CN107963868A - A kind of ceramic coating - Google Patents
A kind of ceramic coating Download PDFInfo
- Publication number
- CN107963868A CN107963868A CN201711398730.1A CN201711398730A CN107963868A CN 107963868 A CN107963868 A CN 107963868A CN 201711398730 A CN201711398730 A CN 201711398730A CN 107963868 A CN107963868 A CN 107963868A
- Authority
- CN
- China
- Prior art keywords
- ceramic coating
- modified filler
- quality
- levelling agent
- zeolite powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Abstract
The invention discloses a kind of ceramic coating, it is related to chemical technology field, is made of following component：Ludox, silane coupling agent, surfactant, levelling agent, modified filler, nano ceramic powder, melamine, diisocyanate, 12 hydroxy stearic acids, ammonium persulfate, deionized water；Ceramic coating prepared by the present invention, green non-pollution, has surface strength height, water resistance, excellent corrosion resistance.
Description
Technical field
The invention belongs to chemical technology field, and in particular to a kind of ceramic coating.
Background technology
Coating Industry in Our Country is with a long history, and output and consumption figure are in rank first, and development prospect is wide, just
It is being increasingly becoming national economy new growth point.The early detection U.S., Japan, South Korea have some ceramic coatings in terms of research,
Report, but have not seen Related product in its domestic market.Since the 1990s, China is engaged in some lists of coating research and development
Position, starts to focus on using sol-gel technique research and development inorganic/organic composite coating, nano superconductive powder body material, high temperature is anti-corrosion painting
Material etc., inorganic aqueous ceramic coating also belongs to one kind therein.Although ceramic coating has occurred for many years, together at home
When there has also been some joint ventures and private enterprise has carried out industrialization, but development speed is still relatively slowly, especially right
The research of inorganic aqueous ceramic coating is seldom.
The content of the invention
The purpose of the present invention is for it is existing the problem of, there is provided a kind of ceramic coating.
The present invention is achieved by the following technical solutions：
A kind of ceramic coating, is made of following component by weight：Ludox 78-82, silane coupling agent 1.5-2.5,
Surfactant 3-5, levelling agent 1.2-1.8, modified filler 32-40, nano ceramic powder 3-5, melamine 2-4, two isocyanides
Sour 1-4,12- hydroxy stearic acid 0.5-1.5, ammonium persulfate 0.02-0.04, deionized water 60-70；
The modified filler preparation method is：
（1）Zeolite powder, silicone oil, calcium carbonate, nanometer titanium dioxide carbon, sodium glutamate are pressed 20:1.2:6:3:0.5 quality proportioning mixes
To the mass concentration for together, being added to 5 times of zeolite powder quality in 3.6% sodium dodecyl sulfate solution, to be heated to 85 DEG C,
Continue 2 it is small when after, then the polyacrylic acid of addition zeolite powder quality 5%, rotation steaming is carried out with 500r/min rotating speeds stirring 40min
It is dry dry, obtain solid mixture；
（2）It is in 2.5% alpha-olefin sodium sulfonate solution by the mass fraction that solid mixture adds 3 times of its quality, then adds
Into vacuum reaction kettle, impregnate 30min, then take out, be ground 2 it is small when, filtering, drying to constant weight, to obtain the final product.
Further, the surfactant is sodium sulfate of polyethenoxy ether of fatty alcohol.
Further, the levelling agent is esters of acrylic acid levelling agent.
Further, the modified filler granularity is 1000 mesh.
Further, vacuum is 0.038MPa in the vacuum reaction kettle, and dipping temperature is 95 DEG C.
The present invention has the following advantages compared with prior art：Ceramic coating prepared by the present invention, green non-pollution, tool
There are surface strength height, water resistance, excellent corrosion resistance, excellent anti-fouling performance and good adhesion, lubricity, firmly
Height, damage resistant, salt spray resistance, acid and alkali-resistance, glossiness height are spent, curing rate is fast, cost is low, good attachment and excellent solvent resistance, this
A little performances are mainly to be obtained by rational formula in the present invention.Use under the same conditions, the painting that coating of the present invention is formed
The service life of layer is higher by 50% than the hardness that general commercially available ceramic coating forms coating.The coating that coating of the present invention is formed it is resistance to
It is more preferable to shine performance, after shining long, it is not easy to change colour, after long-time use, appearance still keeps certain flatness, and durability is good, and
Any surface finish, dirt retention are low；The modified filler prepared by adding the present invention, effectively can uniformly divide in coating system
Dissipate so that the film after curing has good hardness and adhesive force.
Embodiment
Embodiment 1
A kind of ceramic coating, is made of following component by weight：Ludox 78, silane coupling agent 1.5, surface-active
Agent 3, levelling agent 1.2, modified filler 32, nano ceramic powder 3, melamine 2, diisocyanate 1,12- hydroxy stearic acids 0.5,
Ammonium persulfate 0.02, deionized water 60；
The modified filler preparation method is：
（1）Zeolite powder, silicone oil, calcium carbonate, nanometer titanium dioxide carbon, sodium glutamate are pressed 20:1.2:6:3:0.5 quality proportioning mixes
To the mass concentration for together, being added to 5 times of zeolite powder quality in 3.6% sodium dodecyl sulfate solution, to be heated to 85 DEG C,
Continue 2 it is small when after, then the polyacrylic acid of addition zeolite powder quality 5%, rotation steaming is carried out with 500r/min rotating speeds stirring 40min
It is dry dry, obtain solid mixture；
（2）It is in 2.5% alpha-olefin sodium sulfonate solution by the mass fraction that solid mixture adds 3 times of its quality, then adds
Into vacuum reaction kettle, impregnate 30min, then take out, be ground 2 it is small when, filtering, drying to constant weight, to obtain the final product.
Further, the surfactant is sodium sulfate of polyethenoxy ether of fatty alcohol.
Further, the levelling agent is esters of acrylic acid levelling agent.
Further, the modified filler granularity is 1000 mesh.
Further, vacuum is 0.038MPa in the vacuum reaction kettle, and dipping temperature is 95 DEG C.
Embodiment 2
A kind of ceramic coating, is made of following component by weight：Ludox 82, silane coupling agent 2.5, surface-active
Agent 5, levelling agent 1.8, modified filler 40, nano ceramic powder 5, melamine 4, diisocyanate 4,12- hydroxy stearic acids 1.5,
Ammonium persulfate 0.04, deionized water 70；
The modified filler preparation method is：
（1）Zeolite powder, silicone oil, calcium carbonate, nanometer titanium dioxide carbon, sodium glutamate are pressed 20:1.2:6:3:0.5 quality proportioning mixes
To the mass concentration for together, being added to 5 times of zeolite powder quality in 3.6% sodium dodecyl sulfate solution, to be heated to 85 DEG C,
Continue 2 it is small when after, then the polyacrylic acid of addition zeolite powder quality 5%, rotation steaming is carried out with 500r/min rotating speeds stirring 40min
It is dry dry, obtain solid mixture；
（2）It is in 2.5% alpha-olefin sodium sulfonate solution by the mass fraction that solid mixture adds 3 times of its quality, then adds
Into vacuum reaction kettle, impregnate 30min, then take out, be ground 2 it is small when, filtering, drying to constant weight, to obtain the final product.
Further, the surfactant is sodium sulfate of polyethenoxy ether of fatty alcohol.
Further, the levelling agent is esters of acrylic acid levelling agent.
Further, the modified filler granularity is 1000 mesh.
Further, vacuum is 0.038MPa in the vacuum reaction kettle, and dipping temperature is 95 DEG C.
Embodiment 3
A kind of ceramic coating, is made of following component by weight：Ludox 80, silane coupling agent 1.8, surface-active
Agent 4, levelling agent 1.5, modified filler 35, nano ceramic powder 4, melamine 3, diisocyanate 2,12- hydroxy stearic acids 0.8,
Ammonium persulfate 0.03, deionized water 65；
The modified filler preparation method is：
（1）Zeolite powder, silicone oil, calcium carbonate, nanometer titanium dioxide carbon, sodium glutamate are pressed 20:1.2:6:3:0.5 quality proportioning mixes
To the mass concentration for together, being added to 5 times of zeolite powder quality in 3.6% sodium dodecyl sulfate solution, to be heated to 85 DEG C,
Continue 2 it is small when after, then the polyacrylic acid of addition zeolite powder quality 5%, rotation steaming is carried out with 500r/min rotating speeds stirring 40min
It is dry dry, obtain solid mixture；
（2）It is in 2.5% alpha-olefin sodium sulfonate solution by the mass fraction that solid mixture adds 3 times of its quality, then adds
Into vacuum reaction kettle, impregnate 30min, then take out, be ground 2 it is small when, filtering, drying to constant weight, to obtain the final product.
Further, the surfactant is sodium sulfate of polyethenoxy ether of fatty alcohol.
Further, the levelling agent is esters of acrylic acid levelling agent.
Further, the modified filler granularity is 1000 mesh.
Further, vacuum is 0.038MPa in the vacuum reaction kettle, and dipping temperature is 95 DEG C.
Comparative example 1：Differed only in embodiment 1 and modified filler is replaced with into zeolite powder, silicone oil, calcium carbonate, nanometer two
Carbonoxide, sodium glutamate press 20:1.2:6:3:0.5 quality proportioning physical mixed.
Experiment：
Embodiment is respectively adopted to be coated on Etta's plate by the way of brushing or spraying with coating prepared by comparative example, it is quiet under room temperature
Form a film after putting a period of time from dry, prepare the film that thickness is about 1mm and be used for performance test；
The pencil hardness of film is detected using manual method, i.e., model is placed in horizontal table top, holds about 45 degree of pencil
Angle, with pencil not degree of breaking into, scratches in film coated surface.Per standardized road weight will be carried out with penknife to the tip of pencil-lead
New processing, repeats to scratch five, either more than twice film is scratched or wiped if any twice to the pencil of same hardness label
Wound, then record the hardness label of the latter position of this pencil hardness label, is the pencil hardness of film；
The adhesive force of the adhesive force film of film generally has cross-hatching and draws a circle two kinds of test methods of method, this experiment using stroke
Lattice method, scratches coating until bottom plate with razor blade by the model handled well, draws 10 × 10 lattice, per compartment away from about 1 mm,
Pullled with adhesive tape, seen whether to come off；
Table 1
As can be seen from Table 1, the ceramic coating that prepared by the present invention has good hardness and adhesive force.
Claims (5)
1. a kind of ceramic coating, it is characterised in that be made by weight of following component：Ludox 78-82, silane are even
Join agent 1.5-2.5, surfactant 3-5, levelling agent 1.2-1.8, modified filler 32-40, nano ceramic powder 3-5, melamine
Amine 2-4, diisocyanate 1-4,12- hydroxy stearic acid 0.5-1.5, ammonium persulfate 0.02-0.04, deionized water 60-70；
The modified filler preparation method is：
（1）Zeolite powder, silicone oil, calcium carbonate, nanometer titanium dioxide carbon, sodium glutamate are pressed 20:1.2:6:3:0.5 quality proportioning mixes
To the mass concentration for together, being added to 5 times of zeolite powder quality in 3.6% sodium dodecyl sulfate solution, to be heated to 85 DEG C,
Continue 2 it is small when after, then the polyacrylic acid of addition zeolite powder quality 5%, rotation steaming is carried out with 500r/min rotating speeds stirring 40min
It is dry dry, obtain solid mixture；
（2）It is in 2.5% alpha-olefin sodium sulfonate solution by the mass fraction that solid mixture adds 3 times of its quality, then adds
Into vacuum reaction kettle, impregnate 30min, then take out, be ground 2 it is small when, filtering, drying to constant weight, to obtain the final product.
2. a kind of ceramic coating as claimed in claim 1, it is characterised in that the surfactant is fatty alcohol polyoxy
Ethene ether sodium sulfate.
3. a kind of ceramic coating as claimed in claim 1, it is characterised in that the levelling agent is esters of acrylic acid levelling
Agent.
4. a kind of ceramic coating as claimed in claim 1, it is characterised in that the modified filler granularity is 1000 mesh.
5. a kind of ceramic coating as claimed in claim 1, it is characterised in that vacuum is in the vacuum reaction kettle
0.038MPa, dipping temperature are 95 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711398730.1A CN107963868A (en) | 2017-12-22 | 2017-12-22 | A kind of ceramic coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711398730.1A CN107963868A (en) | 2017-12-22 | 2017-12-22 | A kind of ceramic coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107963868A true CN107963868A (en) | 2018-04-27 |
Family
ID=61994702
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711398730.1A Pending CN107963868A (en) | 2017-12-22 | 2017-12-22 | A kind of ceramic coating |
Country Status (1)
| Country | Link |
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| CN (1) | CN107963868A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112094578A (en) * | 2019-06-18 | 2020-12-18 | 佛山市南海区沙头才华化工有限公司 | Preparation method of soft ceramic nano coating |
| CN112094511A (en) * | 2019-06-18 | 2020-12-18 | 佛山市南海区沙头才华化工有限公司 | Preparation method of nano composite ceramic coating |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0532448A (en) * | 1991-07-30 | 1993-02-09 | Reiji Karita | Flame-resistant coating material |
| JPH06271370A (en) * | 1993-03-19 | 1994-09-27 | T T Shii:Kk | Formation of low-temperature curable ceramic/organic polymer multiple coating film |
| DE19748927A1 (en) * | 1997-05-26 | 1998-12-03 | Kruligk Gerd Dipl Ing | Powder coating process for producing glaze, e.g. on ceramic basins |
| CN103553535A (en) * | 2013-09-30 | 2014-02-05 | 安徽华印机电股份有限公司 | Antifouling porcelain-imitate four-in-one paint |
| CN105238103A (en) * | 2015-10-30 | 2016-01-13 | 江门四方英特宝涂料有限公司 | Energy-saving and antibacterial nano ceramic coating |
| CN105238104A (en) * | 2015-10-30 | 2016-01-13 | 江门四方英特宝涂料有限公司 | Nano ceramic coating with high adhesion |
| US20160023951A1 (en) * | 2013-01-07 | 2016-01-28 | Vince Alessi | Thermoset ceramic compositions, inorganic polymer coatings, inorganic polymer mold tooling, inorganic polymer hydraulic fracking proppants, methods of preparation and applications therefore |
-
2017
- 2017-12-22 CN CN201711398730.1A patent/CN107963868A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0532448A (en) * | 1991-07-30 | 1993-02-09 | Reiji Karita | Flame-resistant coating material |
| JPH06271370A (en) * | 1993-03-19 | 1994-09-27 | T T Shii:Kk | Formation of low-temperature curable ceramic/organic polymer multiple coating film |
| DE19748927A1 (en) * | 1997-05-26 | 1998-12-03 | Kruligk Gerd Dipl Ing | Powder coating process for producing glaze, e.g. on ceramic basins |
| US20160023951A1 (en) * | 2013-01-07 | 2016-01-28 | Vince Alessi | Thermoset ceramic compositions, inorganic polymer coatings, inorganic polymer mold tooling, inorganic polymer hydraulic fracking proppants, methods of preparation and applications therefore |
| CN103553535A (en) * | 2013-09-30 | 2014-02-05 | 安徽华印机电股份有限公司 | Antifouling porcelain-imitate four-in-one paint |
| CN105238103A (en) * | 2015-10-30 | 2016-01-13 | 江门四方英特宝涂料有限公司 | Energy-saving and antibacterial nano ceramic coating |
| CN105238104A (en) * | 2015-10-30 | 2016-01-13 | 江门四方英特宝涂料有限公司 | Nano ceramic coating with high adhesion |
Non-Patent Citations (1)
| Title |
|---|
| 张明: "《煤制合成天然气技术与应用》", 30 September 2017, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112094578A (en) * | 2019-06-18 | 2020-12-18 | 佛山市南海区沙头才华化工有限公司 | Preparation method of soft ceramic nano coating |
| CN112094511A (en) * | 2019-06-18 | 2020-12-18 | 佛山市南海区沙头才华化工有限公司 | Preparation method of nano composite ceramic coating |
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Application publication date: 20180427 |
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