CN105694730B - The efficiently water paint of release anion environmental protection sterilization and its preparation construction technology - Google Patents
The efficiently water paint of release anion environmental protection sterilization and its preparation construction technology Download PDFInfo
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- CN105694730B CN105694730B CN201610144538.9A CN201610144538A CN105694730B CN 105694730 B CN105694730 B CN 105694730B CN 201610144538 A CN201610144538 A CN 201610144538A CN 105694730 B CN105694730 B CN 105694730B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/36—Successively applying liquids or other fluent materials, e.g. without intermediate treatment
- B05D1/38—Successively applying liquids or other fluent materials, e.g. without intermediate treatment with intermediate treatment
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/324—Alkali metal phosphate
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Abstract
The efficiently water paint of release anion environmental protection sterilization and its preparation construction technology, belong to preparation and the construction technology field of environment-friendly water-based paint.It is characterized by comprising priming paint, intermediate layer paint and surface lacquers.Water paint of the present invention is not only environment friendly and pollution-free after coating, and can also in room sustained release anion, play the role of sterilize antibacterial, can accomplish active purification promoted living space life quality, be used for a long time it is good for health.At the same time, construction method of the present invention is simple, and even layman perfect can also implement, and painting effect is good, can satisfy the use demand of consumer.
Description
Technical field
The invention belongs to the preparations of environment-friendly water-based paint and construction technology field, and in particular to one kind can efficiently discharge bear from
Subring protects the water paint of sterilization and its prepares construction technology.
Background technique
Paint is tolerant due to having the characteristics that strong hardness, paint film richness height, construction, head when being many people's decorations
Select coating.With the pressure of environmental protection policy, the continuous promotion of consumer's environmental consciousness, provinces and cities especially in all parts of the country have put into effect VOC
Limit standard is discharged, encourages to use non-solvent coating, brings opportunity to the development of the environmental protection coating materials such as water paint.Although traditional
Coating is still in occupation of the biggish market share, but water paint is pollution-free industry, is the direction for painting class future development, the country is originally
The water paint leading enterprise of soil is emerging.
The development of water paint and the shared market share have been undisputable facts increasing year by year, and have speed-raising
Trend.Some enterprises have appreciated that the wide market potential of water paint, research and develop, march one after another, expanding water paint market.
Although water paint superior traditional paint on environmental-protecting performance, in physical property, water paint product exists
The defects of construction is difficult, richness is poor.Defect only in physical property is resolved or even beyond tradition paint, and consumer is
It more can actively select to use water paint, water paint manufacturing enterprise is needed to do technological innovation in water paint performance.
Since the factors such as performance, technology influence, the construction tolerance of water paint is poor more than oiliness woodwork coating, often leads
Cause final paint film effect barely satisfactory.For consumers, they really buy, in fact not instead of coating, apply
Painting effect after expecting use." three points of coating, seven points of coatings " this jargon is used to describe that water paint is more appropriate.Water paint
Difficulty of construction is big, it is necessary to rely on professional coating personnel and construct, could obtain the effect of satisfaction, and to limit water paint general
And one of bottleneck of development.
In addition, the material that consumer when carrying out house ornamentation, can generate finishing pollution is not limited in painting class, and it is traditional
Water paint only no longer additionally causes pollution to aggravate, and the effect of cleaning ambient, automatic bacteriostasis antibiosis is still not achieved, this
It is improvement direction one of of the applicant to product.
Therefore, research and develop a kind of environmental protection of itself clean, and can automatic antibacterial bacteriostatic, using simple construction technology, that is, reachable
It is one of the problem of urgent need to resolve in industry to the water paint of satisfactory painting effect.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of water paint of efficiently release anion environmental protection sterilization and its
Prepare construction technology, not only clean and environmental protection, and can sustained release anion, antibacterial bacteriostatic.Solve second of the present invention
Technical problem are as follows: prepare and construction technology is simple, painting effect is excellent.
In order to solve the above technical problems, the technical scheme is that one kind described in invention efficiently discharges anion ring
Protect the water paint of sterilization, it is characterised in that including priming paint, intermediate layer paint and surface lacquer；
The priming paint includes following component according to mass ratio:
50-55 parts of water-soluble synthetic resin；
13-17 parts of aluminium triphosphate；
17-20 parts of talcum powder；
0.3-0.5 parts of ethylene glycol；
17-20 parts of carboxymethyl cellulose；
3-5 parts of amino alcohol solvay-type titanate esters；
The intermediate layer paint includes following component according to mass ratio:
Tourmaline with lucium 6-7 parts；
40-60 parts of water-soluble synthetic resin；
0.5-1.2 parts of sodium tripolyphosphate；
0.7-1.5 parts of soybean lecithin；
The surface paint includes following component according to mass ratio:
Water-soluble negative ion powder 10-15 parts；
65-70 parts of water-soluble synthetic resin；
8-11 parts of locust bean gum；
4-7 parts of mica powder.
Preferably, more mixed for 2:6 than tourmaline and rare earth according to quality in the intermediate layer paint in tourmaline and lucium
It closes；Wherein tourmaline is both needed to respectively be ground to 12000 mesh or more before mixing with rare earth.
Preferably, the fineness of water-soluble negative ion powder is 11000 mesh or more in the surface paint.
The preparation construction technology of the water paint of the present invention that anion environmental protection sterilization can efficiently be discharged, feature exist
In comprising the following steps:
1) priming paint is prepared
After priming paint is weighed according to component and proportion, it is put into blender after mixing evenly；
2) intermediate layer paint is prepared
Tourmaline and rare earth are weighed respectively first, in accordance with mass ratio, are respectively ground to 12000 mesh or more and are uniformly mixed later；
It weighs water-soluble synthetic resin, sodium tripolyphosphate and soybean lecithin respectively according still further to mass ratio, is mixed uniformly；It will be above-mentioned
Two kinds of mixtures are put into high-speed mixer, under the conditions of 1500 turns/min, vacuum degree -0.6-0.08MPa, are uniformly mixed i.e.
It can；
3) surface paint is prepared
Water-soluble negative ion powder is weighed according to mass ratio, is ground to 11000 mesh or more；By ground water soluble negative
It ion powder and is put into high-speed mixer according to the weighed water-soluble synthetic resin of mass ratio, locust bean gum and mica powder, 1000
Turn/min, vacuum degree -0.6-0.08MPa under the conditions of, be uniformly mixed；
4) it constructs
Priming paint and deionized water are uniformly mixed by first choice according to the ratio of mass ratio 1:1-1.5；It is sprayed on surface to be painted
It primes, coating thickness 0.1-0.8cm is air-dried under the conditions of 20-25 DEG C；By primed surface plucking, plucking depth after air-drying
0.05cm；
Then, intermediate layer paint and deionized water are uniformly mixed according to the ratio of mass ratio 1:1-2；Spray intermediate layer paint, middle layer
The coating thickness of paint is 0.15-0.5cm, is air-dried under the conditions of 25 DEG C；
Finally, surface paint and deionized water are uniformly mixed according to the ratio of mass ratio 1:1-3；Spray surface paint, surface layer
The coating thickness of paint is 0.12-0.15cm, and room temperature is dried in the shade.
Compared with prior art, the beneficial effects of the present invention are:
1. water paint of the present invention, using water-soluble synthetic resin as main component, each functional component is auxiliary material.
In primers, ethylene glycol is surfactant or advanced chaotropic agent, can help the other function group in priming paint
Divide sufficiently dissolution；Carboxymethyl cellulose is in viscose glue shape, increases as adhesive after enabling priming paint and deionized water match uniformly
The attachment and extension power of priming paint cooperate the amino alcohol solvay-type titanate esters that use as thickener, enable priming paint coating it is securely uniform,
Each ingredient not easy to crack is distributed in primers in even suspension shape.In addition, this formula can enable priming paint keep containing certain wet
Degree, avoids cracking, weatherability is stronger.
In middle level in paint, tourmaline and lucium can pass through the performance of rare-earth activated tourmaline purifying formaldehyde；Trimerization
Sodium phosphate not only has dissolution effect, is also used as buffer herein, the function ingredients in intermediate layer paint can be enabled to be uniformly dispersed, especially
The mixture of tourmaline and rare earth, enables it be evenly arranged in intermediate layer paint, plays one's part to the full.Soybean lecithin adds as common food
Add agent, creative conduct emulsion stabilizer, bonding agent and lubricant come using soybean lecithin has hydrophilic and oleophylic herein
Two groups, are capable of the mutual fusion of promotion functions component, and enable its completely soluble.In addition, being added to soybean lecithin
Intermediate layer paint coating surface lubrication is smooth, and the coating convenient for next step surface lacquer is uniform.
The water-soluble negative ion powder of surface lacquer is thickened by locust bean gum and mica powder, and uniformly dispersing is in water-soluble synthetic resin
In, coated surface lacquer is wear-resisting to be resisted dry, and weatherability is strong and environment friendly and pollution-free.It is consolidated since water-soluble negative ion powder can be evenly distributed with
Be present in surface paint, be not easy to reduce the content of negative ion powder that can contact with air in surface paint because of abrasion, stablize and discharge
Anion purifies air, is suitable for directly moving in after being coated in room.
2. it is not only environment friendly and pollution-free after water paint of the present invention coating indoors, and each function ingredients cooperate with
Effect, moreover it is possible to which the high efficiency sustained release anion in room plays the role of sterilizing antibacterial, removes formaldehyde, can accomplish actively
Purification promotes the life quality in living space, is used for a long time good for health.
3. construction method of the present invention is simple, even layman perfect can also implement, and painting effect is good, Neng Gouman
The use demand of sufficient consumer.
Specific embodiment
Present invention is further described in detail With reference to embodiment.
Make a kind of water paint of efficiently release anion environmental protection sterilization of the present invention, including priming paint, intermediate layer paint and
Surface lacquer；
The priming paint includes following component according to mass ratio:
| Component | Embodiment one | Embodiment two | Embodiment three |
| Water-soluble synthetic resin | 50 parts | 53 parts | 55 parts |
| Aluminium triphosphate | 13 parts | 15 parts | 17 parts |
| Talcum powder | 17 parts | 18 parts | 20 parts |
| Ethylene glycol | 0.3 part | 0.45 part | 0.5 part |
| Carboxymethyl cellulose | 17 parts | 18.2 parts | 20 parts |
| Amino alcohol solvay-type titanate esters | 3 parts | 3.8 part | 5 parts |
The intermediate layer paint includes following component according to mass ratio:
| Component | Embodiment one | Embodiment two | Embodiment three |
| Tourmaline and lucium | 6 parts | 6.7 part | 7 parts |
| Water-soluble synthetic resin | 40 parts | 48 parts | 60 parts |
| Sodium tripolyphosphate | 0.5 part | 1 part | 1.2 part |
| Soybean lecithin | 0.7 part | 1.1 part | 1.5 part |
The surface paint includes following component according to mass ratio:
| Component | Embodiment one | Embodiment two | Embodiment three |
| Water-soluble negative ion powder | 30 parts | 38 parts | 45 parts |
| Water-soluble synthetic resin | 65 parts | 68 parts | 70 parts |
| Locust bean gum | 8 parts | 9 parts | 11 parts |
| Mica powder | 4 parts | 5 parts | 7 parts |
In the intermediate layer paint in tourmaline and lucium, mixed according to quality than tourmaline with rare earth for 2:6；Wherein
Tourmaline is both needed to respectively be ground to 12000 mesh or more before mixing with rare earth.It is demonstrated experimentally that the clean-up effect of simple tourmaline
It is limited, and tourmaline and rare earth can excite tourmaline to absorb the effect of formaldehyde by the proportion of science, apply in this water paint
In, since surface paint is thin, the tourmaline in intermediate layer paint can still absorb formaldehyde by surface paint, further purify in room
Air quality.
The fineness of water-soluble negative ion powder is 11000 mesh or more in the surface paint.
The preparation construction technology of the water paint of the present invention that anion environmental protection sterilization can efficiently be discharged, comprising as follows
Step:
1) priming paint is prepared
After priming paint is weighed according to component and proportion, it is put into blender after mixing evenly；
2) intermediate layer paint is prepared
Tourmaline and rare earth are weighed respectively first, in accordance with mass ratio, are respectively ground to 12000 mesh or more and are uniformly mixed later；
It weighs water-soluble synthetic resin, sodium tripolyphosphate and soybean lecithin respectively according still further to mass ratio, is mixed uniformly；It will be above-mentioned
Two kinds of mixtures are put into high-speed mixer, under the conditions of 1500 turns/min, vacuum degree -0.6-0.08MPa, are uniformly mixed i.e.
It can；
3) surface paint is prepared
Water-soluble negative ion powder is weighed according to mass ratio, is ground to 11000 mesh or more；By ground water soluble negative
It ion powder and is put into high-speed mixer according to the weighed water-soluble synthetic resin of mass ratio, locust bean gum and mica powder, 1000
Turn/min, vacuum degree -0.6-0.08MPa under the conditions of, be uniformly mixed；
4) it constructs
Priming paint and deionized water are uniformly mixed by first choice according to the ratio of mass ratio 1:1-1.5；It is sprayed on surface to be painted
It primes, coating thickness 0.1-0.8cm is air-dried under the conditions of 20-25 DEG C；By primed surface plucking, plucking depth after air-drying
0.05cm；
Then, intermediate layer paint and deionized water are uniformly mixed according to the ratio of mass ratio 1:1-2；Spray intermediate layer paint, middle layer
The coating thickness of paint is 0.15-0.5cm, is air-dried under the conditions of 25 DEG C；
Finally, surface paint and deionized water are uniformly mixed according to the ratio of mass ratio 1:1-3；Spray surface paint, surface layer
The coating thickness of paint is 0.12-0.15cm, and room temperature is dried in the shade.
Experiment detection of the water paint of the present invention about release anionic property are as follows:
(note: test basis: JC/T1016-2006)
Experimental result shows that negative aeroion average increase is 7054/cm3。
The anti-microbial property test of water paint of the present invention is tested, as a result as follows:
(note: test basis: " disinfection technology standard (2002 editions) ")
Experimental result shows that anti-microbial property and excellent effect of the invention are suitable in the kitchen and bath's environment of house, can be effective
Improve environmental quality.
In addition, experiment shows the synergistic effect due to each component of the present invention, it is added to common anion merely compared with same type
Traditional water paint of powder, the quantity for discharging anion increase 30%, and rate of release increases 58%, bright to the improvement ability of environment
Aobvious enhancing.
The above described is only a preferred embodiment of the present invention, being not that the invention has other forms of limitations, appoint
It is the present invention that those skilled in the art, which is combined possibly also with the technology contents of the disclosure above, changes or retrofits,
Equivalent embodiment.But without departing from the technical solutions of the present invention, implement according to the technical essence of the invention to above
Any simple modification, equivalent variations and remodeling, still fall within the protection scope of technical solution of the present invention made by example.
Claims (4)
1. a kind of water paint of efficiently release anion environmental protection sterilization, it is characterised in that including priming paint, intermediate layer paint and surface paint；
The priming paint includes following component according to mass fraction:
The intermediate layer paint includes following component according to mass fraction:
The surface paint includes following component according to mass fraction:
2. the water paint of efficient release anion environmental protection sterilization according to claim 1, it is characterised in that: the intermediate layer paint
In middle tourmaline and lucium, mixed according to quality than tourmaline with rare earth for 2:6；Wherein tourmaline mixes it with rare earth
Before be both needed to respectively be ground to 12000 mesh or more.
3. the water paint of efficient release anion environmental protection sterilization according to claim 2, it is characterised in that the surface paint
The fineness of middle water solubility negative ion powder is 11000 mesh or more.
4. the preparation construction technology of the water paint of efficient release anion environmental protection sterilization according to claim 1 to 3,
It is characterized in that comprising the following steps:
1) priming paint is prepared
After priming paint is weighed according to component and proportion, it is put into blender after mixing evenly；
2) intermediate layer paint is prepared
Tourmaline and rare earth are weighed respectively first, in accordance with mass ratio, are respectively ground to 12000 mesh or more and are uniformly mixed later；It presses again
It weighs water-soluble synthetic resin, sodium tripolyphosphate and soybean lecithin respectively according to mass ratio, is mixed uniformly；It will be above two
Mixture is put into high-speed mixer, under the conditions of 1500 turns/min, vacuum degree -0.6-0.08MPa, is uniformly mixed；
3) surface paint is prepared
Water-soluble negative ion powder is weighed according to mass ratio, is ground to 11000 mesh or more；By ground water soluble negative ion
Powder and be put into high-speed mixer according to the weighed water-soluble synthetic resin of mass ratio, locust bean gum and mica powder, 1000 turns/
Under the conditions of min, vacuum degree -0.6-0.08MPa, it is uniformly mixed；
4) it constructs
Priming paint and deionized water are uniformly mixed by first choice according to the ratio of mass ratio 1:1-1.5；Bottom is sprayed on surface to be painted
Paint, coating thickness 0.1-0.8cm are air-dried under the conditions of 20-25 DEG C；By primed surface plucking, plucking depth after air-drying
0.05cm；
Then, intermediate layer paint and deionized water are uniformly mixed according to the ratio of mass ratio 1:1-2；Intermediate layer paint is sprayed, intermediate layer paint
Coating thickness is 0.15-0.5cm, is air-dried under the conditions of 25 DEG C；
Finally, surface paint and deionized water are uniformly mixed according to the ratio of mass ratio 1:1-3；Surface paint is sprayed, surface paint
Coating thickness is 0.12-0.15cm, and room temperature is dried in the shade.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610144538.9A CN105694730B (en) | 2016-03-15 | 2016-03-15 | The efficiently water paint of release anion environmental protection sterilization and its preparation construction technology |
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| CN105694730B true CN105694730B (en) | 2019-08-16 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109852162B (en) * | 2019-02-19 | 2021-05-14 | 杭州琻泰环境科技有限公司 | Fireproof organic negative ion coating and preparation method thereof |
| CN111844344A (en) * | 2020-07-20 | 2020-10-30 | 上海苏云木业有限公司 | Anion bamboo-wood fiber glued formaldehyde-free flame-retardant plate and preparation method thereof |
| CN114933843A (en) * | 2022-03-30 | 2022-08-23 | 温州环诺新材料科技有限公司 | Antibacterial environment-friendly water-based paint and preparation method thereof |
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| CN1398933A (en) * | 2002-07-08 | 2003-02-26 | 北京市建筑涂料厂 | Inner wall paint and putty capable of producing negative air ion |
| CN1687268A (en) * | 2005-05-02 | 2005-10-26 | 复旦大学 | Controlled released stably coating material capable of purifying air and preparation method thereof |
| CN1793246A (en) * | 2005-12-31 | 2006-06-28 | 上海申真阿里佳托涂料有限公司 | Anion inorganic nano wall covering |
| CN104726025A (en) * | 2013-12-24 | 2015-06-24 | 什邡市美的一家木业有限责任公司 | Negative ion furniture paint |
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2016
- 2016-03-15 CN CN201610144538.9A patent/CN105694730B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1398933A (en) * | 2002-07-08 | 2003-02-26 | 北京市建筑涂料厂 | Inner wall paint and putty capable of producing negative air ion |
| CN1687268A (en) * | 2005-05-02 | 2005-10-26 | 复旦大学 | Controlled released stably coating material capable of purifying air and preparation method thereof |
| CN1793246A (en) * | 2005-12-31 | 2006-06-28 | 上海申真阿里佳托涂料有限公司 | Anion inorganic nano wall covering |
| CN104726025A (en) * | 2013-12-24 | 2015-06-24 | 什邡市美的一家木业有限责任公司 | Negative ion furniture paint |
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| CN105694730A (en) | 2016-06-22 |
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