CN101781501B - Tourmalineline environmental protection emulsion paint and preparation method thereof - Google Patents
Tourmalineline environmental protection emulsion paint and preparation method thereof Download PDFInfo
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- CN101781501B CN101781501B CN2010101278603A CN201010127860A CN101781501B CN 101781501 B CN101781501 B CN 101781501B CN 2010101278603 A CN2010101278603 A CN 2010101278603A CN 201010127860 A CN201010127860 A CN 201010127860A CN 101781501 B CN101781501 B CN 101781501B
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Abstract
The invention discloses tourmalineline environmental protection emulsion paint and a preparation method thereof. The invention solves the problem that the existing commercial coating product is not good for environmental protection, can not effectively eliminates the toxic and harmful substances and peculiar smell, the industrialization can not be realized and the negative oxide ion burst size is not good. The tourmalineline environmental protection emulsion paint is prepared by tourmalineline nanometer ultramicro powder, titanium dioxide, water, deformer, dispersing agent, wetting agent, cellulose, heavy calcium powder, acrylic resin, absolute ethyl alcohol, flatting agent additive. The preparation method is as follows: 1. weighing raw material; 2. blending and stirring water, deformer, dispersing agent, wetting agent, cellulose, adding tourmalineline nanometer ultramicro powder, titanium dioxide, heavy calcium powder and acrylic resin, adding absolute ethyl alcohol, flatting agent additive and film formation agent after stirring, and obtaining the sizing agent after stirring; and 3. obtaining the emulsion paint after grinding. The invention can effectively eliminate the toxic and harmful substances and peculiar smell, can realize the industrialization, and has good negative oxide ion burst size and environmental protection effect.
Description
Technical field
The present invention relates to a kind of environment friendly emulsion paint and preparation method thereof.
Background technology
Newly-decorated indoor; Because the use of finishing material and coating can make the indoor peculiar smell that exists; The formaldehyde that discharges in finishing material and the coating, volatile organic matter; The harmful element of benzene, toluene, solubility and radionuclide, the various bacteria that radon, asbestos, the moistening agent in building slab and the native stone material brings, fungi and spore etc.; Indoor pollution source (furniture, sheet material, paint, viscose glue etc.) can constantly discharge obnoxious flavoures such as formaldehyde, ammonia, benzene, these materials can cause human body produce headache, dizzy, eye expands and malaise symptoms such as upper respiratory tract stimulation.Existing commercial coating product is generally deposited not environmental protection, can not neutralize effectively, degrade, decomposes, eliminates hazardous and noxious substances and peculiar smell, so can not move in or handle official business immediately in newly-decorated house.
At present; There is research in coating, to add the Tourmaline powder, utilizes its characteristic to remove hazardous and noxious substances and peculiar smell, like patent " Tomalin environmental protection latex paint (application number: 200710029712.6; applying date: on August 15th, 2007) "; But, cause to realize industrialization because its complex process causes cost too high; The Tourmaline ore microcrystal particle that is adopted is bigger, causes the negative oxygen ion burst size not good, and environment protecting is poor.
Summary of the invention
The present invention generally deposits not environmental protection in order to solve existing commercial coating product, can not neutralize, degrade, decompose, eliminate hazardous and noxious substances and peculiar smell effectively; Patent " Tomalin environmental protection latex paint " exists and can't realize industrialization, the problem of the not good and environment protecting difference of negative oxygen ion burst size, and a kind of Tomalin environmental protection rubber-emulsion paint and preparation method thereof is provided.
The Tomalin environmental protection rubber-emulsion paint is processed by following proportioning:
Tourmaline nano ultrafine powder 10.00Kg
Titanium oxide 23.00Kg
Water 19.00Kg
Skimmer 0.06Kg
Dispersion agent 0.19Kg
Wetting agent 0.10Kg
Mierocrystalline cellulose 0.30Kg
Dicalcium powder 12.00Kg
Vinyl resin 35.00Kg
Absolute ethyl alcohol 2.50Kg
Flow agent 0.05Kg
Film coalescence aid 0.80Kg
Wherein the particle diameter of tourmaline nano ultrafine powder is 150～240 nanometers, and the particle diameter of titanium oxide is 2～30 nanometers.
The preparation method of Tomalin environmental protection rubber-emulsion paint realizes according to the following steps: one, take by weighing the tourmaline nano ultrafine powder of 10.00Kg, the titanium oxide of 23.00Kg, the water of 19.00Kg, the skimmer of 0.06Kg, the dispersion agent of 0.19Kg, the wetting agent of 0.10Kg, the Mierocrystalline cellulose of 0.30Kg, the dicalcium powder of 12.00Kg, the vinyl resin of 35.00Kg, the absolute ethyl alcohol of 2.50Kg, the flow agent of 0.05Kg and the film coalescence aid of 0.80Kg; Two, the water that takes by weighing, skimmer, dispersion agent, wetting agent and Mierocrystalline cellulose are mixed; And stir 15min with the speed of 500r/min; Add tourmaline nano ultrafine powder, titanium oxide, dicalcium powder and the vinyl resin that takes by weighing then, the speed stirring 40min with 1800r/min adds absolute ethyl alcohol, flow agent and the film coalescence aid that takes by weighing again; With static 1h behind the speed stirring 30min of 100～2000r/min, get slurry; Three, slurry is injected shredder, grind 1h with the speed of 200r/min then, promptly get the Tomalin environmental protection rubber-emulsion paint; Wherein the particle diameter of tourmaline nano ultrafine powder is 150～240 nanometers in the step 1,, the particle diameter of titanium oxide is 2～30 nanometers.
Tomalin environmental protection rubber-emulsion paint of the present invention can neutralize, degrade, decompose, eliminate hazardous and noxious substances and peculiar smell effectively.Tomalin environmental protection rubber-emulsion paint of the present invention can permanent release be called as the negative ion of " air VITAMINs "; When airborne moisture contacts with coating, can make moisture generation electrolysis generate negative ion, because atmospheric moisture is sure existence; So airborne water molecules will constantly react with coating; Thereby continue to discharge negative ion, never be interrupted, and through this continuous accumulation; Make indoor negative ion concentration reach metastable higher level, and then remove harmful pollutants and peculiar smell such as formaldehyde in indoor air, ammonia; The far infrared rays of emission also plays the effect of antibacterial bacteriostatic to the bacterium mould; Can launch the far infrared light wave of 4～14 microns of wavelength that are called as " light of life ",, improve the blood circulation and the microcirculqtory system of human body with human body far infrared wave appearance coupling; Also can discharge the little electric current with bioelectrode, being complementary with the bioelectricity of human body is 0.06mA, has mediator's yin-yang when acting on human body, stimulates the circulation of the blood and cause the muscles and joints to relax, effect such as promote sleep; Can stable space energy field, can effectively upset, cushion, offset, block the harm of hertzian wave, water vein waves to human body, can play calmness, the effect of the intense strain of calming the nerves, releive.Can make the room negative ion concentration increase by 1000～2000/cm after the brushing of brushing Tomalin environmental protection rubber-emulsion paint of the present invention
3, surpass 5 times of GB GB50325-2001 standard, and bacteriostatic action is obvious; Can neutralize, degrade, decompose, eliminate airborne hazardous and noxious substances in the room, improve Air quality, environment protecting is good; Can move in immediately behind the finishing, easy to use, method is simple.
The preparation of Tomalin environmental protection rubber-emulsion paint of the present invention need not change the existing coating course of processing, and raw material sources are wider, and cost is low, can realize industrialization.
Embodiment
Technical scheme of the present invention is not limited to following cited embodiment, also comprises the arbitrary combination between each embodiment.
Embodiment one: this embodiment Tomalin environmental protection rubber-emulsion paint is processed by following proportioning:
Tourmaline nano ultrafine powder 10.00Kg
Titanium oxide 23.00Kg
Water 19.00Kg
Skimmer 0.06Kg
Dispersion agent 0.19Kg
Wetting agent 0.10Kg
Mierocrystalline cellulose 0.30Kg
Dicalcium powder 12.00Kg
Vinyl resin 35.00Kg
Absolute ethyl alcohol 2.50Kg
Flow agent 0.05Kg
Film coalescence aid 0.80Kg
Wherein the particle diameter of tourmaline nano ultrafine powder is 150～240 nanometers, and the particle diameter of titanium oxide is 2～30 nanometers.
Skimmer, dispersion agent, wetting agent, flow agent and film coalescence aid are commercially available various types of rubber-emulsion paint special products in this embodiment.
Embodiment two: this embodiment and embodiment one are different is that the particle diameter of tourmaline nano ultrafine powder is 160～220 nanometers, and the particle diameter of titanium oxide is 5～25 nanometers.Other is identical with embodiment one.
Embodiment three: this embodiment and embodiment one are different is that the particle diameter of tourmaline nano ultrafine powder is 170 nanometers, and the particle diameter of titanium oxide is 10 nanometers.Other is identical with embodiment one.
Embodiment four: the preparation method of this embodiment Tomalin environmental protection rubber-emulsion paint realizes according to the following steps: one, take by weighing the tourmaline nano ultrafine powder of 10.00Kg, the titanium oxide of 23.00Kg, the water of 19.00Kg, the skimmer of 0.06Kg, the dispersion agent of 0.19Kg, the wetting agent of 0.10Kg, the Mierocrystalline cellulose of 0.30Kg, the dicalcium powder of 12.00Kg, the vinyl resin of 35.00Kg, the absolute ethyl alcohol of 2.50Kg, the flow agent of 0.05Kg and the film coalescence aid of 0.80Kg; Two, the water that takes by weighing, skimmer, dispersion agent, wetting agent and Mierocrystalline cellulose are mixed; And stir 15min with the speed of 500r/min; Add tourmaline nano ultrafine powder, titanium oxide, dicalcium powder and the vinyl resin that takes by weighing then, the speed stirring 40min with 1800r/min adds absolute ethyl alcohol, flow agent and the film coalescence aid that takes by weighing again; With static 1h behind the speed stirring 30min of 100～2000r/min, get slurry; Three, slurry is injected shredder, grind 1h with the speed of 200r/min then, promptly get the Tomalin environmental protection rubber-emulsion paint; Wherein the particle diameter of tourmaline nano ultrafine powder is 150～240 nanometers in the step 1, and the particle diameter of titanium oxide is a rice in 2～30.
Skimmer, dispersion agent, wetting agent, flow agent and film coalescence aid are commercially available various types of rubber-emulsion paint special products in this embodiment step 1.
The physical index of this embodiment gained Tomalin environmental protection rubber-emulsion paint is following:
Outward appearance: rice white, uniform liquid
Solid content:＞50%
Fineness:＜25um
Gloss: mute light
Contrast ratio:＞0.93
Theoretical area: the 12～14m that brushes
2/ kg (one time)
Alkali resistance 24h is no abnormal
Washability number of times >=500 time.
This embodiment gained Tomalin environmental protection rubber-emulsion paint is through performance test, magnetic induction B>=150mT; Can make the room negative ion concentration increase by 1000～2000/cm
3, be higher than 5 times of GB GB50325-2001 standard, and mould, intestinal bacteria, streptococcus aureus, Pseudomonas fluorescence and Bacillus subtilus had obvious bacteriostatic action.
Embodiment five: this embodiment and embodiment four are different is that the particle diameter of tourmaline nano ultrafine powder in the step 1 is 150 nanometers, and the particle diameter of titanium oxide is 2 nanometers.Other step and parameter are identical with embodiment four.
Embodiment six: this embodiment and embodiment four are different is that the particle diameter of tourmaline nano ultrafine powder in the step 1 is 240 nanometers, and the particle diameter of titanium oxide is 30 nanometers.Other step and parameter are identical with embodiment four.
Claims (6)
1. Tomalin environmental protection rubber-emulsion paint is characterized in that the Tomalin environmental protection rubber-emulsion paint processes by following proportioning:
Wherein the particle diameter of tourmaline nano ultrafine powder is 150～240 nanometers, and the particle diameter of titanium oxide is 2～30 nanometers.
2. a kind of Tomalin environmental protection rubber-emulsion paint according to claim 1, the particle diameter that it is characterized in that the tourmaline nano ultrafine powder is 160～220 nanometers, the particle diameter of titanium oxide is 5～25 nanometers.
3. a kind of Tomalin environmental protection rubber-emulsion paint according to claim 1, the particle diameter that it is characterized in that the tourmaline nano ultrafine powder is 170 nanometers, the particle diameter of titanium oxide is 10 nanometers.
4. the method for a kind of according to claim 1 Tomalin environmental protection rubber-emulsion paint of preparation is characterized in that the preparation method of Tomalin environmental protection rubber-emulsion paint realizes according to the following steps: one, take by weighing the tourmaline nano ultrafine powder of 10.00Kg, the titanium oxide of 23.00Kg, the water of 19.00Kg, the skimmer of 0.06Kg, the dispersion agent of 0.19Kg, the wetting agent of 0.10Kg, the Mierocrystalline cellulose of 0.30Kg, the dicalcium powder of 12.00Kg, the vinyl resin of 35.00Kg, the absolute ethyl alcohol of 2.50Kg, the flow agent of 0.05Kg and the film coalescence aid of 0.80Kg; Two, the water that takes by weighing, skimmer, dispersion agent, wetting agent and Mierocrystalline cellulose are mixed; And stir 15min with the speed of 500r/min; Add tourmaline nano ultrafine powder, titanium oxide, dicalcium powder and the vinyl resin that takes by weighing then, the speed stirring 40min with 1800r/min adds absolute ethyl alcohol, flow agent and the film coalescence aid that takes by weighing again; With static 1h behind the speed stirring 30min of 100～2000r/min, get slurry; Three, slurry is injected shredder, grind 1h with the speed of 200r/min then, promptly get the Tomalin environmental protection rubber-emulsion paint; Wherein the particle diameter of tourmaline nano ultrafine powder is 150～240 nanometers in the step 1, and the particle diameter of titanium oxide is 2～30 nanometers.
5. the method for a kind of Tomalin environmental protection rubber-emulsion paint of preparation according to claim 4, the particle diameter that it is characterized in that tourmaline nano ultrafine powder in the step 1 is 150 nanometers, the particle diameter of titanium oxide is 2 nanometers.
6. the method for a kind of Tomalin environmental protection rubber-emulsion paint of preparation according to claim 4, the particle diameter that it is characterized in that tourmaline nano ultrafine powder in the step 1 is 240 nanometers, the particle diameter of titanium oxide is 30 nanometers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101278603A CN101781501B (en) | 2010-03-19 | 2010-03-19 | Tourmalineline environmental protection emulsion paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101278603A CN101781501B (en) | 2010-03-19 | 2010-03-19 | Tourmalineline environmental protection emulsion paint and preparation method thereof |
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| Publication Number | Publication Date |
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| CN101781501A CN101781501A (en) | 2010-07-21 |
| CN101781501B true CN101781501B (en) | 2012-01-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2010101278603A Expired - Fee Related CN101781501B (en) | 2010-03-19 | 2010-03-19 | Tourmalineline environmental protection emulsion paint and preparation method thereof |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893470A (en) * | 2015-06-05 | 2015-09-09 | 宁波健利康生物研究科技有限公司 | Environmental-friendly coating and preparation technology thereof |
| CN105111904B (en) * | 2015-09-14 | 2018-06-26 | 刘定安 | A kind of water paint and its preparation method and application |
| CN106065290A (en) * | 2016-06-06 | 2016-11-02 | 广州市格利菲生物科技发展有限公司 | A kind of Tomalin environmental protection coating and manufacture method |
| CN106189589A (en) * | 2016-07-22 | 2016-12-07 | 蚌埠市钟钲实业有限责任公司 | A kind of food production machinery antirust paint adding tourmaline powder |
| CN109081635A (en) * | 2018-08-14 | 2018-12-25 | 贵州美诚凯辉电器制造有限公司 | A kind of environmental protection containing Tourmaline takes dim panel material and preparation method thereof |
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| CN1760289A (en) * | 2004-10-14 | 2006-04-19 | 大连振邦氟涂料股份有限公司 | Emulsion coating of negative ion and preparation method |
| CN101108923A (en) * | 2007-08-15 | 2008-01-23 | 陈锦德 | Tomalin environmental protection latex paint |
| CN101139471A (en) * | 2006-09-08 | 2008-03-12 | 青岛喜盈门集团有限公司 | Environment-friendly coating material |
| CN101348627A (en) * | 2008-09-17 | 2009-01-21 | 中国建筑材料科学研究总院 | Dust absorbing, dust removing inner wall decorative coating and preparation thereof |
| CN101486867A (en) * | 2009-02-12 | 2009-07-22 | 张文磊 | Photo-catalytic coating |
-
2010
- 2010-03-19 CN CN2010101278603A patent/CN101781501B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1760289A (en) * | 2004-10-14 | 2006-04-19 | 大连振邦氟涂料股份有限公司 | Emulsion coating of negative ion and preparation method |
| CN101139471A (en) * | 2006-09-08 | 2008-03-12 | 青岛喜盈门集团有限公司 | Environment-friendly coating material |
| CN101108923A (en) * | 2007-08-15 | 2008-01-23 | 陈锦德 | Tomalin environmental protection latex paint |
| CN101348627A (en) * | 2008-09-17 | 2009-01-21 | 中国建筑材料科学研究总院 | Dust absorbing, dust removing inner wall decorative coating and preparation thereof |
| CN101486867A (en) * | 2009-02-12 | 2009-07-22 | 张文磊 | Photo-catalytic coating |
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Granted publication date: 20120118 Termination date: 20120319 |