CN108277095A - A kind of cleaning treatment technique of glass - Google Patents

A kind of cleaning treatment technique of glass Download PDF

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Publication number
CN108277095A
CN108277095A CN201711491855.9A CN201711491855A CN108277095A CN 108277095 A CN108277095 A CN 108277095A CN 201711491855 A CN201711491855 A CN 201711491855A CN 108277095 A CN108277095 A CN 108277095A
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CN
China
Prior art keywords
cleaning treatment
glass
parts
cleaning
spare
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Pending
Application number
CN201711491855.9A
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Chinese (zh)
Inventor
乔业全
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ANHUI DU HI-TECH GLASS Co Ltd
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ANHUI DU HI-TECH GLASS Co Ltd
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Priority to CN201711491855.9A priority Critical patent/CN108277095A/en
Publication of CN108277095A publication Critical patent/CN108277095A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B11/00Cleaning flexible or delicate articles by methods or apparatus specially adapted thereto
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/08Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • B08B3/12Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration by sonic or ultrasonic vibrations
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • C11D3/128Aluminium silicates, e.g. zeolites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D2111/18
    • C11D2111/44
    • C11D2111/46

Abstract

The invention discloses a kind of cleaning treatment techniques of glass, include the following steps:(1)The preparation of cleaning treatment liquid,(2)Glass pretreatment,(3)Cleaning treatment.Cleaning treatment method of the present invention effectively improves the cleaning performance to glass, has the advantages that cleaning efficiency is high, effect is good, ensure that the performance of glass, great application value.

Description

A kind of cleaning treatment technique of glass
Technical field
The invention belongs to cleaning glass processing technology fields, and in particular to a kind of cleaning treatment technique of glass.
Background technology
Glass processing and using when be susceptible to dust, spot, oil stain the problems such as, how to glass carry out cleaning-nursing The problem of concern being had increasing need for as people.General method is to be rinsed using clear water, but this mode can cause largely Water resource waste, and clean it is ineffective.Thus more and more glass cleaners come into being.Glass cleaner Main component is surfactant, and how Surfactant is arranged in pairs or groups and added which kind of remaining auxiliary component becomes The key factor of glass cleaner washing effect.The cleaning performance of most glass cleaners is still undesirable currently on the market, decontamination It is less efficient.In addition, existing cleaning method is simple, it is unable to give full play the effect of detergent, and then is affected Dirty effect.
Invention content
The purpose of the present invention is for existing problem, provide a kind of cleaning treatment technique of glass.
The present invention is achieved by the following technical solutions:
A kind of cleaning treatment technique of glass, includes the following steps:
(1)Cleaning treatment liquid is prepared:
A. it is spare to weigh following substance by corresponding parts by weight:13 ~ 16 parts of lauryl potassium sulfates, 6 ~ 9 parts of fatty alcohol polyoxyethylene ether, 5 ~ 8 parts of calgons, 4 ~ 7 parts of neopelexes, 3 ~ 6 parts of polyethenoxy alkanolamides, 2 ~ 4 parts of modified montmorillonoids Powder, 160 ~ 180 parts of water;
B. all substances that a is weighed will be operated to be put into blender jointly, at 2400 ~ 2600 revs/min of rotating speed stirring Reason 30 ~ 35min after take out cleaning treatment liquid is spare;
(2)Glass pre-processes:
With clear water to glass sparge one time after, then put it into and carry out microwave treatment in microwave treatment instrument, taken out after 15 ~ 20s It is spare;
(3)Cleaning treatment:
By step(2)Treated, and glass is immersed in step(1)It starts the cleaning processing in the cleaning treatment liquid of gained, during which carries out Ultrasonic irradiation is handled, dry after being taken out after 20 ~ 25min.
Further, step(1)The preparation method of modified montmorillonoid powder described in operation a includes the following steps:
1)Montmorillonite powder is first put into 4 ~ 6min of immersion treatment in acid solution, place into after the completion immersion treatment 5 in lye ~ 7min, taking-up is spare after being rinsed one time with deionized water after the completion;
2)By step 1)Treated, and montmorillonite powder is put into progress calcination processing in calcining furnace, is taken out after 1 ~ 1.5h spare;
3)By step 2)Treated, and montmorillonite powder is put into progress radiation treatment in ultraviolet irradiation instrument, is taken after 18 ~ 22min Go out.
Further, step 1)Described in acid solution be mass fraction be 7 ~ 9% phosphoric acid solution;The lye is matter Measure the sodium hydroxide solution that score is 5 ~ 7%.
Further, step 2)Described in calcination processing when control calcining furnace in temperature be 780 ~ 820 DEG C.
Further, step 3)Described in the power of ultraviolet irradiation processing be 680 ~ 730W, the wavelength of ultraviolet light is 290~310nm。
Further, step(2)Described in microwave treatment power be 300 ~ 400W.
Further, step(3)Described in ultrasonic wave frequency be 120 ~ 140kHz.
The present invention has carried out special Optimal improvements to the cleaning treatment technique of glass and has handled, wherein first having prepared a kind of clear Wash treatment fluid, wherein the lauryl potassium sulfate added, fatty alcohol polyoxyethylene ether, calgon, neopelex, Polyethenoxy alkanolamide ingredient coordinates jointly, and the removal effect of most of dirts has been effectively ensured, in order to further enhance place Effect is managed, and is added to modified montmorillonoid meal component, is using montmorillonite as matrix, by soda acid immersion, calcination processing, ultraviolet Line radiation treatment is modified, has prodigious specific surface area and very strong adsorption capacity, can be inhaled to dirts such as dust, graininess It is attached, the efficiency and effect of its removal are further improved, pretreatment operation has been carried out before handling glass cleaning, has utilized microwave Processing reduces the adhesion strength between dirt and glass, finally aid in treatment is carried out using ultrasonic wave in cleaning treatment, into one Step improves removal effect of the cleaning treatment liquid to dirt, has given full play to the use quality of cleaning treatment liquid.
The present invention has the following advantages compared with prior art:
Cleaning treatment method of the present invention effectively improves the cleaning performance to glass, good excellent of, effect high with cleaning efficiency Point ensure that the performance of glass, great application value.
Specific implementation mode
Embodiment 1
A kind of cleaning treatment technique of glass, includes the following steps:
(1)Cleaning treatment liquid is prepared:
A. it is spare to weigh following substance by corresponding parts by weight:13 parts of lauryl potassium sulfates, 6 parts of fatty alcohol polyoxyethylene ether, 5 part six Sodium metaphosphate, 4 parts of neopelexes, 3 parts of polyethenoxy alkanolamides, 2 parts of modified montmorillonoid powder, 160 parts of water;
B. all substances that a is weighed will be operated to be put into blender jointly, with 2400 revs/min of rotating speed stir process Taken out after 30min cleaning treatment liquid is spare;
(2)Glass pre-processes:
With clear water to glass sparge one time after, then put it into and carry out microwave treatment in microwave treatment instrument, taken out after 15s standby With;
(3)Cleaning treatment:
By step(2)Treated, and glass is immersed in step(1)It starts the cleaning processing in the cleaning treatment liquid of gained, during which carries out Ultrasonic irradiation is handled, dry after being taken out after 20min.
Further, step(1)The preparation method of modified montmorillonoid powder described in operation a includes the following steps:
1)Montmorillonite powder is first put into immersion treatment 4min in acid solution, places into immersion treatment 5min in lye after the completion, Taking-up is spare after being rinsed one time with deionized water after the completion;
2)By step 1)Treated, and montmorillonite powder is put into progress calcination processing in calcining furnace, is taken out after 1h spare;
3)By step 2)Treated, and montmorillonite powder is put into progress radiation treatment in ultraviolet irradiation instrument, is taken out after 18min .
Further, step 1)Described in acid solution be mass fraction be 7% phosphoric acid solution;The lye is quality The sodium hydroxide solution that score is 5%.
Further, step 2)Described in calcination processing when control calcining furnace in temperature be 780 DEG C.
Further, step 3)Described in the power of ultraviolet irradiation processing be 680W, the wavelength of ultraviolet light is 290 ~ 295nm。
Further, step(2)Described in microwave treatment power be 300W.
Further, step(3)Described in ultrasonic wave frequency be 120kHz.
Embodiment 2
A kind of cleaning treatment technique of glass, includes the following steps:
(1)Cleaning treatment liquid is prepared:
A. it is spare to weigh following substance by corresponding parts by weight:15 parts of lauryl potassium sulfates, 8 parts of fatty alcohol polyoxyethylene ether, 7 part six Sodium metaphosphate, 6 parts of neopelexes, 5 parts of polyethenoxy alkanolamides, 3 parts of modified montmorillonoid powder, 170 parts of water;
B. all substances that a is weighed will be operated to be put into blender jointly, with 2500 revs/min of rotating speed stir process Taken out after 33min cleaning treatment liquid is spare;
(2)Glass pre-processes:
With clear water to glass sparge one time after, then put it into and carry out microwave treatment in microwave treatment instrument, taken out after 18s standby With;
(3)Cleaning treatment:
By step(2)Treated, and glass is immersed in step(1)It starts the cleaning processing in the cleaning treatment liquid of gained, during which carries out Ultrasonic irradiation is handled, dry after being taken out after 23min.
Further, step(1)The preparation method of modified montmorillonoid powder described in operation a includes the following steps:
1)Montmorillonite powder is first put into immersion treatment 5min in acid solution, places into immersion treatment 6min in lye after the completion, Taking-up is spare after being rinsed one time with deionized water after the completion;
2)By step 1)Treated, and montmorillonite powder is put into progress calcination processing in calcining furnace, is taken out after 1.2h spare;
3)By step 2)Treated, and montmorillonite powder is put into progress radiation treatment in ultraviolet irradiation instrument, is taken out after 20min .
Further, step 1)Described in acid solution be mass fraction be 8% phosphoric acid solution;The lye is quality The sodium hydroxide solution that score is 6%.
Further, step 2)Described in calcination processing when control calcining furnace in temperature be 800 DEG C.
Further, step 3)Described in the power of ultraviolet irradiation processing be 700W, the wavelength of ultraviolet light is 295 ~ 300nm。
Further, step(2)Described in microwave treatment power be 350W.
Further, step(3)Described in ultrasonic wave frequency be 130kHz.
Embodiment 3
A kind of cleaning treatment technique of glass, includes the following steps:
(1)Cleaning treatment liquid is prepared:
A. it is spare to weigh following substance by corresponding parts by weight:16 parts of lauryl potassium sulfates, 9 parts of fatty alcohol polyoxyethylene ether, 8 part six Sodium metaphosphate, 7 parts of neopelexes, 6 parts of polyethenoxy alkanolamides, 4 parts of modified montmorillonoid powder, 180 parts of water;
B. all substances that a is weighed will be operated to be put into blender jointly, with 2600 revs/min of rotating speed stir process Taken out after 35min cleaning treatment liquid is spare;
(2)Glass pre-processes:
With clear water to glass sparge one time after, then put it into and carry out microwave treatment in microwave treatment instrument, taken out after 20s standby With;
(3)Cleaning treatment:
By step(2)Treated, and glass is immersed in step(1)It starts the cleaning processing in the cleaning treatment liquid of gained, during which carries out Ultrasonic irradiation is handled, dry after being taken out after 25min.
Further, step(1)The preparation method of modified montmorillonoid powder described in operation a includes the following steps:
1)Montmorillonite powder is first put into immersion treatment 6min in acid solution, places into immersion treatment 7min in lye after the completion, Taking-up is spare after being rinsed one time with deionized water after the completion;
2)By step 1)Treated, and montmorillonite powder is put into progress calcination processing in calcining furnace, is taken out after 1.5h spare;
3)By step 2)Treated, and montmorillonite powder is put into progress radiation treatment in ultraviolet irradiation instrument, is taken out after 22min .
Further, step 1)Described in acid solution be mass fraction be 9% phosphoric acid solution;The lye is quality The sodium hydroxide solution that score is 7%.
Further, step 2)Described in calcination processing when control calcining furnace in temperature be 820 DEG C.
Further, step 3)Described in the power of ultraviolet irradiation processing be 730W, the wavelength of ultraviolet light is 300 ~ 310nm。
Further, step(2)Described in microwave treatment power be 400W.
Further, step(3)Described in ultrasonic wave frequency be 140kHz.
Cleaning treatment technique of the present invention for impurity removal rate up to 99.8% or more, the transparency of the glass after cleaning reaches 99.8% or more, the efficiency of decontamination improves 60% or more compared with normal treatment process, and handles stay in grade, great popularization and application valence Value.

Claims (7)

1. a kind of cleaning treatment technique of glass, which is characterized in that include the following steps:
(1)Cleaning treatment liquid is prepared:
A. it is spare to weigh following substance by corresponding parts by weight:13 ~ 16 parts of lauryl potassium sulfates, 6 ~ 9 parts of fatty alcohol polyoxyethylene ether, 5 ~ 8 parts of calgons, 4 ~ 7 parts of neopelexes, 3 ~ 6 parts of polyethenoxy alkanolamides, 2 ~ 4 parts of modified montmorillonoids Powder, 160 ~ 180 parts of water;
B. all substances that a is weighed will be operated to be put into blender jointly, at 2400 ~ 2600 revs/min of rotating speed stirring Reason 30 ~ 35min after take out cleaning treatment liquid is spare;
(2)Glass pre-processes:
With clear water to glass sparge one time after, then put it into and carry out microwave treatment in microwave treatment instrument, taken out after 15 ~ 20s It is spare;
(3)Cleaning treatment:
By step(2)Treated, and glass is immersed in step(1)It starts the cleaning processing in the cleaning treatment liquid of gained, during which carries out Ultrasonic irradiation is handled, dry after being taken out after 20 ~ 25min.
2. a kind of cleaning treatment technique of glass according to claim 1, which is characterized in that step(1)It operates described in a The preparation method of modified montmorillonoid powder include the following steps:
1)Montmorillonite powder is first put into 4 ~ 6min of immersion treatment in acid solution, place into after the completion immersion treatment 5 in lye ~ 7min, taking-up is spare after being rinsed one time with deionized water after the completion;
2)By step 1)Treated, and montmorillonite powder is put into progress calcination processing in calcining furnace, is taken out after 1 ~ 1.5h spare;
3)By step 2)Treated, and montmorillonite powder is put into progress radiation treatment in ultraviolet irradiation instrument, is taken after 18 ~ 22min Go out.
3. a kind of cleaning treatment technique of glass according to claim 2, which is characterized in that step 1)Described in acid solution It is the phosphoric acid solution that mass fraction is 7 ~ 9%;The lye is the sodium hydroxide solution that mass fraction is 5 ~ 7%.
4. a kind of cleaning treatment technique of glass according to claim 2, which is characterized in that step 2)Described in calcining It is 780 ~ 820 DEG C that the temperature in calcining furnace is controlled when processing.
5. a kind of cleaning treatment technique of glass according to claim 2, which is characterized in that step 3)Described in it is ultraviolet The power of line radiation treatment is 680 ~ 730W, and the wavelength of ultraviolet light is 290 ~ 310nm.
6. a kind of cleaning treatment technique of glass according to claim 1, which is characterized in that step(2)Described in it is micro- The power of wave processing is 300 ~ 400W.
7. a kind of cleaning treatment technique of glass according to claim 1, which is characterized in that step(3)Described in it is super The frequency of sound wave is 120 ~ 140kHz.
CN201711491855.9A 2017-12-30 2017-12-30 A kind of cleaning treatment technique of glass Pending CN108277095A (en)

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CN108948594A (en) * 2018-08-02 2018-12-07 宣城市聚源精细化工有限公司 A kind of processing method for the additive promoting wood plastic composite strength characteristics
CN109135109A (en) * 2018-08-02 2019-01-04 宣城市聚源精细化工有限公司 A kind of preparation method of water-fast high-strength PVC wood plastic composite
CN109553308A (en) * 2018-12-29 2019-04-02 河南中汇新材科技有限公司 Self-cleaning glass and its manufacturing method
CN110093026A (en) * 2019-05-07 2019-08-06 蚌埠星烁新材料科技有限公司 A kind of recycling technique of polyurethane
CN113073012A (en) * 2020-12-15 2021-07-06 苏州伟之佳光电科技有限公司 Novel glass cleaning process

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CN102899188A (en) * 2012-09-28 2013-01-30 上海群乐船舶附件启东有限公司 Glass cleaner
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CN109135109A (en) * 2018-08-02 2019-01-04 宣城市聚源精细化工有限公司 A kind of preparation method of water-fast high-strength PVC wood plastic composite
CN108867036A (en) * 2018-08-09 2018-11-23 界首市恒仁服饰有限公司 A kind of modification processing method enhancing polyester fiber anti-microbial property
CN108867036B (en) * 2018-08-09 2021-06-01 杭州闻涛锦纶有限公司 Modification treatment method for enhancing antibacterial property of polyester fiber
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CN110093026A (en) * 2019-05-07 2019-08-06 蚌埠星烁新材料科技有限公司 A kind of recycling technique of polyurethane
CN113073012A (en) * 2020-12-15 2021-07-06 苏州伟之佳光电科技有限公司 Novel glass cleaning process

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