CN102504662B - Anion coating material and preparation method thereof - Google Patents

Anion coating material and preparation method thereof Download PDF

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CN102504662B
CN102504662B CN 201110374894 CN201110374894A CN102504662B CN 102504662 B CN102504662 B CN 102504662B CN 201110374894 CN201110374894 CN 201110374894 CN 201110374894 A CN201110374894 A CN 201110374894A CN 102504662 B CN102504662 B CN 102504662B
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negative ion
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screening
nano level
coating material
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CN102504662A (en
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杨震源
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Di Chenhong
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Di Chenhong
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Abstract

The invention relates to a coating material and a preparation method thereof, in particular to an anion coating material and a preparation method thereof, and mainly solves the technical problem that the anion material in the conventional anion coating material is not pretreated. The invention adopts the technical scheme that the anion coating material comprises the following raw materials by weight percentage: acrylic resin 20 to 30 percent, titanium dioxide 10 to 15 percent, calcium carbonate 15 to 20 percent, composite anion material 1 to 4 percent, zinc oxide1 to 3 percent, talcum powder 7 to 11 percent, ethylene glycol 1 to 2 percent, sodium tripolyphosphate 6 to 10 percent, water 21 to 25 percent, and assistant 0.3 to 0.7 percent. The anion coating material not only can be used for decoration, but also can release anions continuously per minute, and can effectively improve the quality of indoor air and remove harmful pollutants in the indoor air, such as formaldehyde and the like.

Description

Negative ion paint and preparation method thereof
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of negative ion paint and preparation method thereof.
Background technology
We know that the time of life 70% spends indoor.Therefore the lucidity of room air will directly have influence on the health of human body.Room air pollution has become to be subjected to one of hot issue of social concerns most at present to the harm of human health, because 68% disease cause is relevant with room air pollution, 80% cancer is relevant with living environment.Proverb is said right: indoor pollution; Healthy formidable enemy.Therefore high-efficient and lasting ground purifies indoor harmful gas, the dreamboat that keeps pure and fresh health environment to become people to pursue.
At indoor pollution; Healthy formidable enemy, so high-efficient and lasting ground purifies indoor harmful gas, the dreamboat that keeps pure and fresh health environment to become people to pursue.At present both at home and abroad for the concentration that improves indoor negative ion all adopts anion generator, in the anion generator operational process, consumed power not only, and in the airborne water molecules of high-frequency electrolysis, produce bromine oxygen, can cause side effect to human body.It is comfortable that the people does not feel under this environment.After anion generator has been bought by some families, still lay aside and neglect.And the negative ion composite granule of being excited is dispersed in and sticks to the finishing material surface in the coating along with convection of air, temperature variation, and natural wind impacts, and the air friction always discharges natural negative ion to the space with carving, and the people is enjoyed in forest indoor; The spirit and QI cleaning on waterfall limit, environment in high spirits.
Summary of the invention
The purpose of this invention is to provide a kind of negative ion paint and preparation method thereof, the anion material that mainly solves in the existing negative ion paint does not carry out pretreated technical problem.
Technical scheme of the present invention: a kind of negative ion paint, the weight percent that its raw material is formed is: acrylic acid resin 20-30%; Titanium dioxide 10-15%; Lime carbonate 15-20%; Composite negative ion material 1-4%; Zinc oxide 1-3%; Talcum powder 7-11%; Ethylene glycol 1-2%; Tripoly phosphate sodium STPP 6-10%, water 21-25%, auxiliary agent 0.3-0.7%.
Preferred raw material weight per-cent is formed: acrylic acid resin 25%; Titanium dioxide 12%; Lime carbonate 17%; Composite negative ion material 2%; Zinc oxide 2%; Talcum powder 9%; Ethylene glycol 1.5%; Tripoly phosphate sodium STPP 8%; Water 23%; Auxiliary agent 0.5%.
The preparation method of negative ion paint may further comprise the steps: 1, composite negative ion material obtains: 1. negative ion adds the screening of material: adopt radioactivity prospecting instrument line style screening nano level tourmalinite, dispel the material of contamination; 2. will through the nano level tourmalinite of screening by grind step by step vibrations screening, high velocity air disperse to make its granularity reach 50nm-80nm 3. then with the nano level tourmalinite of 50nm~80nm by weight 1 ﹕ (0.3-0.7) with screen through radioactivity and industrial high-frequency electrical intensified the nano level tourmalinite that can discharge natural negative ion lastingly and mixes and obtain composite negative ion material; 2, composite negative ion material is mixed with other raw materials by above-mentioned weight percent; 3, the mixture of Huo Deing is handled through high pressure homogenization and is obtained final product.
Beneficial effect of the present invention: not only have decoration functions, and can also continue to discharge negative ion by per minute, can effectively improve IAQ (indoor air quality), dispel formaldehyde in indoor air, toluene, harmful pollutants such as ammonia; This coating cigarette, oil smoke mist, household electrical appliance are produced in the decontamination chamber rapidly atmospheric pollution and electronic pollution; It is multi-functional in one to reduce electromagnetic radiation intensity etc. greatly, its 24 hours sterilizations, sterilization rates reach more than 90%, its health shows as by having improved Air quality, reaches the booster action that strengthens body immunity, the multiple disease of prevention, meets people to environmental protection and healthy double requirements.With coating is that carrier is constructed a pure natural, do not needed any energy just can forever discharge the vert space of negative ion in the space of indoor periphery, and this practical coating becomes people and improves environment, pays attention to the first-selected product of healthy decoration.The invention of natural negative ion paint allows indoor wall can discharge natural negative ion, and cost is low, easy to process, can adopt spraying, roller coating, brushing, blade coating etc.Its application surface is extensive.Along with improving constantly of living standards of the people, the continuous reinforcement of health perception, the application of natural negative ion paint will be increasing.
Embodiment
Embodiment 1-3, raw material form weight percent and see the following form 1
? The acrylic acid resin Titanium dioxide Lime carbonate Composite negative ion material Zinc oxide Talcum powder Ethylene glycol Tripoly phosphate sodium STPP Water purification Auxiliary agent
? 20-30% 10-15% 15-20% 1-4% 1-3% 7-11% 1-2% 6-10% 21-25% 0.3-0.7%
Embodiment 1 25 12 17 2 2 9 1.5 8 23 0.5
Embodiment 2 26 10 19 1 1 7 1 10 24.7 0.3
Embodiment 3 28 14 15 3 2 8 1 6 22.5 0.5
Described auxiliary agent is that conventional commercially available defoamer, flow agent, suspension agent are by 1.5: 2: 1.5 compositions of umber.
The negative ion paint Preparation Method may further comprise the steps: 1, composite negative ion material obtains: 1. negative ion adds the screening of material: adopt radioactivity prospecting instrument line style screening nano level tourmalinite, dispel the material of contamination; 2. will make its granularity reach 50nm-80nm by grinding vibrations screening step by step, high velocity air dispersion through the nano level tourmalinite of screening; The described vibrations of grinding step by step screening is 2000 orders, 4000 orders, 6000 order classified grindings vibrations screening, and described high velocity air dispersion is discrete by 2800 rev/mins of high speed dispersors; 3. be 1 ﹕ 0.3 with the nano level tourmalinite of 50nm~80nm by weight 1 ﹕ 0.5(embodiment 2 then, embodiment 3 is 1 ﹕ 0.7, and all the other are identical with embodiment 1) intensify the nano level tourmalinite mixing that can discharge natural negative ion lastingly through radioactivity screening and industrial high frequency 916 megahertz electricity and obtained composite negative ion material; 2, composite negative ion material being pressed table 1 weight percent mixes with other raw materials; 3, the mixture of Huo Deing is handled through the 400KG high pressure homogenization and is obtained final product.The negative ion paint performance that is obtained sees the following form 2
Sequence number Project Index
1 Condition in container Be uniform state after no lump, the stirring
2 Negative ion generation/cm 3*min 1600
3 Sterilization % 90
4 Appearance of film Smooth, color and luster is even
5 Abrasion resistance 〉= 300
6 VOC volatile organic compounds g/l≤ 200
7 Free formaldehyde g/kg≤ 0.1
8 Soluble chromium mg/kg≤ 60
9 Soluble cadmium mg/kg≤ 75
10 Soluble mercury mg/kg≤ 60
11 Dissoluble lead mg/kg≤ 90
12 Time of drying (surface drying) h 2
13 Alkali resistance 24h No abnormal
14 Contrast ratio 〉= 0.9
15 Low-temperature stability Never degenerate
16 Application property It is accessible to brush two roads
Test conditions: testing laboratory's temperature is 23 ± 2 ℃, and relative humidity is (50 ± 5) %, and coating was placed 24 hours before the test.
The measuring method of negative ion generation is applied to negative ion paint on the KT plate of 150mm * 250mm, dry or dry after put into 1 square metre of test container.Detect and use instrument: SD9207B type atmospheric ion concentration tester; AIC1000 air-anion concentration tester.
Detect step: 1, strict control test chambers temp: 20 ℃, strict control test chamber humidity: 60%RH.2, the zero-bit of adjustment SD9207B type atmospheric ion concentration tester and AIC1000 air-anion concentration tester.3, SD9207B type atmospheric ion concentration determination instrument probe or AIC1000 air-anion concentration probe of tester are put into test container.4, record data and must stablize 1 minute, be generally mean value.
The measuring method of coating sterilization, negative ion paint is applied on the KT plate of 50mm * 50mm, the oven dry or dry the back to be measured, provide the test bacterial classification: intestinal bacteria, streptococcus aureus, bacillus megaterium, Pseudomonas fluorescence and Bacillus subtilus, the sampling bacterium places on the model, puts into 20 ℃ of thermostat containers and takes out mensuration in 24 hours.
Air detection in the coating chamber that Shanghai multiple star environment measuring company limited does, it the results are shown in following table 3
Figure 680397DEST_PATH_IMAGE001
From detected result, has certain effect to eliminating formaldehyde.

Claims (3)

1. negative ion paint, the weight percent that its raw material is formed is: acrylic resin 20-30%; Titanium dioxide 10-15%; Lime carbonate 15-20%; Composite negative ion material 1-4%; Zinc oxide 1-3%; Talcum powder 7-11%; Ethylene glycol 1-2%; Tripoly phosphate sodium STPP 6-10%, water 21-25%, auxiliary agent 0.3-0.7%; Described composite negative ion material obtains by following step: 1. negative ion adds the screening of material: adopt radioactivity prospecting instrument line style screening nano level tourmalinite, dispel the material of contamination; 2. will through the nano level tourmalinite of screening by grind step by step vibrations screening, high velocity air disperse to make its granularity reach 50nm-80nm 3. then with the nano level tourmalinite of 50nm~80nm by weight 1 ﹕ (0.3-0.7) with screen through radioactivity and industrial high-frequency electrical intensified the nano level tourmalinite that can discharge natural negative ion lastingly and mixes and obtain composite negative ion material; Raw material is formed the mixture that obtains and is handled through high pressure homogenization.
2. negative ion paint according to claim 1 is characterized in that the weight percent that its raw material is formed is: acrylic resin 25%; Titanium dioxide 12%; Lime carbonate 17%; Composite negative ion material 2%; Zinc oxide 2%; Talcum powder 9%; Ethylene glycol 1.5%; Tripoly phosphate sodium STPP 8%; Water 23%; Auxiliary agent 0.5%.
3. the preparation method of the described negative ion paint of claim 1, it is characterized in that may further comprise the steps: a, composite negative ion material obtain: 1. negative ion adds the screening of material: adopt radioactivity prospecting instrument line style screening nano level tourmalinite, dispel the material of contamination; 2. will through the nano level tourmalinite of screening by grind step by step vibrations screening, high velocity air disperse to make its granularity reach 50nm-80nm 3. then with the nano level tourmalinite of 50nm~80nm by weight 1 ﹕ (0.3-0.7) with screen through radioactivity and industrial high-frequency electrical intensified the nano level tourmalinite that can discharge natural negative ion lastingly and mixes and obtain composite negative ion material; B, composite negative ion material is mixed with other raw materials by claim 1 weight percent; The mixture of c, acquisition is handled through high pressure homogenization and is obtained final product.
CN 201110374894 2011-11-23 2011-11-23 Anion coating material and preparation method thereof Active CN102504662B (en)

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CN102504662B true CN102504662B (en) 2013-07-31

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103614024B (en) * 2013-10-28 2016-05-25 蚌埠市时代电子有限公司 A kind of antibiotic waterproof coating
CN105567035B (en) * 2016-02-03 2017-12-26 轩脉家居科技(上海)有限公司 Negative ion paint and preparation method thereof
CN107011751A (en) * 2017-04-24 2017-08-04 新昌县恩喜电器有限公司 A kind of electrical equipment negative ion paint and preparation method thereof
CN107674530A (en) * 2017-10-18 2018-02-09 佛山市金蓝领教育科技有限公司 A kind of colorful imitative exterior wall tile coating containing anion powder and preparation method thereof
CN110240845A (en) * 2019-06-26 2019-09-17 广东七色世界环保新材料有限公司 Multi-functional indoor negative ion paint and preparation method thereof
CN110330325A (en) * 2019-07-09 2019-10-15 杨震源 Energy sustained release anion, energy bisque-ware and its preparation method and application

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1398933A (en) * 2002-07-08 2003-02-26 北京市建筑涂料厂 Inner wall paint and putty capable of producing negative air ion
CN1478828A (en) * 2003-08-07 2004-03-03 北京朗诺环保科技有限公司 Negalive ion paint additive

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1398933A (en) * 2002-07-08 2003-02-26 北京市建筑涂料厂 Inner wall paint and putty capable of producing negative air ion
CN1478828A (en) * 2003-08-07 2004-03-03 北京朗诺环保科技有限公司 Negalive ion paint additive

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