CN103834181B - Durable wood wax oil of a kind of environmental protection and preparation method thereof - Google Patents
Durable wood wax oil of a kind of environmental protection and preparation method thereof Download PDFInfo
- Publication number
- CN103834181B CN103834181B CN201410092563.8A CN201410092563A CN103834181B CN 103834181 B CN103834181 B CN 103834181B CN 201410092563 A CN201410092563 A CN 201410092563A CN 103834181 B CN103834181 B CN 103834181B
- Authority
- CN
- China
- Prior art keywords
- oil
- environmental protection
- wood wax
- wax oil
- durable wood
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Paints Or Removers (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The present invention relates to woodwork paint field, be specifically related to durable wood wax oil of a kind of environmental protection and preparation method thereof, its feed components is counted by weight and is comprised: vegetables oil 50-80 part, biological wax 5-20 part, dammar gum 5-10 part, Virahol 5-10 part, ethyl ester 5-10 part, nano silicon 3-5 part, water glass 3-5 part, calcium sulfate 3-5 part, silicone emulsion 2-5 part, polyvinyl butyral acetal 2-5 part, siccative 0.5-1 part, anti skinning agent 0.1-0.3 part, UV light absorber 0.1-0.3 part, mould inhibitor 0.1-0.3 part, wherein, vegetables oil is tung oil and terebinthine mixture, tung oil is 15-30 part, turps is 40-60 part.This durability of product is better, low temperature resistant, fire prevention, not easily peeling, and wear resistance is good, and glossiness is good, can be widely used in the coating protection of woodwork.Its preparation method provides guarantee for this product.
Description
Technical field
The present invention relates to woodwork paint field, be specifically related to durable wood wax oil of a kind of environmental protection and preparation method thereof.
Background technology
Timber itself is not fine and close as metal, and there are a large amount of pore and gap in its surface and inside, and addle foul is easy to infiltrate wood internal along these pores and gap, so do not bear dirty without the furniture surface pole of oil, paint, wax covering with paint.Meanwhile, timber is in atmosphere exposed, and when air ambient is drier, the moisture of timber own can outwards scatter and disappear, and wooden contraction and each several part shrink uneven, will form cracking; When atmospheric moisture is comparatively large or when soaking, timber water-swelling, has easily been out of shape drum again.Use so be that nothing is normal at country's solid wood furniture that we make a clear distinction between the four seasons without covering with paint.Although the protected mode of paint covers the airtight paint film of last layer at wood surface, thoroughly by addle foul and woodenly to keep apart, foul, water to be fallen on lacquer painting and one can have been wiped it, it also avoid timber cause cracking because moisture runs off rapidly with air insulated.But because paint is rich in various to the virulent chemical substance of human body; The few valency height drying conditions of lacquer amount of pure natural is harsh, and the as easy as rolling off a log brushing person's allergy that allows, can cause concrete injury to HUMAN HEALTH.
Wood wax oil is domestic being commonly called as of vegetables oil Wax coatings, a kind of similar paint and the natural woodwork coating being different from paint, it and that paint produced based on petrochemical industry class synthetic resins is completely different at present, raw material mainly with the crude vegetals such as concise oleum lini, palm wax with vegetable wax and coordinate some other natural component merge form, pigment used of mixing colours also reaches food grade.Therefore it is not containing toxic ingredients such as triphen, formaldehyde and heavy metals, does not have pungent smell, and alternative paint is used for house decoration and outdoor garden woodenware.Because oil can penetrate into wood internal, deep layer is carried out to timber and moistens maintenance; Wax can be combined closely with lumber fibre, strengthens surface hardness, water proof anti-soil, and therefore concerning timber, such gold combination can provide outstanding beautifying and provide protection.
But current wood wax oil also exists some defects, as inadequate environmental protection; Poor durability, along with the increase of time, the protection of wood wax oil to timber reduces gradually; Although wood wax oil is protected wood surface, to the profound level inside of timber, but protection is inadequate for it; Not high enough with timber conjugation; Coated side slickness and wear resistance poor.
Summary of the invention
The object of the invention is, in order to overcome at present for the problems referred to above that the wood wax oil of timber coating exists, to provide durable wood wax oil of a kind of environmental protection and preparation method thereof.
In order to reach foregoing invention object, the present invention by the following technical solutions:
The durable wood wax oil of a kind of environmental protection, its feed components is counted by weight and is comprised: vegetables oil 55-80 part, biological wax 5-20 part, dammar gum 5-10 part, Virahol 5-10 part, ethyl ester 5-10 part, nano silicon 3-5 part, water glass 3-5 part, calcium sulfate 3-5 part, silicone emulsion 2-5 part, polyvinyl butyral acetal 2-5 part, siccative 0.5-1 part, anti skinning agent 0.1-0.3 part, UV light absorber 0.1-0.3 part, mould inhibitor 0.1-0.3 part, wherein, vegetables oil is tung oil and terebinthine mixture, tung oil is 15-30 part, and turps is 40-60 part.
Because dammar gum softening temperature is higher, the wood wax oil therefore adopting it to prepare is durable in use; Because dammar gum compares indissoluble solution, mix so adopt Virahol and ethyl ester to carry out auxiliary its with vegetables oil.Nano silicon not only can increase the hardness of coat and improve its fastness to rubbing, can penetrate in timber space simultaneously, forms provide protection to wood internal;
The combination of polyvinyl butyral acetal and silicone emulsion can not only be played waterproof, improve surface tension coat, thus play and scold water effect, and, the conjugation of wood wax oil and timber can be improved, thus avoid wood wax oil to peel off after application, fp effect can also be played.
Preferably, biological wax is one or more in carnauba wax, gama wax, beeswax or insect wax.
Preferably, described siccative is organic acid metal soap.
Preferably, anti skinning agent is anti skinning agent is methyl ethyl ketoxime or Diacetylmonoxime.
Preferably, UV light absorber is benzotriazole.
Preferably, mould inhibitor is copper 8-quinolinolate.
Preferably, the particle diameter of nano silicon is 10-30nm.Nano silicon be added in the hardness that can improve coat to a certain extent, improve the wear resistance of coat, meanwhile, the better effect of nano silicon to penetrate in timber space, and therefore less particle diameter contributes to nano silicon and is combined with timber space.In addition, silicon-dioxide
Water glass add the anti-cryogenic effect that can improve wood wax oil, prevent from causing the peeling of wood wax oil coat or the generation of breakoff phenomenon at low temperatures.
Calcium sulfate add the time of coagulation that not only can adjust wood wax oil, wood wax oil film formation time is reduced, simultaneously calcium sulfate can improve the polishing degree of wood wax oil coat, can in conjunction with follow-up technique for grinding, is slightly polishing or wiping both can obtain good luster effect.
Various supplementary additive add the solid content that improve wood wax oil, thus improve the practical coating effect of wood wax oil, reduce coating difficulty.
Preferably, the particle diameter≤50nm of water glass.
Preferably, the particle diameter≤50nm of calcium sulfate.
A preparation method for the durable wood wax oil of environmental protection, comprises the following steps:
(1) count by weight, to get tung oil be 15-30 part and turps is 40-60 part, and the two amounts to 55-80 part and mixes and be preheated to 160-180 DEG C; Meanwhile, dammar gum 5-10 part is mixed post-heating to 80 DEG C with Virahol 5-10 part, ethyl ester 5-10 part; The heat-processed of two kinds of mixtures adopts ultrasonic wave heating; Meanwhile, by nano silicon 3-5 part, water glass 3-5 part, calcium sulfate 3-5 part, polyvinyl butyral acetal 2-5 part, siccative 0.5-1 part, anti skinning agent 0.1-0.3 part, UV light absorber 0.1-0.3 part, mould inhibitor 0.1-0.3 part mixes and stirs;
(2) after the rear holding temperature of above-mentioned first two mixture mixing being kept 0.5h at 160-170 DEG C, and when continuous stirring and Ultrasonic Heating, in 10min, add last a kind of mixture uniformly continous, and stir;
(3) then after the mixture of step (2) is kept 2-3h at 147-158 DEG C, add silicone emulsion 2-5 part, stir;
(4) then the mixture that step (3) obtains is cooled to room temperature and obtains wood wax oil.
By this preparation method, the combination of dammar gum and vegetables oil can be improved, thus improve the homogeneity of wood wax oil, finally ensure that the quality of wood wax oil product.
Compared with prior art, beneficial effect is in the present invention:
1, weather resistance is better, can there will not be performance variation keeping for a long time;
2, timber deep internal can be deep into, carry out available protecting to wooden;
3, better with the conjugation of timber, can not come off because of external force easily;
4, coated side glossiness is better, and wear resistance is better;
5, coat has ventilation property, can prevent gaseous volatilization in timber from causing coat peeling;
6, there is fire line;
7, low temperature resistant;
8, environmental protection.
Embodiment
Below by specific embodiment, explanation is further described to technical scheme of the present invention.
If without specified otherwise, the raw material adopted in embodiments of the invention is the conventional raw material in this area, and the method adopted in embodiment, is the ordinary method of this area.
Embodiment 1:
A preparation method for the durable wood wax oil of environmental protection, comprises the following steps:
(1) count by weight, to get tung oil be 15 parts and turps is 40 parts, and the two amounts to 55 parts and mixes and be preheated to 170 DEG C; Meanwhile, dammar gum 10 parts and Virahol 5 parts, ethyl ester 7 parts are mixed post-heating to 80 DEG C; The heat-processed of two kinds of mixtures adopts ultrasonic wave heating; Meanwhile, by nano silicon 5 parts, water glass 3 parts, 4 parts, calcium sulfate, polyvinyl butyral acetal 5 parts, siccative 0.5 part, anti skinning agent 0.2 part, UV light absorber 0.3 part, mould inhibitor 0.1 part mixes and stirs;
(2) after the rear holding temperature of above-mentioned first two mixture mixing being kept 0.5h at 165 DEG C, and when continuous stirring and Ultrasonic Heating, in 10min, add last a kind of mixture uniformly continous, and stir;
(3) then after the mixture of step (2) is kept 2h at 158 DEG C, add silicone emulsion 3 parts, stir;
(4) then the mixture that step (3) obtains is cooled to room temperature and obtains wood wax oil.
Biological wax is carnauba wax; Siccative is organic acid metal soap; Anti skinning agent is anti skinning agent is methyl ethyl ketoxime or Diacetylmonoxime; UV light absorber is benzotriazole; Mould inhibitor is copper 8-quinolinolate; The particle diameter of nano silicon is 30nm; Particle diameter≤the 50nm of water glass; Particle diameter≤the 50nm of calcium sulfate.
Embodiment 2:
A preparation method for the durable wood wax oil of environmental protection, comprises the following steps:
(1) count by weight, to get tung oil be 30 parts and turps is 50 parts, and the two amounts to 80 parts and mixes and be preheated to 160 DEG C; Meanwhile, dammar gum 7 parts and Virahol 5 parts, ethyl ester 7 parts are mixed post-heating to 80 DEG C; The heat-processed of two kinds of mixtures adopts ultrasonic wave heating; Meanwhile, by nano silicon 5 parts, water glass 3 parts, 4 parts, calcium sulfate, polyvinyl butyral acetal 5 parts, siccative 0.5 part, anti skinning agent 0.2 part, UV light absorber 0.3 part, mould inhibitor 0.1 part mixes and stirs;
(2) after the rear holding temperature of above-mentioned first two mixture mixing being kept 0.5h at 165 DEG C, and when continuous stirring and Ultrasonic Heating, in 10min, add last a kind of mixture uniformly continous, and stir;
(3) then after the mixture of step (2) is kept 2h at 158 DEG C, add silicone emulsion 4 parts, stir;
(4) then the mixture that step (3) obtains is cooled to room temperature and obtains wood wax oil.
Biological wax is gama wax; Siccative is organic acid metal soap; Anti skinning agent is anti skinning agent is Diacetylmonoxime; UV light absorber is benzotriazole; Mould inhibitor is copper 8-quinolinolate; The particle diameter of nano silicon is 20nm; Particle diameter≤the 50nm of water glass; Particle diameter≤the 50nm of calcium sulfate.
Embodiment 3:
A preparation method for the durable wood wax oil of environmental protection, comprises the following steps:
(1) count by weight, to get tung oil be 18 parts and turps is 60 parts, and the two amounts to 78 parts and mixes and be preheated to 180 DEG C; Meanwhile, dammar gum 5 parts and Virahol 7 parts, ethyl ester 10 parts are mixed post-heating to 80 DEG C; The heat-processed of two kinds of mixtures adopts ultrasonic wave heating; Meanwhile, by nano silicon 3 parts, water glass 4 parts, 5 parts, calcium sulfate, polyvinyl butyral acetal 2 parts, siccative 0.8 part, anti skinning agent 0.3 part, UV light absorber 0.1 part, mould inhibitor 0.2 part mixes and stirs;
(2) after the rear holding temperature of above-mentioned first two mixture mixing being kept 0.5h at 170 DEG C, and when continuous stirring and Ultrasonic Heating, in 10min, add last a kind of mixture uniformly continous, and stir;
(3) then after the mixture of step (2) is kept 2.5h at 147 DEG C, add silicone emulsion 5 parts, stir;
(4) then the mixture that step (3) obtains is cooled to room temperature and obtains wood wax oil.
Biological wax is beeswax; Siccative is organic acid metal soap; Anti skinning agent is anti skinning agent is methyl ethyl ketoxime; UV light absorber is benzotriazole; Mould inhibitor is copper 8-quinolinolate; The particle diameter of nano silicon is 10nm; Particle diameter≤the 50nm of water glass; Particle diameter≤the 50nm of calcium sulfate.
Claims (10)
1. the durable wood wax oil of environmental protection, it is characterized in that, its feed components is counted by weight and is comprised: vegetables oil 50-80 part, biological wax 5-20 part, dammar gum 5-10 part, Virahol 5-10 part, ethyl ester 5-10 part, nano silicon 3-5 part, water glass 3-5 part, calcium sulfate 3-5 part, silicone emulsion 2-5 part, polyvinyl butyral acetal 2-5 part, siccative 0.5-1 part, anti skinning agent 0.1-0.3 part, UV light absorber 0.1-0.3 part, mould inhibitor 0.1-0.3 part, wherein, vegetables oil is tung oil and terebinthine mixture, tung oil is 15-30 part, turps is 40-60 part.
2. the durable wood wax oil of a kind of environmental protection according to claim 1, is characterized in that, biological wax is one or more in carnauba wax, gama wax, beeswax or insect wax.
3. the durable wood wax oil of a kind of environmental protection according to claim 1, is characterized in that, described siccative is organic acid metal soap.
4. the durable wood wax oil of a kind of environmental protection according to claim 1, is characterized in that, anti skinning agent is methyl ethyl ketoxime or Diacetylmonoxime.
5. the durable wood wax oil of a kind of environmental protection according to claim 1, is characterized in that, UV light absorber is benzotriazole.
6. the durable wood wax oil of a kind of environmental protection according to claim 1, is characterized in that, mould inhibitor is copper 8-quinolinolate.
7. the durable wood wax oil of a kind of environmental protection according to claim 1, is characterized in that, the particle diameter of nano silicon is 10-30nm.
8. the durable wood wax oil of a kind of environmental protection according to claim 1, is characterized in that, the particle diameter≤50nm of water glass.
9. the durable wood wax oil of a kind of environmental protection according to claim 1, is characterized in that, the particle diameter≤50nm of calcium sulfate.
10. a preparation method for the durable wood wax oil of a kind of environmental protection as claimed in claim 1, is characterized in that, comprise the following steps:
(1) count by weight, to get tung oil be 15-30 part and turps is 40-60 part, and the two amounts to 50-80 part and mixes and be preheated to 160-180 DEG C; Meanwhile, dammar gum 5-10 part is mixed post-heating to 80 DEG C with Virahol 5-10 part, ethyl ester 5-10 part; The heat-processed of two kinds of mixtures adopts ultrasonic wave heating; Meanwhile, by nano silicon 3-5 part, water glass 3-5 part, calcium sulfate 3-5 part, polyvinyl butyral acetal 2-5 part, siccative 0.5-1 part, anti skinning agent 0.1-0.3 part, UV light absorber 0.1-0.3 part, mould inhibitor 0.1-0.3 part mixes and stirs;
(2), after the rear holding temperature of above-mentioned first two mixture mixing being kept 0.5h at 160-170 DEG C, when continuous stirring and Ultrasonic Heating, in 10min, add last a kind of mixture uniformly continous, and stir;
(3) then after the mixture of step (2) is kept 2-3h at 147-158 DEG C, add silicone emulsion 2-5 part, stir;
(4) then the mixture that step (3) obtains is cooled to room temperature and obtains wood wax oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410092563.8A CN103834181B (en) | 2014-03-14 | 2014-03-14 | Durable wood wax oil of a kind of environmental protection and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410092563.8A CN103834181B (en) | 2014-03-14 | 2014-03-14 | Durable wood wax oil of a kind of environmental protection and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103834181A CN103834181A (en) | 2014-06-04 |
| CN103834181B true CN103834181B (en) | 2016-02-10 |
Family
ID=50798092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410092563.8A Active CN103834181B (en) | 2014-03-14 | 2014-03-14 | Durable wood wax oil of a kind of environmental protection and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103834181B (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105860793A (en) * | 2015-01-21 | 2016-08-17 | 湖南邦弗特新材料技术有限公司 | Durable anti-mildew aqueous wood wax oil, preparation method thereof and application technology thereof |
| CN105440946B (en) * | 2015-12-25 | 2017-11-10 | 北京楚之园环保科技有限责任公司 | Nanometer water wood wax oil and preparation method thereof |
| CN105820755A (en) * | 2016-05-24 | 2016-08-03 | 台州市黄岩海耀工艺品有限公司 | Wall-hung decoration |
| CN106000837A (en) * | 2016-05-30 | 2016-10-12 | 安徽栢林洁具有限公司 | Method for spraying high-pressure steam to bathroom cabinet panel |
| CN105969310A (en) * | 2016-05-30 | 2016-09-28 | 安徽栢林洁具有限公司 | Bottom layer abrasive material for treating bathroom cabinet plates |
| CN106078527B (en) * | 2016-05-30 | 2018-11-09 | 安徽栢林洁具有限公司 | A method of handling bathroom cabinet plank using abrasive material |
| CN106078529B (en) * | 2016-05-30 | 2018-10-02 | 安徽栢林洁具有限公司 | A method of handling bathroom cabinet plank using bottom abrasive material |
| CN106433466A (en) * | 2016-10-11 | 2017-02-22 | 安徽卡塔门窗有限公司 | Environment-friendly coating for door and preparation method of environment-friendly coating |
| CN106752944A (en) * | 2016-12-15 | 2017-05-31 | 江门市蓬江区文森装饰材料有限公司 | A kind of wood paint wood wax oil |
| GB2559137B (en) * | 2017-01-25 | 2022-01-19 | Nicholas Robb Benjamin | Surface coating composition |
| CN106987207B (en) * | 2017-05-11 | 2018-04-24 | 邱平亮 | A kind of environment-friendly spray coating type wood wax oil and its preparation method and application |
| CN107022308B (en) * | 2017-06-01 | 2018-03-30 | 邱平亮 | A kind of UV hardening types wood wax oil and its preparation method and application |
| CN107254254B (en) * | 2017-06-07 | 2019-05-28 | 河北晨阳工贸集团有限公司 | A kind of high conjugation environment-friendlydurable durable wood wax oil and preparation method thereof |
| CN107868614A (en) * | 2017-12-14 | 2018-04-03 | 广东顺德三阳化学有限公司 | A kind of environment-protection nano haze tallow fluid composition and preparation method thereof |
| CN110452616A (en) * | 2019-08-14 | 2019-11-15 | 杭州易贝环保科技有限公司 | A kind of high-durability solid wood maintenance essential oil and preparation method thereof |
| CN110655863A (en) * | 2019-10-17 | 2020-01-07 | 杭州宝力体育设施工程有限公司 | Novel environment-friendly anticorrosive finish paint |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1217051A2 (en) * | 2000-12-22 | 2002-06-26 | Cera Rica Noda Co., Ltd. | Surface treating agent for ligneous floorings and process for manufacturing the same |
| CN101974292A (en) * | 2010-10-09 | 2011-02-16 | 广东嘉宝莉化工集团有限公司 | Hard wax oil and preparation method thereof |
| CN102284990A (en) * | 2011-06-22 | 2011-12-21 | 嘉宝莉化工集团股份有限公司 | White wood wax oil for woodware and preparation method thereof |
| CN102408828A (en) * | 2011-09-29 | 2012-04-11 | 刘光君 | Nano silicon dioxide modified hard wood wax oil and preparation method thereof |
| CN102993966A (en) * | 2012-12-07 | 2013-03-27 | 江门市冠洋涂料化工有限公司 | Wood wax oil and preparation process thereof |
-
2014
- 2014-03-14 CN CN201410092563.8A patent/CN103834181B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1217051A2 (en) * | 2000-12-22 | 2002-06-26 | Cera Rica Noda Co., Ltd. | Surface treating agent for ligneous floorings and process for manufacturing the same |
| CN101974292A (en) * | 2010-10-09 | 2011-02-16 | 广东嘉宝莉化工集团有限公司 | Hard wax oil and preparation method thereof |
| CN102284990A (en) * | 2011-06-22 | 2011-12-21 | 嘉宝莉化工集团股份有限公司 | White wood wax oil for woodware and preparation method thereof |
| CN102408828A (en) * | 2011-09-29 | 2012-04-11 | 刘光君 | Nano silicon dioxide modified hard wood wax oil and preparation method thereof |
| CN102993966A (en) * | 2012-12-07 | 2013-03-27 | 江门市冠洋涂料化工有限公司 | Wood wax oil and preparation process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103834181A (en) | 2014-06-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103834181B (en) | Durable wood wax oil of a kind of environmental protection and preparation method thereof | |
| CN101974292B (en) | Hard wax oil and preparation method thereof | |
| CN106243966A (en) | A kind of composite multifunction double-component aqueous woodenware white finish paint and preparation method thereof | |
| CN101845274A (en) | Coating combination for pure natural woodenware | |
| CN103331791A (en) | Novel hard environment-friendly wood wax oil and preparation method thereof | |
| CN110330892A (en) | A kind of open air high durable type aqueous wood wax oil and preparation method thereof | |
| CN105729597A (en) | Color smoking treatment technology for wood modification face layer | |
| CN105440946A (en) | Nano water-based wood wax oil and preparation method thereof | |
| CN105153856A (en) | Water-based color removing agent and preparation and use method and application thereof | |
| CN102085678B (en) | Wood protective paint as well as preparation method and application thereof | |
| CN109397442A (en) | A kind of processing method of mould proof wooden table-ware | |
| US6755904B2 (en) | Natural paint and method for manufacturing the same | |
| CN108774416A (en) | A kind of ceramics soil resistance buffing wax and preparation method thereof | |
| CN108250960A (en) | Aqueous wood wax oil and preparation method thereof | |
| CN104100063B (en) | Marble veneer stone and preparation method thereof | |
| CN104088427A (en) | Sandstone veneer stone and manufacturing method thereof | |
| WO2008079644A3 (en) | Coating compositions, coatings formed therefrom and methods of making the same | |
| CN109651910A (en) | A kind of coating | |
| CN110256945A (en) | A kind of open air high-weatherability wood wax oil and preparation method thereof | |
| CN108342134A (en) | Aqueous ceramic paint and preparation method thereof and ceramics and preparation method thereof | |
| CN103627280A (en) | Single-component water-based outdoor top-coat varnish | |
| KR101956057B1 (en) | Method for producing water-based coat multy color paint composition and coating composition thereof and coating method using the paint prepared by the method | |
| CN101585692A (en) | Attapulgite exterior wall powder coating | |
| CN109057217A (en) | A kind of imitation stone decorative panel and production technology | |
| CN106675235A (en) | Novel water-based fluorocarbon wall paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |