CN104119716A - Self-cleaning waterproof coating - Google Patents
Self-cleaning waterproof coating Download PDFInfo
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- CN104119716A CN104119716A CN201410293033.XA CN201410293033A CN104119716A CN 104119716 A CN104119716 A CN 104119716A CN 201410293033 A CN201410293033 A CN 201410293033A CN 104119716 A CN104119716 A CN 104119716A
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- 238000004140 cleaning Methods 0.000 title claims abstract description 17
- 239000011248 coating agent Substances 0.000 title abstract description 6
- 238000000576 coating method Methods 0.000 title abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 8
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims abstract description 7
- 239000010455 vermiculite Substances 0.000 claims abstract description 7
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 7
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 7
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 5
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 24
- 239000003973 paint Substances 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 13
- IBMRTYCHDPMBFN-UHFFFAOYSA-N Mono-Me ester-Pentanedioic acid Natural products COC(=O)CCCC(O)=O IBMRTYCHDPMBFN-UHFFFAOYSA-N 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- 239000004816 latex Substances 0.000 claims description 12
- 229920000126 latex Polymers 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000004581 coalescence Methods 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- 239000011734 sodium Substances 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 7
- XISFOXBYRQWDNK-UHFFFAOYSA-N 2-(2-methylphenyl)propan-2-amine;hydrochloride Chemical compound [Cl-].CC1=CC=CC=C1C(C)(C)[NH3+] XISFOXBYRQWDNK-UHFFFAOYSA-N 0.000 claims description 6
- 241001116389 Aloe Species 0.000 claims description 6
- CWNSVVHTTQBGQB-UHFFFAOYSA-N N,N-Diethyldodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CC)CC CWNSVVHTTQBGQB-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 6
- 235000011399 aloe vera Nutrition 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 claims description 6
- 239000004403 ethyl p-hydroxybenzoate Substances 0.000 claims description 6
- 229940043351 ethyl-p-hydroxybenzoate Drugs 0.000 claims description 6
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 claims description 6
- 229940059574 pentaerithrityl Drugs 0.000 claims description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000741 silica gel Substances 0.000 claims description 6
- 229910002027 silica gel Inorganic materials 0.000 claims description 6
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 6
- 229910000165 zinc phosphate Inorganic materials 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- -1 polypropylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- HNPMQPVBUMFEMD-UHFFFAOYSA-N CCCCCCCCCCCC(O)=O.NCC(O)O Chemical compound CCCCCCCCCCCC(O)=O.NCC(O)O HNPMQPVBUMFEMD-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 229960005070 ascorbic acid Drugs 0.000 abstract 1
- 235000010323 ascorbic acid Nutrition 0.000 abstract 1
- 239000011668 ascorbic acid Substances 0.000 abstract 1
- 229910001570 bauxite Inorganic materials 0.000 abstract 1
- XTDYIOOONNVFMA-UHFFFAOYSA-N dimethyl pentanedioate Chemical compound COC(=O)CCCC(=O)OC XTDYIOOONNVFMA-UHFFFAOYSA-N 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 238000009413 insulation Methods 0.000 abstract 1
- 235000021388 linseed oil Nutrition 0.000 abstract 1
- 239000000944 linseed oil Substances 0.000 abstract 1
- 229920001911 maleic anhydride grafted polypropylene Polymers 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 abstract 1
- MFXMOUUKFMDYLM-UHFFFAOYSA-L zinc;dihydrogen phosphate Chemical compound [Zn+2].OP(O)([O-])=O.OP(O)([O-])=O MFXMOUUKFMDYLM-UHFFFAOYSA-L 0.000 abstract 1
- 239000000463 material Substances 0.000 description 5
- 230000032683 aging Effects 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Abstract
The invention discloses a self-cleaning waterproof coating which comprises the following raw materials in parts by weight: 62-70 parts of silicone acrylic emulsion, 1-2 parts of linseed oil, 1-2 parts of zinc dihydrogen phosphate, 1-2 parts of sodium lauroyl sarcosine, 2-3 parts of dimethyl glutarate, 2-3 parts of maleic anhydride grafted polypropylene, 1-2 parts of dimethyl diallyl ammonium chloride, 1-2 parts of tetrabutylammonium bromide, 1.2-2 parts of laurate dihydroxyethylamide, 1-2 parts of isopropanol, 3-5 parts of nano bauxite, 6-8.5 parts of vermiculite powder, 0.5-1 part of ascorbic acid, 6-8 parts of film-forming assistant and 10-17 parts of de-ionized water. The waterproof coating has a very good heat insulation effect, and has good wiping resistance, waterproofness, self-cleaning effect, adhesiveness, acid-base resistance, corrosion resistance and storage stability and long shelf life; the formed coating is stable.
Description
Technical field
The present invention relates generally to a kind of coating, relates in particular to a kind of automatically cleaning waterproof paint.
Background technology
Traditional water-proof material mainly contains the flexible waterproof materials such as waterproof roll, waterproof paint, sealing cement, and taking cement matrix as main, adds the rigidity water-proofing material of liquid medicine agent and other auxiliary agent.The most of waterproofing work of China all adopts conventional waterproof material, conventional waterproof material exist loss of properties on aging, tensile strength low, to shortcomings such as temperature sensitives.Conventional waterproof coating is used for roof waterproof, easily cause aging, dry and cracked, be out of shape, fracture, the phenomenon such as layering, for indoor waterproof, for complex-shaped place, constructional difficulties, and to Seepage, quality is more difficult to ensure, people will spend a large amount of funds every several years and labor force reprocesses, and have not only confused people's orthobiosis, work and the production order, and affect the work-ing life of whole building self-cleaning article.In order to meet the requirement of every profession and trade to waterproof paint, production high-performance, widely used waterproof paint is necessary.
Summary of the invention
The object of the invention is just to provide a kind of automatically cleaning waterproof paint.
The present invention is achieved by the following technical solutions:
A kind of automatically cleaning waterproof paint, it is made up of the raw material of following weight parts:
Organosilicon crylic acid latex 62-70, Semen Lini oil 1-2, primary zinc phosphate 1-2, sodium lauroyl sareosine 1-2, Methyl glutarate 2-3, maleic anhydride inoculated polypropylene 2-3, dimethyl diallyl ammonium chloride 1-2, Tetrabutyl amonium bromide 1-2, lauric acid diethyl amide 1.2-2, Virahol 1-2, nano aluminum alumina 3-5, vermiculite power 6-8.5, xitix 0.5-1, film coalescence aid 6-8, deionized water 10-17;
Described film coalescence aid is made up of the raw material of following weight parts:
Organosilicon crylic acid latex 30-35, extract solution from aloe 0.3-2, ethyl p-hydroxybenzoate 1-2, Sodium Silicofluoride 0.8-1, tetramethylolmethane 2-3, dibutyl tin laurate 0.1-0.2, micropowder silica gel 2-4, trimethyl benzyl ammonia chloride 0.8-2, deionized water 70-75;
Micropowder silica gel is mixed with tetramethylolmethane, at 65-70 DEG C, be uniformly mixed 2-4 minute, add 30-40%, the trimethyl benzyl ammonia chloride of above-mentioned deionized water weight, 100-200 rev/min of dispersed with stirring 6-12 minute, obtains dispersion liquid;
Ethyl p-hydroxybenzoate is mixed with extract solution from aloe, after stirring, join in organosilicon crylic acid latex, insulated and stirred 10-15 minute at 35-40 DEG C, add above-mentioned dispersion liquid, dibutyl tin laurate, be stirred to normal temperature, add the each raw material of residue, 300-400 rev/min of dispersed with stirring 7-10 minute, obtains described film coalescence aid.
A preparation method for automatically cleaning waterproof paint, comprises the following steps:
Sodium lauroyl sareosine is joined in deionized water, add dimethyl diallyl ammonium chloride, vermiculite power after stirring, 50-70 rev/min of dispersed with stirring 3-5 minute, adds Methyl glutarate, stirs;
Primary zinc phosphate, nano aluminum alumina are mixed, add lauric acid diethyl amide, Virahol, be uniformly mixed 3-5 minute at 60-70 DEG C, join in organosilicon crylic acid latex, stir;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 500-600 rev/min of dispersed with stirring 20-30 minute, obtains described automatically cleaning waterproof paint.
Advantage of the present invention is:
Waterproof paint of the present invention has good heat insulating effect, and resistance to wiping is strong, and water-repellancy is strong, and automatically cleaning is effective, and the film of formation is stable, and cohesiveness is strong, resistance to acids and bases, good corrosion resistance, excellent storage stability, long quality-guarantee period.
Embodiment
Embodiment 1
A kind of automatically cleaning waterproof paint, it by following weight parts (kilogram) raw material form:
Organosilicon crylic acid latex 70, Semen Lini oil 2, primary zinc phosphate 1, sodium lauroyl sareosine 2, Methyl glutarate 3, maleic anhydride inoculated polypropylene 3, dimethyl diallyl ammonium chloride 1, Tetrabutyl amonium bromide 1, lauric acid diethyl amide 1.2, Virahol 2, nano aluminum alumina 3, vermiculite power 8.5, xitix 0.5, film coalescence aid 8, deionized water 17;
Described film coalescence aid is made up of the raw material of following weight parts:
Organosilicon crylic acid latex 30-35, extract solution from aloe 0.3, ethyl p-hydroxybenzoate 2, Sodium Silicofluoride 0.8, tetramethylolmethane 3, dibutyl tin laurate 0.2, micropowder silica gel 4, trimethyl benzyl ammonia chloride 0.8, deionized water 75;
Micropowder silica gel is mixed with tetramethylolmethane, at 70 DEG C, is uniformly mixed 2 minutes, add above-mentioned deionized water weight 40%, trimethyl benzyl ammonia chloride, 200 revs/min of dispersed with stirring 12 minutes, obtain dispersion liquid;
Ethyl p-hydroxybenzoate is mixed with extract solution from aloe, after stirring, join in organosilicon crylic acid latex, insulated and stirred 15 minutes at 40 DEG C, add above-mentioned dispersion liquid, dibutyl tin laurate, be stirred to normal temperature, add the each raw material of residue, 400 revs/min of dispersed with stirring 10 minutes, obtain described film coalescence aid.
A preparation method for automatically cleaning waterproof paint, comprises the following steps:
Sodium lauroyl sareosine is joined in deionized water, add dimethyl diallyl ammonium chloride, vermiculite power after stirring, 70 revs/min of dispersed with stirring 3-5 minute, add Methyl glutarate, stir;
Primary zinc phosphate, nano aluminum alumina are mixed, add lauric acid diethyl amide, Virahol, be uniformly mixed 5 minutes at 70 DEG C, join in organosilicon crylic acid latex, stir;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 600 revs/min of dispersed with stirring 30 minutes, obtain described automatically cleaning waterproof paint.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).
Claims (2)
1. an automatically cleaning waterproof paint, is characterized in that what it was made up of the raw material of following weight parts:
Organosilicon crylic acid latex 62-70, Semen Lini oil 1-2, primary zinc phosphate 1-2, sodium lauroyl sareosine 1-2, Methyl glutarate 2-3, maleic anhydride inoculated polypropylene 2-3, dimethyl diallyl ammonium chloride 1-2, Tetrabutyl amonium bromide 1-2, lauric acid diethyl amide 1.2-2, Virahol 1-2, nano aluminum alumina 3-5, vermiculite power 6-8.5, xitix 0.5-1, film coalescence aid 6-8, deionized water 10-17;
Described film coalescence aid is made up of the raw material of following weight parts:
Organosilicon crylic acid latex 30-35, extract solution from aloe 0.3-2, ethyl p-hydroxybenzoate 1-2, Sodium Silicofluoride 0.8-1, tetramethylolmethane 2-3, dibutyl tin laurate 0.1-0.2, micropowder silica gel 2-4, trimethyl benzyl ammonia chloride 0.8-2, deionized water 70-75;
Micropowder silica gel is mixed with tetramethylolmethane, at 65-70 DEG C, be uniformly mixed 2-4 minute, add 30-40%, the trimethyl benzyl ammonia chloride of above-mentioned deionized water weight, 100-200 rev/min of dispersed with stirring 6-12 minute, obtains dispersion liquid;
Ethyl p-hydroxybenzoate is mixed with extract solution from aloe, after stirring, join in organosilicon crylic acid latex, insulated and stirred 10-15 minute at 35-40 DEG C, add above-mentioned dispersion liquid, dibutyl tin laurate, be stirred to normal temperature, add the each raw material of residue, 300-400 rev/min of dispersed with stirring 7-10 minute, obtains described film coalescence aid.
2. a preparation method for automatically cleaning waterproof paint as claimed in claim 1, is characterized in that comprising the following steps:
Sodium lauroyl sareosine is joined in deionized water, add dimethyl diallyl ammonium chloride, vermiculite power after stirring, 50-70 rev/min of dispersed with stirring 3-5 minute, adds Methyl glutarate, stirs;
Primary zinc phosphate, nano aluminum alumina are mixed, add lauric acid diethyl amide, Virahol, be uniformly mixed 3-5 minute at 60-70 DEG C, join in organosilicon crylic acid latex, stir;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 500-600 rev/min of dispersed with stirring 20-30 minute, obtains described automatically cleaning waterproof paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410293033.XA CN104119716B (en) | 2014-06-26 | 2014-06-26 | A kind of automatically cleaning water-repellent paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410293033.XA CN104119716B (en) | 2014-06-26 | 2014-06-26 | A kind of automatically cleaning water-repellent paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104119716A true CN104119716A (en) | 2014-10-29 |
| CN104119716B CN104119716B (en) | 2016-06-15 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410293033.XA Active CN104119716B (en) | 2014-06-26 | 2014-06-26 | A kind of automatically cleaning water-repellent paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104119716B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104313617A (en) * | 2014-11-07 | 2015-01-28 | 合肥大安印刷有限责任公司 | Rust-removing metal surface cleaning agent and preparation method thereof |
| CN104559695A (en) * | 2015-01-08 | 2015-04-29 | 上海贝能环保科技有限公司 | Healthy environmental-friendly paint and preparation method thereof |
| CN107245294A (en) * | 2017-08-08 | 2017-10-13 | 合肥安力电力工程有限公司 | A kind of anti-aging street lamp coating and preparation method thereof |
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| CN101348595A (en) * | 2008-07-28 | 2009-01-21 | 北京大学 | Fluorine-silicon modified self-crosslinking acrylic ester emulsion and preparation thereof |
| WO2009125478A1 (en) * | 2008-04-09 | 2009-10-15 | Ｓｃｉ－Ｐａｉｎｔ Ｊａｐａｎ株式会社 | Thermal insulation coating material |
| CN103540213A (en) * | 2013-09-26 | 2014-01-29 | 芜湖杰诺科技有限公司 | Low-cost, easy-to-clean and waterproof paint |
| CN103602193A (en) * | 2013-11-29 | 2014-02-26 | 深圳市安品有机硅材料有限公司 | Priming paint for water-borne heavy anti-corrosion coating and preparation method thereof |
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2014
- 2014-06-26 CN CN201410293033.XA patent/CN104119716B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2009125478A1 (en) * | 2008-04-09 | 2009-10-15 | Ｓｃｉ－Ｐａｉｎｔ Ｊａｐａｎ株式会社 | Thermal insulation coating material |
| CN101348595A (en) * | 2008-07-28 | 2009-01-21 | 北京大学 | Fluorine-silicon modified self-crosslinking acrylic ester emulsion and preparation thereof |
| CN103540213A (en) * | 2013-09-26 | 2014-01-29 | 芜湖杰诺科技有限公司 | Low-cost, easy-to-clean and waterproof paint |
| CN103602193A (en) * | 2013-11-29 | 2014-02-26 | 深圳市安品有机硅材料有限公司 | Priming paint for water-borne heavy anti-corrosion coating and preparation method thereof |
Non-Patent Citations (1)
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| 何庆迪等: "自清洁涂料的技术发展", 《涂料技术与文摘》, no. 7, 31 July 2012 (2012-07-31), pages 30 - 34 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104313617A (en) * | 2014-11-07 | 2015-01-28 | 合肥大安印刷有限责任公司 | Rust-removing metal surface cleaning agent and preparation method thereof |
| CN104559695A (en) * | 2015-01-08 | 2015-04-29 | 上海贝能环保科技有限公司 | Healthy environmental-friendly paint and preparation method thereof |
| CN104559695B (en) * | 2015-01-08 | 2017-01-18 | 上海贝能环保科技有限公司 | Healthy environmental-friendly paint and preparation method thereof |
| CN107245294A (en) * | 2017-08-08 | 2017-10-13 | 合肥安力电力工程有限公司 | A kind of anti-aging street lamp coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104119716B (en) | 2016-06-15 |
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Effective date of registration: 20240410 Address after: 262700 North Head of Pengjia Daokou San Village, Taitou Town, Shouguang City, Weifang City, Shandong Province Patentee after: Shandong Taiyun waterproof material Co.,Ltd. Country or region after: China Address before: No.18, Shaoji Ershi Road, Banta Town, Laian County, Chuzhou City, Anhui Province Patentee before: ANHUI KUAILAI WATERPROOFING & ANTI-CORROSION Co.,Ltd. Country or region before: China |