (1) prepared mixture；
(4) said mixture matter is sufficiently stirred, adds the sodium hydroxide solution that mass concentration is 30% for Breakup of Liquid Ring
Border is adjusted to 8.00-10.00, places 12 hours in shady place, and after white foam disappearance, calcium stearate and hard is added thereto
Resin acid aluminium；
(5) pH is adjusted to 5.50 using the citric acid solution that mass concentration is 50%；Up to environmentally protective anti-after standing
Scratch aqua type lapping liquid.
The resulting aqua type lapping liquid stability of the present embodiment is strong, is uniformly mixed in 120 hours, no precipitating.By the water
Property lapping liquid and plastic abrasive according to 1:15 ratio mix, aluminium alloy ZL401 is ground, after grinding find product surface
0.2 μm of roughness Ra, lapped face micro- can only distinguish processing direction.
Comparative example 1: preparing aqua type lapping liquid, and each raw material weight is as follows: cocoanut fatty acid diethanolamide 200g, firmly
Resin acid calcium 10g, boric acid 10g, deionized water 780g；Preparation steps are as follows:
(1) under 100 DEG C of heating water baths, deionized water is mixed with boric acid solid, prepares boric acid solution；
(2) obtained boric acid solution is added in cocoanut fatty acid diethanolamide；
(3) said mixture matter is sufficiently stirred, adds the sodium hydroxide solution that mass concentration is 30% for Breakup of Liquid Ring
Border is adjusted to 8.00-10.00, places 12 hours in shady place, and after white foam disappearance, stearate is added thereto；
(4) pH is adjusted to 5.50 using the citric acid solution that mass concentration is 50%；Up to environmentally protective anti-after standing
Scratch aqua type lapping liquid.
The resulting aqua type lapping liquid stability of the present embodiment is poor, and static 24 lamination as a child occur.This is aqueous
Lapping liquid is mixed with plastic abrasive according to mass ratio 1:20, is ground to stainless iron 430, finds that the surface of product is thick after grinding
6.3 μm of rugosity Ra, the visible cutter trade of lapped face.
(compared with embodiment 1, cocoanut fatty acid diethanolamide is not added) in comparative example 2: preparing aqua type lapping liquid, respectively
Raw material weight is as follows: dodecyl benzene sulfonic acid 200g, calcium stearate 10g, boric acid 10g, deionized water 780g；Preparation steps are such as
Under:
(1) under 100 DEG C of heating water baths, deionized water is mixed with boric acid solid, prepares boric acid solution；
(2) obtained boric acid solution is added in dodecyl benzene sulfonic acid；
(3) said mixture matter is sufficiently stirred, adds the sodium hydroxide solution that mass concentration is 30% for Breakup of Liquid Ring
Border is adjusted to 8.00-10.00, places 12 hours in shady place, and after white foam disappearance, calcium stearate is added thereto；
(4) pH is adjusted to 5.50 using the citric acid solution that mass concentration is 50%；Up to environmentally protective anti-after standing
Scratch aqua type lapping liquid.
The resulting aqua type lapping liquid stability of the present embodiment is poor, and static 6 lamination as a child occur.This aqueous is ground
Grinding fluid is mixed with plastic abrasive according to mass ratio 1:20, is ground to stainless iron 430, and the rough surface of product is found after grinding
3.2 μm of Ra of degree, the micro- visible cutter trade of lapped face.
(compared with embodiment 1, scratching resistant is not added) in comparative example 3: aqua type lapping liquid is prepared, each raw material weight is as follows:
Cocoanut fatty acid diethanolamide 50g, dodecyl benzene sulfonic acid 150g, boric acid 10g, deionized water 790g；Preparation steps are such as
Under:
(1) under 100 DEG C of heating water baths, deionized water is mixed with boric acid solid, prepares boric acid solution；
(2) obtained boric acid solution is added in dodecyl benzene sulfonic acid；
(3) said mixture matter is sufficiently stirred, adds the sodium hydroxide solution that mass concentration is 30% for Breakup of Liquid Ring
Border is adjusted to 8.00-10.00, places 12 hours in shady place；
(4) pH is adjusted to 5.50 using the citric acid solution that mass concentration is 50%；Up to environmentally protective anti-after standing
Scratch aqua type lapping liquid.
The resulting aqua type lapping liquid stability of the present embodiment is strong, is uniformly mixed in 120 hours, no precipitating.By the water
Property lapping liquid mixed with plastic abrasive according to mass ratio 1:20, stainless iron 430 is ground, after grinding find product surface
12.5 μm of roughness Ra, the visible grinding marks of lapped face.
Comparative example 4 (compared with embodiment 1, does not adjust pH): preparing aqua type lapping liquid, each raw material weight is as follows: coconut
Fatty acid oil diglycollic amide 50g, dodecyl benzene sulfonic acid 150g, calcium stearate 10g, boric acid 10g, deionized water 780g；Match
Steps are as follows for system:
(1) cocoanut fatty acid diethanolamide and dodecyl benzene sulfonic acid are mixed；
(2) under 100 DEG C of heating water baths, deionized water is mixed with boric acid solid, prepares boric acid solution；
(3) boric acid solution for obtaining step (2) is added in step (1) prepared mixture, and calcium stearate is added
Enter said mixture；Up to environmentally protective scratch resistance aqua type lapping liquid after standing.
The resulting aqua type lapping liquid of the present embodiment cannot achieve stable homogeneous.The aqueous polishing liquid is pressed with plastic abrasive
It is mixed according to mass ratio 1:20, stainless iron 430 is ground, 3.2 μm of surface roughness Ra of product, grinding are found after grinding
The micro- visible cutter trade in surface.
The method of the present invention that the above embodiments are only used to help understand and its core concept.It should be pointed out that for
For those skilled in the art, without departing from the principle of the present invention, if can also be carried out to the present invention
Dry improvement and modification, these improvement and modification are also fallen into the claims in the present invention protection scope.
Claims (8)
1. a kind of environmentally protective scratch resistance aqua type lapping liquid, which is characterized in that the lapping liquid includes following weight percent
Raw material:
2. a kind of environmentally protective scratch resistance aqua type lapping liquid according to claim 1, which is characterized in that the alkyl two
Glycollic amide is cocoanut fatty acid diethanolamide.
3. a kind of environmentally protective scratch resistance aqua type lapping liquid according to claim 1, which is characterized in that the straight chain alkane
Base benzene sulfonic acid is dodecyl benzene sulfonic acid.
4. a kind of environmentally protective scratch resistance aqua type lapping liquid according to claim 1, which is characterized in that the scratch resistance
Agent is one or more of calcium stearate, aluminum stearate, the boric acid of oleic acid surface modification.
5. a kind of environmentally protective scratch resistance aqua type lapping liquid according to claim 1, which is characterized in that addition quality is dense
The citric acid solution that the sodium hydroxide solution and/or mass concentration that degree is 30% are 50% is adjusted the pH of lapping liquid.
6. a kind of environmentally protective scratch resistance aqua type lapping liquid according to claim 1, which is characterized in that the lapping liquid
PH=5.5.
7. a kind of environmentally protective scratch resistance aqua type lapping liquid according to claim 1, which is characterized in that the lapping liquid
Further comprise the raw material of following weight percent:
8. a kind of preparation method of environmentally protective scratch resistance aqua type lapping liquid, which includes the original of following weight percent
Material:
It is prepared according to the following steps to obtain:
(1) alkyl diethanolamide and linear alkyl benzene sulfonic acid are mixed；
(2) under 100 DEG C of heating water baths, deionized water is mixed with boric acid solid, prepares boric acid solution；
(3) boric acid solution for obtaining step (2) is added in step (1) prepared mixture；
(4) said mixture matter is sufficiently stirred, adds the sodium hydroxide solution that mass concentration is 30% for liquid environment tune
Section is placed 12 hours in shady place to 8.00-10.00, after white foam disappearance, scratching resistant is added thereto；
(5) pH is adjusted to 5.50 using the citric acid solution that mass concentration is 50%；Up to environmentally protective scratch resistance after standing
Aqua type lapping liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810707632.XA CN109096925A (en) | 2018-07-02 | 2018-07-02 | A kind of environmentally protective scratch resistance aqua type lapping liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810707632.XA CN109096925A (en) | 2018-07-02 | 2018-07-02 | A kind of environmentally protective scratch resistance aqua type lapping liquid and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109096925A true CN109096925A (en) | 2018-12-28 |
Family
ID=64845363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810707632.XA Pending CN109096925A (en) | 2018-07-02 | 2018-07-02 | A kind of environmentally protective scratch resistance aqua type lapping liquid and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109096925A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110804418A (en) * | 2019-09-18 | 2020-02-18 | 湖州湖磨陶瓷研磨液有限公司 | Grinding paste suitable for plant type polishing block and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10130633A (en) * | 1996-10-28 | 1998-05-19 | Takehara:Kk | Polisher for stainless steel |
| CN102108321A (en) * | 2009-12-25 | 2011-06-29 | 比亚迪股份有限公司 | Metal deoiling agent and deoiling method thereof |
| CN103590044A (en) * | 2013-11-06 | 2014-02-19 | 天津圳鹏清洗技术开发有限公司 | Metal polishing agent and preparation method thereof |
| CN104004574A (en) * | 2014-04-28 | 2014-08-27 | 浙江钱锦气雾剂制品有限公司 | Antirust lubricant |
-
2018
- 2018-07-02 CN CN201810707632.XA patent/CN109096925A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10130633A (en) * | 1996-10-28 | 1998-05-19 | Takehara:Kk | Polisher for stainless steel |
| CN102108321A (en) * | 2009-12-25 | 2011-06-29 | 比亚迪股份有限公司 | Metal deoiling agent and deoiling method thereof |
| CN103590044A (en) * | 2013-11-06 | 2014-02-19 | 天津圳鹏清洗技术开发有限公司 | Metal polishing agent and preparation method thereof |
| CN104004574A (en) * | 2014-04-28 | 2014-08-27 | 浙江钱锦气雾剂制品有限公司 | Antirust lubricant |
Non-Patent Citations (2)
| Title |
|---|
| 姚迎等编著: "《化学知识辞典》", 30 September 1995 * |
| 陈忠民编著: "《机修工一本通》", 30 September 2016 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110804418A (en) * | 2019-09-18 | 2020-02-18 | 湖州湖磨陶瓷研磨液有限公司 | Grinding paste suitable for plant type polishing block and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103590044B (en) | A kind of metal polish | |
| CN102212412B (en) | Water-based cutting fluid with grinding materials treated by surfactant and preparation method thereof | |
| CN102311718B (en) | Aqueous grinding fluid applied to super precision grinding of hard and brittle materials and application method thereof | |
| CN104403774A (en) | Water-based cutting fluid and preparation method thereof | |
| CN105001964A (en) | Microemulsified cutting fluid | |
| CN101870909A (en) | Magnesium alloy cutting liquid | |
| CN100526513C (en) | Wax removal water for cleaning automobile aluminum wheel hub and preparing method thereof | |
| CN106590882A (en) | Emulsion cutting fluid | |
| CN103937414A (en) | Fine polishing liquid for hard disk substrate of computer | |
| CN105296131B (en) | It is a kind of without chlorine, sulphur, the high extreme pressure fully synthetic cutting fluid of phosphorus and preparation method thereof | |
| CN108998183B (en) | Smart phone frame synthetic type high-light cutting fluid and preparation method thereof | |
| CN105733772B (en) | Plant oil base synthetic fat type cutting fluid and preparation method thereof | |
| CN109096925A (en) | A kind of environmentally protective scratch resistance aqua type lapping liquid and preparation method thereof | |
| CN101285204A (en) | Spent meal for treating surface of copper and copper alloy and method for preparing same | |
| CN105001966A (en) | Cutting fluid for aluminum and aluminum alloy | |
| CN106894023B (en) | A kind of aluminium alloy corrosion-inhibiting composition and preparation method thereof | |
| CN108265285B (en) | Neutral copper passivator | |
| CN101747864B (en) | Method for preparing and using emulsion type lapping liquid for steel ball grinding | |
| CN106894030B (en) | Metal conditioner | |
| CN112481009A (en) | Micro-emulsified cutting fluid for processing copper, aluminum and iron materials and preparation method thereof | |
| CN105199825A (en) | Steel ball circulating liquid | |
| CN104357204A (en) | Environment-friendly water-based metal working fluid and preparation method thereof | |
| CN105462503A (en) | Nano stainless-steel precise mechanical polishing solution and preparation method thereof | |
| CN1746282A (en) | Environmental-protective grinding fluid | |
| CN110804484A (en) | Environment-friendly carborundum wire cutting liquid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181228 |
|
| RJ01 | Rejection of invention patent application after publication |