CN105238104A - Nano ceramic coating with high adhesion - Google Patents
Nano ceramic coating with high adhesion Download PDFInfo
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- CN105238104A CN105238104A CN201510733707.8A CN201510733707A CN105238104A CN 105238104 A CN105238104 A CN 105238104A CN 201510733707 A CN201510733707 A CN 201510733707A CN 105238104 A CN105238104 A CN 105238104A
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Abstract
The invention belongs to the technical field of nano coating technologies, and relates to a nano ceramic coating with high adhesion. The nano ceramic coating consists of the following components in part by weight: 40-50 parts of silica sol, 35-45 parts of silane coupling agents, 5-10 parts of special nano materials, 1-2 parts of non-ionic surfactants, 1-2 parts of waterborne leveling agents and 5-10 parts of hard fillers. According to the nano ceramic coating with high adhesion provided by the present invention, by blending of formulations, original properties of the ceramic coating are kept, and meanwhile, the nano ceramic coating has higher adhesion and is particularly suitable for surfaces of cast iron, and production and use costs are reduced.
Description
Technical field
The invention belongs to nano paint technical field, in particular to a kind of strong adhesive force ceramic coating.
Background technology
Ceramic coating, is mainly used in body surface and plays on protection and the not sticky metal object waiting effect, be particularly suitable for the surface of cast iron objects surface without the need to sandblasting roughening treatment.
Ceramic coating is based on silicon sol, be equipped with silane coupling agent, a kind of coating of film forming by the mode of SOL-GEL, this coating has high rigidity, environmental protection, does not contain the various features such as PFOA, uninflammability, solidification value is low, non-adhesion behavior is good, is widely used in the fields such as non-stick pan, track traffic, curtain wall.But general ceramic coating all needs to carry out sandblasting roughening treatment to coated metallic surface when constructing, otherwise does not just have good sticking power, so just virtually add production and application cost.The sticking power that ceramic coating of the present invention is better, is mainly used in cast iron objects surface, without the need to sandblasting roughening treatment during production and application, reduces production cost.
Summary of the invention
Object of the present invention provides a kind of formula of strong adhesive force ceramic coating.
The present invention, by the development of coating, makes ceramic coating have higher sticking power, in Cast Iron Surface without the need to sandblasting roughening treatment, reduces production and application cost.For achieving the above object, the present invention by the following technical solutions:
A kind of strong adhesive force ceramic coating, according to parts by weight, consists of the following composition: the silicon sol of 40 ~ 50 parts, the silane coupling agent of 35 ~ 45 parts, the special nano material of 5 ~ 10 parts, the nonionogenic tenside of 1 ~ 2 part, the water-based flow agent of 1 ~ 2 part, the hard filler of 5 ~ 10 parts.
Further, described silicon sol is the dispersion liquid of nano level silica dioxide granule in water.
Further, described silane coupling agent is tri-alkoxy type.
Further, described flow agent is silicone based or polyacrylic.
Further, described special nano material is mineral-type nano material.
Dispensing information:
Silicon sol belongs to colloidal solution, odorless, nontoxic.Silicon sol is the dispersion liquid of nano level silica dioxide granule in water or in solvent.Because the SiO2 in silicon sol contains a large amount of water and hydroxyl, therefore silicon sol also can be expressed as SiO2.nH2O.Because its heatproof, specific surface area are large, inorganic compact, be the better selection of producing nano inorganic coating, its particle diameter has from hundreds of to several thousand nanometers, and the present invention is generally tens to up to a hundred nanometers for the production of the particle size range of ceramic coating.
Silane coupling agent is the silicoorganic compound of a class in the molecule simultaneously containing two kinds of different chemical character groups, conventional silane coupling agent is tri-alkoxy type, can be that methyl, ethyl, phenyl, vinyl etc. can participate in reacting all can using in the present invention of hydrolysis.
Nonionogenic tenside has a non-ionizing class tensio-active agent in water, because nonionogenic tenside is not exist with ionic condition in the solution, so its stability is high, be not subject to the impact that strong electrolyte exists, also acid is not subject to, the impact of alkali, can be used in combination with other types tensio-active agent, consistency is good, all good solubility is had in all kinds of SOLVENTS, there is not strong adsorption on a solid surface, play the effect of water oil transfer connection in the present invention, part oily matter can be made well to mix, and the surface energy of system can be changed.
Flow agent, it can impel coating in drying and forming-film process, form smooth, smooth, a uniform film.Effectively can reduce and cover with paint, lacquer, colour wash, etc. liquid surface tension, improve a class material of its levelling property and homogeneity, the flow agent that the present invention uses is silicone based or polyacrylic.
Nano material due to particle size little, specific surface area is large, and surface energy is high, and surface atom proportion is large, therefore, shows distinctive surface effects, small-size effect, the large effect of macro quanta tunnel effect three.The special nano material that the present invention uses comprises nano crystal whisker material, filamentary material etc., and this kind of material particle size, all at below 100nm, has good adhesion, adhewsive action to metallic surface.The present invention selects mineral-type nano material, meets all kinds of environmental requirement.
The present invention has following beneficial effect:
This invention, by the modulation of formula, makes ceramic coating keep original performance, also has better sticking power simultaneously, be specially adapted to Cast Iron Surface, reduces production and application cost.
Embodiment
Below in conjunction with specific embodiment, the present invention is described further:
Embodiment 1
A kind of strong adhesive force ceramic coating of the present embodiment, consists of the following composition: the silicon sol of 43 parts, the silane coupling agent of 39 parts, the special nano material of 7 parts, the nonionogenic tenside of 2 parts, the water-based flow agent of 2 parts, the hard filler of 6 parts.
Embodiment 2
A kind of strong adhesive force ceramic coating of the present embodiment, consists of the following composition: the silicon sol of 42 parts, the silane coupling agent of 36 parts, the special nano material of 9 parts, the nonionogenic tenside of 1 part, the water-based flow agent of 1 part, the hard filler of 9 parts.
Embodiment 3
A kind of strong adhesive force ceramic coating of the present embodiment, consists of the following composition: the silicon sol of 49 parts, the silane coupling agent of 44 parts, the special nano material of 9 parts, the nonionogenic tenside of 2 parts, the water-based flow agent of 2 parts, the hard filler of 9 parts.
The above; be only the specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, anyly belongs to those skilled in the art in the technical scope that the present invention discloses; the change that can expect easily or replacement, all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claim.
Claims (5)
1. a strong adhesive force ceramic coating, it is characterized in that, according to parts by weight, consist of the following composition: the silicon sol of 40 ~ 50 parts, the silane coupling agent of 35 ~ 45 parts, the special nano material of 5 ~ 10 parts, the nonionogenic tenside of 1 ~ 2 part, the water-based flow agent of 1 ~ 2 part, the hard filler of 5 ~ 10 parts.
2. a kind of strong adhesive force ceramic coating according to claim 1, is characterized in that, described silicon sol is the dispersion liquid of nano level silica dioxide granule in water.
3. a kind of strong adhesive force ceramic coating according to claim 1, is characterized in that, described silane coupling agent is tri-alkoxy type.
4. a kind of strong adhesive force ceramic coating according to claim 1, it is characterized in that, described flow agent is silicone based or polyacrylic.
5. a kind of strong adhesive force ceramic coating according to claim 1, is characterized in that, described special nano material is mineral-type nano material.
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CN201510733707.8A CN105238104A (en) | 2015-10-30 | 2015-10-30 | Nano ceramic coating with high adhesion |
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CN201510733707.8A CN105238104A (en) | 2015-10-30 | 2015-10-30 | Nano ceramic coating with high adhesion |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106871179A (en) * | 2017-02-28 | 2017-06-20 | 广东美的厨房电器制造有限公司 | Grill and its spraying method and micro-wave oven |
CN106866095A (en) * | 2017-01-21 | 2017-06-20 | 河南省豫星华晶微钻有限公司 | A kind of new ceramics coating containing nanometer diamond alkene and preparation method thereof |
CN107963868A (en) * | 2017-12-22 | 2018-04-27 | 枞阳县三金颜料有限责任公司 | A kind of ceramic coating |
CN109266057A (en) * | 2018-09-14 | 2019-01-25 | 湖南凯斯利新材料有限公司 | Extra-weather-proof high hard abrasion-resistance water inorganic nano ceramic coating of a kind of normal temperature cure and preparation method thereof |
CN113999556A (en) * | 2021-08-24 | 2022-02-01 | 旭贞新能源科技(上海)有限公司 | Anti-corrosion and anti-coking ceramic coating for coal-fired boiler and convenient for state recognition and preparation method thereof |
CN116120769A (en) * | 2023-01-10 | 2023-05-16 | 广东四方英特宝新材料科技有限公司 | Ceramic coating and preparation method and application thereof |
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CN103013193A (en) * | 2012-12-13 | 2013-04-03 | 慧智科技(中国)有限公司 | Titanium-containing ceramic paint and protective coating |
CN102181194B (en) * | 2010-04-22 | 2013-07-24 | 上海宜瓷龙新材料科技有限公司 | Environment-friendly anti-scaling nano-ceramic membrane coating and preparation method of the environment-friendly anti-scaling nano-ceramic membrane coating |
CN103725052A (en) * | 2014-01-10 | 2014-04-16 | 江门四方威凯精细化工有限公司 | Water-based porcelain film coating and preparation method thereof |
CN104725903A (en) * | 2015-03-30 | 2015-06-24 | 佛山市新战略知识产权文化有限公司 | Non-sticking wear-resistant high-temperature-resistant paint and preparation method thereof |
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CN102181194B (en) * | 2010-04-22 | 2013-07-24 | 上海宜瓷龙新材料科技有限公司 | Environment-friendly anti-scaling nano-ceramic membrane coating and preparation method of the environment-friendly anti-scaling nano-ceramic membrane coating |
CN103013193A (en) * | 2012-12-13 | 2013-04-03 | 慧智科技(中国)有限公司 | Titanium-containing ceramic paint and protective coating |
CN103725052A (en) * | 2014-01-10 | 2014-04-16 | 江门四方威凯精细化工有限公司 | Water-based porcelain film coating and preparation method thereof |
CN104725903A (en) * | 2015-03-30 | 2015-06-24 | 佛山市新战略知识产权文化有限公司 | Non-sticking wear-resistant high-temperature-resistant paint and preparation method thereof |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106866095A (en) * | 2017-01-21 | 2017-06-20 | 河南省豫星华晶微钻有限公司 | A kind of new ceramics coating containing nanometer diamond alkene and preparation method thereof |
CN106871179A (en) * | 2017-02-28 | 2017-06-20 | 广东美的厨房电器制造有限公司 | Grill and its spraying method and micro-wave oven |
CN106871179B (en) * | 2017-02-28 | 2019-04-30 | 广东美的厨房电器制造有限公司 | Grill and its spraying method and micro-wave oven |
CN107963868A (en) * | 2017-12-22 | 2018-04-27 | 枞阳县三金颜料有限责任公司 | A kind of ceramic coating |
CN109266057A (en) * | 2018-09-14 | 2019-01-25 | 湖南凯斯利新材料有限公司 | Extra-weather-proof high hard abrasion-resistance water inorganic nano ceramic coating of a kind of normal temperature cure and preparation method thereof |
CN109266057B (en) * | 2018-09-14 | 2020-11-17 | 湖南凯斯利新材料有限公司 | Normal-temperature-cured super-weather-resistant high-hardness wear-resistant water-based inorganic nano ceramic coating and preparation method thereof |
CN113999556A (en) * | 2021-08-24 | 2022-02-01 | 旭贞新能源科技(上海)有限公司 | Anti-corrosion and anti-coking ceramic coating for coal-fired boiler and convenient for state recognition and preparation method thereof |
CN116120769A (en) * | 2023-01-10 | 2023-05-16 | 广东四方英特宝新材料科技有限公司 | Ceramic coating and preparation method and application thereof |
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Application publication date: 20160113 |