CN107142005A - A kind of antifouling plastics put the preparation method of glass box - Google Patents
A kind of antifouling plastics put the preparation method of glass box Download PDFInfo
- Publication number
- CN107142005A CN107142005A CN201710345625.5A CN201710345625A CN107142005A CN 107142005 A CN107142005 A CN 107142005A CN 201710345625 A CN201710345625 A CN 201710345625A CN 107142005 A CN107142005 A CN 107142005A
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- China
- Prior art keywords
- parts
- glass box
- antifouling
- plastics
- preparation
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention disclose the preparation method that a kind of antifouling plastics put glass box, and plastics after shaping put uniform smearing antifouling paint on glass box, plastics are put into a glass box is immediately after put into ultrasonic wave and handle 10 15min, and wherein antifouling paint is made up of the component of following parts by weight：50 60 parts of acroleic acid polyurethane, 47 parts of cyanurate melamine ester, 35 parts of castor oil, 25 parts of heptyl paraben, 14 parts of trifluoroethanol, 35 parts of m-trifluoromethylbenzoic acid methyl esters, 68 parts of perflexane, 0.4 0.6 parts of magnesia, 0.1 0.3 parts of titanium dioxide.The antifouling plastics that the present invention is provided put the preparation method of glass box, and operating method is simple, and anti-fouling effect significantly, may be such that the superincumbent tea stain of contamination, grease, grieshoch can be wiped easily, further improve the quality that plastics put glass box.
Description
Technical field
The invention belongs to the making field that plastics put cup, and in particular to a kind of antifouling plastics put the preparation method of glass box.
Background technology
Auto plasticses put in glass box automobile middle control room a very practical small device, and it is usually by makrolon（PC）、
Polymethyl methacrylate（PMMA）And acrylonitrile-butadiene-styrene copolymer（ABS）Base material is made, and it has strong
The characteristics of degree is high, heat resistance is superior.Because plastics put glass box during use, it is possible to by cup tea pollution or
Remaining spot pollutes, and influences its aesthetic property, and presently commercially available plastics put glass box and do not have good anti-fouling effect.
The content of the invention
In order to solve the above problems, the present invention provides the preparation method that a kind of antifouling plastics put glass box.
The present invention is achieved by the following technical solutions.
A kind of antifouling plastics put the preparation method of glass box, it is characterised in that plastics after shaping are put uniform on glass box
Antifouling paint is smeared, plastics are put into a glass box is immediately after put into ultrasonic wave and handle 10-15min, wherein antifouling paint is by following
The component of parts by weight is made：50-60 parts of acroleic acid polyurethane, 4-7 parts of cyanurate melamine ester, 3-5 parts of castor oil, nipalgin
2-5 parts of heptyl ester, 1-4 parts of trifluoroethanol, 3-5 parts of m-trifluoromethylbenzoic acid methyl esters, 6-8 parts of perflexane, magnesia 0.4-0.6
Part, 0.1-0.3 parts of titanium dioxide.
Specifically, active constituent content is 99% in the cyanurate melamine ester, and its Average Particle Diameters is 10 μm.
Specifically, water content is 0.2% in the castor oil, and insoluble impurities is 0.02%.
Specifically, the trifluoroethanol, m-trifluoromethylbenzoic acid methyl esters, the degree of purity of perflexane are technical pure.
Specifically, the antifouling paint is made of following methods：By cyanurate melamine ester, castor oil, nipalgin
Heptyl ester, trifluoroethanol, m-trifluoromethylbenzoic acid methyl esters, perflexane, magnesia, titanium dioxide sequentially add the poly- ammonia of acrylic acid
In ester, feeding interval is 3min, lasting stirring, after the completion of charging, continues to stir after 15min, finished product.
Technical scheme more than, the beneficial effects of the invention are as follows：
The antifouling plastics that the present invention is provided put the preparation method of glass box, and operating method is simple, and anti-fouling effect significantly, may be such that contamination
Superincumbent tea stain, grease, grieshoch can be wiped easily, further improve the quality that plastics put glass box.Wherein, trifluoro
Ethanol, m-trifluoromethylbenzoic acid methyl esters, perflexane can effectively increase plastics and put glass a box face coat and water and grease etc.
The contact angle of spot so that spot is easy to be wiped putting a glass box surface, greatly improves its antifouling capacity；Add due to fluorine-containing
Plus agent is during use, it is found that it can be reduced in the firmness that coating is combined with matrix, the present invention by adding cyanogen
Urea acid melamine ester, castor oil composition, effectively solve this problem, improve the firm journey that coating is combined with matrix
Degree so that coating is difficult for drop-off, can effectively make it that putting glass box has excellent antifouling capacity for a long time；Heptyl paraben, oxidation
Magnesium, titanium dioxide synergy, can not only strengthen the mechanical property of coating, moreover it is possible to so that coating has certain bacteriostasis；
Using ultrasonication, it can cause in not dry coating, what fluorine compounds were tried one's best is gathered in the surface of coating, further lifting
The antifouling capacity of coating.
Embodiment
Following examples are used to illustrate the present invention, but can not be used for limiting the scope of the present invention.The reality used in embodiment
The condition of applying can be for further adjustments according to the condition of producer, and unaccounted implementation condition is usually conventional laboratory conditions.
Embodiment 1
A kind of antifouling plastics put the preparation method of glass box, it is characterised in that plastics after shaping are put and uniformly smeared on glass box
Plastics are put a glass box immediately after and are put into ultrasonic wave and handle 10min by antifouling paint, and wherein antifouling paint is by following parts by weight
Component is made：50 parts of acroleic acid polyurethane, 4 parts of cyanurate melamine ester, 3 parts of castor oil, 2 parts of heptyl paraben, trifluoro second
1 part of alcohol, 3 parts of m-trifluoromethylbenzoic acid methyl esters, 6 parts of perflexane, 0.4 part of magnesia, 0.1 part of titanium dioxide.
Specifically, active constituent content is 99% in the cyanurate melamine ester, and its Average Particle Diameters is 10 μm.
Specifically, water content is 0.2% in the castor oil, and insoluble impurities is 0.02%.
Specifically, the trifluoroethanol, m-trifluoromethylbenzoic acid methyl esters, the degree of purity of perflexane are technical pure.
Specifically, the antifouling paint is made of following methods：By cyanurate melamine ester, castor oil, nipalgin
Heptyl ester, trifluoroethanol, m-trifluoromethylbenzoic acid methyl esters, perflexane, magnesia, titanium dioxide sequentially add the poly- ammonia of acrylic acid
In ester, feeding interval is 3min, lasting stirring, after the completion of charging, continues to stir after 15min, finished product.
Embodiment 2
A kind of antifouling plastics put the preparation method of glass box, it is characterised in that plastics after shaping are put and uniformly smeared on glass box
Plastics are put a glass box immediately after and are put into ultrasonic wave and handle 13min by antifouling paint, and wherein antifouling paint is by following parts by weight
Component is made：55 parts of acroleic acid polyurethane, 6 parts of cyanurate melamine ester, 4 parts of castor oil, 3 parts of heptyl paraben, trifluoro second
2 parts of alcohol, 4 parts of m-trifluoromethylbenzoic acid methyl esters, 7 parts of perflexane, 0.5 part of magnesia, 0.2 part of titanium dioxide.
Specifically, active constituent content is 99% in the cyanurate melamine ester, and its Average Particle Diameters is 10 μm.
Specifically, water content is 0.2% in the castor oil, and insoluble impurities is 0.02%.
Specifically, the trifluoroethanol, m-trifluoromethylbenzoic acid methyl esters, the degree of purity of perflexane are technical pure.
Specifically, the antifouling paint is made of following methods：By cyanurate melamine ester, castor oil, nipalgin
Heptyl ester, trifluoroethanol, m-trifluoromethylbenzoic acid methyl esters, perflexane, magnesia, titanium dioxide sequentially add the poly- ammonia of acrylic acid
In ester, feeding interval is 3min, lasting stirring, after the completion of charging, continues to stir after 15min, finished product.
Embodiment 3
A kind of antifouling plastics put the preparation method of glass box, it is characterised in that plastics after shaping are put and uniformly smeared on glass box
Plastics are put a glass box immediately after and are put into ultrasonic wave and handle 15min by antifouling paint, and wherein antifouling paint is by following parts by weight
Component is made：60 parts of acroleic acid polyurethane, 7 parts of cyanurate melamine ester, 5 parts of castor oil, 5 parts of heptyl paraben, trifluoro second
4 parts of alcohol, 5 parts of m-trifluoromethylbenzoic acid methyl esters, 8 parts of perflexane, 0.6 part of magnesia, 0.3 part of titanium dioxide.
Specifically, active constituent content is 99% in the cyanurate melamine ester, and its Average Particle Diameters is 10 μm.
Specifically, water content is 0.2% in the castor oil, and insoluble impurities is 0.02%.
Specifically, the trifluoroethanol, m-trifluoromethylbenzoic acid methyl esters, the degree of purity of perflexane are technical pure.
Specifically, the antifouling paint is made of following methods：By cyanurate melamine ester, castor oil, nipalgin
Heptyl ester, trifluoroethanol, m-trifluoromethylbenzoic acid methyl esters, perflexane, magnesia, titanium dioxide sequentially add the poly- ammonia of acrylic acid
In ester, feeding interval is 3min, lasting stirring, after the completion of charging, continues to stir after 15min, finished product.
The method in embodiment is used respectively, antifouling plastics are made and put a glass box, as test group, then chooses one commercially available common
Plastics put glass box and carry out durability against pollution test as a control group,
Test 1：Plastics are put into a glass box to be put into edible oil, then taken out, it is hanging to stand after 1min, wiped with rag, check each
Plastics put the adhesion condition of greasy dirt on glass box；
Test 2：Plastics are put into a glass box to be put into sewage, stood after 5min, the spot situation for checking its surface contamination is taken out；
Test result is as shown in table 1：
The plastics of table 1 put the antifouling test of glass box
| Project | Greasy dirt adheres to | Spot adhesion condition |
| Embodiment 1 | It is completely wiped off | Adhesion amount is few |
| Embodiment 2 | It is completely wiped off | Adhesion amount is few |
| Embodiment 3 | It is completely wiped off | Adhesion amount is few |
| Control group | Remaining more greasy dirt | Larger adhesion amount |
As shown in Table 1, the antifouling plastics that the present invention is provided put the preparation method of glass box, and obtained plastics are put glass box anti-fouling effect and shown
Write, be obviously improved the quality of product.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can
To be improved or converted according to the above description, all these modifications and variations should all belong to the guarantor of appended claims of the present invention
Protect scope.
Claims (5)
1. a kind of antifouling plastics put the preparation method of glass box, it is characterised in that plastics after shaping are put and uniformly applied on glass box
Antifouling paint is smeared, plastics are put into a glass box is immediately after put into ultrasonic wave and handle 10-15min, wherein antifouling paint is by following heavy
The component of amount part is made：50-60 parts of acroleic acid polyurethane, 4-7 parts of cyanurate melamine ester, 3-5 parts of castor oil, nipalgin heptan
2-5 parts of ester, 1-4 parts of trifluoroethanol, 3-5 parts of m-trifluoromethylbenzoic acid methyl esters, 6-8 parts of perflexane, magnesia 0.4-0.6
Part, 0.1-0.3 parts of titanium dioxide.
2. a kind of antifouling plastics according to claim 1 put the preparation method of glass box, it is characterised in that the cyanurate
Active constituent content is 99% in melamine ester, and its Average Particle Diameters is 10 μm.
3. a kind of antifouling plastics according to claim 1 put the preparation method of glass box, it is characterised in that the castor oil
Middle water content is 0.2%, and insoluble impurities is 0.02%.
4. a kind of antifouling plastics according to claim 1 put the preparation method of glass box, it is characterised in that the trifluoro second
Alcohol, m-trifluoromethylbenzoic acid methyl esters, the degree of purity of perflexane are technical pure.
5. a kind of antifouling plastics according to claim 1 put the preparation method of glass box, it is characterised in that the antifouling painting
Material is made of following methods：By cyanurate melamine ester, castor oil, heptyl paraben, trifluoroethanol, m-trifluoromethyl benzene
Methyl formate, perflexane, magnesia, titanium dioxide are sequentially added in acroleic acid polyurethane, and feeding interval is 3min, is persistently stirred
Mix, after the completion of charging, continue to stir after 15min, finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710345625.5A CN107142005A (en) | 2017-05-17 | 2017-05-17 | A kind of antifouling plastics put the preparation method of glass box |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710345625.5A CN107142005A (en) | 2017-05-17 | 2017-05-17 | A kind of antifouling plastics put the preparation method of glass box |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107142005A true CN107142005A (en) | 2017-09-08 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710345625.5A Pending CN107142005A (en) | 2017-05-17 | 2017-05-17 | A kind of antifouling plastics put the preparation method of glass box |
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| Country | Link |
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| CN (1) | CN107142005A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112358661A (en) * | 2020-12-08 | 2021-02-12 | 长泰鑫润橡塑有限公司 | Wear-resistant antifouling silicone rubber sealing ring and preparation process thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201544827U (en) * | 2009-11-19 | 2010-08-11 | 奇瑞汽车股份有限公司 | Anti-fouling waterproofing device for automobile back seats |
| CN102277043A (en) * | 2011-06-22 | 2011-12-14 | 嘉宝莉化工集团股份有限公司 | Algae-clay air purification coating and preparation method thereof |
| CN102702885A (en) * | 2012-06-13 | 2012-10-03 | 天长市银狐漆业有限公司 | Aqueous indoor smoke-free fire-proof coating |
| CN104277619A (en) * | 2014-09-04 | 2015-01-14 | 上海露蕾化工（六安）有限公司 | Hydrophobic self-cleaning paint |
| CN104910779A (en) * | 2015-06-04 | 2015-09-16 | 西安交通大学 | Super-hydrophobic acrylic polyurethane coating and preparation method thereof |
-
2017
- 2017-05-17 CN CN201710345625.5A patent/CN107142005A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201544827U (en) * | 2009-11-19 | 2010-08-11 | 奇瑞汽车股份有限公司 | Anti-fouling waterproofing device for automobile back seats |
| CN102277043A (en) * | 2011-06-22 | 2011-12-14 | 嘉宝莉化工集团股份有限公司 | Algae-clay air purification coating and preparation method thereof |
| CN102702885A (en) * | 2012-06-13 | 2012-10-03 | 天长市银狐漆业有限公司 | Aqueous indoor smoke-free fire-proof coating |
| CN104277619A (en) * | 2014-09-04 | 2015-01-14 | 上海露蕾化工（六安）有限公司 | Hydrophobic self-cleaning paint |
| CN104910779A (en) * | 2015-06-04 | 2015-09-16 | 西安交通大学 | Super-hydrophobic acrylic polyurethane coating and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112358661A (en) * | 2020-12-08 | 2021-02-12 | 长泰鑫润橡塑有限公司 | Wear-resistant antifouling silicone rubber sealing ring and preparation process thereof |
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Application publication date: 20170908 |
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