CN107964459A - A kind of efficiently freeze proof automobile glass cleaning agent and preparation method thereof - Google Patents

A kind of efficiently freeze proof automobile glass cleaning agent and preparation method thereof Download PDF

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Publication number
CN107964459A
CN107964459A CN201711278103.4A CN201711278103A CN107964459A CN 107964459 A CN107964459 A CN 107964459A CN 201711278103 A CN201711278103 A CN 201711278103A CN 107964459 A CN107964459 A CN 107964459A
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parts
cleaning agent
glass cleaning
automobile glass
freeze proof
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CN201711278103.4A
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Inventor
胡春
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ANHUI XIERQI COMMODITY Co Ltd
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ANHUI XIERQI COMMODITY Co Ltd
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Priority to CN201711278103.4A priority Critical patent/CN107964459A/en
Publication of CN107964459A publication Critical patent/CN107964459A/en
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/16—Anti-static materials
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2044—Dihydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to glass cleaner technical field, and in particular to a kind of efficiently freeze proof automobile glass cleaning agent and preparation method thereof；It is made of following raw material：Fatty alcohol polyoxyethylene ether, polyoxyethylene cocounut oil acid esters, diatomite, nano silicon dioxide, butyl glycol ether, palm wax, propane diols, sodium tripolyphosphate, disodium ethylene diamine tetraacetate, lye, solubilizer, defoamer, antistatic additive and deionized water；Using butyl glycol ether and propane diols as raw material in the present invention, both mutually cooperate with, and the anti-freezing property of prepared automobile glass cleaning agent significantly improves；Polyoxyethylene cocounut oil acid esters and polyglyceryl fatty acid ester interaction can play the role of significant increase-volume, and polyoxyethylene cocounut oil acid esters cooperate with ethoxylated alkyl acid amide can also improve the antistatic property of glass cleaner；Diatomite and nano silicon dioxide cooperate and not only have excellent antibacterial, sterilizing ability, can extend the shelf-life of automobile glass cleaning agent.

Description

A kind of efficiently freeze proof automobile glass cleaning agent and preparation method thereof
Technical field
The present invention relates to glass cleaner technical field, and in particular to a kind of efficiently freeze proof automobile glass cleaning agent and its system Preparation Method.
Background technology
Vehicle glass is essential in automobile body accessories, primarily serves protective action.Vehicle glass mainly have with Lower three classes：Laminated glass, tempered glass and local toughened glass, can bear stronger impact force.Vehicle glass presses the position at place Put and be divided into：Four kinds of front windshield, side window glass, rear seat windscreen and skylight glass；Front windshield state compulsion regulation must Must be laminated glass, (some cheap agricultural vehicle fronts are still tempered glass or local toughened glass) side window glass is tempering glass Glass, rear seat windscreen are usually the tempered glass of electrified heating silk.Automobile when driving, can fall to have for a long time above vehicle glass Foul or dust, this is just to need glass cleaner to clean it.
Glass cleaner, glass cleaner are the greasy dirts for cleaning glass surface, its main component is surfactant, Slightly alkalescence or tool is neutral.
There is the non-polar group of hydrophilic polar group and oleophylic at the same time, when its addition in its molecule of glass cleaner When measuring seldom, the surface tension and light-liquid interfacial tension of solvent (being usually water) can be substantially reduced, and with lubrication, increasing The effects such as molten, emulsification, scattered and washing.Glass cleaner has been widely used in family life and industrial cleaning.
Although existing glass cleaner has the function of that vehicle glass can be cleaned, its resistance to frost is poor, and clearly The dirt washed on vehicle glass is less efficient.
The content of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of efficiently freeze proof automobile glass cleaning agent, prepared vapour Car glass cleaner has the advantages that detersive efficiency is high and resistance to frost is good.
In order to achieve the above object, the present invention is achieved by the following technical programs：
A kind of efficiently freeze proof automobile glass cleaning agent, is prepared from the following raw materials in parts by weight：Fatty alcohol polyoxyethylene ether 12-18 parts, 10-15 parts of polyoxyethylene cocounut oil acid esters, 5-9 parts of diatomite, 3-7 parts of nano silicon dioxide, butyl glycol ether 9-13 Part, 6-10 parts of palm wax, 8-12 parts of propane diols, 2-5 parts of sodium tripolyphosphate, 4-8 parts of disodium ethylene diamine tetraacetate, lye 8-12 Part, 3-6 parts of solubilizer, 2-7 parts of defoamer, 5-10 parts of antistatic additive and 55-70 parts of deionized water.
A kind of preparation method of efficiently freeze proof automobile glass cleaning agent, comprises the following steps：
A, deionized water is added into reaction kettle, is warming up to 25-35 DEG C, then sequentially adds fatty alcohol under stirring Polyoxyethylene ether, lye and diatomite, until solid is completely dissolved, obtain component A；
B, again by propane diols, polyoxyethylene cocounut oil acid esters, nano silicon dioxide, butyl glycol ether, palm wax, tripolyphosphate Sodium is added in reaction kettle, is warming up to 50-65 DEG C, and under the speed of 200-350r/min, is reacted 14-20h, obtained component B；
C, when component B is cooled to room temperature, component A is added in component B, then adds surplus stock in reaction kettle, And 50-75min is stirred under the speed of 180-280r/min, up to glass cleaner finished product.
Preferably, the lye selects the sodium hydroxide solution that concentration is 7-13%.
Preferably, the solubilizer selects polyglyceryl fatty acid ester.
Preferably, the defoamer selects silicone emulsion.
Preferably, the antistatic additive selects ethoxylated alkyl acid amide.
Beneficial effect：
Using butyl glycol ether and propane diols as raw material in the present invention, both mutually cooperate with, prepared vehicle glass The anti-freezing property of detergent significantly improves；Polyoxyethylene cocounut oil acid esters and polyglyceryl fatty acid ester interaction can be played significant The effect of increase-volume.Polyoxyethylene cocounut oil acid esters cooperate with ethoxylated alkyl acid amide can also improve the anti-quiet of glass cleaner Electrical property.Furthermore diatomite and nano silicon dioxide cooperate and not only have excellent antibacterial, sterilizing ability, can extend vapour The shelf-life of car glass cleaner, and the transparency of glass cleaner can also be kept for a long time.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention, Technical solution in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the present invention one Divide embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making All other embodiments obtained under the premise of creative work, belong to the scope of protection of the invention.
Embodiment 1：
A kind of efficiently freeze proof automobile glass cleaning agent, is prepared from the following raw materials in parts by weight：Fatty alcohol polyoxyethylene ether 12 parts, 13 parts of polyoxyethylene cocounut oil acid esters, 5 parts of diatomite, 4 parts of nano silicon dioxide, 9 parts of butyl glycol ether, 7 parts of palm wax, It is 8 parts of propane diols, 3 parts of sodium tripolyphosphate, 4 parts of disodium ethylene diamine tetraacetate, 9 parts of lye, 3 parts of solubilizer, 4 parts of defoamer, anti-quiet 60 parts of 5 parts of electric agent and deionized water.
A kind of preparation method of efficiently freeze proof automobile glass cleaning agent, comprises the following steps：
A, deionized water is added into reaction kettle, is warming up to 25 DEG C, then sequentially adds poly alkyl alcohol under stirring Ethylene oxide ether, lye and diatomite, until solid is completely dissolved, obtain component A；
B, again by propane diols, polyoxyethylene cocounut oil acid esters, nano silicon dioxide, butyl glycol ether, palm wax, tripolyphosphate Sodium is added in reaction kettle, is warming up to 50 DEG C, and under the speed of 200r/min, is reacted 14h, obtained component B；
C, when component B is cooled to room temperature, component A is added in component B, then adds surplus stock in reaction kettle, And 50min is stirred under the speed of 180r/min, up to glass cleaner finished product.
Lye selects the sodium hydroxide solution that concentration is 7%.
Solubilizer selects polyglyceryl fatty acid ester.
Defoamer selects silicone emulsion.
Antistatic additive selects ethoxylated alkyl acid amide.
Embodiment 2：
A kind of efficiently freeze proof automobile glass cleaning agent, is prepared from the following raw materials in parts by weight：Fatty alcohol polyoxyethylene ether 14 parts, 10 parts of polyoxyethylene cocounut oil acid esters, 6 parts of diatomite, 3 parts of nano silicon dioxide, 11 parts of butyl glycol ether, 6 parts of palm wax, It is 9 parts of propane diols, 2 parts of sodium tripolyphosphate, 5 parts of disodium ethylene diamine tetraacetate, 8 parts of lye, 4 parts of solubilizer, 2 parts of defoamer, anti-quiet 55 parts of 7 parts of electric agent and deionized water.
A kind of preparation method of efficiently freeze proof automobile glass cleaning agent, comprises the following steps：
A, deionized water is added into reaction kettle, is warming up to 28 DEG C, then sequentially adds poly alkyl alcohol under stirring Ethylene oxide ether, lye and diatomite, until solid is completely dissolved, obtain component A；
B, again by propane diols, polyoxyethylene cocounut oil acid esters, nano silicon dioxide, butyl glycol ether, palm wax, tripolyphosphate Sodium is added in reaction kettle, is warming up to 55 DEG C, and under the speed of 250r/min, is reacted 16h, obtained component B；
C, when component B is cooled to room temperature, component A is added in component B, then adds surplus stock in reaction kettle, And 60min is stirred under the speed of 220r/min, up to glass cleaner finished product.
Lye selects the sodium hydroxide solution that concentration is 9%.
Solubilizer selects polyglyceryl fatty acid ester.
Defoamer selects silicone emulsion.
Antistatic additive selects ethoxylated alkyl acid amide.
Embodiment 3：
A kind of efficiently freeze proof automobile glass cleaning agent, is prepared from the following raw materials in parts by weight：Fatty alcohol polyoxyethylene ether 16 parts, 15 parts of polyoxyethylene cocounut oil acid esters, 7 parts of diatomite, 7 parts of nano silicon dioxide, 12 parts of butyl glycol ether, palm wax 10 Part, 11 parts of propane diols, 5 parts of sodium tripolyphosphate, 7 parts of disodium ethylene diamine tetraacetate, 12 parts of lye, 5 parts of solubilizer, 7 parts of defoamer, 70 parts of 8 parts of antistatic additive and deionized water.
A kind of preparation method of efficiently freeze proof automobile glass cleaning agent, comprises the following steps：
A, deionized water is added into reaction kettle, is warming up to 32 DEG C, then sequentially adds poly alkyl alcohol under stirring Ethylene oxide ether, lye and diatomite, until solid is completely dissolved, obtain component A；
B, again by propane diols, polyoxyethylene cocounut oil acid esters, nano silicon dioxide, butyl glycol ether, palm wax, tripolyphosphate Sodium is added in reaction kettle, is warming up to 60 DEG C, and under the speed of 300r/min, is reacted 18h, obtained component B；
C, when component B is cooled to room temperature, component A is added in component B, then adds surplus stock in reaction kettle, And 65min is stirred under the speed of 250r/min, up to glass cleaner finished product.
Lye selects the sodium hydroxide solution that concentration is 11%.
Solubilizer selects polyglyceryl fatty acid ester.
Defoamer selects silicone emulsion.
Antistatic additive selects ethoxylated alkyl acid amide.
Embodiment 4：
A kind of efficiently freeze proof automobile glass cleaning agent, is prepared from the following raw materials in parts by weight：Fatty alcohol polyoxyethylene ether 18 parts, 14 parts of polyoxyethylene cocounut oil acid esters, 9 parts of diatomite, 6 parts of nano silicon dioxide, 13 parts of butyl glycol ether, 9 parts of palm wax, It is 12 parts of propane diols, 4 parts of sodium tripolyphosphate, 8 parts of disodium ethylene diamine tetraacetate, 11 parts of lye, 6 parts of solubilizer, 5 parts of defoamer, anti- 65 parts of 10 parts of electrostatic agent and deionized water.
A kind of preparation method of efficiently freeze proof automobile glass cleaning agent, comprises the following steps：
A, deionized water is added into reaction kettle, is warming up to 35 DEG C, then sequentially adds poly alkyl alcohol under stirring Ethylene oxide ether, lye and diatomite, until solid is completely dissolved, obtain component A；
B, again by propane diols, polyoxyethylene cocounut oil acid esters, nano silicon dioxide, butyl glycol ether, palm wax, tripolyphosphate Sodium is added in reaction kettle, is warming up to 65 DEG C, and under the speed of 350r/min, is reacted 20h, obtained component B；
C, when component B is cooled to room temperature, component A is added in component B, then adds surplus stock in reaction kettle, And 75min is stirred under the speed of 280r/min, up to glass cleaner finished product.
Lye selects the sodium hydroxide solution that concentration is 13%.
Solubilizer selects polyglyceryl fatty acid ester.
Defoamer selects silicone emulsion.
Antistatic additive selects ethoxylated alkyl acid amide.
It should be noted that herein, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to Non-exclusive inclusion, so that process, method, article or equipment including a series of elements not only will including those Element, but also including other elements that are not explicitly listed, or further include as this process, method, article or equipment Intrinsic key element.In the absence of more restrictions, the key element limited by sentence "including a ...", it is not excluded that Also there are other identical element in process, method, article or equipment including the key element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments The present invention is described in detail, it will be understood by those of ordinary skill in the art that：It still can be to foregoing each implementation Technical solution described in example is modified, or carries out equivalent substitution to which part technical characteristic；And these modification or Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical solution.

Claims (6)

  1. A kind of 1. efficiently freeze proof automobile glass cleaning agent, it is characterised in that：It is prepared from the following raw materials in parts by weight：Poly alkyl alcohol 12-18 parts of ethylene oxide ether, 10-15 parts of polyoxyethylene cocounut oil acid esters, 5-9 parts of diatomite, 3-7 parts of nano silicon dioxide, ethylene glycol 9-13 parts of butyl ether, 6-10 parts of palm wax, 8-12 parts of propane diols, 2-5 parts of sodium tripolyphosphate, 4-8 parts of disodium ethylene diamine tetraacetate, alkali 55-70 parts of 8-12 parts of liquid, 3-6 parts of solubilizer, 2-7 parts of defoamer, 5-10 parts of antistatic additive and deionized water.
  2. A kind of 2. preparation method of efficiently freeze proof automobile glass cleaning agent according to claim 1, it is characterised in that including Following steps：
    A, deionized water is added into reaction kettle, is warming up to 25-35 DEG C, fatty alcohol polyoxy is then sequentially added under stirring Vinethene, lye and diatomite, until solid is completely dissolved, obtain component A；
    B, propane diols, polyoxyethylene cocounut oil acid esters, nano silicon dioxide, butyl glycol ether, palm wax, sodium tripolyphosphate are added again Enter in reaction kettle, be warming up to 50-65 DEG C, and under the speed of 200-350r/min, react 14-20h, obtain component B；
    C, when component B is cooled to room temperature, component A is added in component B, then adds surplus stock in reaction kettle, and 50-75min is stirred under the speed of 180-280r/min, up to glass cleaner finished product.
  3. A kind of 3. efficiently freeze proof automobile glass cleaning agent according to claim 1, it is characterised in that：The lye is selected dense Spend the sodium hydroxide solution for 7-13%.
  4. A kind of 4. preparation method of efficiently freeze proof automobile glass cleaning agent according to claim 2, it is characterised in that：It is described Solubilizer selects polyglyceryl fatty acid ester.
  5. A kind of 5. preparation method of efficiently freeze proof automobile glass cleaning agent according to claim 2, it is characterised in that：It is described Defoamer selects silicone emulsion.
  6. A kind of 6. preparation method of efficiently freeze proof automobile glass cleaning agent according to claim 2, it is characterised in that：It is described Antistatic additive selects ethoxylated alkyl acid amide.
CN201711278103.4A 2017-12-06 2017-12-06 A kind of efficiently freeze proof automobile glass cleaning agent and preparation method thereof Pending CN107964459A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108570370A (en) * 2018-05-10 2018-09-25 深圳市咖沃科技有限公司 A kind of energy conservation and environmental protection exempts from flushing type carwash cleaning Essence and preparation method thereof
CN110584529A (en) * 2019-09-12 2019-12-20 合肥尘洁清洁技术服务有限公司 Cleaning method capable of improving cleanliness of high-rise building glass
CN110655993A (en) * 2018-06-29 2020-01-07 3M创新有限公司 Detergent composition having long-term antibacterial properties
CN112143578A (en) * 2020-09-28 2020-12-29 南京慧智莲华科技有限公司 Biomass glass water for paint surfaces and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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Application publication date: 20180427