CN104449121A - Antibacterial anticorrosive coating - Google Patents

Antibacterial anticorrosive coating Download PDF

Info

Publication number
CN104449121A
CN104449121A CN201410609829.1A CN201410609829A CN104449121A CN 104449121 A CN104449121 A CN 104449121A CN 201410609829 A CN201410609829 A CN 201410609829A CN 104449121 A CN104449121 A CN 104449121A
Authority
CN
China
Prior art keywords
parts
minute
mentioned
add
stirring
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410609829.1A
Other languages
Chinese (zh)
Inventor
路坤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhu Xiangrong Food Co Ltd
Original Assignee
Wuhu Xiangrong Food Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhu Xiangrong Food Co Ltd filed Critical Wuhu Xiangrong Food Co Ltd
Priority to CN201410609829.1A priority Critical patent/CN104449121A/en
Publication of CN104449121A publication Critical patent/CN104449121A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses an antibacterial anticorrosive coating, which is prepared from the following raw materials in parts by weight: 0.5-1 part of trifluopicolide, 2-3 parts of flaxseed gum, 1-2 parts of nano-zinc oxide, 6-10 parts of suzhou clay, 0.1-0.2 part of butyl hydroxy anisole, 1-2 parts of diisopropyl ethanolamine, 2-3 parts of ethylene glycol dimethacrylate, 6-8 parts of titanium dioxide, 91-98 parts of a styrene-acrylic emulsion, 1-3 parts of trisnonyl phenyl phosphite, 2-3 parts of polyisobutene, 0.1-1 part of 2,6-di-t-butyl p-cresol, 130-150 parts of butyl acrylate, 170-200 parts of vinyl acetate, 0.6-2 parts of sodium metasilicate, 0.4-0.7 part of potassium sulfite, 2-3 parts of an emulsifier OP-10, 4-6 parts of a bonding assistant and 500-700 parts of deionized water. The coating disclosed by the invention has good antibacterial and anticorrosive properties, high stripping resistance, high surface resistance and good weather fastness, and does not generate the flake phenomenon in dry air or humid air.

Description

A kind of Antimicrobial preservative coating
Technical field
The present invention relates generally to paint field, particularly relates to a kind of Antimicrobial preservative coating.
Background technology
Compare with common benzene emulsion, acrylate and vinyl acetate emulsion has a lot of high-performances: 1. without APEO, formaldehydeless, health environment-friendly.2. the can opening effect that contrast ratio is high, good.3. film-forming temperature is low, suitably can add film coalescence aid less, reduces coating cost.4. paint film exquisiteness, flat smooth, good decorating effect.5. moderate, for coating producer provides best cost performance, be specially adapted to zero diopter and the half luminous environment friendly health environment protection interior wall emulsion paint of the high-quality preparing high, medium and low PVC.Along with the range of application of acrylate and vinyl acetate emulsion constantly expands, improve the performances such as its cohesiveness, surface resistive, stability further and it can be made better to adapt to the demand of modernization construction.
Summary of the invention
The object of the invention is just to provide a kind of Antimicrobial preservative coating.
The present invention is achieved by the following technical solutions:
A kind of Antimicrobial preservative coating, is characterized in that what it was made up of the raw material of following weight parts:
Three fluopicolide 0.5-1, flaxseed gum 2-3, nano zine oxide 1-2, Suzhou soil 6-10, butylated hydroxy anisole 0.1-0.2, diisopropyl ethanolamine 1-2, Ethylene glycol dimethacrylate 2-3, titanium dioxide 6-8, benzene emulsion 91-98, trisnonyl phenyl phosphite 1-3, polyisobutene 2-3,2,6-ditertbutylparacresol 0.1-1, butyl acrylate 130-150, vinyl acetate 170-200, Starso 0.6-2, potassium sulfite 0.4-0.7, emulsifier op-10 2-3, adhesive aid 4-6, deionized water 500-700;
Described adhesive aid is made up of each raw material of following weight parts:
Methyl methacrylate 4-6, Starso 1-2, calcium sulphoaluminate 3-5, trimethyl hexamethylene diisocyanate 2-3, alkylphenol polyoxyethylene 1-2, vinylformic acid ten trifluoro monooctyl ester 2-4, organosilicon crylic acid latex 30-36, deionized water 20-25;
A, join in deionized water by Starso, stir, raised temperature is 50-60 DEG C, drips alkylphenol polyoxyethylene, adds trimethyl hexamethylene diisocyanate, be stirred to normal temperature after dropwising;
B, vinylformic acid ten trifluoro monooctyl ester is joined in organosilicon crylic acid latex, add calcium sulphoaluminate after stirring, 100-200 rev/min of dispersed with stirring 5-10 minute;
By A, B mixing of materials after above-mentioned process, add methyl methacrylate after stirring, at 60-70 DEG C, stirring reaction 20-30 minute, is cooled to normal temperature, and 400-600 rev/min of dispersed with stirring 10-15 minute, obtains described adhesive aid.
2, a preparation method for Antimicrobial preservative coating as claimed in claim 1, is characterized in that comprising the following steps:
(1) Starso is mixed with potassium sulfite, join in the 10-15% of above-mentioned deionized water weight, stir, obtain initiator solution;
(2) get emulsifier op-10, add the 60-70% of residue deionized water weight, stir, add the 20-30% of above-mentioned flaxseed gum weight, be uniformly mixed 3-6 minute at 50-60 DEG C, be cooled to normal temperature, obtain pre-emulsion;
(3) the 50-60% mixing of the 50-60% of aforesaid propylene acid butyl ester weight, vinyl acetate weight is got, add above-mentioned pre-emulsion, 30-35 minute is uniformly mixed at 60-65 DEG C, raised temperature is 70-75 DEG C, add the 60-65% of above-mentioned initiator solution weight, treat that emulsion is blue phase, insulation 60-70 minute, obtains seed emulsion;
(4) by remaining butyl acrylate, vinyl acetate mixing, insulated and stirred 20-30 minute at 60-80 DEG C, is stirred to normal temperature, obtains mix monomer;
(5) get 2,6-ditertbutylparacresol, add the 10-15% of residue deionized water weight, add above-mentioned mix monomer, remaining initiator solution after stirring, insulated and stirred 10-20 minute at 50-60 DEG C, obtains treatment solution;
(6) in above-mentioned seed emulsion, drip above-mentioned treatment solution, time for adding is 90-120 minute, after dropwising, at 80-90 DEG C, is incubated 50-60 minute, cooling, filters discharging with 200-250 eye mesh screen;
(7) material above-mentioned steps (6) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described Antimicrobial preservative coating.
Advantage of the present invention is:
Coating of the present invention has good Antimicrobial preservative performance, and stripper-resistance is strong, no matter runs into dry air, or damp atmosphere, and all can not produce peeling phenomenon, surface resistive is high, good weatherability.
Embodiment
Embodiment 1
A kind of Antimicrobial preservative coating, is characterized in that what it was made up of the raw material of following weight parts:
Three fluopicolides 0.5, flaxseed gum 3, nano zine oxide 2, Suzhou soil 10, butylated hydroxy anisole 0.1, diisopropyl ethanolamine 1, Ethylene glycol dimethacrylate 3, titanium dioxide 8, benzene emulsion 98, trisnonyl phenyl phosphite 3, polyisobutene 2,2,6-ditertbutylparacresol 0.1, butyl acrylate 150, vinyl acetate 200, Starso 0.6, potassium sulfite 0.7, emulsifier op-10 2, adhesive aid 4, deionized water 500-700;
Described adhesive aid is made up of each raw material of following weight parts:
Methyl methacrylate 6, Starso 1, calcium sulphoaluminate 5, trimethyl hexamethylene diisocyanate 3, alkylphenol polyoxyethylene 2, vinylformic acid ten trifluoro monooctyl ester 4, organosilicon crylic acid latex 36, deionized water 25;
A, join in deionized water by Starso, stir, raised temperature is 60 DEG C, drips alkylphenol polyoxyethylene, adds trimethyl hexamethylene diisocyanate, be stirred to normal temperature after dropwising;
B, vinylformic acid ten trifluoro monooctyl ester is joined in organosilicon crylic acid latex, after stirring, add calcium sulphoaluminate, 200 revs/min of dispersed with stirring 10 minutes;
By A, B mixing of materials after above-mentioned process, add methyl methacrylate after stirring, at 70 DEG C, stirring reaction 30 minutes, is cooled to normal temperature, and 600 revs/min of dispersed with stirring 15 minutes, obtain described adhesive aid.
A preparation method for Antimicrobial preservative coating, is characterized in that comprising the following steps:
(1) Starso is mixed with potassium sulfite, join in 15% of above-mentioned deionized water weight, stir, obtain initiator solution;
(2) get emulsifier op-10, add 70% of residue deionized water weight, stir, be uniformly mixed 6 minutes at adding 30%, 60 DEG C of above-mentioned flaxseed gum weight, be cooled to normal temperature, obtain pre-emulsion;
(3) get 60% of aforesaid propylene acid butyl ester weight, 60% mixing of vinyl acetate weight, add above-mentioned pre-emulsion, at 65 DEG C, be uniformly mixed 35 minutes, raised temperature is 75 DEG C, adds 65% of above-mentioned initiator solution weight, treats that emulsion is blue phase, be incubated 70 minutes, obtain seed emulsion;
(4) by remaining butyl acrylate, vinyl acetate mixing, at 80 DEG C, insulated and stirred 30 minutes, is stirred to normal temperature, obtains mix monomer;
(5) get 2,6-ditertbutylparacresol, add 15% of residue deionized water weight, add above-mentioned mix monomer, remaining initiator solution after stirring, at 60 DEG C, insulated and stirred 20 minutes, obtains treatment solution;
(6) in above-mentioned seed emulsion, drip above-mentioned treatment solution, time for adding is 120 minutes, after dropwising, at 90 DEG C, be incubated 60 minutes, and cooling filters discharging with 250 eye mesh screens;
(7) material above-mentioned steps (6) obtained mixes with each raw material of residue, and 1200 revs/min of dispersed with stirring 30 minutes, obtain described Antimicrobial preservative coating.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).

Claims (2)

1. an Antimicrobial preservative coating, is characterized in that what it was made up of the raw material of following weight parts:
Three fluopicolide 0.5-1, flaxseed gum 2-3, nano zine oxide 1-2, Suzhou soil 6-10, butylated hydroxy anisole 0.1-0.2, diisopropyl ethanolamine 1-2, Ethylene glycol dimethacrylate 2-3, titanium dioxide 6-8, benzene emulsion 91-98, trisnonyl phenyl phosphite 1-3, polyisobutene 2-3,2,6-ditertbutylparacresol 0.1-1, butyl acrylate 130-150, vinyl acetate 170-200, Starso 0.6-2, potassium sulfite 0.4-0.7, emulsifier op-10 2-3, adhesive aid 4-6, deionized water 500-700;
Described adhesive aid is made up of each raw material of following weight parts:
Methyl methacrylate 4-6, Starso 1-2, calcium sulphoaluminate 3-5, trimethyl hexamethylene diisocyanate 2-3, alkylphenol polyoxyethylene 1-2, vinylformic acid ten trifluoro monooctyl ester 2-4, organosilicon crylic acid latex 30-36, deionized water 20-25;
A, join in deionized water by Starso, stir, raised temperature is 50-60 DEG C, drips alkylphenol polyoxyethylene, adds trimethyl hexamethylene diisocyanate, be stirred to normal temperature after dropwising;
B, vinylformic acid ten trifluoro monooctyl ester is joined in organosilicon crylic acid latex, add calcium sulphoaluminate after stirring, 100-200 rev/min of dispersed with stirring 5-10 minute;
By A, B mixing of materials after above-mentioned process, add methyl methacrylate after stirring, at 60-70 DEG C, stirring reaction 20-30 minute, is cooled to normal temperature, and 400-600 rev/min of dispersed with stirring 10-15 minute, obtains described adhesive aid.
2. a preparation method for Antimicrobial preservative coating as claimed in claim 1, is characterized in that comprising the following steps:
(1) Starso is mixed with potassium sulfite, join in the 10-15% of above-mentioned deionized water weight, stir, obtain initiator solution;
(2) get emulsifier op-10, add the 60-70% of residue deionized water weight, stir, add the 20-30% of above-mentioned flaxseed gum weight, be uniformly mixed 3-6 minute at 50-60 DEG C, be cooled to normal temperature, obtain pre-emulsion;
(3) the 50-60% mixing of the 50-60% of aforesaid propylene acid butyl ester weight, vinyl acetate weight is got, add above-mentioned pre-emulsion, 30-35 minute is uniformly mixed at 60-65 DEG C, raised temperature is 70-75 DEG C, add the 60-65% of above-mentioned initiator solution weight, treat that emulsion is blue phase, insulation 60-70 minute, obtains seed emulsion;
(4) by remaining butyl acrylate, vinyl acetate mixing, insulated and stirred 20-30 minute at 60-80 DEG C, is stirred to normal temperature, obtains mix monomer;
(5) get 2,6-ditertbutylparacresol, add the 10-15% of residue deionized water weight, add above-mentioned mix monomer, remaining initiator solution after stirring, insulated and stirred 10-20 minute at 50-60 DEG C, obtains treatment solution;
(6) in above-mentioned seed emulsion, drip above-mentioned treatment solution, time for adding is 90-120 minute, after dropwising, at 80-90 DEG C, is incubated 50-60 minute, cooling, filters discharging with 200-250 eye mesh screen;
(7) material above-mentioned steps (6) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described Antimicrobial preservative coating.
CN201410609829.1A 2014-11-03 2014-11-03 Antibacterial anticorrosive coating Pending CN104449121A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410609829.1A CN104449121A (en) 2014-11-03 2014-11-03 Antibacterial anticorrosive coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410609829.1A CN104449121A (en) 2014-11-03 2014-11-03 Antibacterial anticorrosive coating

Publications (1)

Publication Number Publication Date
CN104449121A true CN104449121A (en) 2015-03-25

Family

ID=52895901

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410609829.1A Pending CN104449121A (en) 2014-11-03 2014-11-03 Antibacterial anticorrosive coating

Country Status (1)

Country Link
CN (1) CN104449121A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774376A (en) * 2015-03-26 2015-07-15 安徽海纳川塑业科技有限公司 Halogen-free fire-retardation polypropylene composite material
CN104877510A (en) * 2015-05-20 2015-09-02 苏州市贝克生物科技有限公司 Anticorrosion antibacterial paint and preparation method thereof
CN104893456A (en) * 2015-05-18 2015-09-09 苏州市贝克生物科技有限公司 Medical sterilization mouldproof coating and preparation method thereof
CN104893379A (en) * 2015-05-18 2015-09-09 苏州市贝克生物科技有限公司 Medical quick-drying sterilization mouldproof coating and preparation method thereof
CN104893380A (en) * 2015-05-18 2015-09-09 苏州市贝克生物科技有限公司 Medical mould-proof coating and preparation method thereof
CN105038346A (en) * 2015-07-11 2015-11-11 安徽欧尚建材有限公司 Special antibacterial and corrosion-resistant heat insulation coating for ceramsite
CN114766317A (en) * 2022-05-06 2022-07-22 甘肃农业大学 Composition for covering soil, covering soil and preparation method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774376A (en) * 2015-03-26 2015-07-15 安徽海纳川塑业科技有限公司 Halogen-free fire-retardation polypropylene composite material
CN104893456A (en) * 2015-05-18 2015-09-09 苏州市贝克生物科技有限公司 Medical sterilization mouldproof coating and preparation method thereof
CN104893379A (en) * 2015-05-18 2015-09-09 苏州市贝克生物科技有限公司 Medical quick-drying sterilization mouldproof coating and preparation method thereof
CN104893380A (en) * 2015-05-18 2015-09-09 苏州市贝克生物科技有限公司 Medical mould-proof coating and preparation method thereof
CN104877510A (en) * 2015-05-20 2015-09-02 苏州市贝克生物科技有限公司 Anticorrosion antibacterial paint and preparation method thereof
CN105038346A (en) * 2015-07-11 2015-11-11 安徽欧尚建材有限公司 Special antibacterial and corrosion-resistant heat insulation coating for ceramsite
CN114766317A (en) * 2022-05-06 2022-07-22 甘肃农业大学 Composition for covering soil, covering soil and preparation method thereof
CN114766317B (en) * 2022-05-06 2023-05-26 甘肃农业大学 Composition for coated soil, coated soil and preparation method of coated soil

Similar Documents

Publication Publication Date Title
CN104449121A (en) Antibacterial anticorrosive coating
CN104449119A (en) Anti-aging rosin coating
CN104449118A (en) Environment-friendly reflective coating
CN104263122A (en) Stable paint
CN104231695A (en) Green antibacterial coating for interior wall
CN104449120A (en) Environment-friendly impermeable coating
CN104263036A (en) Bactericidal organic silicon coating
CN104250504A (en) High-viscosity silicone-acrylic paint
CN104449182A (en) Dirt-resistant anti-doodling coating
CN104263127A (en) Insulating crack-resistant coating for exterior wall
CN104277619A (en) Hydrophobic self-cleaning paint
CN104109408A (en) Building roof waterproof coating
CN104277620A (en) Environment-friendly wall coating
CN104263128A (en) Resin-base paint
CN104449115A (en) Flexible fluorinated coating
CN104449117A (en) Elastic coating for exterior wall decoration
CN104231692A (en) Composite organic silicon coating
CN104403446A (en) Heatproof and fireproof paint
CN104277621A (en) Waterproof coating for building
CN104449114A (en) Nano-polymer waterproof coating
CN104250506A (en) Yellowing-resistant paint
CN104312358A (en) Functional interior wall coating material
CN104263029A (en) Anti-cracking and waterproof coating for wall body
CN104449116A (en) Mixed resin-based high-adhesion coating
CN104263138A (en) Soft antibacterial coating

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150325