CN105733772B - Plant oil base synthetic fat type cutting fluid and preparation method thereof - Google Patents
Plant oil base synthetic fat type cutting fluid and preparation method thereof Download PDFInfo
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- CN105733772B CN105733772B CN201610133947.9A CN201610133947A CN105733772B CN 105733772 B CN105733772 B CN 105733772B CN 201610133947 A CN201610133947 A CN 201610133947A CN 105733772 B CN105733772 B CN 105733772B
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- cutting fluid
- mass ratio
- type cutting
- mixed solution
- oil base
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- 239000002173 cutting fluid Substances 0.000 title claims abstract description 51
- 239000010773 plant oil Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 18
- 239000008158 vegetable oil Substances 0.000 claims abstract description 18
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 16
- 239000000314 lubricant Substances 0.000 claims abstract description 14
- 239000007866 anti-wear additive Substances 0.000 claims abstract description 13
- 238000005260 corrosion Methods 0.000 claims abstract description 11
- 230000007797 corrosion Effects 0.000 claims abstract description 11
- 239000002131 composite material Substances 0.000 claims abstract description 8
- 239000011259 mixed solution Substances 0.000 claims description 25
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims description 17
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 16
- 239000004327 boric acid Substances 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 12
- 229920000570 polyether Polymers 0.000 claims description 11
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 9
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 9
- 229940102253 isopropanolamine Drugs 0.000 claims description 9
- 229920001223 polyethylene glycol Polymers 0.000 claims description 9
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 claims description 9
- 229960003656 ricinoleic acid Drugs 0.000 claims description 9
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 9
- 238000007385 chemical modification Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 229960002645 boric acid Drugs 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 238000004090 dissolution Methods 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 238000003756 stirring Methods 0.000 claims 2
- 238000012545 processing Methods 0.000 abstract description 11
- 239000007788 liquid Substances 0.000 abstract description 10
- 239000002699 waste material Substances 0.000 abstract description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000428 dust Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 239000003921 oil Substances 0.000 abstract description 4
- 235000019198 oils Nutrition 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract description 3
- 229910001018 Cast iron Inorganic materials 0.000 abstract description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 2
- 229910000831 Steel Inorganic materials 0.000 abstract description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004411 aluminium Substances 0.000 abstract description 2
- 229910052782 aluminium Inorganic materials 0.000 abstract description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 2
- 239000010949 copper Substances 0.000 abstract description 2
- 229910052802 copper Inorganic materials 0.000 abstract description 2
- 238000007667 floating Methods 0.000 abstract description 2
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 239000010959 steel Substances 0.000 abstract description 2
- 239000010936 titanium Substances 0.000 abstract description 2
- 229910052719 titanium Inorganic materials 0.000 abstract description 2
- 238000005520 cutting process Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 238000003754 machining Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- -1 alcohol Amine Chemical class 0.000 description 2
- AGLSQWBSHDEAHB-UHFFFAOYSA-N azane;boric acid Chemical compound N.OB(O)O AGLSQWBSHDEAHB-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 230000001934 delay Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000002070 germicidal effect Effects 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 235000010288 sodium nitrite Nutrition 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 241001074085 Scophthalmus aquosus Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000013556 antirust agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
Abstract
The invention discloses a vegetable oil bases to synthesize epoxy-type cutting fluid.The plant oil base synthetic fat type cutting fluid composite weight percent composition is as follows: extreme pressure agent 8-18%, antiwear additive 6-15%, corrosion inhibiter 8-20%, lubricant 5-15%, defoaming agent 0.5-1%, water 30-55%.Plant oil base synthetic fat type cutting fluid provided by the present invention is suitable for the processing of the multiple materials such as steel, cast iron, titanium, aluminium, copper, with the floating dirt of excellent oil slick, heavy iron filings effect, can rapid subsidence separate abrasive dust, keep the cleaning of processing environment, workpiece surface quality is improved, extends the service life of cutting fluid, reduces the discharge of waste liquid.
Description
Technical field
The present invention relates to a kind of machining of metals liquid, in particular to a vegetable oil base synthesizes epoxy-type cutting fluid and its system
Preparation Method.
Background technique
The end of the 20th century is estimated according to domestic and international expert, and cutting fluid processing still accounts for 90% or more of amount of machining, and cutting fluid adds
Work develops towards high speed, strength and high-precision direction.The advanced technologies such as numerically-controlled machine tool, machining center and flexible manufacturing system are gradually
Deeply application.With the development of the technologies such as new material science, some difficult-to-machine materials using increasing, and with the modern times
Change the attention to environmental protection of development and people of Machining Technology for Cutting, this just proposes new higher want to cutting fluid technology
It asks.Therefore research Novel cutting liquid, to improve work pieces process efficiency and quality, tool life reduces processing cost.
Environment is not polluted simultaneously, is one of manufacturing vital task.
Water-base cutting fluid used in country's numerically-controlled machine tool is mainly emulsion, synthetic cutting fluid, microemulsified cutting at present
Liquid, being added to mainly in emulsion cutting fluid, micro-emulsion cutting fluid has sulphur, phosphorus, chlorine and sodium nitrite etc., such cutting fluid uses the longevity
Order short, the discharge of waste liquid causes greatly to pollute to environment.Synthetic cutting fluid component is single, and poor lubricity, antirust is bad, to enterprise
Industry causes economic loss.The appearance of Law on Environmental Protection, so that the equipment of cutting fluid, the total costs such as management and liquid waste processing
Rise.Thus directly promote the rising of production and processing expense.Therefore there is an urgent need to research and develop a kind of function admirable and nontoxic
Novel environment-friendly water-base cutting fluid, to meet the needs of modern cutting technology.
Summary of the invention
In order to solve the above technical problem, the present invention provides vegetable oil base synthesis epoxy-type cutting fluid and its preparation sides
Method.
One vegetable oil base synthesizes epoxy-type cutting fluid, the plant oil base synthetic fat type cutting fluid composite weight percent
It forms as follows: extreme pressure agent 8-18%, antiwear additive 6-15%, corrosion inhibiter 8-20%, lubricant 5-15%, defoaming agent 0.5-1%, water
30-55%.
Preferably, the extreme pressure agent by ricinoleic acid, isopropanolamine, boric acid in mass ratio are as follows: 5:3:2.
Preferably, the antiwear additive is 3:1 by hydramine, boric acid in mass ratio.
Preferably, the corrosion inhibiter is 1:3:1:2 by binary acid, hydramine, polyethylene glycol, borate by mass percentage.
Preferably, the lubricant is 2:1 by the vegetable oil of polyethers, chemical modification by mass percentage.
Preferably, the defoaming agent is polyethers defoaming agent.
Preferably, the water is deionized water.
The preparation method of one vegetable oil base synthesis epoxy-type cutting fluid, including the following steps:
(1), 30 DEG C -90 DEG C are heated water to；
(2), ricinoleic acid, isopropanolamine, boric acid are synthesized by above-mentioned mass ratio in 130 DEG C of pyroreactions, water is added afterwards
In be uniformly mixing to obtain mixed solution A；
(3), hydramine, boric acid are synthesized by above-mentioned mass ratio in 160 DEG C of pyroreactions, rear be added in mixed solution A is stirred
Uniformly obtain mixed solution B；
(4), binary acid, hydramine, polyethylene glycol, borate are synthesized by above-mentioned mass ratio in 130 DEG C of pyroreactions, it is rear to add
Enter in mixed solution B and is uniformly mixing to obtain mixed solution C；
(5), the vegetable oil of polyethers, chemical modification is synthesized by above-mentioned mass ratio in 130 DEG C of pyroreactions, it is rear that mixing is added
Mixed solution D is uniformly mixing to obtain in solution C, rear be added in mixed solution C is uniformly mixing to obtain mixed solution D；
(6), mixed solution D is added by above-mentioned mass ratio in defoaming agent, is sufficiently stirred and after completely dissolution will to above-mentioned substance
PH value is adjusted to 8.5-9.5 and obtains plant oil base synthetic fat type cutting fluid.
Compared with the prior art, the present invention has the following advantages and the utility model has the advantages that
1) it is a variety of to be suitable for (steel, cast iron, titanium, aluminium, copper) etc. for plant oil base synthetic fat type cutting fluid provided by the present invention
The processing of material.
2) plant oil base synthetic fat type cutting fluid provided by the present invention has the floating dirt of excellent oil slick, heavy iron filings (powder) effect
Fruit, can rapid subsidence separate abrasive dust, keep the cleaning of processing environment, improve workpiece surface quality, extend the use of cutting fluid
Service life reduces the discharge of waste liquid.
3) plant oil base synthetic fat type cutting fluid provided by the present invention is able to maintain 1- in the case where not adding of germicide
It never degenerates within 2 years, not smelly, tool life.
4) plant oil base synthetic fat type cutting fluid of the invention is free of sodium nitrite, and phosphorus, sulphur, chlorine, phenol etc. are to human body and ring
Border poisonous and harmful substances, thus it is environmentally protective.
5) plant oil base synthetic fat type cuts concentrated liquor appearance: for yellow transparent liquid, dilution is transparency liquid.Skill
Art index: pH value 8.5-9: aluminum alloy cutting fluid pH value 7.5-8.5: antirust grade A: rust prevention during manufacture 8-20 days.Execution standard:
GB/T6144-2010。
6) cutting fluid of the present invention has excellent cooling and good greasy property, without compositions such as mineral oil.
7) there is good anticorrosive property and rust-preventing characteristic, it is few to generate work waste liquid when use, and it is easy to handle, reduce environment dirt
Dye.
Specific embodiment
Technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is only
A part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, ordinary skill people
Member's all other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.
The present invention discloses vegetable oil base synthesis epoxy-type cutting fluid, the plant oil base synthetic fat type cutting fluid composite
Weight percent composition is as follows: extreme pressure agent 8-18%, antiwear additive 6-15%, corrosion inhibiter 8-20%, lubricant 5-15%, defoaming agent
0.5-1%, water 30-55%.
Preferably, the extreme pressure agent by ricinoleic acid, isopropanolamine, boric acid in mass ratio are as follows: 5:3:2；The antiwear additive
It is in mass ratio 3:1 by hydramine, boric acid；The corrosion inhibiter by binary acid, hydramine, polyethylene glycol, borate by mass percentage
For 1:3:1:2；The lubricant polyethers, chemical modification vegetable oil be by mass percentage 2:1；The defoaming agent is polyethers
Defoaming agent；The water is deionized water.
Embodiment one:
The plant oil base synthetic fat type cutting fluid composite mass fraction composition is as follows: extreme pressure agent 10, delays antiwear additive 12
Lose agent 14, lubricant 15, defoaming agent 0.5, water 48.5.
Wherein, the mass fraction composition of the extreme pressure agent is as follows: ricinoleic acid 5, isopropanolamine 3, boric acid press 2；It is described anti-
The mass fraction composition of grinding agent is as follows: hydramine 9, amine borate 3；The mass fraction composition of the corrosion inhibiter is as follows: binary acid 2, alcohol
Amine 6, polyethylene glycol 2, borate 5；The mass fraction composition of the lubricant is as follows: the vegetable oil 5 of polyethers 10, chemical modification.
Embodiment two:
The plant oil base synthetic fat type cutting fluid composite mass fraction composition is as follows: extreme pressure agent 17, delays antiwear additive 15
Lose agent 7, lubricant 12, defoaming agent 1, water 48.
Wherein, the mass fraction composition of the extreme pressure agent is as follows: ricinoleic acid 8.5, isopropanolamine 5.1, boric acid press 3.4；
The mass fraction composition of the antiwear additive is as follows: hydramine 11.25, boric acid press 3.75；The mass fraction composition of the corrosion inhibiter is such as
Under: binary acid 1, hydramine 3, polyethylene glycol 1, borate 2；The mass fraction composition of the lubricant is as follows: polyethers 8, chemistry change
The vegetable oil 4 of property.
Embodiment three:
The plant oil base synthetic fat type cutting fluid composite mass fraction composition is as follows: extreme pressure agent 8, antiwear additive 8, inhibition
Agent 20, lubricant 8, defoaming agent 1, water 55.
Wherein, the mass fraction composition of the extreme pressure agent is as follows: ricinoleic acid 4, isopropanolamine 2.4, boric acid press 1.6；Institute
The mass fraction composition for stating antiwear additive is as follows: hydramine 6, amine borate 2；The mass fraction composition of the corrosion inhibiter is as follows: binary acid
2.86, hydramine 8.58, polyethylene glycol 2.86, borate 5.72；The mass fraction composition of the lubricant is as follows: polyethers 5.33,
The vegetable oil 2.67 of chemical modification.
The preparation method of vegetable oil base synthesis epoxy-type cutting fluid disclosed by the invention, including the following steps:
(1), 30 DEG C -90 DEG C are heated water to；
(2), ricinoleic acid, isopropanolamine, boric acid are synthesized by above-mentioned mass ratio in 130 DEG C of pyroreactions, water is added afterwards
In be uniformly mixing to obtain mixed solution A；
(3), hydramine, boric acid are synthesized by above-mentioned mass ratio in 160 DEG C of pyroreactions, rear be added in mixed solution A is stirred
Uniformly obtain mixed solution B；
(4), binary acid, hydramine, polyethylene glycol, borate are synthesized by above-mentioned mass ratio in 130 DEG C of pyroreactions, it is rear to add
Enter in mixed solution B and is uniformly mixing to obtain mixed solution C；
(5), the vegetable oil of polyethers, chemical modification is synthesized by above-mentioned mass ratio in 130 DEG C of pyroreactions, it is rear that mixing is added
Mixed solution D is uniformly mixing to obtain in solution C, rear be added in mixed solution C is uniformly mixing to obtain mixed solution D；
(6), mixed solution D is added by above-mentioned mass ratio in defoaming agent, is sufficiently stirred and after completely dissolution will to above-mentioned substance
PH value is adjusted to 8.5-9.5 and obtains plant oil base synthetic fat type cutting fluid.
Using extreme pressure agent, antiwear additive, corrosion inhibiter, lubricant compound synergic, achieve the purpose that improve lubrication extreme pressure property,
And sufficiently supplementing water-soluble synthetic ester on this basis improves lubrication extreme pressure property further, utilizes borides substance
Antibacterial feature, so that cutting fluid is had the long-life in the case where not adding of germicide.Using antirust agent, the composite synergistic of sustained release agent, make
The rustless property of cutting fluid enhances, and is able to satisfy the processing request of different metal materials.Under the action of selected surfactant, have
The elimination abrasive dust of effect generated electrostatic in grinding process, makes tiny abrasive dust that can quickly sink under the gravity of itself
Drop separation, extends the service life of cutting fluid, keeps the cleaning of processing environment, reduce the discharge of waste liquid.
Above-mentioned plant oil base synthetic fat type cutting fluid is made into 5% aqueous solution, be used for ferrous metal, non-ferrous metal (vehicle,
Milling, boring, brill, mill) etc..The cutting fluid is nontoxic, has no irritating odor, is hard water resistance, resisting miscellaneous oil, and cutting fluid is not in use process
It is rotten, non-maintaining, low emission, it is only necessary to which timing supplement cutting fluid can meet the needs of machining accuracy, be a kind of ideal
Cutting oil substitute.
Plant oil base synthetic fat type cutting fluid provided by the invention and preparation method thereof is biodegradable, and operating environment is clear
Clean, free from extraneous odour, without any side effects, pollution-free, non-maintaining, low emission only need to add, and 1-2 is just discharged once, can improve
Metal parts machining accuracy meets the plant oil base cutting fluid of every cutting grinding process requirement simultaneously.
Simultaneously use vegetable oil chemical modifying process, solve current cutting fluid stability is poor, rust-preventing characteristic is poor, lubricity not
Foot, extreme pressure agent environmental issue, performance can be maintained like in soft water and hard water, provide hard alloy epoch high cutting speed and
Good lubricity and cooling required by big charge ratio, can tool life, in the alternative pure oil of certain occasions
Processing.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair
Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (1)
1. a vegetable oil base synthesizes epoxy-type cutting fluid, which is characterized in that the plant oil base synthetic fat type cutting fluid composite
Weight percent composition is as follows: extreme pressure agent 8-18%, antiwear additive 6-15%, corrosion inhibiter 8-20%, lubricant 5-15%, defoaming agent
0.5-1%, water 30-55%, each the sum of weight percent that forms is 100%；The extreme pressure agent by ricinoleic acid, isopropanolamine,
Boric acid is in mass ratio are as follows: 5:3:2 is prepared；The corrosion inhibiter by binary acid, hydramine, polyethylene glycol, borate in mass ratio
It is prepared for 1:3:1:2, the antiwear additive is prepared in mass ratio for 3:1 by hydramine, boric acid, and the lubricant is by gathering
Ether, chemical modification vegetable oil be prepared in mass ratio for 2:1, the defoaming agent be polyethers defoaming agent, the water be go
Ionized water；The plant oil base synthetic fat type cutting fluid method is prepared to include the following steps:
(1) 30 DEG C -90 DEG C are heated water to；
(2) ricinoleic acid, isopropanolamine, boric acid are synthesized by above-mentioned mass ratio in 130 DEG C of pyroreactions, after be added to the water stirring
Uniformly obtain mixed solution A；
(3) hydramine, boric acid are synthesized by above-mentioned mass ratio in 160 DEG C of pyroreactions, rear be added in mixed solution A stirs evenly
To mixed solution B；
(4) binary acid, hydramine, polyethylene glycol, borate are synthesized by above-mentioned mass ratio in 130 DEG C of pyroreactions, rear be added is mixed
It closes in solution B and is uniformly mixing to obtain mixed solution C；
(5) vegetable oil of polyethers, chemical modification is synthesized by above-mentioned mass ratio in 130 DEG C of pyroreactions, mixed solution C is added afterwards
In be uniformly mixing to obtain mixed solution D；
(6) mixed solution D is added by above-mentioned mass ratio in defoaming agent, be sufficiently stirred to above-mentioned substance after completely dissolution by pH value
It is adjusted to 8.5-9.5 and obtains plant oil base synthetic fat type cutting fluid.
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| CN108690699A (en) * | 2017-04-06 | 2018-10-23 | 河北九五新材料科技有限公司 | A kind of preparation method of water-base cutting fluid |
| CN108559600B (en) * | 2018-01-03 | 2021-04-20 | 上海丽卡环保技术有限公司 | Emulsion for fine processing of steel workpiece, preparation method and post-treatment process thereof |
| CN108048194B (en) * | 2018-01-03 | 2021-02-09 | 平湖市立库德润滑油有限公司 | Emulsion for fine processing of steel workpiece with water solution hardness of more than 200ppm, preparation method and post-treatment process thereof |
| CN112852530A (en) * | 2021-01-25 | 2021-05-28 | 广东德帕化学有限公司 | Special high-precision hard alloy cutting oil for core-moving machine |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101870909A (en) * | 2009-04-24 | 2010-10-27 | 东莞太平洋博高润滑油有限公司 | Magnesium alloy cutting liquid |
| CN103351927A (en) * | 2013-08-05 | 2013-10-16 | 山东天泰钢塑有限公司 | Multifunctional fully-synthetic cutting fluid and preparation method thereof |
| CN104194907A (en) * | 2014-09-01 | 2014-12-10 | 中钢集团郑州金属制品研究院有限公司 | Water-based cutting fluid for metal processing and preparation method of water-based cutting fluid |
| WO2015177150A1 (en) * | 2014-05-22 | 2015-11-26 | Basf Se | Lubricant compositions containing beta-glucans |
| CN105154198A (en) * | 2015-08-26 | 2015-12-16 | 开封市奥科宝特种油剂有限公司 | Novel biodegradable vegetable-oil-based water-soluble cutting fluid |
-
2016
- 2016-03-09 CN CN201610133947.9A patent/CN105733772B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101870909A (en) * | 2009-04-24 | 2010-10-27 | 东莞太平洋博高润滑油有限公司 | Magnesium alloy cutting liquid |
| CN103351927A (en) * | 2013-08-05 | 2013-10-16 | 山东天泰钢塑有限公司 | Multifunctional fully-synthetic cutting fluid and preparation method thereof |
| WO2015177150A1 (en) * | 2014-05-22 | 2015-11-26 | Basf Se | Lubricant compositions containing beta-glucans |
| CN104194907A (en) * | 2014-09-01 | 2014-12-10 | 中钢集团郑州金属制品研究院有限公司 | Water-based cutting fluid for metal processing and preparation method of water-based cutting fluid |
| CN105154198A (en) * | 2015-08-26 | 2015-12-16 | 开封市奥科宝特种油剂有限公司 | Novel biodegradable vegetable-oil-based water-soluble cutting fluid |
Non-Patent Citations (1)
| Title |
|---|
| 聚乙二醇硼酸酯防锈润滑剂的合成与性能;马其坤等;《上海化工》;20090228;第34卷(第2期);第15-17页 * |
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