CN1398933A - Inner wall paint and putty capable of producing negative air ion - Google Patents

Inner wall paint and putty capable of producing negative air ion Download PDF

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Publication number
CN1398933A
CN1398933A CN 02123891 CN02123891A CN1398933A CN 1398933 A CN1398933 A CN 1398933A CN 02123891 CN02123891 CN 02123891 CN 02123891 A CN02123891 A CN 02123891A CN 1398933 A CN1398933 A CN 1398933A
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CN
China
Prior art keywords
negative aeroion
wall
rare
putty
accounts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 02123891
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Chinese (zh)
Other versions
CN1204214C (en
Inventor
白树军
金宗哲
张连松
冀志江
隋同波
王静
颜学武
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Building Paint Plant
China Building Materials Academy CBMA
Original Assignee
Inst Of Cement Science And Novel Building Material Chinese Academy Of Building
BEIJING BUILDING PAINT PLANT
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Publication date
Application filed by Inst Of Cement Science And Novel Building Material Chinese Academy Of Building, BEIJING BUILDING PAINT PLANT filed Critical Inst Of Cement Science And Novel Building Material Chinese Academy Of Building
Priority to CN 02123891 priority Critical patent/CN1204214C/en
Publication of CN1398933A publication Critical patent/CN1398933A/en
Application granted granted Critical
Publication of CN1204214C publication Critical patent/CN1204214C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The present invention is a technology of applying RE activated composite schorl powder capable of producing negative air ion in inner wall paint and putty. The RE activated composite schorl powder capable of producing negative air ion is added into inner wall paint and putty during their production or before their application, so that inner wall decoration material capable of producing negative air ion is formed. The combined use of inner wall and putty with the superfine RE activated composite schorl powder can increase the density of negative ion in the air effectively.

Description

Can produce the dope for inner wall of architecture and the inner wall putty of negative aeroion
Affiliated technical field
The present invention relates to inner wall of building finishing material interior wall coating, inner wall putty.This material except function with decorative material for internal wall, meet the National Environmental specification of quality, have efficient generation negative aeroion function especially.
Background technology
Germany scientist Elst in 1889 and Ge Teer have found the existence of negative aeroion, have affirmed the biological meaning that negative aeroion exists to A Sha Maas in 1902 etc.The effect of negative aeroion is admitted by vast medical circle, except useful HUMAN HEALTH, also has sterilization, dedusting, deodorization.Generally speaking, the concentration of the space negative aeroion in the confined chamber of city is at 100/cm 3Below, 100~300/cm in street of greening 3, suburb, wilderness or 500~1000/cm in park 3, 10000/cm of health resort zone such as beach, forest and waterfall 3About.The reason that room air negative ion concentration level is low comprises factors such as number, natural ventilation, pollution.According to the theory that geodesy and atmosphere joint committee of geographical physics League of Nations adopt, negative aeroion is O 2 -(H 2O) or OH -(H 2O) nOr CO 4 -(H 2O) nObviously, indoor air-anion concentration is low, is unfavorable for HUMAN HEALTH; That the concentration that improves the room air negative ion makes it to reach is outdoor, the level in suburb, wilderness or park is one of main purpose of the present invention.
Japanese environmentalist Kubo in 1986 finds that tourmalinite has anti-water pollution effect, and 1998 annual interests are declared the United States Patent (USP) of " method and apparatus that produces the air alkalion " with the brine electrolysis effect of tourmalinite.At present, mainly improve the concentration of room air negative ion, its main drawback with air negative ion generator: the one, consumes energy, the 2nd, when adopting corona discharge to produce negative aeroion, be easy to produce obnoxious flavour, as: oxynitride NO xWith ozone O 3Deng.
Summary of the invention
The present invention is intended to contain the building coating that can in use constantly produce negative aeroion by providing, and solves the low problem of indoor negative ion concentration thereby utilize no energy consumption not have the technique means that obnoxious flavour supervenes.
The present invention is for overcoming the various shortcoming of above-mentioned air negative ion generator for this reason, and the transmitting anion function of developing the decorative material for internal wall that utilizes buildings increases the room air negative ion concentration and reaches outdoor wilderness level, and the utilization that does not have the consumption of the energy and other pollution is added rare-earth activated efficient generation negative aeroion tourmalinite composite superfine powder and dope for inner wall of architecture with efficient generation negative aeroion and the inner wall putty produced.
The shortcoming that the present invention overcomes the anion generator power consumption and pollutes utilizes employed putty of buildings interior decoration interior wall and coating to produce negative aeroion to increase negative ion concentration in the air.Main raw is the composition tourmaline powder body of rare-earth activated efficient generation negative aeroion in the generation negative aeroion coating, after it is mixed with various emulsions such as pure acrylic acid emulsion, various acrylic resin, vinylformic acid Synolac, organosilicon crylic acid latex, acrylate and vinyl acetate emulsion, benzene-acrylic emulsions, just formed and to have produced the negative aeroion dope for inner wall of architecture, and it is mixed in the putty paste commonly used, just can make and can produce the negative aeroion inner wall putty.
The interior wall coating prescription that can efficiently produce negative aeroion comprises:
Produce air negative ion material: rare-earth activated efficient generation negative aeroion tourmalinite composite superfine powder, account for 1%~30% of coating total amount, said rare-earth activated efficient generation negative aeroion tourmalinite composite superfine powder is to be mixed by tourmalinite rare earth composite salt or oxide compound and photocatalytic semiconductor material.
Base-material, i.e. filmogen: mainly comprise following several emulsion commonly used:
Wherein a kind of of various emulsions such as pure acrylic acid emulsion, various acrylic resin, vinylformic acid Synolac, organosilicon crylic acid latex, acrylate and vinyl acetate emulsion, benzene-acrylic emulsion, weight accounts for 10%~25% of coating total amount.
Filler: zinc sulfide white, superfine talcum powder, ultrafine heavy calcium, attapulgite, titanium dioxide, wollastonite powder, kaolin, wilkinite, nano zine oxide, nano titanium oxide etc. are wherein at least a, and weight accounts for 23%~50% of coating total amount.
Other auxiliary agent: totals such as dispersion agent, film coalescence aid, thickening material, defoamer, flow agent, sanitas, pH value conditioning agent, sanitas account for 1%~5% of coating total amount.
Water: account for 20%~30% of coating total amount.
Said superfine powder is meant that particle diameter below 10 microns, is preferably person below 5 microns among the present invention.
The nagative ion inner wall coating producing process describes in detail
1. prepare: with dispersion agent, thickening material and the suitable solution of other assistant concentration, base-material, filler and rare-earth activated efficient generation negative aeroion tourmalinite composite superfine powder take by weighing standby according to the ratio of prescription;
2. white slurry preparation: water, dispersion agent, auxiliary agent, part defoamer are modulated into solution in reactor, add the filler that is added successively, disperse fully to grind, cross vibratory screening apparatus, squeeze into stirred pot through sand mill at whipping process;
3. finished product preparation: the base-material of in stirred pot, packing into, pour at following white slurry of whipped state, stir, add flow agent, sanitas, defoamer, thickening material and an amount of pH value conditioning agent then;
4. discharging is packed.
Can produce negative aeroion inner wall putty prescription
Coating emulsion: a kind of 15~20% in the various emulsions such as pure acrylic acid emulsion, various acrylic resin, vinylformic acid Synolac, organosilicon crylic acid latex, acrylate and vinyl acetate emulsion, benzene-acrylic emulsion
Mierocrystalline cellulose 5~15%
In fine particle calcium carbonate and the coarse whiting at least a 30~40%
Talcum powder 10~20%
Water 10~20%
Anion material 5~10%
The explanation of negative ion putty production technique
1. white slurry preparation: take by weighing water 10~20%, put into stirred pot, add in fine particle calcium carbonate and the coarse whiting at least aly 30~40% in whipping process successively, talcum powder 10~20% stirs;
2. in white slurry whipping process, add anion material 5~10%, stir;
3. on basis 2., Mierocrystalline cellulose is added and be uniformly dispersed;
4. in dispersion process, add emulsion;
5. finished product packing.
Embodiment
Can produce the interior wall coating formulation examples 1 (by weight, as follows) of negative aeroion
The batching title Weight
Acrylic emulsion coatings anion material water auxiliary agent ?62% ?10% ?25% ?3%
Total amount ?100%
Nagative ion inner wall formulation for coating material example 2
The batching title Weight
Acetate propylene acid filler anion material water auxiliary agent ?20% ?46% ?5% ?25% ?4%
Total amount ?100%
Nagative ion inner wall formulation for coating material example 3
The batching title Weight
Benzene emulsion filler anion material water auxiliary agent 20% 36% 15% 25% 4%
Total amount 100%
The production technique of three prescriptions is identical with the front
Three kinds of paint formulation are brushed to 1 cubic metre simulation room by indoor normal construction requirement, and after the drying to be filmed, airtight 24 hours, with the airion concentration in the Air Ion Counter mensuration storehouse of AlphaLab company limited product, the result was as follows:
Prescription 1 Prescription 2 Prescription 3 Blank contrast Outside air
800/m 3 700/m 3 850/m 3 300/m 3 450/m 3
Test result shows that the negative aeroion amount that the big more coating of rare-earth activated efficient generation negative aeroion tourmalinite composite superfine powder addition brings out is big more.
Negative ion putty formulation examples 1:
The batching title Weight
Putty paste anion material water 75% 10% 15%
Total amount 100%
Negative ion putty formulation examples 2:
The batching title Weight
Benzene emulsion Natvosol fine particle calcium carbonate coarse whiting anion material talcum powder water 15% 10% 18% 18% 10% 15% 14%
Total amount 100%
Negative ion putty formulation examples 3:
The batching title Weight
Acrylate and vinyl acetate emulsion Natvosol fine particle calcium carbonate coarse whiting anion material talcum powder water 15% 10% 15.5 15.5 15% 15% 14%
Total amount 100%
Testing method and result: 500 grams are coated onto 2m by the made putty capable of releasing negative ion of said ratio 2Be sealed in 1/m after to be dried on the sheet glass 3In the airtight storehouse 24 hours, the Air Ion Counter that produces with AlphaLab company limited measured the airion concentration in the storehouse, and the result is as follows:
Prescription 1 Prescription 2 Prescription 3 Blank contrast Outside air
750/m 3 750/m 3 900/m 3 350/m 3 450/m 3
Can clearly learn from above example and practical application test comparison, dope for inner wall of architecture and inner wall putty that the present invention utilizes rare-earth activated efficient generation negative aeroion tourmalinite composite superfine powder development to be produced have the function of efficient generation negative aeroion, alternative air negative ion generator, and have no energy consumption or do not have the advantage that other is attended by the harmful substances generation.
Annotate: said anion material is available from steel source, Xining Industrial Co., Ltd. of group in the above embodiment of the present invention, and title material is for activating tourmaline powder, and this activation tourmaline powder can need be mixed three kinds of components arbitrarily and get by the client.

Claims (7)

1, a kind of dope for inner wall of architecture that can produce negative aeroion is characterized in that in pure acrylic acid emulsion, various acrylic acid resin, vinylformic acid Synolac, organosilicon crylic acid latex, acrylate and vinyl acetate emulsion, benzene-acrylic emulsion adding the composition tourmaline powder body of the rare-earth activated efficient generation negative aeroion that accounts for coating gross weight 1%~30%.
2, the dope for inner wall of architecture that can produce negative aeroion according to claim 1, the composition tourmaline powder body that it is characterized in that said rare-earth activated efficient generation negative aeroion is La, Ce, Nd rare earth composite salt or oxide compound, the mixture of tourmalinite ultrafine powder and Nano semiconductor powder, three's tourmalinite by weight percentage accounts for 58%~90%, rare earth composite salt or oxide compound account for 2%~40%, and the Nano semiconductor powder accounts for 2%~40%.
3, the dope for inner wall of architecture that can produce negative aeroion according to claim 2 is characterized in that said Nano semiconductor powder is to be selected from least a in titanium dioxide, zinc oxide, stannic oxide, ferric oxide, the Tungsten oxide 99.999 etc.
4, a kind of inner wall putty that can produce negative aeroion is characterized in that in known inner wall putty adding the composition tourmaline powder body of the rare-earth activated efficient generation negative aeroion that accounts for putty gross weight 1%~30%.
5, the inner wall putty that can produce negative aeroion according to claim 4 is characterized in that the composition tourmaline powder body of rare-earth activated efficient generation negative aeroion accounts for 5%~20% of putty gross weight.
6, according to claim 4 or the 5 described inner wall putties that can produce negative aeroion, the composition tourmaline powder body that it is characterized in that said rare-earth activated efficient generation negative aeroion is one or more and the mixture that is selected from least a Nano semiconductor powder in titanium dioxide, zinc oxide, stannic oxide, ferric oxide, the Tungsten oxide 99.999 etc. in the ultrafine powder of La, Ce, Nd rare earth composite salt or oxide compound and chosen from Fe tourmalinite, dravite, iron dravite, elbaite.
7, the inner wall putty that can produce negative aeroion according to claim 6, the each component content that it is characterized in that constituting the composition tourmaline powder body of rare-earth activated efficient generation negative aeroion is by weight percentage: tourmalinite accounts for 58%~90%, rare earth composite salt or oxide compound account for 2%~40%, and the Nano semiconductor powder accounts for 2%~40%.
CN 02123891 2002-07-08 2002-07-08 Inner wall paint and putty capable of producing negative air ion Expired - Fee Related CN1204214C (en)

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Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 02123891 CN1204214C (en) 2002-07-08 2002-07-08 Inner wall paint and putty capable of producing negative air ion

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CN1204214C CN1204214C (en) 2005-06-01

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CN100439461C (en) * 2004-12-16 2008-12-03 许绍凰 Nano bactericidal negative ion alkyd enamel
CN1982379B (en) * 2005-12-15 2010-05-05 福建裕和皓月生物工程材料有限公司 Inner-wall coating composition
CN101851805A (en) * 2010-05-18 2010-10-06 田小兵 Photocatalytic multifunctional fiber material and preparation method thereof
CN102504662A (en) * 2011-11-23 2012-06-20 杨震源 Anion coating material and preparation method thereof
CN101362921B (en) * 2008-08-16 2012-12-05 佛山夫田涂料化工有限公司 Grit wear-resistant anion wood lacquer for Children
CN103709830A (en) * 2013-11-27 2014-04-09 佛山市东鹏陶瓷有限公司 Colored glaze mixed negative ion ink for ink-jet printing on ceramic and preparation method thereof
CN103788744A (en) * 2014-01-29 2014-05-14 长沙市芙蓉区群翔建筑涂料厂 Negative-ion net-flavor inner wall elastic anti-cracking putty paste and production method thereof
CN104119800A (en) * 2014-07-15 2014-10-29 三棵树涂料股份有限公司 Special-effect heath indoor wall aqueous paint composition and preparation method thereof
CN104164124A (en) * 2014-08-20 2014-11-26 中山艺展装饰工程有限公司 Saffron crocus scent type health putty paste and preparation method thereof
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CN109423256A (en) * 2017-08-24 2019-03-05 宁波墅朗环保科技有限公司 Air ion matchmaker and preparation method thereof
CN108102487A (en) * 2017-10-31 2018-06-01 德华兔宝宝装饰新材股份有限公司 A kind of interior wall coating of adjustable negative ion amount and preparation method thereof
CN108383423A (en) * 2018-03-09 2018-08-10 福建省南安市飞力岗石有限公司 A kind of artificial stone and its production method capable of releasing negative ion
CN110343416A (en) * 2018-04-03 2019-10-18 哈尔滨森易环保科技有限公司 A kind of environmental protection negative ion paint and its preparation method and application
CN109852162A (en) * 2019-02-19 2019-06-07 杭州琻泰环境科技有限公司 Organic negative ion paint of fire-type and preparation method thereof
CN109852162B (en) * 2019-02-19 2021-05-14 杭州琻泰环境科技有限公司 Fireproof organic negative ion coating and preparation method thereof
CN114262545A (en) * 2022-01-07 2022-04-01 陈学 Emulsion paint containing negative oxygen ions and preparation method thereof

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