CN106883948A - A kind of glass cleaner and preparation method thereof - Google Patents
A kind of glass cleaner and preparation method thereof Download PDFInfo
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- CN106883948A CN106883948A CN201710103543.XA CN201710103543A CN106883948A CN 106883948 A CN106883948 A CN 106883948A CN 201710103543 A CN201710103543 A CN 201710103543A CN 106883948 A CN106883948 A CN 106883948A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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Abstract
The present invention relates to cleaning agent technical field, and in particular to a kind of glass cleaner and preparation method thereof, the glass cleaner is made up of the raw material of following weight portion：14 16 parts of Cocoamidopropyl betaine, 48 parts of sodium alkyl benzene sulfonate, 57 parts of oxystearin, 68 parts of tartaric acid, 35 parts of thio-acid sodium, 12 parts of salicylic acid, 13 parts of aminobenzoic acid, 46 parts of toluenesulfonic acid sodium salt, 13 parts of additive, 24 parts of nano-calcium carbonate sodium, 68 parts of mica powder, 48 parts of modified kaolin, 10 12 parts of deionized water.Glass cleaner of the invention, free from extraneous odour, evaporation rate is very slow, only needs to be rinsed with a small amount of water during cleaning, and glass light is such as new after cleaning, and the glass cleaner preparation process is simple, practical, is adapted to be promoted in this area.
Description
【Technical field】
The present invention relates to cleaning agent technical field, and in particular to a kind of glass cleaner and preparation method thereof.
【Background technology】
Glass can be used widely due to its various excellent properties in all trades and professions, for example glass wall, windowpane, glass
Glass door, safety glass sports equipment etc., glass can all be oxidized discoloration using surface after long, while the surface of glass
Various dirts can be stained with, the light transmittance and sight of glass is reduced, so carrying out cleaning to glass seems necessary.
The common clean method to glass is exactly to be wiped with wet rag, so dust that can clean out glass surface, for
Some obstinate dirts such as oil smoke, glue etc., are to be difficult to be cleaned out with common clean method, so clearing glass will be used
Clean dose.In existing cleaning agent, there is a kind of peculiar smell, be a little pungent for some sensitive groups, some cleaning agent cleanings
Effect is bad, and some cleaning effects are good but can have certain extent of corrosion to glass simultaneously, also needed after dirt is cleaned out
Use substantial amounts of water to be rinsed, serious waste water resource, often also have apparent washmarking on glass after bath, and
Need to wipe it with dry wipe, waste manpower.Therefore, a kind of new glass cleaner requires study.
【The content of the invention】
It is an object of the invention to：There is peculiar smell for existing glass cleaner, volatile, cleaning effect is not good or right
A kind of the problems such as glass has corrosiveness, there is provided glass cleaner and preparation method thereof, the glass cleaner free from extraneous odour and clear
Clean effect is good, not volatile, will not produce corrosiveness to glass, and the preparation method of the glass cleaner is simple.
To achieve these goals, the technical solution adopted by the present invention is as follows：
A kind of glass cleaner, the glass cleaner is made up of the raw material of following weight portion：Cocamidopropyl propyl amide is sweet
14-16 parts of dish alkali, sodium alkyl benzene sulfonate 4-8 parts, oxystearin 5-7 parts, tartaric acid 6-8 parts, 3-5 parts of thio-acid sodium, bigcatkin willow
It is sour 1-2 parts, aminobenzoic acid 1-3 parts, toluenesulfonic acid sodium salt 4-6 parts, additive 1-3 parts, 2-4 parts of nano-calcium carbonate sodium, mica powder 6-8
Part, modified kaolin 4-8 parts, deionized water 10-12 parts.
In the present invention, further, the additive is that citric acid and sodium metasilicate compare 3 according to weight:The mixing of 2 compositions
Thing.
In the present invention, further, the preparation method of the modified kaolin is：Kaolin is roasted at 400-500 DEG C
After burning 3-4 hours, clay into power, then be 10-15% hydrogen peroxide dippings 3-5 hours with mass fraction, last deionized water washing,
Powder is added to percentage by weight in 1-3% silane coupler solutions, then to carry out ultrasonic disperse after drying, is stirred, done
It is dry, it is finely ground, obtain final product modified kaolin.
In the present invention, further, the preparation method of the silane coupler is, first that silane coupler is soluble in water,
The solution that mass fraction is 0.5-2% is prepared into, glacial acetic acid is subsequently adding, its pH is adjusted to 5.5, stirred 5 minutes, obtained final product.
In the present invention, further, the time of the ultrasonic disperse is 30 minutes, and whipping temp is 80 DEG C, mixing time
It it is 30 minutes, drying temperature is 100 DEG C, drying time is 2 hours.
A kind of preparation method of glass cleaner as described above, concretely comprises the following steps：
(1) in parts by weight, deionized water is heated to 40-50 DEG C first, then by sodium salicylate, aminobenzoic
Acid, benzene sulfonic acid sodium salt are poured slowly into deionized water, are stirred 3-5 minutes；Nano-calcium carbonate sodium, mica powder are added, while stirring one
While being heated to 80-90 DEG C, 10-15 minutes is stood, obtain mixed liquor A, mixed liquor A is then cooled to normal temperature, it is stand-by；
(2) toward addition Cocoamidopropyl betaine, sodium alkyl benzene sulfonate in mixed liquor A, stop after being heated to 80-90 DEG C
Heating, adds modified kaolin, oxystearin, tartaric acid, thio-acid sodium, whipping temp to be subsequently adding film forming to 55-65 DEG C
Agent, additive, stir to normal temperature, obtain final product.
In the present invention, further, in the step (1) and step (2), the speed of heating is intensification 5- per minute
10℃。
In the present invention, further, in the step (1) and step (2), the mode of stirring is nitrogen flushing gas agitating.
In the present invention, further, in the step (1), the mode of cooling is under vacuum conditions with drop per minute
Warm 5-7 DEG C of speed is cooled to 45-50 DEG C, is incubated 2-4 hours, is then put into air and is cooled to normal temperature.
In sum, by adopting the above-described technical solution, the beneficial effects of the invention are as follows：
1st, glass cleaner of the invention, with deionized water as matrix, Cocoamidopropyl betaine coordinates benzene sulfonamide
Sour sodium, both combine has very strong oxidisability and volatility, and dirt-removing power is strong, and rate of volatilization is fast, causes cleaning agent being sprayed onto
Often just volatilized because having little time to wipe when on glass, caused serious waste, therefore during preparation
Modified kaolin is added, after by roasting, immersion, ultrasonic disperse, drying, the diameter of atom reduces kaolin, atom
Between distance can become big, but in acid condition, the interatomic ability of attracting each other can still be strengthened a lot, modified kaolin atom
After being combined with other atoms in the solution, the chelating agent constituted with oxystearin, tartaric acid, thio-acid sodium is added, can subtracted
The volatility of few solution, adds the solubilizer constituted with sodium salicylate, aminobenzoic acid, benzene sulfonic acid sodium salt, and solubilizer can promote
Enter during the dirt of glass surface dissolved into solution, and then dirt is oxidized and dispels；Add with nano-calcium carbonate sodium and mica powder group
Into polishing agent coordinate additive using can allow cleaning after glass it is more bright bright and clean；The mutually coordinated common work of each composition
Under, can allow the glass cleaner that there is more preferable integration capability.
2nd, glass cleaner of the invention, is safe from harm to human body, and in the absence of any peculiar smell, environmental protection is being sprayed onto glass
After being wiped on glass, need to only be rinsed with a small amount of clear water can just make glass take on an entirely new look, while will not leave behind any water on glass
Trace, saves water resource, meanwhile, make the surface no longer adsorption of dust of glass etc. small in a period of time after glass cleaning
Particle, reduces the cleaning frequency of glass, it may have good anti-fog effect, practical, is adapted to be promoted in this area.
【Specific embodiment】
Embodiment 1：
A kind of glass cleaner, is made up of the raw material of following weight portion：14 parts of Cocoamidopropyl betaine, benzene sulfonamide
4 parts of sour sodium, 5 parts of oxystearin, 6 parts of tartaric acid, 3 parts of thio-acid sodium, 1 part of salicylic acid, 1 part of aminobenzoic acid, toluenesulfonic acid
4 parts of sodium, 1 part of additive, 2 parts of nano-calcium carbonate sodium, 6 parts of mica powder, 4 parts of modified kaolin, 10 parts of deionized water.
Wherein, additive is that citric acid and sodium metasilicate compare 3 according to weight:The mixture of 2 compositions.
Wherein, the preparation method of modified kaolin is：After kaolin is calcined 3 hours at 400 DEG C, clay into power, then
It is 10% hydrogen peroxide dipping 3 hours with mass fraction, powder is added to percentage by weight by last deionized water washing after drying
In for 1% silane coupler solution, ultrasonic disperse is then carried out, stirred, dried, finely ground, the time of the ultrasonic disperse is 30
Minute, whipping temp is 80 DEG C, and mixing time is 30 minutes, and drying temperature is 100 DEG C, and drying time is 2 hours；Obtain final product modified
Kaolin.The preparation method of the silane coupler is, first that silane coupler is soluble in water, is prepared into mass fraction and is
0.5% solution, is subsequently adding glacial acetic acid, and its pH is adjusted into 5.5, stirs 5 minutes, obtains final product.
The glass cleaner that said ratio is obtained is prepared from using following methods, is concretely comprised the following steps：
(1) in parts by weight, first by deionized water with 5 DEG C of the heating rate of heating up per minute to 40 DEG C, so
Sodium salicylate, aminobenzoic acid, benzene sulfonic acid sodium salt are poured slowly into deionized water afterwards, are stirred 3 minutes, the mode of stirring is blows
Nitrogen gas stirring；Nano-calcium carbonate sodium, mica powder are added, is stirred while being arrived with the heating rate for heating up 5 DEG C per minute
80 DEG C, 10 minutes are stood, obtain mixed liquor A, mixed liquor A is then cooled to normal temperature, the mode of cooling is under vacuum conditions
45 DEG C are cooled to 5 DEG C of speed of cooling per minute, 2 hours are incubated, are then put into air and are cooled to normal temperature；It is stand-by；
(2) toward addition Cocoamidopropyl betaine, sodium alkyl benzene sulfonate in mixed liquor A, with adding for 5 DEG C of intensification per minute
Hot speed stops heating after being heated to 80 DEG C, adds modified kaolin, oxystearin, tartaric acid, thio-acid sodium, whipping temp
To 55 DEG C, the mode of stirring is nitrogen flushing gas agitating, is subsequently adding additive, stirs to normal temperature, obtains final product.
Embodiment 2：
A kind of glass cleaner, is made up of the raw material of following weight portion：15 parts of Cocoamidopropyl betaine, benzene sulfonamide
6 parts of sour sodium, 6 parts of oxystearin, 7 parts of tartaric acid, 4 parts of thio-acid sodium, 1.5 parts of salicylic acid, 2 parts of aminobenzoic acid, toluene sulphur
5 parts of sour sodium, 2 parts of additive, 3 parts of nano-calcium carbonate sodium, 7 parts of mica powder, 6 parts of modified kaolin, 11 parts of deionized water.
Wherein, additive is that citric acid and sodium metasilicate compare 3 according to weight:The mixture of 2 compositions.
Wherein, the preparation method of modified kaolin is：After kaolin is calcined 3.5 hours at 450 DEG C, clay into power,
It is 12.5% hydrogen peroxide dipping 4 hours with mass fraction again, powder is added to weight hundred by last deionized water washing after drying
Divide than in 2% silane coupler solution, then to carry out ultrasonic disperse, stirring, dry, finely ground, the time of the ultrasonic disperse
It it is 30 minutes, whipping temp is 80 DEG C, mixing time is 30 minutes, drying temperature is 100 DEG C, drying time is 2 hours；Obtain final product
Modified kaolin.The preparation method of the silane coupler is, first that silane coupler is soluble in water, is prepared into mass fraction and is
1.25% solution, is subsequently adding glacial acetic acid, and its pH is adjusted into 5.5, stirs 5 minutes, obtains final product.
The glass cleaner that said ratio is obtained is prepared from using following methods, is concretely comprised the following steps：
(1) in parts by weight, first by deionized water with 7.5 DEG C of the heating rate of heating up per minute to 45 DEG C,
Then sodium salicylate, aminobenzoic acid, benzene sulfonic acid sodium salt are poured slowly into deionized water, are stirred 4 minutes, the mode of stirring is
Nitrogen flushing gas agitating；Nano-calcium carbonate sodium, mica powder are added, is stirred while being added with the rate of heat addition for heating up 7.5 DEG C per minute
Heat stands 12.5 minutes to 85 DEG C, obtains mixed liquor A, and mixed liquor A then is cooled into normal temperature, and the mode of cooling is in vacuum
47.5 DEG C are cooled to 6 DEG C of speed of cooling per minute under state, 3 hours are incubated, are then put into air and are cooled to normal temperature, treated
With；
(2) toward addition Cocoamidopropyl betaine, sodium alkyl benzene sulfonate in mixed liquor A, with 7.5 DEG C of intensification per minute
Heating rate adds modified kaolin, oxystearin, tartaric acid, thio-acid sodium, stirring temperature to stopping heating after 85 DEG C
To 60 DEG C, the mode of stirring is nitrogen flushing gas agitating to degree, is subsequently adding additive, stirs to normal temperature, obtains final product.
Embodiment 3：
A kind of glass cleaner, is made up of the raw material of following weight portion：16 parts of Cocoamidopropyl betaine, benzene sulfonamide
8 parts of sour sodium, 7 parts of oxystearin, 8 parts of tartaric acid, 5 parts of thio-acid sodium, 2 parts of salicylic acid, 3 parts of aminobenzoic acid, toluenesulfonic acid
6 parts of sodium, 3 parts of additive, 4 parts of nano-calcium carbonate sodium, 8 parts of mica powder, 8 parts of modified kaolin, 12 parts of deionized water.
Wherein, additive is that citric acid and sodium metasilicate compare 3 according to weight:The mixture of 2 compositions.
Wherein, the preparation method of modified kaolin is：After kaolin is calcined 4 hours at 500 DEG C, clay into power, then
It is 15% hydrogen peroxide dipping 5 hours with mass fraction, powder is added to percentage by weight by last deionized water washing after drying
In for 3% silane coupler solution, ultrasonic disperse is then carried out, stirred, dried, finely ground, the time of the ultrasonic disperse is 30
Minute, whipping temp is 80 DEG C, and mixing time is 30 minutes, and drying temperature is 100 DEG C, and drying time is 2 hours, is obtained final product modified
Kaolin.The preparation method of the silane coupler is, first that silane coupler is soluble in water, and it is 2% to be prepared into mass fraction
Solution, be subsequently adding glacial acetic acid, its pH is adjusted to 5.5, stir 5 minutes, obtain final product.
The glass cleaner that said ratio is obtained is prepared from using following methods, is concretely comprised the following steps：
(1) in parts by weight, first by deionized water with 10 DEG C of the heating rate of heating up per minute to 50 DEG C, so
Sodium salicylate, aminobenzoic acid, benzene sulfonic acid sodium salt are poured slowly into deionized water afterwards, are stirred 5 minutes, the mode of stirring is blows
Nitrogen gas stirring；Nano-calcium carbonate sodium, mica powder are added, is stirred while being arrived with the heating rate for heating up 10 DEG C per minute
90 DEG C, 15 minutes are stood, obtain mixed liquor A, mixed liquor A is then cooled to normal temperature, the mode of cooling is under vacuum conditions
50 DEG C are cooled to 7 DEG C of speed of cooling per minute, 4 hours are incubated, are then put into air and are cooled to normal temperature, it is stand-by；
(2) toward addition Cocoamidopropyl betaine, sodium alkyl benzene sulfonate in mixed liquor A, with 10 DEG C of intensification per minute
Heating rate adds modified kaolin, oxystearin, tartaric acid, thio-acid sodium, stirring temperature to stopping heating after 90 DEG C
To 65 DEG C, the mode of stirring is nitrogen flushing gas agitating to degree, is subsequently adding additive, stirs to normal temperature, obtains final product.
In order to further prove characteristic of the invention, comparative testing below is done respectively：
Contrast groups 1：Cocoamidopropyl betaine in composition, sodium alkyl benzene sulfonate are removed, other modes are strictly pressed
Carried out according to embodiment 2.
Contrast groups 2：Modified kaolin in composition is removed, other modes are carried out in strict accordance with embodiment 2.
Contrast groups 3：The modified kaolin of composition is substituted for what is produced by Datong Jin Yuan kaolin Co., Ltd
Kaolin, other modes are carried out in strict accordance with embodiment 2.
The glass cleaner that contrast groups 1-3 and embodiment of the present invention 1-3 is made, then the one kind for taking in the market sale are taken respectively
Green umbrella glass cleaner, in the case of condition identical, determines cleaning effect respectively, then records each situation such as following table：
As can be seen from the above table, glass cleaner of the invention, free from extraneous odour, evaporation rate is very slow, in cleaning process
In only need to be rinsed with a small amount of water, glass light is adapted to be promoted in this area as new after cleaning.
Described above is directed to the detailed description of preferably possible embodiments of the invention, but embodiment is not limited to this hair
Bright patent claim, the equal change completed under the technical spirit suggested by all present invention or modification change, all should belong to
Cover the scope of the claims in the present invention.
Claims (9)
1. a kind of glass cleaner, it is characterised in that：The glass cleaner is made up of the raw material of following weight portion：Cocounut oil acyl
14-16 parts of amine CAB, sodium alkyl benzene sulfonate 4-8 parts, oxystearin 5-7 parts, tartaric acid 6-8 parts, thio-acid sodium 3-5
Part, salicylic acid 1-2 parts, aminobenzoic acid 1-3 parts, toluenesulfonic acid sodium salt 4-6 parts, additive 1-3 parts, 2-4 parts of nano-calcium carbonate sodium, cloud
Female powder 6-8 parts, modified kaolin 4-8 parts, deionized water 10-12 parts.
2. a kind of glass cleaner according to claim 1, it is characterised in that：The additive is citric acid and sodium metasilicate
Compare 3 according to weight:The mixture of 2 compositions.
3. a kind of glass cleaner according to claim 1, it is characterised in that：The preparation method of the modified kaolin
For：After kaolin is calcined 3-4 hours at 400-500 DEG C, clay into power, then be 10-15% dioxygen water loggings with mass fraction
Bubble 3-5 hours, last deionized water washing, percentage by weight is added to for 1-3% silane coupler solutions after drying by powder
In, ultrasonic disperse is then carried out, stir, dry, it is finely ground, obtain final product modified kaolin.
4. a kind of glass cleaner according to claim 4, it is characterised in that：The preparation method of the silane coupler
For, it is first that silane coupler is soluble in water, the solution that mass fraction is 0.5-2% is prepared into, glacial acetic acid is subsequently adding, by its pH
5.5 are adjusted to, are stirred 5 minutes, obtained final product.
5. a kind of glass cleaner according to claim 4, it is characterised in that：The time of the ultrasonic disperse is 30 points
Clock, whipping temp is 80 DEG C, and mixing time is 30 minutes, and drying temperature is 100 DEG C, and drying time is 2 hours.
6. the preparation method of a kind of glass cleaner according to claim 1-6 any one, it is characterised in that：Specific step
Suddenly it is：
(1) in parts by weight, deionized water is heated to 40-50 DEG C first, then by sodium salicylate, aminobenzoic acid, benzene
Sodium sulfonate is poured slowly into deionized water, is stirred 3-5 minutes；Nano-calcium carbonate sodium, mica powder are added, is stirred while heating
To 80-90 DEG C, 10-15 minutes is stood, obtain mixed liquor A, mixed liquor A is then cooled to normal temperature, it is stand-by；
(2) toward addition Cocoamidopropyl betaine, sodium alkyl benzene sulfonate in mixed liquor A, stop adding after being heated to 80-90 DEG C
Heat, adds modified kaolin, oxystearin, tartaric acid, thio-acid sodium, whipping temp to be subsequently adding addition to 55-65 DEG C
Agent, stirs to normal temperature, obtains final product.
7. the preparation method of a kind of glass for vehicle window cleaning agent according to claim 7, it is characterised in that：In the step
(1) and in step (2), the speed of heating is 5-10 DEG C of intensification per minute.
8. the preparation method of a kind of glass for vehicle window cleaning agent according to claim 7, it is characterised in that：In the step
(1) and in step (2), the mode of stirring is nitrogen flushing gas agitating.
9. the preparation method of a kind of glass for vehicle window cleaning agent according to claim 7, it is characterised in that：In the step
(1) in, the mode of cooling is to be cooled to 45-50 DEG C with the speed of 5-7 DEG C of cooling per minute under vacuum conditions, and 2-4 is small for insulation
When, then it is put into air and is cooled to normal temperature.
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| CN201710103543.XA CN106883948A (en) | 2017-02-24 | 2017-02-24 | A kind of glass cleaner and preparation method thereof |
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| CN201710103543.XA CN106883948A (en) | 2017-02-24 | 2017-02-24 | A kind of glass cleaner and preparation method thereof |
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Cited By (1)
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|---|---|---|---|---|
| CN108277095A (en) * | 2017-12-30 | 2018-07-13 | 安徽杜氏高科玻璃有限公司 | A kind of cleaning treatment technique of glass |
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Application publication date: 20170623 |