CN106345202B - Macromolecule air purifying preparation and preparation method thereof - Google Patents
Macromolecule air purifying preparation and preparation method thereof Download PDFInfo
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- CN106345202B CN106345202B CN201610919399.2A CN201610919399A CN106345202B CN 106345202 B CN106345202 B CN 106345202B CN 201610919399 A CN201610919399 A CN 201610919399A CN 106345202 B CN106345202 B CN 106345202B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
- B01D47/06—Spray cleaning
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/38—Removing components of undefined structure
- B01D53/44—Organic components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/58—Ammonia
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/90—Chelants
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
- B01D2257/7027—Aromatic hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
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- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a kind of macromolecule air purifying preparation and preparation method thereof.The macromolecule air purifying preparation is made up of the raw material of following weight parts：5 15 parts of acrylic resin, 5 15 parts of ethanol, 0.5 5 parts of polyvinyl alcohol, 0.1 1 parts of stabilizer, 0.1 1 parts of chelating agent, 0.5 5 parts of antiseptic, 5 15 parts of nonionic surfactant, 50 70 parts of water.Macromolecule air purifying preparation of the invention, pernicious gas that can be in effectively sterilized, decomposition chamber, absorption minute dusts, eliminates the unusual smell, and substantially increases the air quality of interior, improves environment；Long action time, had good sustained release effect.
Description
Technical field
The present invention relates to a kind of air purifying preparation, and in particular to a kind of macromolecule air purifying preparation and preparation method thereof.
Background technology
The primary pollution source of Chinese indoor environment is from building, decoration and furniture, and formaldehyde, benzene, ammonia pollution are exceeded
The healthy of people is had a strong impact on.Can be largely classified into finishing pollution and furniture pollutes two aspects.
Paint and coating, leather, the carpet of various finishings for being used in fitment process etc., the master that these materials are caused
It is benzene, toluene, TVOC etc., such as woodwork plate to want pollutant, and itself is nontoxic from natural for timber, but urine aldehyde is used during its processing
Glue sticking, and form the pollution sources of formaldehyde, and the use of the main component of glue is formaldehyde in fitting up, paint also has a large amount of pungent
Benzene.
The formaldehyde of the generation such as coating, adhesive used also becomes in the material and furniture manufacturing process of furniture use
One of major pollutants of room air pollution, and formaldehyde has strong carcinogenic and tumor promotion.Lot of documents is recorded, formaldehyde
Influence to health is mainly manifested in allotriosmia, stimulation, allergy, abnormal pulmonary function, dysfunction of liver and immunologic function
The aspect such as abnormal.Therefore, the selection of furniture and furniture abatement of pollution later can not be ignored.
At present remove room air residual contamination material should be activated carbon first.There is physical absorption and chemistry to inhale for it
Attached double grading, can selectively adsorb the various harmful substances in air, to reach the purpose of disinfecting, deodorizing.But activity
Charcoal takes from coal, is limited to country higher to the protection of the energy and its preparation cost, it is impossible to extensive popularization, thus cannot be wide
It is general to use.
The invention provides a kind of macromolecule air purifying preparation, with good covering power, adhesive force and excellent stabilization
Property.
The content of the invention
For deficiencies of the prior art, one of the technical problems to be solved by the invention are to provide a kind of high score
Sub- air purifying preparation.
One of technical problems to be solved by the invention are to provide the preparation method of above-mentioned macromolecule air purifying preparation.
Technical problem of the invention, is achieved by following technical proposals：
A kind of macromolecule air purifying preparation, is made up of the raw material of following weight parts：Acrylic resin 5-15 parts, ethanol 5-15
Part, polyvinyl alcohol 0.5-5 parts, stabilizer 0.1-1 parts, chelating agent 0.1-1 parts, antiseptic 0.5-5 parts, nonionic surfactant
5-15 parts, water 50-70 parts.
Preferably, described stabilizer is sodium acid carbonate and/or sodium dihydrogen phosphate.
Preferably, described chelating agent is disodium ethylene diamine tetraacetate and/or sodium ethylenediamine tetramethylenephosphonate.
Preferably, described antiseptic is laurene, limonene, 3,7,11- trimethyl -1,3,6,10- 10 two carbon-tetraene
In one or more of mixture.
It is highly preferred that described antiseptic is by laurene, limonene, 3,7,11- trimethyl -1,3,6,10- ten two carbon-four
Alkene is mixed, the laurene, limonene, 3,7,11- trimethyl -1, and the mass ratio of 3,6,10- 10 two carbon-tetraene is (1-
3)：(1-3)：(1-3).
Preferably, described nonionic surfactant is trihydroxy ethylamine oleate soap, N, N- diethanols lauramide, Pork and beans
One or more of mixture in cool sour diglycollic amide.
It is highly preferred that described nonionic surfactant is by trihydroxy ethylamine oleate soap, N, N- diethanols lauramide, meat
Myristic acid diglycollic amide is mixed, the trihydroxy ethylamine oleate soap, N, N- diethanols lauramide, myristic acid diethanol
The mass ratio of acid amides is (1-3)：(1-3)：(1-3).
Present invention also offers the preparation method of above-mentioned macromolecule air purifying preparation, ethanol is added to the water stirring mixing equal
It is even, it is subsequently adding acrylic resin, polyvinyl alcohol and is uniformly mixed, add nonionic surfactant, stabilizer, chelating
Agent, antiseptic are uniformly mixed and obtain final product.
Macromolecule air purifying preparation of the invention, pernicious gas that can be in effectively sterilized, decomposition chamber, adsorbs small powder
Dirt, eliminate the unusual smell, substantially increase the air quality of interior, improve environment；Long action time, had good sustained release effect.
Specific embodiment
With reference to embodiment, the present invention is described further, as described below, is only to preferable implementation of the invention
Example, not does the limitation of other forms to the present invention, and any those skilled in the art are possibly also with the disclosure above
Technology contents be changed to the Equivalent embodiments of equal change.It is every without departing from the present invention program content, according to the present invention
Technical spirit any simple modification that following examples are made or equivalent variations, all fall within protection scope of the present invention.
Each raw material introduction in embodiment：
Acrylic resin, No. CAS：9003-01-4, the specific trade mark for using Guangzhou Fei Rui Chemical Co., Ltd.s to provide is card
The acrylic resin of ripple 940.
Ethanol, No. CAS：64-17-5.
Polyvinyl alcohol, No. CAS：9002-89-5, it is specific using Shanghai Petrochemial Co Ltd, China Petrochemical Corp's production
The trade mark be PVA 2488 (088-50), the polyvinyl alcohol of average degree of polymerization 2400-2500.
Sodium dihydrogen phosphate, No. CAS：7558-80-7.
Disodium ethylene diamine tetraacetate, No. CAS：139-33-3.
Laurene, No. CAS：123-35-3.
Limonene, i.e. dipentene, No. CAS：138-86-3.
3,7,11- trimethyl -1,3,6,10- 10 two carbon-tetraene, No. CAS：502-61-4.
Trihydroxy ethylamine oleate soap, No. CAS：10277-04-0.
N, N- diethanol lauramide, No. CAS：120-40-1.
Myristic acid diglycollic amide, No. CAS：7545-23-5.
Embodiment 1
Macromolecule air purifying preparation raw material：12 parts of acrylic resin, 10 parts of ethanol, 3 parts of polyvinyl alcohol, sodium dihydrogen phosphate
0.3 part, 0.15 part of disodium ethylene diamine tetraacetate, 1.8 parts of antiseptic, 9 parts of nonionic surfactant, 60 parts of water.
Described antiseptic presses quality by laurene, limonene, 12 carbon of 3,7,11- trimethyl -1,3,6,10--tetraene
Than being 1：1：1 is uniformly mixed and obtains.
Described nonionic surfactant is by trihydroxy ethylamine oleate soap, N, N- diethanols lauramide, myristic acid two
Glycollic amide is 1 in mass ratio：1：1 is uniformly mixed and obtains.
The preparation method of above-mentioned macromolecule air purifying preparation：Ethanol is added to the water 5 points are stirred under 300 revs/min of rotating speed
Clock is well mixed, and is subsequently adding the stirring under 300 revs/min of rotating speed of acrylic resin, polyvinyl alcohol and is well mixed for 10 minutes, then adds
Enter nonionic surfactant, sodium dihydrogen phosphate, disodium ethylene diamine tetraacetate, antiseptic and 15 points are stirred under 300 revs/min of rotating speed
Clock is well mixed.Obtain the macromolecule air purifying preparation of embodiment 1.
Embodiment 2
It is substantially the same manner as Example 1, differ only in：Described antiseptic by limonene, 3,7,11- trimethyl -1,
12 carbon of 3,6,10--tetraene is 1 in mass ratio：1 is uniformly mixed and obtains.Obtain the macromolecule purification of air of embodiment 2
Agent.
Embodiment 3
It is substantially the same manner as Example 1, differ only in：Described antiseptic by laurene, 3,7,11- trimethyl -1,
12 carbon of 3,6,10--tetraene is 1 in mass ratio：1 is uniformly mixed and obtains.Obtain the macromolecule purification of air of embodiment 3
Agent.
Embodiment 4
It is substantially the same manner as Example 1, differ only in：Described antiseptic is in mass ratio by laurene, limonene
1：1 is uniformly mixed and obtains.Obtain the macromolecule air purifying preparation of embodiment 4.
Embodiment 5
It is substantially the same manner as Example 1, differ only in：Described nonionic surfactant is by N, N- diethanols 12
Acid amides, myristic acid diglycollic amide are 1 in mass ratio：1 is uniformly mixed and obtains.Obtain the macromolecule air of embodiment 5
Cleanser.
Embodiment 6
It is substantially the same manner as Example 1, differ only in：Described nonionic surfactant is by triethanolamine oleate
Soap, myristic acid diglycollic amide are 1 in mass ratio：1 is uniformly mixed and obtains.The macromolecule air for obtaining embodiment 6 is net
Agent.
Embodiment 7
It is substantially the same manner as Example 1, differ only in：Described nonionic surfactant is by triethanolamine oleate
Soap, N, N- diethanols lauramide are 1 in mass ratio：1 is uniformly mixed and obtains.The macromolecule air for obtaining embodiment 7 is net
Agent.
Test case 1
Anti-microbial property is carried out to the macromolecule air purifying preparation of embodiment 1-7 and interior PM2.5 concentration performance tests are reduced.
By the Ministry of Public Health《Disinfection technology standard》The working specification of (version in 2002) carries out unmanned room sterilization,
Equipment：
1st, test strain：Air natural bacteria；
2nd, nutrient agar：Beef extract 1g, yeast extract 2g, peptone 5g, NaCl 5g, agar 15g, add water constant volume
It is 7.4 to adjust PH to 1000ml；
3rd, biochemical cultivation case PSH-300；
4th, six grades of sieve aperture air impact formula samplers.
Method：
Foundation《Disinfection technology standard》(version in 2002), it is 21m to select 7 volumes3Unmanned room carry out on-the-spot disinfection examination
Test, air natural bacteria is sampled 10 minutes before being carried out disinfection after closed room, as control before sterilization, while in test room
PM2.5 concentration and concentration of formaldehyde are used as control；The macromolecule air purifying preparation 50mL of sprinkling embodiment 1-7 carries out disinfection respectively,
Room air natural bacteria is sampled 10 minutes after sterilizing 1 hour, while PM2.5 concentration and concentration of formaldehyde in test room.Will
Sampling plate is put 37 DEG C and is cultivated 48 hours, observes clump count.Bacterium colony after clump count/test before natural bacteria extinction rate (%)=test
PM2.5 concentration × % after PM2.5 concentration/test before number × %, PM2.5 reduced rate (%)=test, formaldehyde elimination factor (%)=
Concentration of formaldehyde × % after concentration of formaldehyde/test before test.Concrete outcome is shown in Table 1.
Table 1：Test result list position：%
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (laurene, limonene, 3,7,11- trimethyl -1,3,6,10-
12 carbon-tetraene compounding) test result be substantially better than embodiment 2-4 (laurene, limonene, 3,7,11- trimethyl -1,3,6,
Any the two compounding in 12 carbon of 10--tetraene).Comparing embodiment 1 and embodiment 5-7, embodiment 1 (trihydroxy ethylamine oleate soap,
N, N- diethanol lauramide, myristic acid diglycollic amide compounding) test result is substantially better than embodiment 5-7 (triethanolamines
Oleate soap, N, any the two compounding in N- diethanols lauramide, myristic acid diglycollic amide).
Claims (4)
1. a kind of macromolecule air purifying preparation, it is characterised in that be made up of the raw material of following weight parts：Acrylic resin 5-15
Part, ethanol 5-15 parts, polyvinyl alcohol 0.5-5 parts, stabilizer 0.1-1 parts, chelating agent 0.1-1 parts, antiseptic 0.5-5 parts, it is non-from
Sub- surfactant 5-15 parts, water 50-70 parts；
Described antiseptic is mixed by laurene, limonene, 3,7,11- trimethyl -1,3,6,10- 10 two carbon-tetraene, institute
It is (1-3) to state laurene, limonene, the mass ratio of 12 carbon of 3,7,11- trimethyl -1,3,6,10--tetraene：(1-3)：(1-
3)；
Described nonionic surfactant is by trihydroxy ethylamine oleate soap, N, N- diethanols lauramide, myristic acid diethanol
Acid amides is mixed, the trihydroxy ethylamine oleate soap, N, N- diethanols lauramide, the mass ratio of myristic acid diglycollic amide
It is (1-3)：(1-3)：(1-3).
2. macromolecule air purifying preparation as claimed in claim 1, it is characterised in that described stabilizer be sodium acid carbonate and/
Or sodium dihydrogen phosphate.
3. macromolecule air purifying preparation as claimed in claim 1, it is characterised in that described chelating agent is ethylenediamine tetra-acetic acid
Disodium and/or sodium ethylenediamine tetramethylenephosphonate.
4. as any one of claim 1-3 macromolecule air purifying preparation preparation method, it is characterised in that by ethanol plus
To enter be uniformly mixed in water, be subsequently adding acrylic resin, polyvinyl alcohol and be uniformly mixed, add non-ionic surface work
Property agent, stabilizer, chelating agent, antiseptic are uniformly mixed and obtain final product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610919399.2A CN106345202B (en) | 2016-10-21 | 2016-10-21 | Macromolecule air purifying preparation and preparation method thereof |
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| CN201610919399.2A CN106345202B (en) | 2016-10-21 | 2016-10-21 | Macromolecule air purifying preparation and preparation method thereof |
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| CN106345202B true CN106345202B (en) | 2017-07-07 |
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| CN108380019A (en) * | 2018-03-21 | 2018-08-10 | 上海薇蒂实业发展有限公司 | A kind of polymerization macromolecule is dispelled taste agent concentrate and preparation method thereof except aldehyde |
| CN108392666A (en) * | 2018-05-17 | 2018-08-14 | 徐夫队 | A kind of healthy and safe elevator air purifying preparation |
| CN108990978A (en) * | 2018-09-11 | 2018-12-14 | 贵州全世通精密机械科技有限公司 | One kind is for air dehumidifier filter core macromolecule bacteria remover and preparation method thereof |
| CN109486227A (en) * | 2018-10-11 | 2019-03-19 | 朱登年 | A kind of odor adsorption agent and its application in low VOC plastic matrix |
| CN110506738A (en) * | 2019-08-27 | 2019-11-29 | 江苏瑞丰科技实业有限公司 | A kind of efficient sterilizing air cleaning spray |
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| JP2002273145A (en) * | 2001-03-15 | 2002-09-24 | Mariko Koizumi | Formaldehyde scavenger, method for treating woody plate, and woody plate |
| WO2004076034A1 (en) * | 2003-02-24 | 2004-09-10 | Vandine Robert W | Gas scrubbing reagent and methods for using same |
| CN101181677A (en) * | 2007-06-20 | 2008-05-21 | 北京理工大学 | High-efficiency formaldehyde scavenging agent |
| CN102057961A (en) * | 2010-11-15 | 2011-05-18 | 赵正坤 | Air purifying composition and preparation method and use thereof |
| CN102626584B (en) * | 2012-04-11 | 2014-12-03 | 合肥工业大学 | Combined type indoor air purifier |
| CN103694815A (en) * | 2013-12-06 | 2014-04-02 | 华阳新兴科技（天津）集团有限公司 | Scrapable formaldehyde closed film and preparation method thereof |
| CN104474860A (en) * | 2014-11-04 | 2015-04-01 | 成都彩虹电器（集团）中南有限公司 | Antibacterial and formaldehyde removing indoor air purification composition and preparation method thereof |
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