CN109504561A - It is a kind of for removing the cleaning agent of body surface radioactive pollution - Google Patents

It is a kind of for removing the cleaning agent of body surface radioactive pollution Download PDF

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Publication number
CN109504561A
CN109504561A CN201811589991.6A CN201811589991A CN109504561A CN 109504561 A CN109504561 A CN 109504561A CN 201811589991 A CN201811589991 A CN 201811589991A CN 109504561 A CN109504561 A CN 109504561A
Authority
CN
China
Prior art keywords
cleaning agent
cleaning
body surface
agent
radioactive pollution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811589991.6A
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Chinese (zh)
Inventor
刘风丽
王廷学
王志远
王茜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenyang Hi Tech Co Ltd
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Shenyang Hi Tech Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenyang Hi Tech Co Ltd filed Critical Shenyang Hi Tech Co Ltd
Priority to CN201811589991.6A priority Critical patent/CN109504561A/en
Publication of CN109504561A publication Critical patent/CN109504561A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3245Aminoacids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/08Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/263Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/34Organic compounds containing sulfur
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/20Industrial or commercial equipment, e.g. reactors, tubes or engines

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Cleaning By Liquid Or Steam (AREA)

Abstract

The invention discloses cleaning agent technical fields, specific field is a kind of for removing the cleaning agent of body surface radioactive pollution, it is grouped as by the group of following volumes number: 35~45 parts of EHS0106 cleaning agent, 1~2 part of compounding agent, 150~300 parts of solvent, cleaning agent completes the cleaning process of dirt using the dissolution of chemistry and the release effect of physics jointly, the scale of body surface, rust deposite and radioactive soil and iron body is detached from, and make Ca by compounding agent2+、Mg2+、Fe2+、UO2 2+And U4+Plasma quickly forms complex compound and chelate, promote the quick dissolution of dirt, dirt enters in cleaning solution, the radioactive pollution degree of steel material and production scene equipment is greatly lowered, improve steel material and production scene equipment reuse ratio, radioactive contamination level is reduced, improves working environment, is conducive to the health of operator.

Description

It is a kind of for removing the cleaning agent of body surface radioactive pollution
Technical field
The present invention relates to cleaning agent technical field, specific field is a kind of for removing the clear of body surface radioactive pollution Lotion.
Background technique
With the development of nuclear industry and the application popularization of nuclear technology, in industrial production, scientific research and application process, largely Body surface by containing radionuclide substance pollute, the radionuclide being especially attached in body surface dirt, Since radionuclide is difficult to clean off, so that a large amount of material, equipment, the radioactive activity of building surface are higher, work is influenced The safety for making environment makes contaminated material, equipment and building be difficult to recycle, and utilization rate and utilization rate are greatly reduced, Heavy losses are economically generated, while also bringing certain difficulty to engineering is retired.
By the radioactive environment diversity that object is contacted, so it is in more that body surface, which is formed by radioactive pollution also, Sample is often deposited together mutually for radioactive soil and scale, rust deposite etc., forms the radioactive soil of body surface.Wherein The main component of radioactive soil is UO2、UO3、Na2U2O7And by UO2 2+The various uranium-bearing salts that ion is formed;Scale it is main Ingredient is carbonate scale, sulfate scale and silicate scale;The main component of rust deposite is the mixture of the various oxides of iron.Three Mixed deposit together, increases the removing difficulty of radioactive pollutant.
Many institutes are well-known, and being cleaned using chemical method by the body surface of radioactive pollution is a kind of more commonly used method, But ideal cleaning effect is not achieved in general chemical method, even if some cleaning agents are to removal body surface radioactivity Pollution has certain effect, but cleaning effect is generally all undesirable, it is difficult to actual application is obtained, for this purpose, we have proposed one Plant the cleaning agent for removing body surface radioactive pollution.
Summary of the invention
The purpose of the present invention is to provide a kind of for removing the cleaning agent of body surface radioactive pollution, above-mentioned to solve The problem of being proposed in background technique.
To achieve the above object, the invention provides the following technical scheme: it is a kind of for removing body surface radioactive pollution Cleaning agent, be grouped as by the group of following volumes number:
35~45 parts of EHS0106 cleaning agent
1~2 part of compounding agent
150~300 parts of solvent.
Preferably, the EHS0106 cleaning agent includes EDTA, ammonium citrate, D-9, T-C6, H-381 and butyl glycol ether.
Preferably, the compounding agent is N.N- dimethyl-thiocarbamic acid sodium.
Preferably, the solvent is deionized water.
Preferably, include the following steps:
1) mixes compounding agent with deionized water, is heated to compounding agent and is completely dissolved, spare;
2) solution that step 1) is obtained quantify by above-mentioned volume parts and be mixed by with EHS0106 cleaning agent, is stirred It is uniformly mixed to it, obtains cleaning agent stoste, it is spare;
3) mixes the cleaning agent stoste that step 2) is obtained with the solvent of above-mentioned volume parts, stirs evenly, obtains The cleaning agent of body surface radioactive pollution must be used to remove.
Preferably, following method is respectively adopted for steel plate and production scene equipment to handle:
1) processing mode of steel plate: the steel plate containing radioactive soil is placed in service sink, is injected into service sink clear Lotion, cleaning way are to impregnate, and cleaning temperature is 15~50 degrees Celsius, and scavenging period is 0.5~2 hour, and punching is used after cleaning Wash water is rinsed steel plate can be completed and remove contamination;
2) cleaning way of the production scene equipment: by the surface of getting dirty of cleaning agent even application to production scene equipment, Middle cleaning way is spraying, and cleaning temperature is 20~30 degrees Celsius, and a scavenging period is 8~15 minutes, is made after cleaning Production scene equipment is rinsed can be completed with flushing water and is removed contamination.
Compared with prior art, the beneficial effects of the present invention are: it is a kind of for removing the clear of body surface radioactive pollution Lotion, the present invention are compounded by EHS0106 cleaning agent with compounding agent, and new cleaning agent is had developed, primary to steel plate materials Property soaking and washing, cleaning efficiency reachable 80% or more carries out disposable spray finishing cleaning to production scene equipment, and cleaning efficiency can 50% or more is reached, has the characteristics that efficiently, quickly, to substrate to corrode small, easy to use, which utilizes chemical dissolution The release effect of effect and physics completes the cleaning process of dirt jointly, by the scale, rust deposite and radioactive soil of body surface It is detached from iron body, and Ca is made by compounding agent2+、Mg2+、Fe2+、UO2 2+And U4+Plasma quickly forms complex compound and chelate, Promote the quick dissolution of dirt, dirt enters in cleaning solution, and the radioactivity of steel material and production scene equipment is greatly lowered Pollution level improves steel material and production scene equipment reuse ratio, reduces radioactive contamination level, improves working environment, Be conducive to the health of operator.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution of the present invention is clearly and completely described, it is clear that institute The embodiment of description is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, Every other embodiment obtained by those of ordinary skill in the art without making creative efforts, belongs to this hair The range of bright protection.
Embodiment 1: it is a kind of for removing the cleaning agent of body surface radioactive pollution, it is grouped as by the group of following volumes: EHS0106 cleaning agent 35mL, compounding agent 1mL, solvent 150mL.
Steel plate containing radioactive soil is placed in service sink, injects above-mentioned cleaning agent into service sink, 15 degrees Celsius, It impregnates 0.5 hour, is rinsed well steel plate with flushing water.
By the surface of getting dirty of cleaning agent even application to production scene equipment, cleaning temperature is 20 degrees Celsius, primary to clean Time is 8 minutes, is rinsed well with flushing water to production scene equipment.
Embodiment 2: it is a kind of for removing the cleaning agent of body surface radioactive pollution, it is grouped as by the group of following volumes: EHS0106 cleaning agent 37mL, compounding agent 1.3mL, solvent 180mL.
Steel plate containing radioactive soil is placed in service sink, injects above-mentioned cleaning agent into service sink, 20 degrees Celsius, It impregnates 1 hour, is rinsed well steel plate with flushing water.
By the surface of getting dirty of cleaning agent even application to production scene equipment, cleaning temperature is 23 degrees Celsius, primary to clean Time is 9 minutes, is rinsed well with flushing water to production scene equipment.
Embodiment 3: it is a kind of for removing the cleaning agent of body surface radioactive pollution, it is grouped as by the group of following volumes: EHS0106 cleaning agent 40mL, compounding agent 1.5mL, solvent 200mL.
Steel plate containing radioactive soil is placed in service sink, injects above-mentioned cleaning agent into service sink, 26 degrees Celsius, It impregnates 1 hour, is rinsed well steel plate with flushing water.
By the surface of getting dirty of cleaning agent even application to production scene equipment, cleaning temperature is 25 degrees Celsius, primary to clean Time is 10 minutes, is rinsed well with flushing water to production scene equipment.
Embodiment 4: it is a kind of for removing the cleaning agent of body surface radioactive pollution, it is grouped as by the group of following volumes: EHS0106 cleaning agent 43mL, compounding agent 1.8mL, solvent 250mL.
Steel plate containing radioactive soil is placed in service sink, injects above-mentioned cleaning agent into service sink, 40 degrees Celsius, It impregnates 1.5 hours, is rinsed well steel plate with flushing water.
By the surface of getting dirty of cleaning agent even application to production scene equipment, cleaning temperature is 27 degrees Celsius, primary to clean Time is 13 minutes, is rinsed well with flushing water to production scene equipment.
Embodiment 5: it is a kind of for removing the cleaning agent of body surface radioactive pollution, it is grouped as by the group of following volumes: EHS0106 cleaning agent 45mL, compounding agent 2mL, solvent 300mL.
Steel plate containing radioactive soil is placed in service sink, injects above-mentioned cleaning agent into service sink, 50 degrees Celsius, It impregnates 2 hours, is rinsed well steel plate with flushing water.
By the surface of getting dirty of cleaning agent even application to production scene equipment, cleaning temperature is 30 degrees Celsius, primary to clean Time is 15 minutes, is rinsed well with flushing water to production scene equipment.
To Examples 1 to 5 preparation it is a kind of for remove the cleaning effect of the cleaning agent of body surface radioactive pollution into Row test, test result are shown in Table 1:
The result shows that a kind of for removing the cleaning agent of body surface radioactive pollution, to the disposable soaking and washing of steel plate, Cleaning efficiency reachable 80% or more carries out disposable spray finishing cleaning to production scene equipment, cleaning efficiency reachable 50% with On, have the characteristics that efficiently, quickly, to substrate to corrode it is small, easy to use, suitable for remove the radioactive soil of steel surface with The radioactive pollution degree of steel material and production scene equipment is greatly lowered in the cleaning of keeping a public place clean of production scene equipment, improves Steel material and production scene equipment reuse ratio reduce radioactive contamination level, improve working environment, are conducive to operator Health.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (6)

1. a kind of for removing the cleaning agent of body surface radioactive pollution, it is characterised in that: by the component of following volumes number Composition:
35~45 parts of EHS0106 cleaning agent
1~2 part of compounding agent
150~300 parts of solvent.
2. according to claim 1 a kind of for removing the cleaning agent of body surface radioactive pollution, it is characterised in that: institute Stating EHS0106 cleaning agent includes EDTA, ammonium citrate, D-9, T-C6, H-381 and butyl glycol ether.
3. according to claim 1 a kind of for removing the cleaning agent of body surface radioactive pollution, it is characterised in that: institute Stating compounding agent is N.N- dimethyl-thiocarbamic acid sodium.
4. according to claim 1 a kind of for removing the cleaning agent of body surface radioactive pollution, it is characterised in that: institute Stating solvent is deionized water.
5. according to claim 1 a kind of for removing the cleaning agent of body surface radioactive pollution, it is characterised in that: packet Include following steps:
1) mixes compounding agent with deionized water, is heated to compounding agent and is completely dissolved, spare;
2) solution that step 1) is obtained quantify by above-mentioned volume parts and be mixed by with EHS0106 cleaning agent, is stirred to it Uniformly mixing obtains cleaning agent stoste, spare;
3) mixes the cleaning agent stoste that step 2) is obtained with the solvent of above-mentioned volume parts, stirs evenly, is used In the cleaning agent for removing body surface radioactive pollution.
6. according to claim 1 a kind of for removing the cleaning agent of body surface radioactive pollution, it is characterised in that: right Following method is respectively adopted in steel plate and production scene equipment to be handled:
1) processing mode of steel plate: the steel plate containing radioactive soil is placed in service sink, and cleaning is injected into service sink Agent, cleaning way are to impregnate, and cleaning temperature is 15~50 degrees Celsius, and scavenging period is 0.5~2 hour, use and rinse after cleaning Water is rinsed steel plate can be completed and remove contamination;
2) cleaning way of the production scene equipment: by the surface of getting dirty of cleaning agent even application to production scene equipment, wherein clearly Mode is washed as spraying, cleaning temperature is 20~30 degrees Celsius, and a scavenging period is 8~15 minutes, and punching is used after cleaning Wash water is rinsed can be completed and remove contamination to production scene equipment.
CN201811589991.6A 2018-12-25 2018-12-25 It is a kind of for removing the cleaning agent of body surface radioactive pollution Pending CN109504561A (en)

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Application Number Priority Date Filing Date Title
CN201811589991.6A CN109504561A (en) 2018-12-25 2018-12-25 It is a kind of for removing the cleaning agent of body surface radioactive pollution

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Application Number Priority Date Filing Date Title
CN201811589991.6A CN109504561A (en) 2018-12-25 2018-12-25 It is a kind of for removing the cleaning agent of body surface radioactive pollution

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Publication Number Publication Date
CN109504561A true CN109504561A (en) 2019-03-22

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110452779A (en) * 2019-09-11 2019-11-15 郑州华核新材料科技有限公司 Fabric surface adhesive nuclide decontaminating agent and preparation method thereof
CN111269761A (en) * 2020-02-13 2020-06-12 金丝甲(上海)安全防范技术有限公司 Decontamination liquid and application thereof in decontamination of actinide nuclide and transition metal nuclide pollution
CN114085676A (en) * 2021-11-30 2022-02-25 中国原子能科学研究院 Radioactive contaminated soil cleaning agent composition, cleaning agent, preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1338757A (en) * 2001-09-12 2002-03-06 中国人民解放军济南军区联勤部军事医学研究所 Film for removing surficial radioactivity pollution and process for preparing its filming agent
CN104562054A (en) * 2014-12-10 2015-04-29 中核四川环保工程有限责任公司 Chemical efficient detergent as well as preparation method and using method thereof
CN104789392A (en) * 2015-04-08 2015-07-22 武汉网绿环境技术咨询有限公司 Cleaning agent for removing radionuclides and using method of cleaning agent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1338757A (en) * 2001-09-12 2002-03-06 中国人民解放军济南军区联勤部军事医学研究所 Film for removing surficial radioactivity pollution and process for preparing its filming agent
CN104562054A (en) * 2014-12-10 2015-04-29 中核四川环保工程有限责任公司 Chemical efficient detergent as well as preparation method and using method thereof
CN104789392A (en) * 2015-04-08 2015-07-22 武汉网绿环境技术咨询有限公司 Cleaning agent for removing radionuclides and using method of cleaning agent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110452779A (en) * 2019-09-11 2019-11-15 郑州华核新材料科技有限公司 Fabric surface adhesive nuclide decontaminating agent and preparation method thereof
CN111269761A (en) * 2020-02-13 2020-06-12 金丝甲(上海)安全防范技术有限公司 Decontamination liquid and application thereof in decontamination of actinide nuclide and transition metal nuclide pollution
CN114085676A (en) * 2021-11-30 2022-02-25 中国原子能科学研究院 Radioactive contaminated soil cleaning agent composition, cleaning agent, preparation method and application thereof

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Application publication date: 20190322