CN105419605A - Environment-friendly and odorless furniture and manufacturing method therefor - Google Patents

Environment-friendly and odorless furniture and manufacturing method therefor Download PDF

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Publication number
CN105419605A
CN105419605A CN201510974592.1A CN201510974592A CN105419605A CN 105419605 A CN105419605 A CN 105419605A CN 201510974592 A CN201510974592 A CN 201510974592A CN 105419605 A CN105419605 A CN 105419605A
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China
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furniture
environmental protection
environment
friendly
clean taste
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CN201510974592.1A
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Chinese (zh)
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CN105419605B (en
Inventor
黄毅
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Hunan Mingren Holding Group Co ltd
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Shanghai Taohong Chemical Technology Co Ltd
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Priority to CN201510974592.1A priority Critical patent/CN105419605B/en
Priority to CN201711298785.5A priority patent/CN107760186A/en
Publication of CN105419605A publication Critical patent/CN105419605A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses environment-friendly and odorless furniture and a manufacturing method therefor. The manufacturing method comprises the following steps: (1) carrying out sheet material pretreatment; (2) carrying out wash coat brushing; (3) carrying out putty scraping; (4) carrying out polishing; (5) carrying out undercoat coating; (6) carrying out dry sanding; and (7) brushing a sheet material with a layer of environment-friendly and odorless paint. According to the environment-friendly and odorless furniture disclosed by the invention, used topcoat ingeniously disperses various difficult-dispersed raw materials through selecting reasonable adjuvants and has good anti-microbial and formaldehyde removing functions; by brushing the surface of the furniture with the topcoat, the source of formaldehyde emission is directly blocked, formaldehyde in indoor air is trapped under the condition of normal temperature, formaldehyde is cleared in a standing manner, and thus the quality of the indoor air can be kept normal; and the manufacturing method disclosed by the invention is simple, and the environment-friendly and odorless furniture is environment-friendly, energy-saving, long-life and very attractive, is good in practicability and can adorn and beautify living environment.

Description

Clean taste furniture of environmental protection and preparation method thereof
Technical field
The present invention relates to furniture processing technology field, be specifically related to clean taste furniture of a kind of environmental protection and preparation method thereof.
Background technology
In the China of 21 century, along with the further opening in market, there is the furniture of more and more new style.After basic life requirement is met, some start the impact for health of the quality focusing on life staying idle at home, particularly family product, and therefore environmental protection furniture is valued by the people gradually, and green consumption agitation has also promoted the development of environmental protection furniture.
Environmental protection furniture refers to that those are based on the basis of ecological industry, reasonable development, utilize nature material to produce can meet user's particular demands, be of value to user's health, and there is the furniture of high cultural deposits and scientific and technological content.Wherein comprise which floor implication: one, pollution-free, the toxicological harmless of furniture itself; Two, higher artistic connotation and aesthetic function to be had, echo mutually with indoor design, create a harmonious graceful telecommuting environment; Three, be convenient to reclaim, process, recycling, when furniture no longer use process time, can not to environment.
Plate fitment refers to and is main base material with wood-based plate, take plate as the assembling-disassembling furniture of basic structure.Common artificial board has glued board, core-board, shaving board, medium density fibre board (MDF) etc.Glued board (clamping plate) is usually used in making the diastrophic furniture of needs; Core-board performance affects by board core material matter sometimes; Shaving board (being again particle board, bagasse board) material is loosened, only for low-grade furniture.That cost performance is high, the most the most frequently used is medium density fibre board (MDF) (MDF).The common finishing material of plate fitment has veneer (be commonly called as and paste wooden skin), woodgrained paper (being commonly called as paster), PVC offset plate, polyester lacquer painting (being commonly called as baking vanish) etc.
Furniture lacquer can make woodenware DELICATE AND SIMPLE BAMBOO more attractive in appearance beautiful; improve furniture itself with harsh hand; make furniture not climate and Drought-wet change affect, not only play the effect of Preservation woodenware DELICATE AND SIMPLE BAMBOO, and whole family life can also be made to become more comfortable.
The invention provides the clean taste furniture of a kind of environmental protection, there is excellent antibacterial clean taste performance.
Summary of the invention
For above shortcomings in prior art, one of technical problem to be solved by this invention is to provide the preparation method of the clean taste furniture of a kind of environmental protection.
Two of technical problem to be solved by this invention is to provide the clean taste furniture of environmental protection prepared by aforesaid method.
The present invention seeks to be achieved through the following technical solutions:
A preparation method for the clean taste furniture of environmental protection, comprises the following steps:
(1) sheet material pre-treatment;
(2) brush seal coat
(3) ash is scraped;
(4) polish;
(5) priming;
(6) dry sand;
(7) the clean taste paint of brush one deck environmental protection on sheet material.
Preferably,
Described environmental protection clean taste paint is 1:(0.6-0.9 by main paint, solidifying agent, thinner in mass ratio): (0.4-0.8) is formulated.
Described main paint is prepared from by the raw material of following weight parts: acrylic resin 88-92 part, titanium dioxide 12-18 part, sodium dibutyl naphthalene sulfonate 2-3 part, dimethyl silicone oil 0.4-0.6 part, vinyl acetic monomer 8-12 part, propylene glycol monomethyl ether acetate 8-12 part, antiseptic-germicide 1.8-2.2 part, methanal trapping agent 0.8-2.2 part;
Described antiseptic-germicide is made up of 40-60wt%1-methylol-5,5-dimethyl hydantion and 40-60wt%1,3-dihydroxy ethyl-5,5-dimethyl hydantion.
Described methanal trapping agent is by 2-hydroxy-2-methyl propionyl hydrazine, 2,2-dimethyl propylene hydrazides, malonyl-hydrazine mix, the mass ratio of described 2-hydroxy-2-methyl propionyl hydrazine, 2,2-dimethyl propylene hydrazides, malonyl-hydrazine is (1-3): (1-3): (1-3).
Described solidifying agent, can adopt the DesmodurN-3390 hexamethylene diisocyanate trimer of the DesmodurN-75 hexamethylene diisocyanate biruet of German Bayer company or German Bayer company.
Further, described solidifying agent can by 50-60wt% vinyl acetic monomer and 40-50wt%1, and hexamethylene-diisocyanate is prepared from.
Described thinner can adopt the omnipotent board Polyester Paint thinner of Yongkang City navigation chemical industry operation or the model of Shanghai Tian Da coating company limited to be XSSJ-8 thinner.
Further, described thinner is prepared from by 50-60wt% vinyl acetic monomer and 40-50wt% propylene glycol monomethyl ether acetate.
Described acrylic resin can adopt the DesmophenAXP2412 of German Bayer company, and hydroxyl value is 66.
Present invention also offers the preparation method of above-mentioned main paint: acrylic resin, titanium dioxide, sodium dibutyl naphthalene sulfonate, dimethyl silicone oil, antiseptic-germicide, methanal trapping agent, vinyl acetic monomer added in high speed dispersor and mix; Again through sand mill sand milling to fineness be 25-35 μm; Add propylene glycol monomethyl ether acetate again to mix, obtain described main paint.
Present invention also offers the preparation method of above-mentioned solidifying agent: vinyl acetic monomer and hexamethylene diisocyanate are mixed, obtain described solidifying agent.
Present invention also offers the preparation method of above-mentioned thinner: vinyl acetic monomer and propylene glycol monomethyl ether acetate are mixed, obtain described thinner.
Present invention also offers the clean taste furniture of a kind of environmental protection, adopt aforesaid method to be prepared from.
Concrete, in the present invention:
Hexamethylene diisocyanate, No. CAS: 822-06-0.
Vinyl acetic monomer, No. CAS: 141-78-6.
Propylene glycol monomethyl ether acetate, No. CAS: 148462-57-1.
Sodium dibutyl naphthalene sulfonate, No. CAS: 25417-20-3.
Dimethyl silicone oil, No. CAS: 63148-62-9.
1-methylol-5,5-dimethyl hydantion, No. CAS: 116-25-6.
1,3-dihydroxy ethyl-5,5-dimethyl hydantion, No. CAS: 26850-24-8.
2-hydroxy-2-methyl propionyl hydrazine, No. CAS: 42596-46-3.
2,2-dimethyl propylene hydrazides, No. CAS: 42826-42-6.
Malonyl-hydrazine, No. CAS: 3815-86-9.
The clean taste furniture of environmental protection of the present invention, finish paint used is by selecting reasonable auxiliary agent, the starting material of various difficulty dispersion are disperseed cleverly, there is good antibacterial aldehydes removal function, brushing, at furniture surface, is not only directly blocked the root of formaldehyde emission, and is caught formaldehyde in indoor air under possessing normal temperature condition, permanently effective removing formaldehyde, makes IAQ (indoor air quality) keep normal; Preparation technology of the present invention is simple, and be a kind of environmental protection, energy-conservation, life-span length, furniture very attractive in appearance, practicality is good, can intersperse and beautify the living environment.
Embodiment
Below in conjunction with embodiment, the present invention is described further, the following stated, only to preferred embodiment of the present invention, not do other forms of restriction to the present invention, any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed to the Equivalent embodiments of equal change.Everyly do not depart from the present invention program's content, any simple modification done following examples according to technical spirit of the present invention or equivalent variations, all drop in protection scope of the present invention.
Embodiment raw material is introduced:
Titanium dioxide, No. CAS: 13463-67-7, adopt Du Pont, model is the rutile titanium dioxide of R-960.
Acrylic resin, No. CAS: 9003-01-4.The model adopting Shenzhen Jin Fengyuan macromolecular material company limited to provide is the thermoplastic acrylic resin of RS-68P.
Medium density fibre board (MDF), adopts Suzhou City Tian Yemu industry company limited specification to be 4*10*12, pine medium density fibre board (MDF).
Sand paper, adopt Korea S deer board DEERFOS sand paper, model is ACM66, granularity is 240,400,600 3 kind of specification.
Embodiment 1
Main raw materials for varnish: acrylic resin 90kg, titanium dioxide 15kg, sodium dibutyl naphthalene sulfonate 2.5kg part, dimethyl silicone oil 0.5kg, vinyl acetic monomer 10kg, propylene glycol monomethyl ether acetate 10kg, antiseptic-germicide 2kg, methanal trapping agent 1.8kg.
Described antiseptic-germicide is made up of 1kg1-methylol-5,5-dimethyl hydantion and 1kg1,3-dihydroxy ethyl-5,5-dimethyl hydantion.
Described methanal trapping agent is mixed by 0.6kg2-hydroxy-2-methyl propionyl hydrazine, 0.6kg2,2-dimethyl propylene hydrazides, 0.6kg malonyl-hydrazine.
The preparation method of main paint: linear velocity high speed dispersion acrylic resin, titanium dioxide, sodium dibutyl naphthalene sulfonate, dimethyl silicone oil, antiseptic-germicide, methanal trapping agent, vinyl acetic monomer being added 25m/s in high speed dispersor mixes for 25 minutes; Again through sand mill sand milling to fineness be 30 μm; Add propylene glycol monomethyl ether acetate to be again uniformly mixed, obtain described main paint.
Solidifying agent is by 55kg vinyl acetic monomer and 45kg1, and hexamethylene-diisocyanate is prepared from.Vinyl acetic monomer and hexamethylene diisocyanate are added stirrer for mixing even, obtain described solidifying agent.
Described thinner is prepared from by 55kg vinyl acetic monomer and 45kg propylene glycol monomethyl ether acetate.Vinyl acetic monomer and propylene glycol monomethyl ether acetate are added stirrer for mixing even, obtain described thinner.
The preparation method of the clean taste furniture of environmental protection, comprises the following steps:
(1) medium density fibre board (MDF) granularity is that the sand paper of 240 carries out sanding polishing by sheet material pre-treatment, polishing rear surface dedusting;
(2) brush seal coat, adopts painting way uniform brush one deck seal coat (adopting the 2L woodenware sealing wax seal coat that Hebei Chenyang IndustrialL&trade Group Co., Ltd. produces) on sheet material, japanning amount 100g/m 2;
(3) ash is scraped, by fresh pig blood and titanium dioxide in mass ratio for 9:1 mixes, fresh pig blood and titanium dioxide after uniform brush one deck mixing on sheet material, applying amount 50g/m 2;
(4) polish; Sanding polishing is carried out, polishing rear surface dedusting with the sand paper that granularity is 400;
(5) priming; by the main paint of the clear priming paint of the excellent PU of obliging woodenware of Zijinghua Paint's production, solidifying agent, thinner in mass ratio for 2:1:0.8 mixes; adopt painting way uniform priming on sheet material, japanning amount 100g/m 2;
(6) dry sand: carry out sanding polishing with the sand paper that granularity is 600, polishing rear surface dedusting;
(7) upper finish paint, mixes for 1:0.8:0.6 in mass ratio by the main paint of clean for environmental protection taste paint, solidifying agent, thinner, adopts painting way clean taste paint of uniform brush one deck environmental protection on sheet material, japanning amount 200g/m 2, adopt halogen lamp uniform irradiation 1h on sheet material, dry, the clean taste furniture of environmental protection of the present invention can be obtained.
Embodiment 2
Prepare the clean taste furniture of environmental protection by the method for embodiment 1, difference is only: described methanal trapping agent is mixed by 0.9kg2-hydroxy-2-methyl propionyl hydrazine, 0.9kg2,2-dimethyl propylene hydrazides.Obtain the clean taste furniture of environmental protection of embodiment 2.
Embodiment 3
Prepare the clean taste furniture of environmental protection by the method for embodiment 1, difference is only: described methanal trapping agent is mixed by 0.9kg2-hydroxy-2-methyl propionyl hydrazine, 0.9kg malonyl-hydrazine.Obtain the clean taste furniture of environmental protection of embodiment 3.
Embodiment 4
Prepare the clear taste furniture of high color inhibition draft by the method for embodiment 1, difference is only: described methanal trapping agent is mixed by 0.9kg2,2-dimethyl propylene hydrazides, 0.9kg malonyl-hydrazine.Obtain the clear taste furniture of high color inhibition draft of embodiment 4.
Embodiment 5
Prepare the clean taste furniture of environmental protection by the method for embodiment 1, difference is only: described antiseptic-germicide is 2kg1-methylol-5,5-dimethyl hydantion.Obtain the clean taste furniture of environmental protection of embodiment 5.
Embodiment 6
Prepare the clean taste furniture of environmental protection by the method for embodiment 1, difference is only: described antiseptic-germicide is 2kg1,3-dihydroxy ethyl-5,5-dimethyl hydantion.Obtain the clean taste furniture of environmental protection of embodiment 6.
Test case 1
The obtained furniture of above-described embodiment 1-6 is carried out performance test.
Measure the purifying formaldehyde performance of paint film by JC/T1074-2008, wherein purifying formaldehyde performance >=75% be I class, >=80% be II class, decontamination effect improving persistence >=60% is I class, and >=65% is II class; Anti-microbial property presses GB/T21866-2008 antibiotic paint anti-microbial property measuring method and antibacterial effect, HG/T3980-2007 antibiotic paint measure, and test item is antibacterial test and fungus-proof test.
Antibacterial test: intestinal bacteria ATYCC25922, streptococcus aureus ATCC6538.
Fungus-proof test: aspergillus niger AS3.4463, terreus AS3.3935, paecilomyces varioti AS3.4253, penicillium funiculosum AS3.3875, Aureobasidium pullulans AS3.3984, Chaetomium globosum AS3.4254.Fungus-proof test judgement criteria comprises: 0 grade is not namely long, amplifies 50 times of lower observations and have no growth under microscope; 1 grade of i.e. vestige growth, i.e. naked eyes visible growth, but growth area coverage is less than 10%; Namely 2 grades grow area coverage and be greater than 10%; Concrete test-results is as shown in table 1-3:
Table 1: environmental protection clean taste furniture performance test results table
Comparing embodiment 1-4, (methanal trapping agent adopts 2-hydroxy-2-methyl propionyl hydrazine, 2 to embodiment 1,2-dimethyl propylene hydrazides, malonyl-hydrazine are composite) purifying formaldehyde successful is better than embodiment 2-4 (methanal trapping agent to adopt in 2-hydroxy-2-methyl propionyl hydrazine, 2,2-dimethyl propylene hydrazides, malonyl-hydrazine arbitrarily both composite); Comparing embodiment 1 and embodiment 5-6, (antiseptic-germicide adopts 1-methylol-5 to embodiment 1,5-dimethyl hydantion and 1,3-dihydroxy ethyl-5,5-dimethyl hydantion is composite) anti-microbial property is obviously better than embodiment 5-6 (antiseptic-germicide adopts 1-methylol-5, single raw material in 5-dimethyl hydantion and 1,3-dihydroxy ethyl-5,5-dimethyl hydantion).
The stability in storage of the clean taste paint of the present invention's environmental protection used is good, and the content of objectionable impurities is all within the claimed range of GB18581-2009, and the present invention has enough safety in utilization; Paint film water white transparency, flat smooth, resistance to acids and bases are good, have good defencive function to coated family.

Claims (4)

1. a preparation method for the clean taste furniture of environmental protection, is characterized in that, comprise the following steps:
(1) sheet material pre-treatment;
(2) brush seal coat;
(3) ash is scraped;
(4) polish;
(5) priming;
(6) dry sand;
(7) the clean taste paint of brush one deck environmental protection on sheet material.
Described environmental protection clean taste paint is 1:(0.6-0.9 by main paint, solidifying agent, thinner in mass ratio): (0.4-0.8) is formulated;
Described main paint is prepared from by the raw material of following weight parts: acrylic resin 88-92 part, titanium dioxide 12-18 part, sodium dibutyl naphthalene sulfonate 2-3 part, dimethyl silicone oil 0.4-0.6 part, vinyl acetic monomer 8-12 part, propylene glycol monomethyl ether acetate 8-12 part, antiseptic-germicide 1.8-2.2 part, methanal trapping agent 0.8-2.2 part;
Described antiseptic-germicide is made up of 40-60wt%1-methylol-5,5-dimethyl hydantion and 40-60wt%1,3-dihydroxy ethyl-5,5-dimethyl hydantion.
Described methanal trapping agent is by 2-hydroxy-2-methyl propionyl hydrazine, 2,2-dimethyl propylene hydrazides, malonyl-hydrazine mix, the mass ratio of described 2-hydroxy-2-methyl propionyl hydrazine, 2,2-dimethyl propylene hydrazides, malonyl-hydrazine is (1-3): (1-3): (1-3).
2. the preparation method of the clean taste furniture of environmental protection as claimed in claim 1, it is characterized in that, described solidifying agent can by 50-60wt% vinyl acetic monomer and 40-50wt%1, and hexamethylene-diisocyanate is prepared from.
3. the preparation method of the clean taste furniture of environmental protection as claimed in claim 1, it is characterized in that, described thinner is prepared from by 50-60wt% vinyl acetic monomer and 40-50wt% propylene glycol monomethyl ether acetate.
4. the clean taste furniture of environmental protection, is characterized in that, adopts method according to any one of claim 1-3 to be prepared from.
CN201510974592.1A 2015-12-22 2015-12-22 Environmentally friendly net taste furniture and preparation method thereof Active CN105419605B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106366803A (en) * 2016-08-29 2017-02-01 广东花王涂料有限公司 Outdoor woodware coating technology

Citations (2)

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Publication number Priority date Publication date Assignee Title
CN101181677A (en) * 2007-06-20 2008-05-21 北京理工大学 High-efficiency formaldehyde scavenging agent
CN104119792A (en) * 2014-07-19 2014-10-29 金甲化工企业(中山)有限公司 Double-component polyurethane coating capable of eliminating formaldehyde in air

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101181677A (en) * 2007-06-20 2008-05-21 北京理工大学 High-efficiency formaldehyde scavenging agent
CN104119792A (en) * 2014-07-19 2014-10-29 金甲化工企业(中山)有限公司 Double-component polyurethane coating capable of eliminating formaldehyde in air

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
叶汉慈: "《木用涂料与涂装工》", 31 October 2008, 化学工艺出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106366803A (en) * 2016-08-29 2017-02-01 广东花王涂料有限公司 Outdoor woodware coating technology

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CN107760186A (en) 2018-03-06

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