CN104277619A - Hydrophobic self-cleaning paint - Google Patents

Hydrophobic self-cleaning paint Download PDF

Info

Publication number
CN104277619A
CN104277619A CN201410449245.2A CN201410449245A CN104277619A CN 104277619 A CN104277619 A CN 104277619A CN 201410449245 A CN201410449245 A CN 201410449245A CN 104277619 A CN104277619 A CN 104277619A
Authority
CN
China
Prior art keywords
parts
minute
deionized water
add
mentioned
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410449245.2A
Other languages
Chinese (zh)
Inventor
夏明才
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Lulei Chemical (lu'an) Co Ltd
Original Assignee
Shanghai Lulei Chemical (lu'an) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Lulei Chemical (lu'an) Co Ltd filed Critical Shanghai Lulei Chemical (lu'an) Co Ltd
Priority to CN201410449245.2A priority Critical patent/CN104277619A/en
Publication of CN104277619A publication Critical patent/CN104277619A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C09D5/1668—Vinyl-type polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a hydrophobic self-cleaning paint which is prepared from the following raw materials in parts by weight: 0.8-2 parts of epoxy chloropropane, 3-4 parts of polyvinylidene fluoride, 0.5-1 part of hydroxypropyl methylcellulose, 2-3 parts of lithium silicate, 2-3 parts of dibutyl benzene dicarboxylate, 2-4 parts of pentaerythritol, 0.6-1 part of antioxidant DLTP (dilauryl thiodipropionate), 2-4 parts of stalactite powder, 10-14 parts of wollastonite powder, 1-3 parts of polyoxyethylene oleate, 120-140 parts of butyl acrylate, 160-200 parts of vinyl acetate, 500-700 parts of deionized water, 0.4-2 parts of sodium persulfate, 2-3 parts of sodium diisopropyl naphthalene sulfonate, 0.7-2 parts of fatty alcohol polyethenoxy ether ammonium sulfate and 3-6 parts of binding assistant. The paint has the advantages of favorable stain resistance, favorable leakage resistance and the like, can obviously improve the problems of whitening when meeting water and dust adhesion in the wall, prevents the coated film from discoloration, cracking and the like, and can ensure the building outer wall surface to be clean and luxuriant.

Description

A kind of hydrophobic chalking paint
?
Technical field
The present invention relates generally to paint field, particularly relates to a kind of hydrophobic chalking paint.
Background technology
Be applied to body surface can be formed there is protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprise oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.Paint take organic solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is used water dissolving or the coating with water-dispersion.Coating is as one of the main material of house decoration, and the large percentage accounted in decorations, buys the whether qualified environment directly having influence on overall finishing effect and room of coating, sometimes even can produce harm greatly to the health of human body.At present along with the generation of various coating, the quality requirements of coating is also improved constantly, and improve constantly coating quality and can play very large help for building, life.
Summary of the invention
The object of the invention is just to provide a kind of hydrophobic chalking paint.
The present invention is achieved by the following technical solutions:
A kind of hydrophobic chalking paint, is characterized in that what it was made up of the raw material of following weight parts:
Epoxy chloropropane 0.8-2, polyvinylidene difluoride (PVDF) 3-4, Vltra tears 0.5-1, lithium silicate 2-3, phthalic acid dibutyl ester 2-3, tetramethylolmethane 2-4, anti-oxidant DLTP 0.6-1, Stalactitum powder 2-4, wollastonite powder 10-14, polyoxyethylene oleic acid ester 1-3, butyl acrylate 120-140, vinyl acetate 160-200, deionized water 500-700, Sodium Persulfate 0.4-2, di-isopropyl sodium naphthalene sulfonate 2-3, AESA 0.7-2, adhesive aid 3-6;
Described adhesive aid is made up of each raw material of following weight parts:
Organosilicon crylic acid latex 30-35, methyl methacrylate 2-4, exsiccated ammonium alum 1-2, emulsifier op-10 0.5-1, ammonium persulphate 0.7-1, Triethylene glycol dimethacrylate 2-3, triolein 1-2, titania powder 2-4, deionized water 10-14;
By titania powder, Triethylene glycol dimethacrylate, triolein mixing, 3-4 minute is uniformly mixed at 70-75 DEG C, add 40-50%, the ammonium persulphate of above-mentioned deionized water weight, 100-150 rev/min of dispersed with stirring 10-13 minute, obtains dispersion liquid;
Emulsifier op-10 and exsiccated ammonium alum are mixed to join in remaining deionized water, at 60-70 DEG C, are uniformly mixed 3-5 minute, add methyl methacrylate, dispersion liquid, be stirred to normal temperature, add each raw material of residue, obtain described adhesive aid.
A preparation method for hydrophobic chalking paint, is characterized in that comprising the following steps:
(1) Sodium Persulfate is joined in the 10-15% of above-mentioned deionized water weight, stir, obtain initiator solution;
(2) by di-isopropyl sodium naphthalene sulfonate, tetramethylolmethane mixing, add the 60-70% of residue deionized water weight, AESA is added after stirring, insulated and stirred 10-20 minute at 50-60 DEG C, raised temperature is 70-80 DEG C, adds polyoxyethylene oleic acid ester, insulated and stirred 4-10 minute, be cooled to normal temperature, obtain pre-emulsion;
(3) the 40-50% mixing of the 30-40% of aforesaid propylene acid butyl ester weight, vinyl acetate weight is got, add above-mentioned pre-emulsion, 30-35 minute is uniformly mixed at 60-65 DEG C, raised temperature is 70-75 DEG C, add above-mentioned initiator solution, treat that emulsion is blue phase, insulation 60-70 minute, obtains seed emulsion;
(4) by remaining butyl acrylate, vinyl acetate mixing, insulated and stirred 20-30 minute at 60-80 DEG C, obtains mix monomer;
(5) in above-mentioned seed emulsion, drip mix monomer, time for adding is 90-120 minute, after dropwising, is incubated 50-60 minute, adds anti-oxidant DLTP, be uniformly mixed at 80-90 DEG C, cooling, filters discharging with 200-250 eye mesh screen;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described hydrophobic chalking paint.
Advantage of the present invention is:
Coating anti-soil of the present invention, leakage resistance are good, significantly can improve the advantage such as the whiting of chance water, dust attachment of body of wall, prevent film coated surface from occurring the phenomenons such as variable color cracking can ensureing that skin surface energy keeps clean magnificent surface muchly.The titania powder added in adhesive aid of the present invention can improve resistivity against fire and surface resistive, methyl methacrylate, exsiccated ammonium alum, emulsifier op-10, triolein mix with organosilicon crylic acid latex and effectively can improve cohesive strength, ammonium persulphate can promote the consistency between each raw material, improves the surface stability of finished product.
Embodiment
Embodiment 1
A kind of hydrophobic chalking paint, is characterized in that what it was made up of the raw material of following weight parts:
Epoxy chloropropane 0.8, polyvinylidene difluoride (PVDF) 4, Vltra tears 0.5, lithium silicate 2, phthalic acid dibutyl ester 2, tetramethylolmethane 4, anti-oxidant DLTP 0.6, Stalactitum powder 4, wollastonite powder 14, polyoxyethylene oleic acid ester 3, butyl acrylate 120-140, vinyl acetate 200, deionized water 700, Sodium Persulfate 0.4, di-isopropyl sodium naphthalene sulfonate 3, AESA 0.7, adhesive aid 6;
Described adhesive aid is made up of each raw material of following weight parts:
Organosilicon crylic acid latex 35, methyl methacrylate 4, exsiccated ammonium alum 2, emulsifier op-10 0.5, ammonium persulphate 0.7, Triethylene glycol dimethacrylate 3, triolein 2, titania powder 4, deionized water 14;
By titania powder, Triethylene glycol dimethacrylate, triolein mixing, be uniformly mixed 4 minutes, add 50% of above-mentioned deionized water weight, ammonium persulphate at 75 DEG C, 150 revs/min of dispersed with stirring 13 minutes, obtain dispersion liquid;
Emulsifier op-10 and exsiccated ammonium alum are mixed to join in remaining deionized water, at 60 DEG C, are uniformly mixed 5 minutes, add methyl methacrylate, dispersion liquid, be stirred to normal temperature, add each raw material of residue, obtain described adhesive aid.
A preparation method for hydrophobic chalking paint, is characterized in that comprising the following steps:
(1) Sodium Persulfate is joined in the 10-15% of above-mentioned deionized water weight, stir, obtain initiator solution;
(2) by di-isopropyl sodium naphthalene sulfonate, tetramethylolmethane mixing, add 70% of residue deionized water weight, AESA is added after stirring, insulated and stirred 20 minutes at 60 DEG C, raised temperature is 80 DEG C, adds polyoxyethylene oleic acid ester, insulated and stirred 10 minutes, be cooled to normal temperature, obtain pre-emulsion;
(3) get 40% of aforesaid propylene acid butyl ester weight, 50% mixing of vinyl acetate weight, add above-mentioned pre-emulsion, at 65 DEG C, be uniformly mixed 35 minutes, raised temperature is 75 DEG C, adds above-mentioned initiator solution, treats that emulsion is blue phase, be incubated 70 minutes, obtain seed emulsion;
(4) by remaining butyl acrylate, vinyl acetate mixing, at 80 DEG C, insulated and stirred 30 minutes, obtains mix monomer;
(5) in above-mentioned seed emulsion, drip mix monomer, time for adding is 120 minutes, after dropwising, and is incubated 60 minutes, adds anti-oxidant DLTP, be uniformly mixed at 90 DEG C, and cooling filters discharging with 250 eye mesh screens;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 1200 revs/min of dispersed with stirring 20-30 minute, obtain described hydrophobic chalking paint.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).

Claims (2)

1. a hydrophobic chalking paint, is characterized in that what it was made up of the raw material of following weight parts:
Epoxy chloropropane 0.8-2, polyvinylidene difluoride (PVDF) 3-4, Vltra tears 0.5-1, lithium silicate 2-3, phthalic acid dibutyl ester 2-3, tetramethylolmethane 2-4, anti-oxidant DLTP 0.6-1, Stalactitum powder 2-4, wollastonite powder 10-14, polyoxyethylene oleic acid ester 1-3, butyl acrylate 120-140, vinyl acetate 160-200, deionized water 500-700, Sodium Persulfate 0.4-2, di-isopropyl sodium naphthalene sulfonate 2-3, AESA 0.7-2, adhesive aid 3-6;
Described adhesive aid is made up of each raw material of following weight parts:
Organosilicon crylic acid latex 30-35, methyl methacrylate 2-4, exsiccated ammonium alum 1-2, emulsifier op-10 0.5-1, ammonium persulphate 0.7-1, Triethylene glycol dimethacrylate 2-3, triolein 1-2, titania powder 2-4, deionized water 10-14;
By titania powder, Triethylene glycol dimethacrylate, triolein mixing, 3-4 minute is uniformly mixed at 70-75 DEG C, add 40-50%, the ammonium persulphate of above-mentioned deionized water weight, 100-150 rev/min of dispersed with stirring 10-13 minute, obtains dispersion liquid;
Emulsifier op-10 and exsiccated ammonium alum are mixed to join in remaining deionized water, at 60-70 DEG C, are uniformly mixed 3-5 minute, add methyl methacrylate, dispersion liquid, be stirred to normal temperature, add each raw material of residue, obtain described adhesive aid.
2. a preparation method for hydrophobic chalking paint as claimed in claim 1, is characterized in that comprising the following steps:
(1) Sodium Persulfate is joined in the 10-15% of above-mentioned deionized water weight, stir, obtain initiator solution;
(2) by di-isopropyl sodium naphthalene sulfonate, tetramethylolmethane mixing, add the 60-70% of residue deionized water weight, AESA is added after stirring, insulated and stirred 10-20 minute at 50-60 DEG C, raised temperature is 70-80 DEG C, adds polyoxyethylene oleic acid ester, insulated and stirred 4-10 minute, be cooled to normal temperature, obtain pre-emulsion;
(3) the 40-50% mixing of the 30-40% of aforesaid propylene acid butyl ester weight, vinyl acetate weight is got, add above-mentioned pre-emulsion, 30-35 minute is uniformly mixed at 60-65 DEG C, raised temperature is 70-75 DEG C, add above-mentioned initiator solution, treat that emulsion is blue phase, insulation 60-70 minute, obtains seed emulsion;
(4) by remaining butyl acrylate, vinyl acetate mixing, insulated and stirred 20-30 minute at 60-80 DEG C, obtains mix monomer;
(5) in above-mentioned seed emulsion, drip mix monomer, time for adding is 90-120 minute, after dropwising, is incubated 50-60 minute, adds anti-oxidant DLTP, be uniformly mixed at 80-90 DEG C, cooling, filters discharging with 200-250 eye mesh screen;
(6) material above-mentioned steps (5) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described hydrophobic chalking paint.
CN201410449245.2A 2014-09-04 2014-09-04 Hydrophobic self-cleaning paint Pending CN104277619A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410449245.2A CN104277619A (en) 2014-09-04 2014-09-04 Hydrophobic self-cleaning paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410449245.2A CN104277619A (en) 2014-09-04 2014-09-04 Hydrophobic self-cleaning paint

Publications (1)

Publication Number Publication Date
CN104277619A true CN104277619A (en) 2015-01-14

Family

ID=52252985

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410449245.2A Pending CN104277619A (en) 2014-09-04 2014-09-04 Hydrophobic self-cleaning paint

Country Status (1)

Country Link
CN (1) CN104277619A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107142005A (en) * 2017-05-17 2017-09-08 马鞍山瑞美塑业有限公司 A kind of antifouling plastics put the preparation method of glass box
CN110592928A (en) * 2019-08-27 2019-12-20 安徽太平洋特种网业有限公司 Processing method for improving anti-pollution stability of flat filament dry net

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1696219A (en) * 2004-05-11 2005-11-16 张海波 Environmental protection type Nano Coating
CN103145912A (en) * 2013-03-11 2013-06-12 北京科技大学 Preparation method of titanium dioxide nano powder-modified fluorine-containing acrylate emulsion

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1696219A (en) * 2004-05-11 2005-11-16 张海波 Environmental protection type Nano Coating
CN103145912A (en) * 2013-03-11 2013-06-12 北京科技大学 Preparation method of titanium dioxide nano powder-modified fluorine-containing acrylate emulsion

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107142005A (en) * 2017-05-17 2017-09-08 马鞍山瑞美塑业有限公司 A kind of antifouling plastics put the preparation method of glass box
CN110592928A (en) * 2019-08-27 2019-12-20 安徽太平洋特种网业有限公司 Processing method for improving anti-pollution stability of flat filament dry net

Similar Documents

Publication Publication Date Title
CN104449121A (en) Antibacterial anticorrosive coating
CN104263122A (en) Stable paint
CN104449119A (en) Anti-aging rosin coating
CN104449118A (en) Environment-friendly reflective coating
CN104277619A (en) Hydrophobic self-cleaning paint
CN104263127A (en) Insulating crack-resistant coating for exterior wall
CN104263125A (en) Polymer exterior wall paint
CN104231695A (en) Green antibacterial coating for interior wall
CN104250504A (en) High-viscosity silicone-acrylic paint
CN104263036A (en) Bactericidal organic silicon coating
CN104277620A (en) Environment-friendly wall coating
CN104277621A (en) Waterproof coating for building
CN104263128A (en) Resin-base paint
CN104231771A (en) Lightweight coating
CN104263031A (en) Smooth bubble-free decorative paint
CN104449120A (en) Environment-friendly impermeable coating
CN104231770A (en) Fireproof coating
CN104231766A (en) Sound-absorbing and heat-insulating paint
CN104250485A (en) Low-cost energy-saving paint
CN104449115A (en) Flexible fluorinated coating
CN104231828A (en) Green and natural antibacterial coating
CN104356703A (en) Decorative type hard coating
CN104263029A (en) Anti-cracking and waterproof coating for wall body
CN104263139A (en) Fiber-reinforced paint
CN104356835A (en) Macromolecular emulsion paint

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20150114

RJ01 Rejection of invention patent application after publication